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Novel titanium vanadate with superior Naþtransport kinetics for rapid charging and low-temperature sodium ion batteries

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Green Energy & Environment 2025年第2期10卷 374-381页

作者： Dan Lv Liehao Wei Cheng Wang Mingyue Wang Zhongchao Bai Yameng Fan Dongdong Wang Nana Wang Jian Yang key laboratory of Advanced Ceramics and Machining Technology(ministry of education) School of Materials Science and EngineeringTianjin UniversityTianjin300072China key laboratory of colloid and interface chemistry Ministry of EducationSchool of Chemistry and Chemical EngineeringShandong UniversityJinan250100China Tianjin key Lab of Indoor Air Environmental Quality Control School of Environmental Science and TechnologyTianjin UniversityTianjin300072China Institute for Superconducting and Electronic Materials University of WollongongWollongongAustralia Institute of Energy Materials Science(IEMS) University of Shanghai for Science and Technology516 Jungong RoadShanghai200093China

Sodium-ion batteries(SIBs)hold great promise for large-scale energy storage in the post-lithium-ion battery era due to their high rate performance and long lifespan,although their sluggish Naþtransformation kinetics still require *** by the excellent electrochemical performance of titanium-based anode materials,here,we present a novel titanium vanadate@carbon(TVO@C)material as anode for *** TVO@C material is synthesized via a facile coprecipitation method,with the following annealing process in an acetylene *** opened ion channel and the oxygen vacancies within TVO@C facilitate the diffusion of Naþions,reducing their diffusion ***,an ultrahigh rate of 100 A g^(-1)and long life of 10,000 cycles have been ***,the TVO@C electrode exhibits stable performance,not only at room temperature,but also at temperatures as low as 20 *** TVO@CjjNa_(3)V_(2)(PO_(4))_(3)@C full cells have also achieved stable discharge/charge for 500 *** is believed that this strategy provides new insight into the development of advanced electrodes and provides a new opportunity for constructing novel high rate electrodes.

关键词： Anode High rate Titanium vanadate Sodium ion batteries

Barrierless reactions of C2 Criegee intermediates with H_(2)SO_(4)and their implication to oligomers and new particle formation

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Journal of Environmental Sciences 2025年第3期149卷 574-584页

作者： Yang Cheng Chao Ding Tianlei Zhang Rui Wang Ruxue Mu Zeyao Li Rongrong Li Juan Shi Chongqin Zhu Institute of Theoretical and Computational chemistry Shaanxi Key Laboratory of CatalysisSchool of Chemical&Environment ScienceShaanxi University of TechnologyHanzhongShaanxi 723001China College of chemistry Key Laboratory of Theoretical&Computational Photochemistry of Ministry of EducationBeijing Normal UniversityBeijing 100190China

The formation of oligomeric hydrogen peroxide triggered by Criegee intermediate maybe contributes significantly to the formation and growth of secondary organic aerosol(SOA).However,to date,the reactivity of C2 Criegee intermediates(CH_(3)CHOO)in areas contaminated with acidic gas remains poorly ***,high-level quantum chemical calculations and Born-Oppenheimer molecular dynamics(BOMD)simulations are used to explore the reaction of CH_(3)CHOO and H_(2)SO_(4)both in the gas phase and at the airwater *** the gas phase,the addition reaction of CH_(3)CHOO with H_(2)SO_(4)to generate CH_(3)HC(OOH)OSO_(3)H(HPES)is near-barrierless,regardless of the presence of water *** simulations showthat the reaction at the air-water interface is even faster than that in the gas *** calculations reveal that the HPES has a tendency to aggregate with sulfuric acids,ammonias,and water molecules to form stable clusters,meanwhile the oligomerization reaction of CH_(3)CHOO with HPES in the gas phase is both thermochemically and kinetically ***,it is noted that the interfacial HPES−ion can attract H_(2)SO_(4),NH_(3),(COOH)_(2)and HNO_(3)for particle formation from the gas phase to the water ***,the results of this work not only elucidate the high atmospheric reactivity of C2 Criegee intermediates in polluted regions,but also deepen our understanding of the formation process of atmospheric SOA induced by Criegee intermediates.

