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Frontiers of Chemical science and Engineering 2024年第9期18卷 25-36页

作者： Fan Zhang Yanzhu Guo Xianhong Wu Ce Gao Qingda An Zhongjian Tian Runcang Sun key laboratory of pulp and paper science&technology of ministry of education Qilu University of TechnologyShandong Academy of SciencesJinan 250353China The Liaoning Province key laboratory of paper and pulp Engineering The Dalian Key Laboratory of High Value Application and Development of Botanical ResourcesThe Key Laboratory of High Value Utilization of Botanical Resources of China Light IndustryDalian Polytechnic UniversityDalian 116034China

A novel carboxylated lactose/sodium lignosulfonate/polyacrylic acid hydrogel composites with self-reduction capacity was successfully synthesized by self-assembly *** hydrogel with well-developed porous structure provided abundant anchoring points and reduction capacity for transforming Ag^(+)into silver *** nanoparticles dispersed among the network of hydrogel and the composites exhibited catalytic *** catalytic performance was evaluated via degradation of p-nitrophenol,rhodamine B,methyl orange and methylene blue,which were catalyzed with corresponding reaction rate constants of 0.04338,0.07499,0.04891,and 0.00628 s^(–1),*** addition,the catalyst exhibited stable performance under fixed-bed condition and the corresponding conversion rate still maintained more than 80%after 540 ***,the catalytic performance still maintained effective in tap water and simulated *** catalytic efficiency still remained 99.7%with no significant decrease after 8 cycles.

关键词： carboxylated lactose Ag NPs self-reduction nitrogenous wastewater

Flexible, thermal processable, self-healing, and fully bio-based starch plastics by constructing dynamic imine network

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Green Energy & Environment 2024年第10期9卷 1610-1618页

作者： Xiaoqian Zhang Haishan Zhang Guowen Zhou Zhiping Su Xiaohui Wang State key laboratory of pulp and paper Engineering South China University of Technology

The serious environmental threat caused by petroleum-based plastics has spurred more researches in developing substitutes from renewable *** is desirable for fabricating bioplastic due to its abundance and renewable ***,limitations such as brittleness,hydrophilicity,and thermal properties restrict its widespread *** overcome these issues,covalent adaptable network was constructed to fabricate a fully bio-based starch plastic with multiple advantages via Schiff base *** strategy endowed starch plastic with excellent thermal processability,as evidenced by a low glass transition temperature （Tg=20.15℃）.Through introducing Priamine with long carbon chains,the starch plastic demonstrated superior flexibility （elongation at break=45.2%） and waterproof capability （water contact angle=109.2°）.Besides,it possessed a good thermal stability and self-adaptability,as well as solvent resistance and chemical *** work provides a promising method to fabricate fully bio-based plastics as alternative to petroleum-based plastics.

关键词： Bioplastic Covalent adaptable networks Schiff base chemistry Thermal processability Self-healing

Optimizing hemicelluloses pre-extraction in eucalyptus kraft pulping:A pathway towards enhancing pulp mill biorefineries

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Chinese Journal of Chemical Engineering 2024年第6期70卷 162-172页

作者： Yuhan Wang Danqi Xue Jingjing Zhuo Zhouyang Xiang State key laboratory of pulp and paper Engineering South China University of TechnologyGuangzhou 510640China

A critical pathway towards enhancing pulp mill biorefineries is to integrate the extraction and utilization of hemicelluloses into the pulping ***,an industrial pre-extraction strategy for hemicelluloses targeting eucalyptus kraft pulping process was *** solution or pulping white liquor was used to pre-extract hemicelluloses before the actual pulping *** response surface methodology(RSM)technique was applied to investigate the most suitable conditions to maximize the yield of these hemicelluloses while simultaneously minimizing the damage to pulp yields and ***(105 to 155℃),alkali concentration(3%to 8%),sulfidity(20%to 30%)and retention time(19 to 221 min)were combined to evaluate their effects on hemicellulose yields and chemical *** optimal pre-extraction conditions identified in this work(5.75%NaOH concentration,25%sulfidity at 135℃for 60 min)successfully allowed recovering 4.8%of hemicelluloses(based on the wood dry mass)and limited damages to pulp yields and *** cellulose content in pulp can even be increased by about 10%.Hemicellulose emulsification properties were also evaluated,which were comparable to synthetic *** study provides an industrial pathway to effectively separate and utilize wood hemicelluloses from the pulping process,which has the potential to improve the economy and material utilization of pulp and paper mills.

