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Self-adaptive gas flow and phase change behaviors during hydrate exploitation by alternate injection of N2 and CO_(2)

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petroleum Science 2024年第3期21卷 2120-2129页

作者： Bo-Jian Cao Yi-Fei Sun Hong-Nan Chen Jin-Rong Zhong Ming-Long Wang Ming Wang Chang-Yu Sun Guang-Jin Chen State key laboratory of Heavy Oil Processing China University of PetroleumBeijing102249China School of Chemistry and Chemical Engineering Changsha University of Science&TechnologyChangsha410114HunanChina

Since hydrate resources play a part of the stratigraphic framework structure in sediments,establishing a safe and economic method for hydrates exploitation remains the primary challenge to this *** the proposed methods,the spontaneous displacement of CH_(4) from hydrate cages by CO_(2) seems to be a perfect mechanism to address gas production and CO_(2) storage,especially in today's strong demand for carbon reduction and replacing clean *** extensive lab researches,in the past decade,injecting a mixture of CO_(2) and small molecule gas has become a key means to enhance displacement efficiency and has great potential for ***,there is a lack of in-depth research on gas flow in the reservoir,while the injected gas always passes through low-saturated hydrate areas with high permeability and then occurs gas channel in a short term,finally resulting in the decreases in gas production efficiency and produced gas ***,we explored a new injection-production mode of alternate injection of N2 and CO_(2) in order to fully coordinate the advantages of N2 in enhanced hydrate decomposition and CO_(2) in solid storage and heat *** alternate"taking"and"storing"processes perfectly repair the problem of the gas channel,achieving self-regulation effect of CH_(4) recovery and CO_(2) *** 3-D experimental results show that compared to the mixed gas injection,CH_(4) recovery is increased by>50%and CO_(2) storage is increased by>70%.Additionally,this alternate injection mode presented a better performance in CH_(4) concentration of produced gas and showed outstanding N2 utilization ***,we analyzed its self-adaptive gas flow mechanism and proposed an application model of"one injection and multiple production".We look forward to this study accelerating the application of CO_(2)-CH_(4) replacement technology.

关键词： Hydrate Replacement CH_(4) recovery CO_(2)storage Reservoir remediation

Differences and identification on multi-time hydrocarbon generation of carboniferous-permian coaly source rocks in the Huanghua Depression,Bohai Bay Basin

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petroleum Science 2024年第2期21卷 765-776页

作者： Jin-Jun Xu Xian-Gang Cheng Shu-Nan Peng Jun-Cai Jiang Qi-Long Wu Da Lou Fu-Qi Cheng La-Mei Lin National key laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao 266580ShandongChina PetroChina Dagang Oilfield Company Tianjin300280China

Coal is a solid combustible mineral,and coal-bearing strata have important hydrocarbon generation potential and contribute to more than 12%of the global hydrocarbon ***,the deposition and hydrocarbon evolution process of ancient coal-bearing strata is characterized by multiple geological times,leading to obvious distinctions in their hydrocarbon generation potential,geological processes,and production,which affect the evaluation and exploration of hydrocarbon resources derived from coaly source rocks *** study aimed to identify the differences on oil-generated parent macerals and the production of oil generated from different coaly source rocks and through different oil generation *** with the analysis of previous tectonic burial history and hydrocarbon generation history,high-temperature and high-pressure thermal simulation experiments,organic geochemistry,and organic petrology were performed on the Carboniferous-Permian(C-P)coaly source rocks in the Huanghua Depression,Bohai Bay *** oil-generated parent macerals of coal's secondary oil generation process(SOGP)were mainly hydrogen-rich collotelinite,collodetrinite,sporinite,and cutinite,while the oil-generated parent macerals of tertiary oil generation process(TOGP)were the remaining small amount of hydrogen-rich collotelinite,sporinite,and cutinite,as well as dispersed soluble organic matter and unexhausted residual *** with coal,the oil-generated parent macerals of coaly shale SOGP were mostly sporinite and *** part of hydrogen-poor vitrinite,lacking hydrocarbon-rich macerals,and macerals of the TOGP,in addition to some remaining cutinite and a small amount of crude oil and bitumen from SOGP contributed to the oil *** results indicated that the changes in oil yield had a good junction between SOGP and TOGP,both coal and coaly shale had higher SOGP aborted oil yield than TOGP starting yield,and coaly shale TOGP peak oil yield was low

关键词： Thermal simulation Multi-time oil generation processes Coaly source rock Carboniferous-permian Huanghua Depression

Preparation and performance evaluation of the slickwater using novel polymeric drag reducing agent with high temperature and shear resistance ability