关键词： Criegee intermediates H_(2)SO_(4) Atmospheric behavior Air-water interface Chemical processes

Soil colloids can significantly enhance spreading of polybromodiphenyl ethers in groundwater by serving as an effective carrier

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Journal of Environmental Sciences 2025年第1期147卷 93-100页

作者： Lin Duan Min Li Jiameng Liu Wei Chen College of Environmental Science and Engineering Ministry of Education Key Laboratory of Pollution Processes and Environmental CriteriaTianjin Key Laboratory of Environmental Remediation and Pollution ControlNankai UniversityTianjin 300350China

Polybromodiphenyl ethers(PBDEs),the widely used flame retardants,are common contaminants in surface soils at e-waste recycling *** association of PBDEs with soil colloids has been observed,indicating the potential risk to groundwater due to colloid-facilitated ***,the extent to which soil colloidsmay enhance the spreading of PBDEs in groundwater is largely ***,we report the co-transport of decabromodiphenyl ester(BDE-209)and soil colloids in saturated porous *** colloids released froma soil sample collected at an e-waste recycling site in Tianjin,China,contain high concentration of PBDEs,with BDE-209 being the most abundant conger(320±30 mg/kg).The colloids exhibit relatively high mobility in saturated sand columns,under conditions commonly observed in groundwater ***,under all the tested conditions(i.e.,varying flow velocity,pH,ionic species and ionic strength),the mass of eluted BDE-209 correlates linearly with that of eluted soil colloids,even though the mobility of the colloids varies markedly depending on the specific hydrodynamic and solution chemistry conditions ***,the mass of BDE-209 retained in the columns also correlates strongly with themass of retained ***,the PBDEs remain bound to soil colloids during transport in porous *** in this study indicate that soil colloidsmay significantly promote the transport of PBDEs in groundwater by serving as an effective *** might be the reason why the highly insoluble and adsorptive PBDEs are found in groundwater at some PBDE-contaminated sites.

关键词： Polybromodiphenyl ethers Soil colloids E-waste recycling sites Groundwater Facilitated transport

Transforming waste particles into valuable adsorbents via amyloid-mediated molecular engineering

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Science China chemistry 2025年第1期68卷 317-328页

作者： Qingmin Yang Jian Zhao Yujia Zhang Xingyu Zhou Hao Ren Bowen Hu Zhongli Lei Lixin Chen Peng Yang key laboratory of Applied Surface and colloid chemistry Ministry of EducationSchool of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China School of Material and Chemical Engineering Bengbu UniversityBengbu 233030China Anhui Provincial Engineering laboratory of Silicon-Based Materials Bengbu 233030China Xi’an key laboratory of Polymeric Soft Matter School of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China International Joint Research Center on Functional Fiber and Soft Smart Textile School of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China School of chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi’an 710129China

The high-value utilization of industrial solid waste using a facile and eco-friendly process is of great interest and significance in reducing environmental pollution and developing a green circular ***,we propose an amyloid-mediated molecular engineering strategy to transform particulate waste into valuable adsorbents for metal *** method has the advantage of aqueous solution fabrication under mild conditions without the use of high-temperature hydrothermal methods and toxic chemical ***-mediated molecular engineering manipulates the phase transition of bovine serum albumin(BSA)on particulate waste surfaces,resulting in a remarkable~3.1 times improvement in the adsorption capacity of fly ash,a typical industrial solid waste for gold ions after modification with the phase-transitioned BSA(PTB).The resultant adsorption ability was 69–1,980 times higher than those of conventional and emerging adsorbent materials such as ion exchange resins,activated carbon(AC),covalent organic frameworks(COFs),and metal-organic frameworks(MOFs).We further demonstrated the application of our PTB-modified materials in the recovery of precious metals from low-grade gold ore and electronic waste ***,this strategy could increase the value of waste materials nearly 27 *** addition,this method is generally extendable to other conventional industrial adsorbents such as resin,clay,and Al_(2)O_(3),and enhances their adsorption capabilities at least ***,this work provides a simple and green approach for improving the adsorption performance of solid particles,and is expected to develop into a universal strategy for transforming waste particles into high-value-added products.

关键词： amyloid-like protein aggregates surface engineering fly ash solid waste adsorption

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Exfoliated metal oxide ultrathin nanosheets with supported Pd nanoparticles enabling the one-pot reaction of phenol into caprolactam

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Science China chemistry 2025年

作者： Xiaomeng Cheng Bingfeng Chen Lei Zhang Tianjiao Wang Sen Luan Yang Sun Huizhen Liu Buxing Han Beijing National laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and Thermodynamics CAS Research/Education Center for Excellence in Molecular Sciences Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences School of chemistry and Chemical Engineering University of Chinese Academy of Sciences Shanghai key laboratory of Green chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular & Process EngineeringSchool of Chemistry and Molecular Engineering East China Normal University

