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Rational Design and Construction of a CdS QDs/InVO4 Atomic-Layer（110）/（110） Facet S-Scheme Heterojunction for Highly Efficient Photocatalytic Degradation of C2H4

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Energy & Environmental Materials 2024年第3期7卷 215-222页

作者： Yuanpeng Dong Peizhu Ji Xinyue Xu Rong Li Yin Wang Kevin Peter Homewood Xiaohong Xia Yun Gao Xuxing Chen Ministry of Education key laboratory for the Green Preparation and application of Functional Materials School of Materials Science&Engineering Hubei University Hubei key laboratory of low dimensional Optoelectronic Materials and Devices Hubei University of Arts and Science State key laboratory of structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences United Water (Xianning) Company Limited

Exploring high efficiency S-scheme heterojunction photocatalysts with strong redox ability for removing volatile organic compounds from the air is of great interest and ***,how to predict and regulate the transport of photogenerated carriers in heterojunctions is a great ***,density functional theory calculations were first used to successfully predict the formation of a CdS quantum dots/InVO4atomic-layer （110）/（110） facet S-scheme ***,a CdS quantum dots/InVO4atomic-layer was synthesized by in-situ loading of CdS quantum dots with （110） facets onto the（110） facets of *** a result of the deliberately constructed built-in electric field between the adjoining facets,we obtain a remarkably enhanced photocatalytic degradation rate for *** rate is 13.8 times that of pure CdS and 13.2 times that of pure ***-situ irradiated X-ray photoelectron spectroscopy,photoluminescence and time-resolved photoluminescence measurements were carried *** experiments validate that the built-in electric field enhanced the dissociation of photoexcited excitons and the separation of free charge carriers,and results in the formation of S-scheme charge transfer *** reaction mechanism of the photocatalytic C2H4oxidation is investigated by in-situ electron paramagnetic *** work provides a mechanistic insight into the construction and optimization of semiconductor heterojunction photocatalysts for application to environmental remediation.

关键词： CdS QDs InVO4 atomic-layer photocatalysis S-scheme volatile organic compounds

Gravitational wave fluxes on generic orbits in near-extreme Kerr spacetime:Higher spin and large eccentricity

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Science China(physics,Mechanics & Astronomy) 2024年第11期Mechanics & Astronomy) .卷 20-32页

作者： Changkai Chen Jiliang Jing Department of physics Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of EducationSynergetic Innovation Center for Quantum Effects and Applications Hunan Normal University

To accurately obtain the waveform template of gravitational waves, substantial computational resources and extremely high precision are often required. In a previous study, we employed the confluent Heun function to obtain an exact solution to the Teukolsky equation. This approach allowed us to efficiently and accurately calculate the gravitational wave flux for a particle in circular orbits around a Schwarzschild black hole. Building on this method, we now extend its application to calculate the asymptotic gravitational wave fluxes from a particle in generic orbits around a near-extreme Kerr black hole. Our extended method proves particularly effective in handling computational challenges associated with large eccentricities(e = 0.9), higher spins(a = 0.999), higher harmonic modes, and strong-field regions. The results we obtained significantly outperform those derived from the numerical integration method based on the Mano-Suzuki-Takasugi method.

关键词： gravitational wave fluxes exact solution Teukolsky equation near-extreme Kerr black hole

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A pseudoclassical theory for the wavepacket dynamics of the kicked rotor model

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Science China(physics,Mechanics & Astronomy) 2024年第3期67卷 34-43页

作者： Zhixing Zou Jiao Wang Department of physics and key laboratory of low dimensional Condensed Matter physics(Department of Education of Fujian Province) Xiamen UniversityXiamen 361005China Lanzhou Center for Theoretical physics Lanzhou UniversityLanzhou 730000China

In this study, we propose a generalized pseudoclassical theory for the kicked rotor model in an attempt to discern the footprints of the classical dynamics in the deep quantum regime. Compared with the previous pseudoclassical theory that applies only in the neighborhoods of the lowest two quantum resonances, the proposed theory is applicable in the neighborhoods of all quantum resonances in principle by considering the quantum effect of the free rotation at a quantum resonance. In particular, it is confirmed by simulations that the quantum wavepacket dynamics can be successfully forecasted based on the generalized pseudoclassical dynamics, offering an intriguing example where it is feasible to bridge the dynamics in the deep quantum regime to the classical dynamics. The application of the generalized pseudoclassical theory to the PT-symmetric kicked rotor is also discussed.

