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Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation

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Chinese Chemical Letters 2024年第7期35卷 183-187页

作者： Shiyu Pan Bo Cao Deling Yuan Tifeng Jiao Qingrui Zhang Shoufeng Tang State key laboratory of Metastable Materials Science and technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseSchool of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China

To surmount the obstacles of traditional Fenton method and synchronously utilize Cu^(2+)and polyphenol in water,an improved Fenton-like reaction applying calcium peroxide(CaO_(2))as H_(2)O_(2)source and regulating by the complex of Cu^(2+)-tartaric acid(TA,a representative of polyphenol)was constructed.A typical antibiotic,metronidazole(MTZ)could be effectively eliminated by the Cu^(2+)/TA/CaO_(2)system,and the optimized parameters were as follows:0.1 mmol/L Cu^(2+),2 mmol/L TA,2 mmol/L CaO_(2),and initial *** spectrum confirmed the formation of Cu^(2+)-TA complex,which promoted the Cu^(2+)/Cu+circulation through decreasing the Cu^(2+)/Cu^(+) couple redox potential,which further enhanced the H_(2)O_(2)decomposition and the formation of reactive *** radical was dominant for MTZ degradation,followed by oxygen and superoxide *** degradation intermediates of MTZ were detected and their evolution way was ***,the ternary process showed a wide p H tolerance(3–8)for removing MTZ and broad applicability for eliminating other dyes and *** work provided a reference for Cu-based Fenton-like strategy for organic wastewater settlement.

关键词： Cupric ion Tartaric acid Complexation Calcium peroxide Metronidazole removal

Geochronological and geochemical constraints on the petrogenesis and geodynamic process of Hemler,Vlinder,and Il'ichev seamount lavas in NW Pacific

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Science China Earth Sciences 2024年第6期67卷 1856-1871页

作者： Xun WEI Yan ZHANG Xuefa SHI Hui ZHANG key laboratory of Marine Geology and Metallogeny First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China laboratory for Marine Geology Qingdao Marine Science and Technology CenterQingdao 266237China Shandong key laboratory of deep Sea Mineral Resources Development(Preparatory) Qingdao 266061China

Oceanic intraplate volcanoes with linear age progressions are usually accepted to be derived from melting of an upwelling mantle *** seamount groups in NW Pacific,however,show complex age-distance relationships that are difficult to explain using the classic“mantle plume hypothesis”,and thus their origins are *** this study,we present ^(40)Ar-^(39)Ar age,geochemical,and Sr-Nd-Pb-Hf isotopic data of lavas from Hemler,Vlinder,and Il’ichev seamounts in NW Pacific,to elucidate their petrogenesis and geodynamic *** lavas from Hemler,Vlinder,and Il’ichev seamounts are classified as alkali basalt,basanite/nephelinite,and *** with Mg O>8 wt.%exhibit high contents of CaO,FeO^(T),and TiO_(2),similar to the composition of melts formed from reaction between carbonated eclogite-derived melts and fertile *** lavas have elevated Zr/Hf ratios(40.6-45.2)and negative Zr and Hf anomalies,indicating the presence of a carbonate component in the mantle *** are enriched in incompatible trace elements and have enriched mantle 1(EM1)-like SrNd-Pb-Hf isotopic *** isotopic compositions of Vlinder,Il’ichev basanite,and Hemler lavas in this study are similar to the Rarotonga *** occurring at the same seamount,the Il’ichev alkali basalts display more depleted SrNd-Hf isotopic compositions compared to Il’ichev *** to plate tectonic reconstruction results,the ages of Hemler(100.1 Ma),Vlinder pre-(100.2 Ma)and post-shield(87.5 Ma),and Il’ichev(56.4 Ma)lavas clearly deviate from the Macdonald,Arago,Rarotonga,and Samoa hotspot tracks,indicating that they cannot directly originate from mantle *** propose that in the mid-Cretaceous,when the Pacific plate passed over Rarotonga hotspot,melting of Rarotonga plume formed the Vlinder(main-shield stage),Pako,and Ioah *** Rarotonga(and possibly Samoa)plume materials would have been dispersed into the surrounding asthenosphere by mantle conve

关键词： Mantle plume Magellan seamount trail Carbonated mantle component Hotspot Lithosphere extension