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petroleum Science 2024年第2期21卷 1113-1121页

作者： Ming-Wei Zhao Zhen-Feng Ma Cai-Li Dai WeiWu Yong-Quan Sun Xu-Guang Song Yun-Long Cheng Xiang-Yu Wang National key laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580ShandongChina Shandong key laboratory of Oilfield Chemistry China University of Petroleum(East China)Qingdao266580ShandongChina Sinopec Shengli Oilfield Dongying257001ShandongChina Department of Chemical and Materials Engineering University of AlbertaEdmontonAB T6G 1H9Canada East China petroleum Bureau of Sinopec Nanjing210011JiangsuChina

Slickwater fracturing fluids are widely used in the development of unconventional oil and gas resources due to the advantages of low cost,low formation damage and high drag reduction ***,their performance is severely affected at high *** reducing agent is the key to determine the drag reducing performance of *** this work,in order to further improve the temperature resistance of slickwater,a temperature-resistant polymeric drag reducing agent(PDRA)was synthesized and used as the basis for preparing the temperature-resistant *** slickwater system was prepared with the compositions of 0.2 wt%PDRA,0.05 wt%drainage aid nonylphenol polyoxyethylene ether phosphate(NPEP)and 0.5 wt%anti-expansion agent polyepichlorohydrindimethylamine(PDM).The drag reduction ability,rheology properties,temperature and shear resistance ability,and core damage property of slickwater were systematically studied and *** contrast to on-site drag reducing agent(DRA)and HPAM,the temperature-resistant slickwater demonstrates enhanced drag reduction efficacy at 90℃,exhibiting superior temperature and shear resistance ***,the drag reduction retention rate for the slickwater achieved an impressive 90.52%after a 30-min shearing ***,the core damage is only 5.53%.We expect that this study can broaden the application of slickwater in high-temperature reservoirs and provide a theoretical basis for field applications.

关键词： Unconventional resources Polymeric drag reducing agent Slickwater High drag reduction rate Temperature resistance

Fractal Characteristics and Main Controlling Factors of High-Quality Tight Sandstone Reservoirs in the Southeastern Ordos Basin

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Journal of Earth Science 2024年第2期35卷 631-641页

作者： Ruilin Hao Wenhui Huang Jiu Bo Li Yuan key laboratory for Marine Reservoir Evolution and Hydrocarbon Abundance Mechanism School of Energy ResourcesChina University of GeosciencesMinistry of EducationBeijing100083China

Due to the complex conditions and strong heterogeneity of tight sandstone reservoirs,the reservoirs should be classified and the controlling factors of physical properties should be *** thin section observations,cathodoluminescence,scanning electron microscopy(SEM),X-ray diffraction(XRD),and high-pressure mercury injection(HPMI)were used to classify and optimize the *** Brooks-Corey model and stepwise regression were used to study the fractal dimension and main controlling factors of the physical properties of the high-quality *** results show that the reservoirs in the study area can be divided into four types,and the high-quality reservoir has the best physical properties and pore-throat *** the high-quality reservoir,the homogeneity of transitional pores was the best,followed by that of micropores,and the worst was *** porosity was controlled by depth and *** model with standardized coefficients is y=12.454−0.778×(Depth)+0.395×(Kaolinite).The permeability was controlled by depth,illite/montmorillonite,and siliceous cement,and the model with standardized coefficients is y=1.689−0.683×(Depth)−0.395×(Illite/Montmorillonite)−0.337×(Siliceous Cement).The pore-throat evolutionary model shows that the early-middle diagenetic period was when the reservoir physical properties were at their best,and the kaolinite intercrystalline pores and residual intergranular pores were the most important.

关键词： fractal dimension main controlling factors stepwise regression high-quality tight sandstone reservoir Ordos Basin petroleum geolgoy

Wavefield Separation of Distributed Acoustic Sensing Vertical Seismic Profile Data Based on Multichannel Vector Median Filtering

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Journal of Earth Science 2024年第2期35卷 712-716页

作者： Zijuan Ma Jun Lu Feng Zhang Pinbo Ding Zhidong Cai key laboratory of Intraplate Volcanoes and Earthquakes Ministry of EducationChina University of GeosciencesBeijing 100083China College of Geophysics China University of PetroleumBeijing 102249China New resources Geophysical Exploration Division BGP Inc.CNPCZhuozhouHebei 072751China

INTRODUCTION Distributed acoustic sensing(DAS)is a novel and popular technology for vertical seismic profile(VSP)data acquisition because of its many advantages,including full vertical coverage,high sampling density,low cost,and resistance to stressors(high temperature and pressure).The current industrial application of DAS in borehole exploration acquires single-mode *** records strain rates,which are then converted to particle velocities by the modem before being written to the disk.