关键词： quantum-classical correspondence kicked rotor model pseudoclassical theory wavepacket dynamics

Competitive assembling strategy to construct carbon nitride homojunctions for boosting photocatalytic performance

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Journal of Materials Science & Technology 2024年第5期172卷 23-32页

作者： Hua-Wei Zhang Yuan-Yuan Li Bo Li Jing-Hui Shi Tao Huang Gui-Fang Huang Anlian Pan Wangyu Hu Wei-Qing Huang School of physics&Electronic Engineering Zhengzhou University of Light IndustryZhengzhou 450002China key laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education&Hunan Provincial key laboratory of low-dimensional structural physics and Devices School of Physics and ElectronicsHunan UniversityChangsha 410082China College of Materials Science and Engineering Hunan UniversityChangsha 410082China

Both morphology and composition have a great influence on the properties and functions of materials,however,how to rational modulate both of them to achieve their synergistic effects has been a longstanding ***,we demonstrate a competitive assembling strategy for the construction of metal-free graphite carbon nitride(CN)homojunctions in which morphology and composition can be easily controlled simultaneously by only changing the ratio of assembly raw *** homojunctions are comprised of porous nanotubular S-doped CN(SCN)grafted with CN nanovesicles,which are derived from thermal polycondensation of melamine-thiocyanuric acid(M-T)/melamine-cyanuric acid(M-C)supramolecular hybrid *** unique architecture and component engineering endows the novel SCN-CN homojunction with abundant active sites,enhanced visible trapping ability,and intimate interface *** a result,the synthesized SCN-CN homojunctions demonstrate high photocatalytic activity for hydrogen evolution and pollutant *** developed strategy opens up intriguing opportu-nities for the rational construction of intricate metal-free heterostructures with controllable architecture and interfacial contact for applications in energy-related fields.

关键词： Competitive assembling strategy Supramolecular hybrid blocks Homojunctions Graphite carbon nitride Photocatalytic

Cucurbit[8]uril-regulated face-to-face dimerization assembly enhanced photosensitization and photocatalysis

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Science China Chemistry 2024年第5期67卷 1605-1612页

作者： Haigen Nie Die Hu Zhiyao Zeng Yan Fan Yaxin Zhai Xin-Long Ni key laboratory of Chemical Biology and Traditional Chinese Medicine Ministry of Educational of ChinaKey Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan ProvinceCollege of Chemistry and Chemical EngineeringHunan Normal UniversityChangsha 410081China key laboratory of low-dimensional Quantum Structures and Quantum Control of Ministry of Education Department of PhysicsHunan Normal UniversityChangsha 410081China

In water, N,N′-diarylpyridinium thiazolo[5,4-d]thiazole guests(G1–G3) were encapsulated by cucurbit[8]uril(Q[8]) to construct Q[8]_(3)/G_(2) complexes, in which the encapsulated G molecules exist as an exact face-to-face dimer. These complexation behaviors have been indicated by proton nuclear magnetic resonance(~1H NMR) spectroscopy and isothermal titration calorimetry(ITC),and have been confirmed by X-ray single crystal structural analysis of Q[8]_(3)/G2_(2). While free guests G1–G3 have no ability to sensitize singlet oxygen, they all become effective singlet oxygen sensitizers when complexed with Q[8]. By irradiation of white light, Q[8]_(3)/G_(2) complexes induced selective oxidation of aryl sulfide to aryl sulfoxide in good yields and selective oxidation of dimethyl sulfide(DMS) to dimethyl sulfoxide(DMSO) in excellent yields without over-oxidation to dimethyl sulfone(DMSO_(2))even for elongated irradiation. High-yield photo-oxidation of DMS to DMSO_(2) was only achieved by irradiation of blue light in the presence of Q[8]_(3)/G1_(2), which was also effective in photobleaching of Rhodamine B in water. The higher photo-oxidation power of Q[8]_(3)/G1_(2) has been ascribed to an additional generation of reactive oxygen species besides singlet oxygen.

关键词： host-guest interaction dimerization macrocycles photosensitization

Heterointerface Engineering-Induced Oxygen Defects for the Manganese Dissolution Inhibition in Aqueous Zinc Ion Batteries

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Energy & Environmental Materials 2024年第03期7卷 116-126页

作者： Wentao Qu Yong Cai Baohui Chen Ming Zhang Hunan Provincial key laboratory of low-dimensional structural physics&Devices School of Physics and ElectronicsHunan University Engineering Research Center of Advanced Semiconductor Technology and application of Ministry of Education&key laboratory for Micro-/Nano-Opto-electronic Devices of Ministry of Education College of Semiconductors(College of Integrated Circuits)Hunan University Changsha Semiconductor Technology and application Innovation Research Institute College of Semiconductors (College of Integrated Circuits)Hunan University State key laboratory of Disaster Prevention & Reduction for Power Grid Transmission and Distribution Equipment (Hunan Electric Power Corporation Disaster Prevention and Reduction Center)

