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Unraveling post-growth mechanisms of monolayer CsPbBr3 nanocubes:Laser-enhanced transformations and cathodoluminescence-electron microscopy correlations

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Journal of Energy Chemistry 2025年第01期 146-156页

作者： Mingxing Li Xiaoge Wang Xiaofan Cao Zhiqun He Chunjun Liang Mingxing Chen Jing Ju Fangtian You key laboratory of luminescence and optical information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing National laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering Peking University

Lead-halide perovskite nanoparticles（LHP NPs） are highly promising materials for next-generation displays and solid-state lighting due to their exceptional optical properties. However, their inherent instability presents a significant challenge. Recent advances have demonstrated that optoelectronic devices based on monolayer nanoparticle films exhibit both high luminescence efficiency and long-term *** research demonstrates that mobility limitations and anisotropic alignments in CsPbBr3nanocube monolayer films are key to their stabilization, hindering spontaneous growth through face-to-face fusion and resulting in the formation of connecting necks in a diagonal direction. Introducing laser irradiation confirmed this by significantly accelerating nanocubes growth, increasing mobility, and enhancing local structural ordering, leading to larger and more regularly shaped nanosheets. Fourier transform infrared spectroscopy and energy dispersive spectroscopy line-scan analyses indicated that laser irradiation did not disrupt the ligand structure. Transmission electron microscopy and correlative cathodoluminescence electron microscopy revealed the effects of post-growth and heterogeneous structures, including enhanced luminescence and inhomogeneous intensity in the nanosheets. These findings deepen the understanding of the post-growth mechanism of monolayer nanoparticles and the structure-emission correlation and highlight the unique role of laser irradiation in directing the formation of well-defined and regular nanostructures.

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Performance improvement of MEH-PPV:PCBM solar cells using bathocuproine and bathophenanthroline as the buffer layers

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Chinese Physics B 2011年第6期20卷 540-545页

作者：刘晓东赵谡玲徐征张福俊张天慧龚伟闫光孔超王永生徐叙瑢 key laboratory of luminescence and optical information of ministry of education Beijing Jiaotong University

In this work, bathocuproine （BCP） and bathophenanthroline （Bphen）, commonly used in small-molecule organic solar cells （OSCs）, are adopted as the buffer layers to improve the performance of the polymer solar cells （PSCs） based on poly（2-methoxy-5-（2-ethylhexyloxy）-1,4-phenylenevinylene）（MEH-PPV）： [6,6]-phenyl-C61-butyric acid methyl ester （PCBM） bulk heterojunction. By inserting BCP or Bphen between the active layer and the top cathode, all the performance parameters are dramatically improved. The power conversion efficiency is increased by about 70% and 120% with 5-am BCP and 12-nm Bphen layers, respectively, when compared with that of the devices without any buffer layer. The performance enhancement is attributed to BCP or Bphen （i） increasing the optical field, and hence the absorption in the active layer, （ii） effectively blocking the excitons generated in MEH-PPV from quenching at organic/aluminum （Al） interface due to the large band-gap of BCP or Bphen, which results in a significant reduction in series resistance （Rs）, and （iii） preventing damage to the active layer during the metal deposition. Compared with the traditional device using LiF as the buffer layer, the BCP-based devices show a comparable efficiency, while the Bphen-based devices show a much larger efficiency. This is due to the higher electron mobility in Bphen than that in BCP, which facilitates the electron transport and extraction through the buffer layer to the cathode.

关键词： polymer solar cells bathocuproine bathophenanthroline buffer layer

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Influence of small-molecule material on performance of polymer solar cells based on MEH-PPV:PCBM blend

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Chinese Physics B 2010年第11期19卷 691-697页

作者：刘晓东徐征张福俊赵谡玲张天慧龚伟宋晶路孔超闫光徐叙瑢 key laboratory of luminescence and optical information Beijing Jiaotong UniversityMinistry of Education