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A study on vector mediator top-philic dark matter

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Communications in Theoretical Physics 2024年第8期76卷 69-80页

作者： Yanyan Hu Yandong Liu Yuanyuan Liu College of Nuclear Science and technology Beijing Normal University Joint Laboratory of Jinping Ultra-low Radiation Background Measurement of Ministry of Ecology and Environment Jinping Deep Underground Frontier Science and Dark Matter Key Laboratory of Sichuan Province Key Laboratory of Beam Technology of Ministry of Education Beijing Radiation Center

We conducted a study on a simplified dark matter model that introduces a vector-like intermediate particle, facilitating exclusive interactions between dark matter and the top quark in the Standard Model. The analysis focused on the relic density of Dirac-type fermion dark matter and highlighted the complementary role of direct detection in constraining the dark matter model. Notably, in instances when dark matter mass is small, the tree-level two-body annihilation process experiences suppression. In such scenarios, the contributions of the threebody process(■) and the one-loop process(■ → gg) dominate the relic *** regard to direct detection, calculations were performed for the two-loop contribution to the dark-matter–gluon interaction, yielding the corresponding spin-independent scattering cross section.

关键词： dark matter effective field theory new physics

3D digital-image correlation insight into generalized relaxation behavior of sandstone under stress and pore pressure coupling

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第7期16卷 2516-2536页

作者： Cancan Chen Heping Xie Jiang Xu Seisuke Okubo Shoujian Peng Cunbao Li Minghui Li State key laboratory of Intelligent Construction and Healthy Operation and Maintenance of deep Underground Engineering Shenzhen UniversityShenzhen518060China Guangdong Provincial key laboratory of deep Earth Sciences and Geothermal Energy Exploitation and Utilization Institute of Deep Earth Sciences and GreenEnergyCollege of Civil and Transportation EngineeringShenzhen UniversityShenzhen518060China State key laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing400044China

The occurrence of geological hazards and the instability of geotechnical engineering structures are closely related to the time-dependent behavior of ***,the idealization boundary condition for constant stress in creep or constant strain in relaxation is not usually attained in natural geological ***,generalized relaxation tests that explore the simultaneous changes of stress and strain with time under different stress levels with constant pore-water pressure are conducted in this *** results show that in area I,area II,and area III,the stress and strain both change synchronously with time and show similar evolutionary laws as the strain-time curve for creep or the stress-time curve for *** the applied stress level surpasses the sci or scd threshold,the variations in stress and strain and their respective rates of change exhibit a significant *** radial deformation and its rate of change exhibit greater sensitivity in response to stress *** apparent strain deforms homogeneously at the primary stage,and subsequently,gradually localizes due to the microcrack development at the secondary ***,interconnection of the microcracks causes the formation of a shear-localization zone at the tertiary *** strain-time responses inside and outside the localization zone are characterized by local strain accumulation and inelastic unloading during the secondary and tertiary stages,*** width of the shear-localization zone is found to range from 4.43 mm to 7.08 mm and increased with a longer *** electron microscopy(SEM)reveals a dominant coalescence of intergranular cracks on the fracture surface,and the degree of physiochemical deterioration caused by water-rock interaction is more severe under a longer *** brittle sandstone’s time-dependent deformation is essentially controlled by microcrack development during generalized relaxation,and its expectancy-life is determi

关键词： Generalized relaxation Stress level Direction coefficient Major-strain field Microcrack damage Stress threshold

Experimental study on the effect of water absorption level on rockburst occurrence of sandstone

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第1期16卷 136-152页

作者： Dongqiao Liu Jie Sun Pengfei He Manchao He Binghao Cao Yuanyuan Yang State key laboratory for Geomechanics and deep Underground Engineering China University of Mining and Technology(Beijing)Beijing100083China School of Mechanics and Civil Engineering China University of Mining and Technology(Beijing)Beijing100083China Institute for deep Underground Science and Engineering China University of Mining and Technology(Beijing)Beijing100083China

To investigate the mechanism of rockburst prevention by spraying water onto the surrounding rocks,15 experiments are performed considering different water absorption levels on a single ***-speed photography and acoustic emission(AE)system are used to monitor the rockburst *** effect of water on sandstone rockburst and the prevention mechanism of water on sandstone rockburst are analyzed from the perspective of energy and failure *** results show that the higher the ab-sorption degree,the lower the intensity of the rockburst after absorbing water on single side of *** is reflected in the fact that with the increase in the water absorption level,the ejection velocity of rockburst fragments is smaller,the depth of the rockburst pit is shallower,and the AE energy is *** the water absorption level of 100%,the magnitude of rockburst intensity changes from medium to *** prevention mechanism of water on sandstone rockburst is that water reduces the capacity of sandstone to store strain energy and accelerates the expansion of shear cracks,which is not conducive to the occurrence of plate cracking before rockburst,and destroys the conditions for rockburst incubation.

