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Effect of quaternary basicity on reduction behavior of iron-bearing dust pellets

Journal of Iron and Steel Research(International) 2023年第7期30卷 1356-1366页

作者： Tao Yang Jing-shu An Xing-wang Li Shuang Liu Xu Gao Lei Ma Jie Lei Hong-ming Long School of metallurgical Engineering Anhui University of TechnologyMa’anshan 243032AnhuiChina key laboratory of metallurgical emission reduction&resources recycling(Anhui University of Technology) Ministry of EducationMa’anshan 243002AnhuiChina

The treatment of iron-bearing dusts and sludges by the rotary hearth furnace process has the advantage of sufficient utilization of valuable metals and a high impurity removal rate,but the lower strength of the metallized product needs to be addressed.The effects of quaternary basicity R4(w(CaO+MgO)/w(SiO_(2)+Al_(2)O_(3)))on the reduction behavior and physical and chemical properties of metallized pellets,including phase composition,compressive strength,microstructure and soft melting area,were investigated with FactSage thermodynamic software and experiments.The strength of metallized pellets depended on the gangue composition,such as CaO,MgO,Al_(2)O_(3) and SiO_(2),due to the altered chemical composition,physical phase composition,microscopic morphology and stability of the slag phase.The reduction of carbon-bearing pellets was significantly promoted by suitable basicity.The lower basicity(R_(4)1.8)also increased the amount of liquid phase and improved the strength of the pellets,due to the granular iron crystals bonded into sheets.Notably,the main component of the liquid phase in high-basicity conditions was calcium ferrite.Although the additional amount of liquid phase was beneficial to the strength of the metallized pellets,calcium disilicate was formed at R_(4)=1.6,resulting in a reduction in the compressive strength of the pellets to 1521.9 N/pellet.

关键词： metallurgical solid waste Iron-bearing dust Iron-bearing sludge Rotary hearth furnace Quaternary basicity Metallized pellet High-temperature performance Metallized pellet High-temperature performance

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Leaching process of phosphorus and iron from steelmaking slag into malic acid solution

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Journal of Iron and Steel Research(International) 2022年第6期29卷 951-960页

作者： Ning-ning Lv Chang Su Hui Kong Hai-chuan Wang Yuan-chi Dong key laboratory of metallurgical emission reduction and resources recycling Ministry of EducationAnhui University of TechnologyMa’anshan 243002AnhuiChina School of metallurgical Engineering Anhui University of TechnologyMa’anshan 243002AnhuiChina

In order to remove phosphorus element from steelmaking slag and decrease iron loss,malic acid was selected as the leaching agent to dissolve steelmaking slag.Firstly,the influences of different factors,such as malic acid concentration,slag particle size,temperature,liquid/solid ratio and stirring speed,on the leaching ratios of phosphorus and iron were studied.Then,the kinetics for the leaching process of phosphorus was analyzed.The results showed that the leaching ratios of phosphorus and iron increase significantly with increasing the malic acid solution concentration and liquid/solid ratio.When the concentration of malic acid solution increases up to 0.01492 mol/L,about 80%phosphorus can be dissolved,and iron leaching ratio is less than 17%.In addition,decreasing slag particle size can obviously increase the leaching ratio of phosphorus.However,temperature and stirring speed have no significant effect on the dissolution of phosphorus and iron.The leaching kinetics of phosphorus follows the unreacted shrinking core model.Diffusion through product layer is the rate-limiting step of the leaching process,and the corresponding apparent activation energy is determined to be 3.32 kJ/mol.Finally,a semi-empirical kinetic equation was established.

关键词： Leaching process Steelmaking slag Phosphorus Iron Malic acid solution

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Agglomeration and bonding mechanism of typical metallurgical solid wastes

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Journal of Iron and Steel Research(International) 2023年第7期30卷 1390-1400页

作者： Ting Wu Yu-qi Kong Jiu-chang Zhang Xin-yu Wang Lei Ma Tao Yang Jie Lei Hong-ming Long School of metallurgical Engineering Anhui University of TechnologyMa’anshan 243032AnhuiChina key laboratory of metallurgical emission reduction&resources recycling(Anhui University of Technology) Ministry of EducationMa’anshan 243032AnhuiChina