关键词： Seismic Vertical borehole

Intricate Fault Systems in Longmenshan Structural Belt's Northern End: Exploring Structural Evolution and Seismic Rupture Behavior in the Eastern Tibetan Plateau

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Journal of Earth Science 2024年

作者： Hanyu Huang Renqi Lu Dengfa He Jinliang Gao Weikang Zhang Lingyu Kang State key laboratory of Earthquake Dynamics Institute of Geology China Earthquake Administration State key laboratory of Oil and Gas Reservoir Geology and Exploitation Institute of Sedimentary Geology Chengdu University of Technology College of Energy resources China University of Geosciences PetroChina Research Institute of petroleum Exploration and Development

The Longmenshan Structural Belt on the eastern edge of the Tibetan Plateau experienced the impactful Mw 7.9 2008 Wenchuan earthquake， causing a 350 km surface rupture. Traditional models attribute this to the Beichuan and Pengguan faults， but our research reveals a complex fault system at the northern end， with inconsistencies in surface rupture， aftershock distribution， and focal mechanisms. We integrates shallow geology， active source seismic reflection， and magnetotelluric profiling to establish a deep structural model for the northern end of the Longmenshan Structural Belt. This area exhibits dominant reverse thrust nappe tectonics， and analyzing the tectonic evolution history provides insights into deformation propagation from the orogenic belt toward the Sichuan Basin. Focal mechanism analysis and relocated aftershock data reveals two distinct types of seismogenic structures in the northern end of the Longmenshan Structural Belt. In the middle to northern segments， the reverse fault type is attributed to reactivated pre-existing faults. Conversely， at the northern end， the strike-slip fault type originates from high-angle co-seismic rupture cutting through pre-existing reverse faults. This study enhances our understanding of fault complexity and seismic mechanisms in the northeastern Longmenshan Structural Belt， providing new insights into regional tectonics.

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Numerical study on local scour characteristics around submarine pipelines in the Yellow River Delta silty sandy soil under waves and currents

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Deep Underground Science and Engineering 2024年第2期3卷 182-196页

作者： Peng Yu Ruigeng Hu Jike Zhang Qi Yang Jieru Zhao Lei Cao Chenghao Zhu key laboratory of Geological Safety of Coastal Urban Underground Space Ministry of Natural ResourcesQingdaoChina Qingdao Geo-Engineering Surveying Institute(Qingdao Geological Exploration Development Bureau) QingdaoChina Sinopec petroleum Engineering Corporation DongyingChina State key laboratory of Hydroscience and Engineering Tsinghua UniversityBeijingChina Department Civil and Environmental Engineering Politecnico di MilanoMilanItaly College of Environmental Science and Engineering Ocean University of ChinaQingdaoChina

Due to their high reliability and cost-efficiency,submarine pipelines are widely used in offshore oil and gas resource *** to the interaction of waves,currents,seabed,and pipeline structures,the soil around submarine pipelines is prone to local scour,severely affecting their operational *** the Yellow River Delta as the research area and based on the renormalized group(RNG)k-εturbulence model and Stokes fifth-order wave theory,this study solves the Navier-Stokes(N-S)equation using the finite difference *** volume of fluid(VOF)method is used to describe the fluid-free surface,and a threedimensional numerical model of currents and waves-submarine pipeline-silty sandy seabed is *** rationality of the numerical model is verified using a self-built waveflow *** this basis,in this study,the local scour development and characteristics of submarine pipelines in the Yellow River Delta silty sandy seabed in the prototype environment are explored and the influence of the presence of pipelines on hydrodynamic features such as surrounding flow field,shear stress,and turbulence intensity is *** results indicate that(1)local scour around submarine pipelines can be divided into three stages:rapid scour,slow scour,and stable *** maximum scour depth occurs directly below the pipeline,and the shape of the scour pits is asymmetric.(2)As the water depth decreases and the pipeline suspension height increases,the scour becomes more intense.(3)When currents go through a pipeline,a clear stagnation point is formed in front of the pipeline,and the flow velocity is positively correlated with the depth of *** study can provide a valuable reference for the protection of submarine pipelines in this area.