关键词： Rockburst Water Prevention effect Crack evolution

Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes

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Chinese Chemical Letters 2024年第6期35卷 146-154页

作者： Shili Wang Mamitiana Roger Razanajatovo Xuedong Du Shunli Wan Xin He Qiuming Peng Qingrui Zhang State key laboratory of Metastable Materials Science and technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseYanshan UniversityQinhuangdao 066004China Hebei key laboratory of Agroecological Safetye key laboratory Hebei University of Environmental EngineeringQinhuangdao 066102China College of Life&Environment Sciences Huangshan UniversityHuangshan 245041China

In some industrial wastewater,heavy metals combine with organic complexing agents to form heavy metal complexes(HMCs).These HMCs can be difficult to decompose and remove through conventional techniques due to their higher stability than free heavy metal *** recent years,persulfate based advanced oxidation processes(PS-based AOPs)have been recognized as a viable technique for HMCs ***,a comprehensive and in-depth understanding of the relevant HMCs decomplexation mechanisms in PS-based AOPs is still *** review delineates the current progress of HMCs decomplexation in PS-based *** discuss the distinctions between the two widely used oxidant types in PS-based AOPs ***,we summarize and highlight the decomplexation mechanisms based on electron and energy transfer,and degradation pathways of *** also emphasize the effects of environmental water constituents,namely p H,inorganic ions,and natural organic matter(NOM),on HMCs ***,we identify the existing challenges and perspectives that will steer the direction of advancing PS-based AOPs to remove HMCs.

关键词： Heavy metal complexes Persulfate Advanced oxidation processes Decomplexation mechanisms Electron and energy transfer

Instability mechanism of mining roadway passing through fault at different angles in kilometre-deep mine and control measures of roof cutting and NPR cables

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Journal of Mountain Science 2024年第1期21卷 236-251页

作者： SUN Xiaoming WANG Jian ZHAO Wenchao MING Jiang ZHANG Yong LI Zhihu MIAO Chengyu GUO Zhibiao HE Manchao State key laboratory for Geomechanics and deep Underground Engineering China University of Mining and Technology(Beijing)Beijing 100083China School of Mechanics and Civil Engineering China University of Mining and Technology(Beijing)Beijing 100083China

The angle α between the fault strike and the axial direction of the roadway produces different damage characteristics. In this paper, the research methodology includes theoretical analyses, numerical simulations and field experiments in the context of the Daqiang coal mine located in Shenyang, China. The stability control countermeasure of "pre-splitting cutting roof + NPR anchor cable"(PSCR-NPR) is simultaneously proposed. According to the different deformation characteristics of the roadway, the faults are innovatively classified into three types, with α of type I being 0°-30°, α of type II being 30°-60°, and α of type III being 60°-90°. The full-cycle stress evolution paths during mining roadway traverses across different types of faults are investigated by numerical simulation. Different pinch angles α lead to high stress concentration areas at different locations in the surrounding rock. The non-uniform stress field formed in the shallow surrounding rock is an important reason for the instability of the roadway. The pre-cracked cut top shifted the high stress region to the deep rock mass and formed a low stress region in the shallow rock mass. The high prestressing NPR anchor cable transforms the non-uniform stress field of the shallow surrounding rock into a uniform stress field. PSCR-NPR is applied in the fault-through roadway of Daqiang mine. The low stress area of the surrounding rock was enlarged by 3-7 times, and the cumulative convergence was reduced by 45%-50%. It provides a reference for the stability control of the deep fault-through mining roadway.