The agglomeration of solid wastes is a key factor for subsequent utilization,while the difficulty in agglomeration and high cost have become common problems in the recycling process.The disk pelletizing process was adopted,based on the optimization method by liquid binder addition,and the influence mechanism of the ratio of typical solid wastes as blast furnace dust(BFD)and sludge generated by oxygen converter gas recovery(OGS)was explored.Meanwhile,the effect of binder solution concentration on the quality of green pellets was studied.Derived from the contact angle detection and infrared spectrum analysis,the liquid bridge model was established to study the bonding mechanism.The results showed that OGS had stronger adsorption effect with binder,and the hydrophilicity of BFD was better.When the concentration of binder was higher than 0.2 wt.%,the contact angle between the binder and BFD was bigger than that with OGS,while the capillary force between particles reduced with larger contact angle.The increment in the binder concentration increased the viscous force between particles and the maximum separation distance.The ultimate drop strength and compressive strength were related to the type of viscous force,and the compressive strength reflected the strength of the force between particles intuitively,while the drop strength represented the comprehensive forces of green pellets.Reasonable combination of BFD and OGS was available for pelletizing process,while the ratio of BFD should not exceed 32.0%,and binder C was added in the form of solution with the addition amount of 0.4 wt.%,which can reduce the cost of binder by 20–30¥/t.

关键词： metallurgical solid waste Iron-bearing dust Organic binder Liquid bridge Green pellet

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Effect of BaO and MgO on structure and properties of aluminate slag with various CaO/Al_(2)0_(3)ratios

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Journal of Iron and Steel Research(International) 2024年第1期31卷 204-214页

作者： Yu-qi Kong Ting Wu Wen-zhi Xia Wen Yang Hai-chuan Wang School of metallurgical Engineering Anhui University of TechnologyMa’anshan243032AnhuiChina key laboratory of metallurgical emission reduction and Resource recycling(Ministry of Education) Anhui University of TechnologyMa’anshan243002AnhuiChina

To provide theoretical guidance for performance stability control of low-reactive mold fluxes,the effects of BaO and MgO on the structure and properties of aluminate slag with various CaO/Al_(2)0_(3)(C/A)ratios were investigated using the Fourier transform infrared spectrometer,Raman spectroscope,hemispherical melting point instrument,rotational viscometer and X-ray diffractometer.The results indicated that with BaO and MgO addition,the structure polymerization was first weakened and then enhanced at C/A of 1.1,and the transition contents corresponded to 8 wt.%BaO and 2 wt.%MgO,respectively,while the structure polymerization decreased continuously at C/A of 1.3.Since the viscosity change was well consistent with the structure evolution,the polymerization degree played a more prominent role in the slag viscosity than superheat degree when the melting temperature difference was within 40℃.The break temperature decreased initially and then increased with augment of BaO and MgO at C/A of 1.1,while it manifested a decrease trend with BaO addition,and it decreased obviously but then turned to increase with MgO increment at C/A of 1.3.The crystallization phase and crystallization ratio kept stable with BaO increment,while the crystallization ratio rose greatly with MgO promoting LiAlO_(2)precipitation at C/A of 1.1.The crystal types of all experimental slags were mainly Ca_(12)Al_(14)O_(33)and CaF_(2)at C/A of 1.3,and the precipitation of crystalline phase BaAl2O4 demonstrated a rising trend,while that of Ca_(12)Al_(14)O_(33)gradually declined with BaO augment.

关键词： Aluminate slag Structure MgO BaO Viscosity Property

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Size analysis of slag eye formed by gas blowing in ladle refining

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Journal of Iron and Steel Research(International) 2017年第3期24卷 243-250页

作者： Ning-ning Lv Liu-shun Wu Hai-chuan Wang Yuan-chi Dong Chang Su School of metallurgical Engineering Anhui University of Technology Ma'anshan 243032 Anhui China Key Laboratory of Metallurgical Emission Reduction & Resources Recycling Ministry of Education Ma' anshan 243002 AnhuiChina

The formation of slag eye in a gas stirred ladle was studied through cold models and industrial trials. In the cold model,water and sodium tungstate solution were employed to simulate liquid steel,and silicon oil was employed to simulate slag. The simulation results revealed that the gas flow rate and bath height had strong effects on the slag eye size. In particular,the thickness of slag layer played a strong role in the slag eye size. In addition,the slag eye could not be formed when the thickness of the top layer was more than 4 cm in water-silicone oil model.Besides,the section area of vessel had a great impact on the slag eye size. Industrial trials results showed a similar trend that the gas flow rate was very significant on the slag eye size. The predictions of the existing models showed larger predictions deviations compared with the experimental data. Moreover,a new model without fitting parameters was developed based on force balance and mathematical derivation,and verified by the experimental data. The new model provides the prediction with small deviations by comparing with the data acquired from cold models and industrial trials.