关键词： local scour numerical simulation submarine pipelines Yellow River Delta

Cretaceous integrative stratigraphy,biotas,and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年第4期67卷 1229-1289页

作者： Dangpeng XI Guobiao LI Shijun JIANG Xin RAO Tian JIANG Tianyang WANG Zuohuan QIN Yasu WANG Jianzhong JIA Muhammad KAMRAN Zhongye SHI Yuyang WU Panxi WANG Lixin SUN Qinggao ZENG Xiaoqiao WAN State key laboratory of Biogeology and Environmental Geology China University of GeosciencesBeijing 100083China College of Oceanography Hohai UniversityNanjing 213200China key laboratory of Palaeobiology and petroleum Stratigraphy Nanjing Institute of Geology and PaleontologyChinese Academy of SciencesNanjing 210008China State key laboratory of Tibetan Plateau Earth System Environmentand Resources(TPESER)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China China National Offshore Oil Corporation Limited Beijing 100028China Shanghai Science and Technology Museum Shanghai 200120China Xizang Bureau of Geological and Mineral Exploration and Development Lhasa 850000China Tianjin Geological Survey Center of China Geological Survey Tianjin 300170China

The Cretaceous Period is a vital time interval in deciphering the evolutionary history of the Neo-Tethys Ocean and the convergence of different plates and blocks across the Qinghai-Tibetan Plateau.A detailed stratigraphic framework and paleogeographic patterns are the basis for understanding the evolution of the Neo-Tethys Ocean and the formation of the QinghaiTibetan ***,the Cretaceous stratigraphy,biota,paleogeography,and major geological events in the Qinghai-Tibetan Plateau are analyzed to establish an integrative stratigraphic framework,reconstruct the paleogeography during the Cretaceous Period,and decode the history of the major geological *** Cretaceous rocks of the Qinghai-Tibetan Plateau and its surrounding area are predominantly marine deposits,with a small amount of interbedded marine-terrestrial and terrestrial *** Indus-Yarlung Tsangpo Suture Zone was responsible for the deposition of deep marine sediments dominated by ophiolite suites and radiolarian *** the south,the Tethys Himalayas and Indus Basin received marine sediments of varying depths and lithology;to the north,the Xigaze and Ladakh forearc basins are also filled with marine *** Lhasa Block,Karakorum Block,western Tarim Basin,and West Burma block consist of shallow marine,interbedded marine-terrestrial,and terrestrial *** Qiangtang Basin and other areas are dominated by terrestrial *** Cretaceous strata of the Qinghai-Tibetan Plateau and its surrounding areas are widely distributed and diversified,with abundant foraminifera,calcareous nannofossils,radiolarians,ammonites,bivalves,and *** the basis of integrated lithostratigraphic,biostratigraphic,geochronologic,and chemostratigraphic analyses,we proposed herein a comprehensive stratigraphic framework for the Cretaceous Period of the eastern *** analyzing the Cretaceous biota of different biogeographic zones from eastern Neo-Tethys and its surrounding a

关键词： Qinghai-Tibetan Plateau Tethys Cretaceous Stratigraphy Biota Paleogeography

Surface ozone in global cities:A synthesis of basic features,exposure risk,and leading meteorological driving factors

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Geography and Sustainability 2024年第1期5卷 64-76页

作者： Jinmian Ni Jiming Jin Yanwen Wang Bin Li Qian Wu Yanfei Chen Shenwen Du Yilin Li Chao He College of resources and Environment Yangtze UniversityWuhan 430100China Hubei key laboratory of petroleum Geochemistry and Environment Yangtze UniversityWuhan 430100China School of Resource and Environmental Science Wuhan UniversityWuhan 430079China Economics and Management College China University of GeosciencesWuhan 430074China

Long-term exposure to high surface ozone(O_(3))concentrations,a complex oxidative atmospheric pollutant,can adversely impact human *** on O_(3)monitoring data from 261 cities worldwide in 2020,generalized additive model(GAM)and spatial data analysis(SDA)methods were applied in this study to quantitatively evaluate the spatiotemporal distribution of O_(3)concentration,exposure risk,and dominant meteorological *** indicated that over 40%of the cities worldwide were exposed to harmful O_(3)concentration ranges(40-60μg/m^(3)),with most cities distributed in China and ***,significant seasonal variations in global O_(3)concentrations were observed,presenting as summer(45.6μg/m^(3))>spring(47.3μg/m^(3))>autumn(38.0μg/m^(3))>winter(33.6μg/m^(3)).Exposure analysis revealed that approximately 12.2%of the population in 261 cities were exposed to an environment with high O_(3)concentrations(80-160μg/m^(3)),with about 36.32 million people in major ***,the persistent increase in high O_(3)levels worldwide is a critical factor contributing to threats to human ***,GAM results indicated temperature,relative humidity,and wind speed as primary determinants of O_(3)*** synergy of meteorological factors is critical for understanding O_(3)*** findings are important for enforcing robust air quality policies and mitigating public risk.

关键词： Ozone pollution Spatiotemporal variation Exposure risk GAM Meteorological factors