In this work, the influence of a small-molecule material, tris（8-hydroxyquinoline） aluminum （Alq3）, on bulk heterojunction （BHJ） polymer solar cells （PSCs） is investigated in devices based on the blend of poly（2-methoxy-5-（2- ethylhexyloxy）-1,4-phenylenevinylene）（MEH-PPV） and [6,6]-phenyl-C61-butyric acid methyl ester （PCBM）. By doping Alq3 into MEH-PPV：PCBM solution, the number of MEH-PPV excitons can be effectively increased due to the energy transfer from Alq3 to MEH-PPV, which probably induces the increase of photocurrent generated by excitons dissociation. However, the low carrier mobility of Alq3 is detrimental to the efficient charge transport, thereby blocking the charge collection by the respective electrodes. The balance between photon absorption and charge transport in the active layer plays a key role in the performance of PSCs. For the case of 5 wt.% Alq3 doping, the device performance is deteriorated rather than improved as compared with that of the undoped device. On the other hand, we adopt Alq3 as a buffer layer instead of commonly used LiF. All the photovoltaic parameters are improved, yielding an 80% increase in power conversion efficiency （PCE） at the optimum thickness （1 nm） as compared with that of the device without any buffer layer. Even for the 5 wt.% Alq3 doped device, the PCE has a slight enhancement compared with that of the standard device after modification with 1 nm （or 2 nm） thermally evaporated Alq3. The performance deterioration of Alq3-doped devices can be explained by the low solubility of Alq3, which probably deteriorates the bicontinuous D-A network morphology; while the performance improvement of the devices with Alq3 as a buffer layer is attributed to the increased light harvesting, as well as blocking the hole leakage from MEH-PPV to the aluminum （Al） electrode due to the lower highest occupied molecular orbital （HOMO） level of Alq3 compared with that of MEH-PPV.

关键词： bulk heterojunction polymer solar cells Alq3 doping buffer layer

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Mueller matrix analysis for all optical fiber co-existence of birefringence-polarization dependent gain-mode coupling at a single wavelength

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Chinese Physics B 2011年第11期20卷 13-18页

作者：尚超吴重庆李政勇杨双收高凯强余贶琭冯震 key laboratory of education ministry on luminescence and optical information Technology Institute of Optical InformationBeijing Jiaotong University

Birefringence （polarization-related phase-shift）, polarization dependent gain （PDG） and mode coupling are three factors that may synchronously influence the transmission of single-wavelength polarized light in optical fibers. This paper obtains a new Mueller matrix analysis, which can be used under conditions that all these three factors are existing and changing. According to our transmission model, the state of polarization （SOP） changes along an optical mierostructure fiber with co-existence of birefringence-PDG-mode coupling were simulated. The simulated results, which show the phenomena of SOP constringency, are in good agreement with previous theoretical analyses.

关键词： Mueller matrix birefringence polarization dependent gain mode coupling

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A simple encapsulation method for organic optoelectronic devices

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Chinese Physics B 2014年第8期23卷 322-326页

作者：孙倩倩安桥石张福俊 key laboratory of luminescence and optical information Ministry of Education Beijing Jiaotong University

The performances of organic optoelectronic devices, such as organic light emitting diodes and polymer solar cells, have rapidly improved in the past decade. The stability of an organic optoelectronic device has become a key problem for further development. In this paper, we report one simple encapsulation method for organic optoelectronic devices with a parafilm, based on ternary polymer solar cells （PSCs）. The power conversion efficiencies （PCE） of PSCs with and without encapsulation decrease from 2.93% to 2.17% and from 2.87% to 1.16% after 168-hours of degradation under an ambient environment, respectively. The stability of PSCs could be enhanced by encapsulation with a parafilm. The encapsulation method is a competitive choice for organic optoelectronic devices, owing to its low cost and compatibility with flexible devices.

关键词： organic optoelectronic devices stability encapsulation

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Solution-processed polymer photodetectors with trap-assisted photomultiplication

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Science China(Physics,Mechanics & Astronomy) 2015年第5期58卷 88-92页

作者： HAN ZiHong ZHANG Hui TIAN QiuShuo LI LingLiang ZHANG FuJun key laboratory of luminescence and optical information Ministry of Education Beijing Jiaotong University

Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene）（P3HT）： indene-C60 bisadduct （ICBA） as the active layer. The maximum external quantum efficiency （EQE） is 685% for the device with 2% ICBA doping ratio, which is much higher than that of OPDs with P3HT：ICBA （1：1） as the active layer. The PM phenomenon is attributed to the hole tunneling injection assisted by trapped electron in ICBA near A1 cathode, which can be demonstrated from the EQE spectra and transient photocurrent curves of OPDs with different ICBA doping ratios.