Two-dimensional（2D） oxide nanomaterials have great potential for various applications but face challenges due to strong interlayer interactions. In this work, we propose a novel and facile method to exfoliate layered transition metal oxides into ultrathin nanosheets functionalized with phosphate species by the combination of ball-milling and liquid-exfoliation with phosphoric acid. The resulting HNbMoO6nanosheets with supported Pd nanoparticles displayed excellent catalytic performance in the one-pot conversion of phenol into caprolactam（CPL）, achieving a yield of up to 71.9%. This one-pot route avoids the energy-intensive intermediate separation process in conventional multi-step approaches to CPL. The superior catalytic performance of the catalysts is attributed to the tunable Br?nsted acid/Lewis acid ratio and readily accessible active sites on the ultrathin nanosheets. This research demonstrates a new methodology for constructing ultrathin nanosheets and preparing bifunctional catalysts for tandem reactions, which opens the way for one-pot production of CPL.

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Hybrid conductive-lithophilic-fluoride triple protection interface engineering:Dendrite-free reverse lithium deposition for high-performance lithium metal batteries

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Journal of Energy chemistry 2025年第2期101卷 416-428页

作者： Huiying Li Chang Hong Runming Tao Xiaolang Liu Jianxing Wang Jianyu Chen Shuhao Yao Jiazhi Geng Guang Zheng Jiyuan Liang key laboratory of Optoelectronic Chemical Materials and Devices of ministry of education School of Optoelectronic Materials & Technology Jianghan University Applied Materials Division Argonne National Laboratory State key laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM) Nanjing University of Posts & Telecommunications

Lithium metal batteries（LMBs） with high energy density are impeded by the instability of solid electrolyte interface（SEI） and the uncontrolled growth of lithium（Li） *** mitigate these challenges,optimizing the SEI structure and Li deposition behavior is the key to stable *** study novelty proposes a facile synthesis of MgF2/carbon（C） nanocomposite through the mechanochemical reaction between metallic Mg and polytetrafluoroethylene（PTFE） powders,and its modified polypropylene（PP）separator enhances LMB *** in-situ formed highly conductive fluorine-doped C species play a crucial role in facilitating ion/electron transport,thereby accelerating electrochemical kinetics and altering Li deposition *** cycling,the in-situ reaction between MgF2and Li leads to the formation of LiMg alloy,along with a LiF-rich SEI layer,which reduces the nucleation overpotential and reinforces the interphase strength,leading to homogeneous Li deposition with dendrite-free *** from these merits,the Li metal is densely and uniformly deposited on the MgF2/C@PP separator side rather than on the current collector ***,the symmetric cell with MgF2/C@PP exhibits superb Li plating/stripping performance over 2800 h at 1 mA cm-2and 2 mA h *** importantly,the assembled Li@MgF2/C@PPILiFePO4full cell with a low negative/positive ratio of 3.6delivers an impressive cyclability with 82.7% capacity retention over 1400 cycles at 1 C.

关键词： Lithium metal batteries Mechanochemical reaction MgF2 Reverse deposition Separator modification

Boosting charge extraction and efficiency of inverted perovskite solar cells through coordinating group modification at the buffer layer/cathode interface

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Nano Research 2025年第1期18卷 415-423页

作者： Zhiqing Liang Ziqiu Ren Ziyu Wang Nan Yan Ling Li Bo Zhang Yanlin Song College of chemistry Zhengzhou UniversityZhengzhou 450052China key laboratory of Applied Surface and colloid chemistry ministry of education Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China key laboratory of Green Printing Institute of ChemistryChinese Academy of Sciences(ICCAS)Beijing Engineering Research Center of Nanomaterials for Green Printing TechnologyNational Laboratory for Molecular Sciences(BNLMS)Beijing 100190China

In inverted perovskite solar cells (PSCs),effective modification of the interface between the metalcathode and electron transport layer (ETL) is crucial forachieving high performance and stability. Herein, sulfonatedbathocuproine, commonly known as disodium bathocuproinedisulfonate (BCDS), was employed as a cathode buffer layerto address the interfacial issues at the [6,6]-phenyl-C61-butyricacid methyl ester (PCBM)/Ag interface. BCDS possesses theability to form coordinate bonds with Ag electrodes. Theutilization of the BCDS buffer layer enhanced the chargeextraction capability at the cathode interface whilesimultaneously achieving interfacial defect passivation,improving interfacial contact and increasing the built-in electricfield. Consequently, a power conversion efficiency (PCE) of25.06% was achieved. Furthermore, owing to the excellent filmforminguniformity of BCDS on PCBM, the stability of thedevice was also improved. After storage in dry air for morethan 2000 h, the device maintained 96% of its initial efficiency. This work underscores the remarkable potential of tailoringcoordination groups to enhance charge extraction efficiency at the ETL-cathode interface, unveiling a promising newfrontier in buffer layer development and performance optimization strategies for PSCs.

