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Hydrogen release of NaBH_(4) below 60 ℃ with binary eutectic mixture of xylitol and erythritol additive

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Chinese Journal of Chemical Engineering 2024年第7期71卷 225-234页

作者： Yugang Shu Jiaguang Zheng Chengguo Yan Ao Xia Meiling Lv Zhenxuan Ma Zhendong Yao School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China key laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China College of Materials and Chemistry China Jiliang UniversityHangzhou 310018China

NaBH_(4) was widely regarded as a low-cost hydrogen storage material due to its high-mass hydrogen capacity of approximately 10.8%(mass)and high volumetric hydrogen capacity of around 115 g·L^(–1).However,it exhibits strong stability and requires temperatures above 500℃ for hydrogen release in practical *** this study,two polyhydric alcohols,xylitol and erythritol(XE),were prepared as a binary eutectic sugar alcohol through a grinding-melting *** binary eutectic sugar alcohol was used as a proton-hydrogen carrier to destabilize NaBH_(4).The 19NaBH_(4)-16XE composite material prepared by ball milling could start releasing hydrogen at 57.5℃,and the total hydrogen release can reach over 88.8%(4.45%(mass))of the theoretical *** the 19NaBH_(4)-16XE composite was pressed into solid blocks,the volumetric hydrogen capacity of the block-shaped composite could reach 67.2 g·L^(–1).By controlling the temperature,the hydrogen desorption capacity of the NaBH_(4)-XE composite material was controllable,which has great potential for achieving solid-state hydrogen production from NaBH_(4).

关键词： Hydrogen Desorption Binary mixture NaBH_(4) Xylitol Erythritol

Ant-nest-inspired porous structure for MXene composites with high-performance energy-storage and actuating multifunctions

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Nano Research 2024年第7期17卷 6673-6685页

作者： Yi Wang Guanfeng Xue Zhiling Luo Wei Zhang Luzhuo Chen Fujian Provincial key laboratory of Quantum Manipulation and New Energy Materials College of Physics and EnergyFujian Normal UniversityFuzhou 350117China Fujian Provincial Collaborative Innovation Center for Advanced High-Field Superconducting Materials and Engineering Fuzhou 350117China

Integrating energy-storage devices(supercapacitors)and shape-deformation devices(actuators)advances the miniaturization and multifunctional development of soft ***,soft robots necessitate supercapacitors with high energy-storage performance and actuators with excellent actuation ***,inspired by ant nests,we present a porous structure fabricated by MXene-graphene-methylcellulose(M-GMC)composite,which overcomes the self-stacking of MXene nanosheets and offers a larger specific surface *** porous structure provides more channels and active sites for electrolyte ions,resulting in high energy storage *** areal capacitance of the M-GMC electrode reaches up to 787.9 mF·cm^(−2),significantly superior to that of the pristine MXene electrode(449.1 mF·cm^(−2)).Moreover,the M-GMC/polyethylene bilayer composites with energy storage and multi-responsive actuation functions are *** M-GMC is used as the electrode and the polyethylene is used as the encapsulation layer of the quasi-solid-state ***,the actuators fabricated by the bilayer composites can be driven by light or low voltage(≤9 V).The maximum bending curvature is up to 5.11 cm^(−1).Finally,a smart gripper and a fully encapsulated smart integrated circuit based on the M-GMC/polyethylene are *** smart gripper enables programmable control with multi-stage *** applications realize the intelligence and miniaturization of soft *** ant-nest-inspired M-GMC composites would provide a promising development strategy for soft robots and smart integrated devices.

关键词： MXene graphene ant nest supercapacitor actuator multi-functional

Temperature-controlled DCP Fluorescent Probe Based on Hydrogel-immobilized Quantum Dots Composite

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Journal of Wuhan University of Technology(Materials Science) 2024年第4期39卷 931-936页

作者：童伊琳杨坤 HAN Xuecai YU Kan BAO Jiaqi Faculty Information Science and Technology Wenhua CollegeWuhan 430074China State key laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430074China Yangtze Optical Fibre and Cable Joint Stock Limited Company Wuhan 430074China

A composite was created by incorporating the quantum dot-enhanced SiO_(2)nanoparticles within this *** on this composite,a temperature-controlled fluorescent probe for DCP was developed.A meticulous examination of this probe revealed its attributes and factors affecting its *** using temperature modulation,the probe was adept at detecting DCP concentrations ranging between 1.0×10^(-6)and 9.0×10^(-6)mol/*** a probe offers remarkable selectivity,repeatability,and robust stability,so that the detection of DCP can be carried out at different temperatures,and a fast,reliable,sensitive and low-cost intelligent detection method is realized.