关键词： organic photodetectors photomultiplication P3HT ICBA

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optical time-domain differentiation based on intensive differential group delay

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Chinese Physics B 2011年第10期20卷 267-271页

作者：李政勇余向志吴重庆 key laboratory of luminescence and optical information of the ministry of education and Institute of optical information Beijing Jiaotong University

An optical time-domain differentiation scheme is proposed and demonstrated based on the intensive differential group delay in a high birefringence fibre waveguide. Results show that the differentiation waveforms agree well with the mathematically calculated derivatives. Both error and efficiency will increase when the birefringence fibre becomes longer, and the error rises up more quickly while the efficiency approaches to a maximum of ~0.25. By using a 1-m birefringence fibre a lower error of ~0.26% is obtained with an efficiency of 1% for the first-order differentiation of 10-ps Gaussian optical pulses, and the high-order optical differentiation up to 4th order is achieved with an error less than 3%. Due to its compact structure being easy to integrate and cascade into photonic circuits, our scheme has great potential for ultrafast signal processing.

关键词： optical signal processing differentiation differential group delay

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Phase-locked all-optical differential polarization demodulation

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Chinese Physics B 2014年第6期23卷 283-286页

作者：史骥李政勇张革王海洋王一旭吴重庆 key laboratory of luminescence and optical information of ministry of education Beijing Jiaotong University

A novel scheme of differential polarization demodulation is presented and demonstrated based on a polarized asym- metrical Mach-Zehnder interferometer configuration with polarization control. To enhance the stability of the demodulator, a phase-lock device is designed, and it is composed of a symmetric 3 × 3 coupler and a feedback circuit. For further estab- lishing a differential polarization-shift keying （DPolSK） transmission system, we successfully carry out the demodulation experiments on 10-Gb/s DPolSK optical signals for the first time. Due to the all-optical structure with phase-lock, our scheme is available to realize the DPolSK optical communication in practical optical fiber systems.

关键词： optical communication systems demodulation polarization

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Improved performance of P3HT:PCBM solar cells by both anode modification and short-wavelength energy utilization using Tb(aca)_3phen

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Chinese Physics B 2014年第9期23卷 585-589页

作者：卓祖亮王永生何大伟富鸣 key laboratory of luminescence and optical information of the ministry of education Beijing Jiaotong University

The performance of P3HT：PCBM solar cells was improved by anode modification using spin-coated Tb（aca）3phen ultrathin films. The modification of the Tb（aca）3phen ultrathin film between the indium tin oxide （ITO） anode and the PEDOT：PSS layer resulted in a maximum power conversion efficiency （PCE） of 2.99% compared to 2.66% for the reference device, which was due to the increase in the short-circuit current density （Jsc）. The PCE improvement could be attributed to the short-wavelength energy utilization and the optimized morphology of the active layers. Tb（aca）3phen with its strong down-conversion luminescence properties is suitable for the P3HT：PCBM blend active layer, and the absorption region of the ternary blend films is extended into the near ultraviolet region. Furthermore, the crystallization and the surface morphol- ogy of P3HT：PCBM films were improved with the Tb（aca）3phen ultrathin film. The ultraviolent-visible absorption spectra, atomic force microscope （AFM）, and X-ray diffraction （XRD） of the films were investigated. Both anode modification and short-wavelength energy utilization using Tb（aca）3phen in P3HT：PCBM solar cells led to about a 12% PCE increase.

关键词： P3HT:PCBM anode modification polymer solar cells

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Investigation on performance of all optical buffer with large dynamical delay time based on cascaded double loop optical buffers

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Chinese Physics B 2010年第9期19卷 420-427页

作者：王拥军吴重庆忻向军余贶琭张晓磊 School of Electronic Engineering Beijing University of Posts and Telecommunications key laboratory of information Photonics and optical Communications of education ministry Institute of optical information Beijing Jiaotong UniversityKey Laboratory of Education Ministry on Luminescence and Optical Information Technology

optical buffers are critical for optical signal processing in future optical packet-switched networks. In this paper, a theoretical study as well as an experimental demonstration on a new optical buffer with large dynamical delay time is carried out based on cascaded double loop optical buffers （I：）LOBs）. It is found that pulse distortion can be restrained by a negative optical control mode when the optical packet is in the loop. Noise analysis indicates that it is feasible to realise a large variable delay range by cascaded DLOBs. These conclusions are validated by the experiment system with 4-stage cascaded DLOBs. Both the theoretical simulations and the experimental results indicate that a large delay range of 1-9999 times the basic delay unit and a fine granularity of 25 ns can be achieved by the cascaded DLOBs. The performance of the cascaded DLOBs is suitable for the all optical networks.

关键词： all optical packets switching optical buffer with large delay range signals impairment noise analysis of semiconductor optical amplifier

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