关键词： Hemicelluloses Xylan Pre-extraction Kraft pulping Emulsifying Response surface methodology(RSM)

A highly sensitive fluorescent probe RN-NA reveals peroxynitrite as a novel biomarker for primary open angle glaucoma

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International Journal of Ophthalmology(English edition) 2024年第2期17卷 219-227页

作者： Bo Qin Yuan Lei Luo Bao You-Jia Zhang Ke-Yin Liu Yu-Hong Chen Department of Ophthalmology&Visual science Eye&ENT HospitalShanghai Medical CollegeFudan UniversityShanghai 200031China key laboratory of Myopia NHFPC(Fudan University)Shanghai Key Laboratory of Visual Impairment and Restoration(Fudan University)Shanghai 200031China State key laboratory of Biobased Material and Green papermaking Key Laboratory of Pulp&Paper Science and Technology of Shandong Province/Ministry of EducationQilu University of TechnologyShandong Academy of SciencesJinan 250353Shandong ProvinceChina

AIM:To directly quantify peroxynitrite(ONOO-)using a highly sensitive fluorescence resonance energy transfer probe RN-NA,investigate the association between ONOOand primary open angle glaucoma(POAG),and clarify whether RN-NA could be used as a potential tool for POAG ***:Plasma and aqueous humor(AH)samples were collected from POAG patients(n=100,age:59.70±6.87y)and age-related cataract(ARC)patients(n=100,age:61.15±4.60y)admitted to our ***,RN-NA was used to detect ONOO-in plasma and AH samples,and the relationship between ONOO-level and POAG was analyzed using binary logistic ***,Pearson correlation analysis was applied to characterize the correlation of the levels of ONOO-with the patients’age,intraocular pressure(IOP),and mean deviation of visual field *** ONOO-scavenger MnTMPyP was employed to treat the 3-morpholinosyndnomine(SIN-1)-induced ocular hypertension in mice(n=7,6-8wk).Finally,the IOP and ONOO-in both eyes were measured 30min after the last drug ***:ONOO-levels of AH and plasma were significantly higher in the POAG group than in the ARC group(P<0.01).Additionally,ONOO-levels were closely correlated with POAG in a binary logistic regression analysis[odds ratio(OR)=1.008,95%confidence interval(CI):1.002-1.013,P<0.01 for AH;OR=1.004,95%CI:1.002-1.006,P<0.001 for plasma].Pearson correlation analysis showed that ONOO-levels in AH or plasma were positively associated with visual field defects(R=0.51,P<0.01 for AH;R=0.45,P<0.001 for plasma),and ONOO-levels in plasma and AH were correlated in the POAG group(R=0.69,P<0.001).However,administering MnTMPyP to mouse eyes reversed the elevated IOP caused by SIN-1(P<0.05).CONCLUSION:ONOO-levels in AH and plasma,detected by RN-NA,are significantly related to POAG and positively correlated with visual field defects in POAG ***,ONOO-is a potential biomarker of POAG,especially advanced ***,anti-nitration compounds may be novel ocular hypotens

关键词： peroxynitrite fluorescent probe RN-NA primary open angle glaucoma 3-morpholinosyndnomine

Nickel-catalyzed arylcyanation of alkenes via cyano group translocation:access to 1,n-dinitriles or 4-amino nitriles

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science China Chemistry 2024年第9期67卷 2975-2981页

作者： Xiaohong Li Shenfan Wang Xiangxiang Fu Donghui Xing Zeyuan Fu Yuanfu Deng Huanfeng Jiang Liangbin Huang State key laboratory of pulp and paper Engineering School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China

Herein,a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been *** transformations provided a robust approach to constructing structurally diverse 1,n-dinitriles or 4-amino nitriles from easily prepared and commercially available starting *** cyano group translocation was achieved,involving the addition into the intramolecular C–N triple bond followed by the retro-Thorpe *** studies revealed that high temperature and CsHCO_(3) as the base were crucial for the cyano group translocation.