关键词： Slag eye Cold model Industrial trial Gas blowing Ladle refining

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Resource utilization of flue gas calcium-based desulfurization ash:a comprehensive review

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Journal of Iron and Steel Research(International) 2023年第3期30卷 405-418页

作者： Dong-xiang Meng Ru-fei Wei Fei-hu Zhang Hong-ming Long Yuan-yuan Zhou School of metallurgical Engineering Anhui University of TechnologyMa’anshan 243032AnhuiChina key laboratory of metallurgical emission reduction and resources recycling Ministry of EducationAnhui University of TechnologyMa’anshan 243032China Industrial Development Research Center China Metallurgical Industry Planning and Research InstituteBeijing 100013China

Calcium-based desulfurization ash(CDA)is mainly produced in dry and semi-dry flue gas desulfurization processes.The property of CDA is extremely unstable because its main component,calcium sulfite,makes it difficult to be directly applied to the field of building materials.The modification of desulfurization ash can be realized by high-temperature oxidation and wet oxidation.After modification,CDA can be widely used in building materials.Hydrothermal oxidation has broad development prospects because it can complete the oxidation of CDA and the removal of impurity elements at the same time.CDA can be used to prepare high value-added products of calcium sulfate whiskers and ecological rubber fillers.

关键词： Calcium-based desulfurization ash Oxidation modification Building material Calcium sulfate whisker Flue gas desulfurization

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Infrared Emissivity of La0.8Sr0.2MnO3 with Three Different Structures

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Journal of Wuhan University of Technology(Materials Science) 2018年第2期33卷 338-342页

作者：宋路路申星梅 CHENG Guoqing WU Xingrong LI Liaosha AnHui Province key laboratory of Metallurgy Engineering & resources recycling Anhui University of Technology Ma 'anshan 243002 China Key Laboratory of Metallurgical Emission Reduction & Resources Recycling of Ministry of Education Anhui University of Technology Ma ' anshan 243002 China

La_（0.8）Sr_（0.2）MnO_3 samples with rhombohedral, orthohombic and monoclinic structures were prepared by solid state reaction, sol-gel and co-precipitation methods, respectively. Lattice parameters, grain size, morphology, infrared absorption and emissivity of samples were investigated. The results indicated that the average crystallite size calculated from XRD result and particle size of orthohombic sample were smaller than those of the other two samples, and honeycomb shape grains were observed in orthohombic sample. Due to lower crystal symmetry, Mn-O stretching vibration peaks of the three samples shifted to higher infrared wavenumber. According to the theory of wave optics and Kirchhoff law, bigger rhombohedral sample showed higher emissivity than monoclinic one. However, due to the honeycomb structure of orthohombic sample, repeated reflection and scattering led to the increase of absorption, and orthohombic sample exhibited the highest emissivity.

关键词： optical materials microstructure light absorption light reflection

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Application status and comparison of dioxin removal technologies for iron ore sintering process

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Journal of Iron and Steel Research(International) 2018年第4期25卷 357-365页

作者： Hong-ming Long Qi Shi Hong-liang Zhang Ru-fei Wei Tie-jun Chun Jia-xin Li Key Laboratory of Metallurgical Emission Reduction & Resources Recycling Ministry of Education Anhui University of Technology Ma'anshan 243002 Anhui China School of metallurgical Engineering Anhui University of Technology Ma'anshan 243002 Anhui China

The emission of dioxins from the iron ore sintering process is the largest emission source of dioxins, and the reduction in dioxin emission from the iron ore sintering process to the environment is increasingly important. Three approaches to control the emission of dioxins were reviewed： source control, process control, and terminal control. Among them, two terminal control technologies, activated carbon adsorption and selective reduction technology, were discussed in detail. Following a comparison of the reduction technologies, the terminal control method was indicated as the key technology to achieve good control of dioxins during the sintering process. For the technical characteristics of the sintering process and flue gas, multiple methods should be collectively considered, and the most suitable method may be addition of inhibitors ＋ ultra-clean dust collection （electrostatic precipitation/bag filter）＋ desulphurization ＋ selective catalytic reduction to sufficiently remove multiple pollutants, which provides a direction for the cooperative disposal of flue gas pollutants in future.