关键词： Kilometre-deep mine Fault Mining roadway Failure mechanism Pre-splitting cutting roof High pre-stress NPR anchor cable

A whole process damage constitutive model for layered sandstone under uniaxial compression based on Logistic function

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Journal of Central South University 2024年第7期31卷 2411-2430页

作者： LIU Dong-qiao GUO Yun-peng LING Kai LI Jie-yu State key laboratory for Geomechanics and deep Underground Engineering China University of Mining and Technology-BeijingBeijing 100083China School of Mechanics and Civil Engineering China University of Mining and Technology-BeijingBeijing 100083China

Bedding structural planes significantly influence the mechanical properties and stability of engineering rock *** study conducts uniaxial compression tests on layered sandstone with various bedding angles(0°,15°,30°,45°,60°,75°and 90°)to explore the impact of bedding angle on the deformational mechanical response,failure mode,and damage evolution processes of *** develops a damage model based on the Logistic equation derived from the modulus’s degradation considering the combined effect of the sandstone bedding dip angle and *** model is employed to study the damage accumulation state and its evolution within the layered rock *** research also introduces a piecewise constitutive model that considers the initial compaction characteristics to simulate the whole deformation process of layered sandstone under uniaxial *** results revealed that as the bedding angle increases from 0°to 90°,the uniaxial compressive strength and elastic modulus of layered sandstone significantly decrease,slightly increase,and then decline *** corresponding failure modes transition from splitting tensile failure to slipping shear failure and back to splitting tensile *** indicated by the modulus’s degradation,the damage characteristics can be categorized into four stages:initial no damage,damage initiation,damage acceleration,and damage deceleration *** theoretical damage model based on the Logistic equation effectively simulates and predicts the entire damage evolution ***,the theoretical constitutive model curves closely align with the actual stress−strain curves of layered sandstone under uniaxial *** introduced constitutive model is concise,with fewer parameters,a straightforward parameter determination process,and a clear physical *** study offers valuable insights into the theory of layered rock mechanics and holds implications for ensuring the safety of rock engineering.

关键词： layered sandstone uniaxial compression damage evolution Logistic function constitutive model

Parboiled rice supplementation alleviates high-fat diet-induced hyperlipidemia by regulating genes and gut microbiota in mice

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Food Science and Human Wellness 2024年第3期13卷 1422-1438页

作者： Xiuxiu Wu Tianyi Guo Biao Li Shuai Han Zuomin Hu Yi Luo Dandan Qin Yaping Zhou Feijun Luo Qinlu Lin National Research Center of Rice deep Process and Byproducts Hunan Provincial Key Laboratory of Grain-oil Deep Process and Quality ControlHunan Provincial Key Laboratory of Forestry Edible Resources Safety and ProcessingCentral South University of Forestry and TechnologyChangsha 410004China College of Life Science and technology Central South University of Forestry and TechnologyChangsha 410004China Department of Clinical Medicine Medical College of XiangyaCentral South UniversityChangsha 410008China

Dietary parboiled rice(PR)has a low risk of disease,but little is known about the contribution of PR to the prevention of *** potential role and underlying mechanisms of PR in hyperlipidemia were evaluated in this *** C57BL/6J mice were fed with a normal diet,high-fat diet(HFD)containing refined rice(HFDRR)or PR(HFDPR).It was found that PR intervention improved lipid accumulation in *** data analysis revealed that 27 genes were up-regulated(mostly involved in lipid breakdown)and 86 genes were down-regulated(mostly involved in inflammatory responses)in the HFDPR group compared to the HFDRR *** 15 differentially expressed genes(DEGs)were validated by quantitative real-time PCR(RT-qPCR),while protein interaction network showed that protein tyrosine phosphatase receptor type C(PTPRC)has a central *** gut microbiota of mice was also altered after different dietary treatments,with higher ratio of Firmicutes and Bacteroidetes,increased abundances of Ruminococcaceae,Lachnospiraceae,Christensenellaceae,Porphyromonadaceae,Rikenellaceae and Prevotellaceae,and decreased abundances of Lactobacillaceae,Peptostreptococcaceae,Erysipelotrichaceae and Actinobacteria in the HFDRR *** addition,it was observed that PPAR signaling pathway may act as a bridge between DEGs and differential gut *** results suggested that PR can prevent hyperlipidemia by modulating liver genes and gut microbiota.

关键词： Parboiled rice Blood lipids Transcriptome Gut microbiota PPAR Signaling pathway