关键词： arylcyanation nickel catalysis cyano group translocation 1 n-dinitriles 4-amino nitriles

Distributed Optimal Variational GNE Seeking in Merely Monotone Games

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IEEE/CAA Journal of Automatica Sinica 2024年第7期11卷 1621-1630页

作者： Wangli He Yanzhen Wang IEEE the key laboratory of Smart Manufacturing in Energy Chemical Process Ministry of EducationEast China University of Science and TechnologyShanghai 200237China

In this paper, the optimal variational generalized Nash equilibrium(v-GNE) seeking problem in merely monotone games with linearly coupled cost functions is investigated, in which the feasible strategy domain of each agent is coupled through an affine constraint. A distributed algorithm based on the hybrid steepest descent method is first proposed to seek the optimal v-GNE. Then, an accelerated algorithm with relaxation is proposed and analyzed, which has the potential to further improve the convergence speed to the optimal v-GNE. Some sufficient conditions in both algorithms are obtained to ensure the global convergence towards the optimal v-GNE. To illustrate the performance of the algorithms, numerical simulation is conducted based on a networked Nash-Cournot game with bounded market capacities.

关键词： Distributed algorithms equilibria selection generalized Nash equilibrium(GNE) merely monotone games

Synergistic effects and kinetics analysis for co-pyrolysis of vacuum residue and plastics

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Frontiers of Chemical science and Engineering 2024年第5期18卷 71-81页

作者： Chao Wang Xiaogang Shi Aijun Duan Xingying Lan Jinsen Gao Qingang Xiong State key laboratory of Heavy Oil Processing China University of Petroleum-BeijingBeijing 102249China State key laboratory of pulp and paper Engineering South China University of TechnologyGuangzhou 510640China

This study utilizedathermogravimetric analyzer to assess the thermal decomposition behaviors and kinetics properties of vacuum residue(VR)and low-density polyethylene(LDPE)*** kinetic parameters were calculated using the Friedman *** demonstrate the interactive effects between LDPE and VR during the co-pyrolysis process,the disparity in mass loss and mass loss rate between the experimental and calculated values was *** co-pyrolysis curves obtained through estimation and experimentation exhibited significantdeviations,whichwerei influencedby temperature and mixing ratio.A negative synergistic interaction was observed between LDPE and VR,although this inhibitory effect could be mitigated or eliminated by reducing the LDPE ratio in the mixture and increasing the ***-pyrolysisprocess resulted in a reduction in carbon residue,which could be attributed to the interaction between LDPE and the heavy fractions,particularly resin and asphaltene,present in *** findings align with the pyrolysis behaviors exhibited by the four VR ***,it was observed that the co-pyrolysis process exhibited lower activation energy as the VR ratio increased,indicating a continuous enhancement in the reactivity of the mixed samples during co-pyrolysis.

关键词： co-pyrolysis heavy residual oil polyethylene thermogravimetric analysis synergistic effects

Data-driven Wasserstein distributionally robust chance-constrained optimization for crude oil scheduling under uncertainty

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Chinese Journal of Chemical Engineering 2024年第5期69卷 152-166页

作者： Xin Dai Liang Zhao Renchu He Wenli Du Weimin Zhong Zhi Li Feng Qian key laboratory of Smart Manufacturing in Energy Chemical Process Ministry of EducationEast China University of Science and TechnologyShanghai 200237China Engineering Research Center of Process System Engineering Ministry of EducationEast China University of Science and TechnologyShanghai 200237China

Crude oil scheduling optimization is an effective method to enhance the economic benefits of oil *** uncertainties,including uncertain demands of crude distillation units(CDUs),might make the production plans made by the traditional deterministic optimization models infeasible.A data-driven Wasserstein distributionally robust chance-constrained(WDRCC)optimization approach is proposed in this paper to deal with demand uncertainty in crude oil ***,a new deterministic crude oil scheduling optimization model is developed as the basis of this *** Wasserstein distance is then used to build ambiguity sets from historical data to describe the possible realizations of probability distributions of uncertain demands.A cross-validation method is advanced to choose suitable radii for these ambiguity *** deterministic model is reformulated as a WDRCC optimization model for crude oil scheduling to guarantee the demand constraints hold with a desired high probability even in the worst situation in ambiguity *** proposed WDRCC model is transferred into an equivalent conditional value-at-risk representation and further derived as a mixed-integer nonlinear programming *** case studies from a real-world refinery are conducted to show the effectiveness of the proposed ***-of-sample tests demonstrate that the solution of the WDRCC model is more robust than those of the deterministic model and the chance-constrained model.