Manganese-based material is a prospective cathode material for aqueous zinc ion batteries （ZIBs） by virtue of its high theoretical capacity,high operating voltage,and low ***,the manganese dissolution during the electrochemical reaction causes its electrochemical cycling stability to be *** this work,heterointerface engineering-induced oxygen defects are introduced into heterostructure MnO2（δa-MnO2） by in situ electrochemical activation to inhibit manganese dissolution for aqueous zinc ion ***,the heterointerface between the disordered amorphous and the crystalline MnO2of δa-MnO2is decisive for the formation of oxygen *** the experimental results indicate that the manganese dissolution of δa-MnO2is considerably inhibited during the charge/discharge *** analysis indicates that the oxygen defect regulates the electronic and band structure and the Mn-O bonding state of the electrode material,thereby promoting electron transport kinetics as well as inhibiting Mn ***,the capacity of δa-MnO2does not degrade after 100 cycles at a current density of 0.5 Ag-1and also 91%capacity retention after 500cycles at 1 *** study provides a promising insight into the development of high-performance manganese-based cathode materials through a facile and low-cost strategy.

关键词： electrochemical activation heterointerface manganese dissolution inhibition oxygen defects zinc ion batteries

Band structures of strained kagome lattices

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Chinese physics B 2024年第2期33卷 456-463页

作者：徐露婷杨帆 Center for Joint Quantum Studies and Department of physics School of ScienceTianjin UniversityTianjin 300354China Tianjin key laboratory of low dimensional Materials physics and Preparing Technology Department of PhysicsTianjin UniversityTianjin 300354China

Materials with kagome lattices have attracted significant research attention due to their nontrivial features in energy *** theoretically investigate the evolution of electronic band structures of kagome lattices in response to uniaxial strain using both a tight-binding model and an antidot model based on a periodic muffin-tin *** is found that the Dirac points move with applied ***,the flat band of unstrained kagome lattices is found to develop into a highly anisotropic shape under a stretching strain along y direction,forming a partially flat band with a region dispersionless along ky direction while dispersive along kx *** results shed light on the possibility of engineering the electronic band structures of kagome materials by mechanical strain.

关键词： kagome lattice strain band structure engineering

Enhanced measurement precision with continuous interrogation during dynamical decoupling

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Chinese physics B 2024年第3期33卷 88-94页

作者：张军杜鹏敬雷徐鹏尤力张文献 key laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and TechnologyWuhan UniversityWuhan 430072China State key laboratory of low-dimensional Quantum physics Department of PhysicsTsinghua UniversityBeijing 100084China Wuhan Institute of Quantum Technology Wuhan 430206China

Dynamical decoupling(DD)is normally ineffective when applied to DC *** its straightforward implementation,DD nulls out DC signal as well while suppressing *** work proposes a phase relay method that is capable of continuously interrogating the DC signal over many DD *** illustrate its efficacy when applied to the measurement of a weak DC magnetic field with an atomic spinor Bose-Einstein *** approaching standard quantum limit or Heisenberg limit are potentially realizable for a coherent spin state or a squeezed spin state of 10000 atoms,respectively,while ambient laboratory level noise is suppressed by *** work offers a practical approach to mitigate the limitations of DD to DC measurement and would find other applications for resorting coherence in quantum sensing and quantum information processing research.

关键词： quantum sensing continuous interrogation quantum magnetometer dynamical decoupling Heisenberg limit

Lorentz violation induces isospectrality breaking in Einstein-bumblebee gravity theory

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Science China(physics,Mechanics & Astronomy) 2024年第8期67卷 87-96页

作者： Wentao Liu Xiongjun Fang Jiliang Jing Jieci Wang Department of physics Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of EducationSynergetic Innovation Center for Quantum Effects and ApplicationsHunan Normal UniversityChangsha 410081China

In this study,we investigate the quasinormal modes(QNMs)of a Lorentz-violating spacetime,factoring in a cosmological constant,within the framework of Einstein-bumblebee *** findings reveal that the interaction of spacetime with an anisotropic bumblebee field imparts distinct contributions to the axial and polar sectors of the vector *** subsequently breaks the isospectrality typically observed in vector *** evidence strongly indicates isospectral breaking in the vector modes of Einstein-bumblebee black holes:a pronounced breakage in the real part of the frequencies,while the imaginary component seems less *** isospectral breaking indicates the existence of two different waveforms in the Ringdown phase of the black hole,which provides a potential signal of quantum gravity observable in current experiments.

关键词： Lorentz-violating isospectral breaking quasinormal modes

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