关键词： Iron ore sintering process Dioxins Removal technology Activated carbon adsorption Selective catalyticreduction

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Simulation research on oxygen mass transfer between steel and slag in IF steel refining process

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Journal of Iron and Steel Research(International) 2020年第4期27卷 409-419页

作者： Ai-jun Deng Ding-dong Fan Hai-chuan Wang Can-hua Li School of metallurgical Engineering Anhui University of TechnologyMa’anshan 243002AnhuiChina key laboratory of metallurgical emission reduction&Resource recycling(Ministry of Education) Ma’anshan 243002AnhuiChina

The effects of oxidizing slag on oxygen mass transfer and inclusions in different stages of IF(interstitial-free)steel refining were investigated by several heat simulation experiments.The results of the experiments showed that the oxidizability of slag changed considerably during different refining stages.Keeping the content of FeO in the slag within 1 wt.%would narrow the difference of slag oxidizability,stabilize the content of[Al]s in the steel,avoid secondary oxidation of molten steel by the slag,and reduce the inclusions.When the mass transfer of FeO in the slag phase was a limiting step,the secondary oxidation reaction occurred at the steel–slag interface;when the diffusion of oxygen in the molten steel was a limiting step,the secondary oxidation reaction took place inside the molten steel.The oxygen transfer rate was affected by the mass transfer coefficient of oxygen.For every 0.0001m/s increase in mass transfer coefficient,the oxygen transfer rate increased by about 2.2×10^-6 min^-1.By changing the mass transfer coefficient,the oxygen transfer rate of the slag to the molten steel can be controlled.

关键词： IF steel Slag Steel–slag interface Inclusion Oxygen mass transfer Mass transfer coefficient

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Enhanced electrochemical property of FePO_4-coated LiNi_(0.5)Mn_(1.5)O_4 as cathode materials for Li-ion battery

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Science Bulletin 2017年第14期62卷 1004-1010页

作者： Ting-Feng Yi Yan-Mei Li Xiao-Ya Li Jing-Jing Pan Qianyu Zhang Yan-Rong Zhu School of Chemistry and Chemical Engineering Anhui University of Technology Key Laboratory of Metallurgical Emission Reduction & Resources Recycling Ministry of Education Anhui University of Technology School of Environment and Civil Engineering Dongguan University of Technology

Pristine LiNi_(0.5)Mn_(1.5)O_4and FePO_4-coated one with Fd-3m space groups were prepared by a sol-gel method.The structure and performance were studied by X-ray diffraction(XRD)rietveld refinement,scanning electron microscopy(SEM),high resolution transmission electron microscopy(HRTEM),energy dispersive spectrometer(EDS)mapping,electrochemical impedance spectroscopy(EIS)and chargedischarge tests,respectively.The lattice parameters of all samples almost remain the same from the Rietveld refinement,revealing that the crystallographic structure has no obvious difference between pristine LiNi_(0.5)Mn_(1.5)O_4and FePO_4-coated one.All materials show similar morphologies with uniform particle distribution with small particle size,and FePO_4coating does not affect the morphology of LiNi_(0.5)Mn_(1.5)O_4material.EDS mapping and HRTEM show that FePO_4may be successfully wrapped around the surfaces of LiNi_(0.5)Mn_(1.5)O_4particles,and provides an effective coating layer between the electrolyte and the surface of LiNi_(0.5)Mn_(1.5)O_4particles.FePO_4(1 wt%)-coated LiNi_(0.5)Mn_(1.5)O_4cathode shows the highest discharge capacity at high rate(2C)among all samples.After 80 cycles,the reversible discharge capacity of FePO_4(1 wt%)coated Li Ni-0.5Mn1.5O4is 117 m Ah g1,but the pristine one only has 50 m Ah g^(-1).FePO_4coating is an effective and controllable way to stabilize the LiNi_(0.5)Mn_(1.5)O_4/electrolyte interface,and avoids the direct contact between LiNi_(0.5)Mn_(1.5)O_4powders and electrolyte,then suppresses the side reactions and enhances the electrochemical performance of the LiNi_(0.5)Mn_(1.5)O_4.

关键词：电化学性能正极材料锂离子电池 Rietveld精修包覆溶胶-凝胶方法扫描电子显微镜高分辨透射电镜

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