关键词： Distributions Model Optimization Crude oil scheduling Wasserstein distance Distributionally robust chance constraints

EmotionIC: emotional inertia and contagion-driven dependency modeling for emotion recognition in conversation

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science China(Information sciences) 2024年第8期67卷 130-146页

作者： Yingjian LIU Jiang LI Xiaoping WANG Zhigang ZENG School of Artificial Intelligence and Automation Huazhong University of Science and Technology Hubei key laboratory of Brain-inspired Intelligent Systems Huazhong University of Science and Technology key laboratory of Image Processing and Intelligent Control (Huazhong University of science and technology) Ministry of Education Institute of Artificial Intelligence Huazhong University of Science and Technology

Emotion recognition in conversation(ERC) has attracted growing attention in recent years as a result of the advancement and implementation of human-computer interface technologies. In this paper,we propose an emotional inertia and contagion-driven dependency modeling approach(EmotionIC) for ERC tasks. Our EmotionIC consists of three main components, i.e., identity masked multi-head attention(IMMHA), dialogue-based gated recurrent unit(DiaGRU), and skip-chain conditional random field(SkipCRF).Compared to previous ERC models, EmotionIC can model a conversation more thoroughly at both the feature-extraction and classification levels. The proposed model attempts to integrate the advantages of attention-and recurrence-based methods at the feature-extraction level. Specifically, IMMHA is applied to capture identity-based global contextual dependencies, while Dia GRU is utilized to extract speaker-and temporal-aware local contextual information. At the classification level, SkipCRF can explicitly mine complex emotional flows from higher-order neighboring utterances in the conversation. Experimental results show that our method can significantly outperform the state-of-the-art models on four benchmark *** ablation studies confirm that our modules can effectively model emotional inertia and contagion.

关键词： emotion recognition in conversation emotional inertia and contagion multi-head attention gated recurrent unit conditional random field

Simultaneous enhancement of energy storage performance and thermal stability of NaNbO_(3)-based ceramics via multi-scale modulation

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Journal of Materiomics 2024年第3期10卷 670-681页

作者： Peng Nong Dafu Zeng Yue Pan Qinpeng Dong Mingzhao Xu Xiang Wang Jiaming Wang Huanfu Zhou Xu Li Xiuli Chen key laboratory of Nonferrous Materials and New Processing technology Ministry of EducationSchool of Materials Science and EngineeringGuilin University of TechnologyGuilin541004China

More and more attention is being paid to the environmental friendliness of the dielectric capacitors,which have a rapid charging and discharging speed and steady ***,the low recoverable energy storage density(W_(rec))limits the practical application of dielectric capacitors in solid-state energy storage *** this paper,(1-x)(0.92NaNbO_(3)-0.08Bi(Mg_(0.5)Ti_(0.5)O_(3))-xSrTiO_(3))(x=0.05,0.10,0.15,0.20)energy storage ceramics were fabricated based on various strategies such as nanodomain engineering,component and grain size *** excellent energy storage performance(W_(rec)~6.0 J/cm^(3),η~81.0%)was obtained in ***_(3)could enhance the internal disorder,improve the relaxation properties and increase the breakdown field strength of ***-cantly domain relaxor behavior,as evidenced by Vogel-Fulcher(V-F)model,provides strong evidence for restraining early polarization *** addition,Pulse charge/discharge tests have illustrated that the sample has excellent and stable charge/discharge performance(CD~1,068.9 A/cm^(2),PD~96.1 MW/cm^(3),t0.9 z 0.99 ms)It is concluded that there is a huge prospect of NN-BMT-0.15ST ceramics as a kind of pulsed-power-storing electronics.

关键词： NaNbO_(3) Breakdown field strength Lead-free ceramics Energy storage Power density