关键词： perovskite solar cells buffer layer bathocuproine disulfonate coordination group modification electron transport layer(ETL)-cathode interface

Efficient and Stable Photoassisted Lithium‑Ion Battery Enabled by Photocathode with Synergistically Boosted Carriers Dynamics

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Nano-Micro Letters 2025年第3期17卷 440-454页

作者： Zelin Ma Shiyao Wang Zhuangzhuang Ma Juan Li Luomeng Zhao Zhihuan Li Shiyuan Wang Yazhou Shuang Jiulong Wang Fang Wang Weiwei Xia Jie Jian Yibo He Junjie Wang Pengfei Guo Hongqiang Wang State key laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi’an 710072People’s Republic of China State key laboratory of Solidification Processing School of Materials Science and Engineering DepartmentNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China State key laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China Research and Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518063People’s Republic of China key laboratory of Applied Surface and colloid chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi’an 710119People’s Republic of China

Efficient and stable photocathodes with versatility are of significance in photoassisted lithium-ion batteries(PLIBs),while there is always a request on fast carrier transport in electrochemical active *** work proposes a general approach of creating bulk heterojunction to boost the carrier mobility of photocathodes by simply laser assisted embedding of plasmonic *** employed in PLIBs,it was found effective for synchronously enhanced photocharge separation and transport in light charging ***,experimental photon spectroscopy,finite difference time domain method simulation and theoretical analyses demonstrate that the improved carrier dynamics are driven by the plasmonic-induced hot electron injection from metal to TiO_(2),as well as the enhanced conductivity in TiO2 matrix due to the formation of oxygen vacancies after Schottky *** from these merits,several benchmark values in performance of TiO2-based photocathode applied in PLIBs are set,including the capacity of 276 mAh g^(−1) at 0.2 A g^(−1) under illumination,photoconversion efficiency of 1.276%at 3 A g^(−1),less capacity and Columbic efficiency loss even through 200 *** results exemplify the potential of the bulk heterojunction strategy in developing highly efficient and stable photoassisted energy storage systems.

关键词： Photoassisted lithium-ion batteries Bulk heterojunction Carrier dynamics TiO2 nanofiber Plasmonic metal nanocrystals

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Buried interface bridging for inverted cesium-formamidinium triiodide perovskite solar cells with long operational stability

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Science China chemistry 2025年第1期68卷 163-173页

作者： Chenhui Zhang Chunjun Liang Fulin Sun Ting Zhu Xinghai Huang Yuzhu Guo Xinyu Guo Kunyang Ge Dan Li Fangtian You Zhiqun He key laboratory of Luminescence and Optical Information Ministry of EducationInstitute of Optoelectronic TechnologyBeijing Jiaotong UniversityBeijing 100044China Department of Physics School of Physical Science and EngineeringBeijing Jiaotong UniversityBeijing 100044China

In the field of perovskite solar cells(PSCs),the research on defects in the buried interface has been relatively limited due to its non-exposure;however,this interface significantly impacts the performance enhancement of inverted *** study employs phenylethylammonium chloride(PEACl)molecules as a buffer layer to modify the buried interface of p-i-n structured PSCs,aiming to enhance the uniformity of self-assembled monolayers(SAMs)and facilitate the uniform nucleation and growth of perovskite films on the ***,the introduction of the PEACl buffer layer effectively passivates defects at the bottom of the perovskite layer and notably enhances the crystal quality of the perovskite film by mitigating residual stress,thereby reducing nonradiative recombination *** these optimizations,the MA-free PSCs treated with PEACl achieve a power conversion efficiency(PCE)of 24.11%,with significant improvements in storage,thermal stability,and operational *** noteworthy is the device's performance in an unencapsulated state,whereas after 1,500 hours of continuous light operation stability testing,it retains 97%of its original *** study not only enriches the systematic understanding of the characteristics of the buried interface in PSCs but also contributes significantly to advancing the commercial production of perovskite photovoltaic technology.

关键词： defect-induced recombination buried interfaces inverted perovskite solar cells crystallization lattice mismatch

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