关键词： temperature-controlled fluorescent probe hydrogel-immobilized quantum dots composite DCP

ALKBH5 gene polymorphisms and risk of neuroblastoma in Chinese children from Jiangsu province

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Cancer Innovation 2024年第2期3卷 72-79页

作者： Qian Guan Xinxin Zhang Jiabin Liu Chunlei Zhou Jinhong Zhu Haiyan Wu Zhenjian Zhuo Jing He Department of Pediatric Surgery Guangzhou Institute of PediatricsGuangdong Provincial Key Laboratory of Research in Structural Birth Defect DiseaseGuangdong Provincial Clinical Research Center for Child HealthGuangzhou Women and Children's Medical CenterGuangzhou Medical UniversityGuangzhouGuangdongChina Department of Pathology Children's Hospital of Nanjing Medical UniversityNanjingJiangsuChina Department of Clinical laboratory BiobankHarbin Medical University Cancer HospitalHarbinHeilongjiangChina laboratory Animal Center School of Chemical Biology and BiotechnologyPeking University Shenzhen Graduate SchoolShenzhenGuangdongChina

Background:Neuroblastoma is one of the most common extracranial malignant solid tumors in *** homolog 5(ALKBH5)is an RNA N6-methyladenosine(m6A)demethylase that plays a critical role in tumorigenesis and *** assessed the association between single nucleotide polymorphisms(SNPs)in ALKBH5 and the risk of neuroblastoma in a case-control study including 402 patients and 473 non-cancer ***:Genotyping was determined by the TaqMan *** association between ALKBH5 polymorphisms(rs1378602 and rs8400)and the risk of neuroblastoma was evaluated using the odds ratio(OR)and 95%confidence interval(CI).Results:We found no strong association of ALKBH5 rs1378602 and rs8400 with neuroblastoma *** stratification analysis by age,sex,primary site,and clinical stage showed that the rs1378602 AG/AA genotype was associated with a lower risk of neuroblastoma in males(adjusted OR=0.58,95%CI=0.35–0.97,p=0.036)and children with retroperitoneal neuroblastoma(adjusted OR=0.58,95%CI=0.34–0.98,p=0.040).Conclusions:ALKBH5 SNPs do not seem to be associated with neuroblastoma *** studies are required to confirm this negative result and reveal the relationship between gene polymorphisms of the m6A modifier ALKBH5 and neuroblastoma.

关键词： ALKBH5 neuroblastoma polymorphism susceptibility

Morphological analysis for thermodynamics of cavitation collapse near fractal solid wall

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Chinese Physics B 2024年第6期33卷 422-432页

作者：单鸣雷杨雨阚雪芬殷澄韩庆邦 Jiangsu key laboratory of Power Transmission and Distribution Equipment Technology Hohai UniversityChangzhou 213022China College of Information Science and Technology Nanjing Forestry UniversityNanjing 210000China Department of Transportation Engineering Jiangsu Shipping CollegeNantong 226000China

A fractal geometric boundary with natural wall features is introduced into a hybrid lattice-Boltzmann-method(LBM)multiphase model. The physical model of cavitation bubble collapse near the irregular geometric wall is established to study the thermodynamic characteristics of the bubble collapse. Due to the lack of periodicity, symmetry, spatial uniformity and obvious correlation in the LBM simulation of the bubble collapse near the fractal wall, the morphological analysis based on Minkowski functional is introduced into the thermodynamic investigation of cavitation bubble so as to analyze and obtain the effective information. The results show that the Minkowski functional method can employed to study the temperature information in complex physical fields hierarchically and quantitatively. The high/low temperature region of the cavitation flow is explored, and thermal effect between irregular and fractal geometric wall and cavitation bubble can be revealed. It illustrates that LBM and morphological analysis complement each other, and morphological analysis can also be used as an optional and potential tool in research field of complex multiphase flows.

关键词： lattice Boltzmann method cavitation bubble morphological analysis

Structure-regulated fluorine-containing additives to improve the performance of perovskite solar cells

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Nano Research 2024年第7期17卷 6080-6086页

作者： Peiya Chen Xiaoman Bi Hao Yan Yingjie Zhao Yihao Liu Zhuo Huang Qian Xiao Yongpeng Yang Shasha Zhang Yiqiang Zhang Yanlin Song Henan Institute of Advanced Technology College of ChemistrySchool of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China key laboratory of Green Printing CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of Sciences(ICCAS)Beijing Engineering Research Center of Nanomaterials for Green Printing TechnologyNational Laboratory for Molecular Sciences(BNLMS)Beijing 100190China

Perovskite solar cells(PSCs)have seen remarkable progress in recent years,largely attributed to various additives that enhance both efficiency and *** these,fluorine-containing additives have garnered significant interest because of their unique hydrophobic properties,effective defect passivation,and regulation capability on the crystallization ***,a targeted structural approach to design such additives is necessary to further enhance the performance of ***,fluoroalkyl ethylene with different fluoroalkyl chain lengths(CH_(2)CH(CF_(2))nCF_(3),n=3,5,and 7)as liquid additives is used to investigate influences of fluoroalkyl chain lengths on crystallization regulation and defect *** findings indicate that optimizing the quantity of F groups plays a crucial role in regulating the electron cloud distribution within the additive *** optimization fosters strong hydrogen bonds and coordination effects with FA+and uncoordinated Pb^(2+),ultimately enhancing crystal quality and device ***,1H,1H,2H-perfluoro-1-hexene(PF_(3))with the optimal number of F presents the most effective modulation effect.A PSC utilizing PF_(3)achieves an efficiency of 24.05%,and exhibits exceptional stability against humidity and thermal *** work sheds light on the importance of tailored structure designs in additives for achieving high-performance PSCs.

关键词： perovskite solar cells fluorine number additive structure crystallization regulation defect passivation

Combined UAMP and MF Message Passing Algorithm for Multi-Target Wideband DOA Estimation with Dirichlet Process Prior

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Tsinghua Science and Technology 2024年第4期29卷 1069-1081页

作者： Shanwen Guan Xinhua Lu Ji Li Rushi Lan Xiaonan Luo Guangxi key laboratory of Image and Graphic Intelligent Processing Guilin University of Electronic TechnologyGuilin 541004China Guilin Huigu Institute of AI Industrial Technology Guilin 541004China School of Information Engineering Nanyang Institute of TechnologyNanyang 473000China

When estimating the direction of arrival (DOA) of wideband signals from multiple sources, the performance of sparse Bayesian methods is influenced by the frequency bands occupied by signals in different directions. This is particularly true when multiple signal frequency bands overlap. Message passing algorithms (MPA) with Dirichlet process (DP) prior can be employed in a sparse Bayesian learning (SBL) framework with high precision. However, existing methods suffer from either high complexity or low precision. To address this, we propose a low-complexity DOA estimation algorithm based on a factor graph. This approach introduces two strong constraints via a stretching transformation of the factor graph. The first constraint separates the observation from the DP prior, enabling the application of the unitary approximate message passing (UAMP) algorithm for simplified inference and mitigation of divergence issues. The second constraint compensates for the deviation in estimation angle caused by the grid mismatch problem. Compared to state-of-the-art algorithms, our proposed method offers higher estimation accuracy and lower complexity.

关键词： wideband direction of arrival(DOA)estimation sparse Bayesian learning(SBL) unitary approximate message passing(UAMP)algorithm Dirichlet process(DP)

A robust tensor watermarking algorithm for diffusion-tensor images

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Frontiers of Information Technology & Electronic Engineering 2024年第3期25卷 384-397页

作者： Chengmeng LIU Zhi LI Guomei WANG Long ZHENG State key laboratory of Public Big Data College of Computer Science and TechnologyGuizhou UniversityGuiyang 550025China

Watermarking algorithms that use convolution neural networks have exhibited good robustness in studies of deep learning ***,after embedding watermark signals by convolution,the feature fusion eficiency of convolution is relatively low;this can easily lead to distortion in the embedded *** distortion occurs in medical images,especially in diffusion tensor images(DTIs),the clinical value of the DTI is *** address this issue,a robust watermarking algorithm for DTIs implemented by fusing convolution with a Transformer is proposed to ensure the robustness of the watermark and the consistency of sampling distance,which enhances the quality of the reconstructed image of the watermarked DTIs after embedding the watermark *** the watermark-embedding network,Ti-weighted(Tlw)images are used as prior *** correlation between T1w images and the original DTI is proposed to calculate the most significant features from the T1w images by using the Transformer *** maximum of the correlation is used as the most significant feature weight to improve the quality of the reconstructed *** the watermark extraction network,the most significant watermark features from the watermarked DTI are adequately learned by the Transformer to robustly extract the watermark signals from the watermark *** results show that the average peak signal-to-noise ratio of the watermarked DTI reaches 50.47 dB,the diffusion characteristics such as mean diffusivity and fractional anisotropy remain unchanged,and the main axis deflection angleαAc is close to *** proposed algorithm can effectively protect the copyright of the DTI and barely affects the clinical diagnosis.

关键词： Robust watermarking algorithm Transformer Image reconstruction Diffusion tensor images Soft attention Hard attention Tl-weighted images

Syntheses,Structures,and Properties of Two Cobalt(Ⅱ)Coordination Complexes Based on(Fluorene-9,9-diyl)dipropanoic Acid and 1,3-Bis(imidazol-1-yl)butane Ligands

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Chinese Journal of Structural Chemistry 2018年第7期37卷 1139-1145页

作者：田雨滨王梦张文宋楠楠宋新建胡卫兵冯驸 School of Chemical and Environmental Engineering Hubei Institute for Nationalities key laboratory of Biological Resources Protection and Utilization of hubei province Hubei Institute for Nationalities

Two new cobalt（II） coordination complexes, namely [Co（HL）2（biim）（H2O）2]n·n H2O（1） and [Co（Et L）2（biim）]n·3 n（H2O）·2 n（Et HL）（2）（H2L =（fluorene-9,9-diyl）dipropanoic acid, biim = 1,3-bis（imidazol-1-yl）butane）, have been synthesized using the same starting reactants but different solvent medium. The two complexes exhibit distinctly different structures. Compound 1 exhibits a one-dimensional linear chain structure. However, complex 2 reveals a one-dimensional zigzag chain structure. Thermogravimetric analyses（TGA） and luminescent properties of these two complexes have been discussed.

关键词： coordination complexes fluorene luminescent properties