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Evaluation of the binding affinity and antioxidant activity of phlorizin to pepsin and trypsin

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Food Science and Human Wellness 2024年第1期13卷 392-400页

作者： Jing Zhang Lan Tang Xia Hu Zhen Zeng Wen Wu Fang Geng Hui Li Di Wu Meat Processing key laboratory of Sichuan Province School of Food and Biological EngineeringChengdu UniversityChengdu 610106China School of Chemical engineering Sichuan UniversityChengdu 610065China

Phlorizin(PHL)is a natural compound with strong antioxidant properties mainly found in *** this paper,the interaction mechanism of PHL with pepsin and trypsin was comparatively evaluated by computer simulation,fluorescence spectra,circular dichroism(CD),and Fourier transform infrared(FT-IR)spectra at a molecular *** spectra showed that PHL quenches the pepsin/trypsin by static *** parameters indicated that PHL binds to pepsin mainly through hydrogen bonds and van der Waals forces,and that of trypsin was electrostatic *** ground state complexes PHL and protease have a moderate affinity of 105 L/mol PHL binds more strongly to trypsin than to *** and FT-IR spectra results showed that pepsin/trypsin decreased theβ-sheet content and slightly changed its secondary structure upon *** experimental results are mutually verified with the predicted computer-aid simulation *** PHL and trypsin binding,the antioxidant capacity of PHL was ***,the antioxidant capacity of PHL was decreased after binding to *** work elucidates the binding of PHL binding mechanisms to pepsin/trypsin and provides useful information for the digestion of PHL to improve the application of PHL in food processing.

关键词： Interaction Phlorizin Pepsin Trypsin Antioxidation

Study on flow characteristics and phase holdup in a slurry bubble column coupled with mild agitation Author links open overlay panel

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Particuology 2024年第8期91卷 226-234页

作者： Qingyuan An Jiantao Li Lei Zhang Nailiang Wang Pengfei Zhang Zhenghong Luo Chunxi Lu State key laboratory of High-Efficiency Coal Utilization and Green Chemical engineering Ningxia UniversityYinchuan750021China State key laboratory of Heavy Oil Processing College of Chemical Engineering and EnvironmentChina University of Petroleum BeijingBeijing102249China Department of Chemical&biological engineering Monash UniversityVictoria3800Australia

A pilot-scale experimental setup was constructed to investigate the effect of mild agitation on the bubble characteristics and phase holdup in a slurry bubble *** agitation positively impacts the axial uniform distribution of solid holdup,though it shows insignificant influence on the radial *** homogenous regime,mild agitation promotes the coalescence of bubbles,and the effect becomes stronger with increasing agitator *** mild agitation contributes to a decrease in bubble size in heterogeneous flow *** agitation presents a significant effect on the gas holdup by adjusting the bubble size and bubble motion *** modification was introduced to predict the gas holdup considering the effects of mild agitation,a necessary consideration for applications requiring mild *** adapted model predicts gas holdup with a maximum error of 12.9%.

关键词： Slurry bubble column Mild agitation Phase holdup Bubble characteristics

Temperature-dependent solubility of Rebaudioside A in methanol/ethanol and ethyl acetate mixtures:Experimental measurements and thermodynamic modeling

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Chinese Journal of Chemical engineering 2024年第8期72卷 164-176页

作者： Zhenguang Liu Zexiang Ding Yifeng Cao Baojian Liu Qiwei Yang Zhiguo Zhang Qilong Ren Zongbi Bao key laboratory of Biomass Chemical engineering of Ministry of Education College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310058China Institute of Zhejiang University-Quzhou Quzhou 324000China

The equilibrium solubility of Rebaudioside A(Reb A)FormⅡin binary mixtures of methanol/ethanol and ethyl acetate was quantitatively determined within the temperature range of 283.15—328.15 K at ambient *** experimental findings indicate a positive correlation between the solubility of Reb A(FormⅡ)and both the temperature and the methanol/ethanol content in the solvent *** describe the solubility data,six distinct models were employed:the modified Apelblat equation,theλh model,the combined nearly ideal binary solvent/Redlich—Kister(CNIBS/R—K)model,the van't HoffJouyban-Acree(VJA)model,the Apelblat-Jouyban-Acree(AJA)model,and the non-random two-liquid(NRTL)*** combined nearly ideal binary solvent/Redlich—Kister model exhibited the most precise fit for solubility in methanol+ethyl acetate mixtures,reflected by an average relative deviation(ARD)of 0.0011 and a root mean square deviation(RMSD)of 12×10^(-7).Conversely,for ethanol+ethyl acetate mixtures,the modified Apelblat equation provided a superior correlation(ARD=0.0014,RMSD=4×10^(-7)).Furthermore,thermodynamic parameters associated with the dissolution of Reb A(FormⅡ),including enthalpy,entropy,and the Gibbs energy change,were inferred from the *** findings underscore that the dissolution process is predominantly endothermic across the solvent systems ***,the entropy changes appear to have a significant influence on the Gibbs free energy associated with the dissolution of Reb A(FormⅡ),suggesting that entropic factors may play a pivotal role in the studied systems.

关键词： Rebaudioside A Solubility Thermodynamic modeling Dissolution Binary solvent

Cycling performance of layered oxide cathode materials for sodium-ion batteries

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1720-1744页

作者： Jinpin Wu Junhang Tian Xueyi Sun Weidong Zhuang School of Metallurgical and ecological engineering University of Science and Technology BeijingBeijing 100083China State key laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Beijing key laboratory for Green Recovery and Extraction of Rare and Precious Metals University of Science and Technology BeijingBeijing 100083China

Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple *** performance is an important criterion for evaluating the application prospects of ***,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application ***,this review proposes several strategies to address these ***,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion ***,homogeneous surface coating and concentration gradient modification are *** addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are ***,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials.

关键词： sodium-ion battery layered oxide materials cycling performance bulking doping surface coating concentration gradient mixed structure high-entropy

Rapid synthesis of oxygen-defected molybdenum oxides quantum dots as efficient nanozymes for healing diabetic ulcers

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Nano Research 2024年第7期17卷 6376-6385页

作者： Fangjun Cao Hui Feng Jiaxin Yao Xiang Hou Tiezhi Jin Junfeng Hui Shaanxi key laboratory of Qinling ecological Security Shaanxi Institute of ZoologyXi’an 710072China engineering Research Center of Western Resource Innovation Medicine Green Manufacturing Ministry of EducationSchool of Chemical EngineeringNorthwest UniversityXi'an 710069China Shaanxi key laboratory of Degradable Biomedical Materials and Shaanxi R&D Center of Biomaterials and Fermentation engineering School of Chemical EngineeringNorthwest UniversityXi'an 710069China

The continuous inflammatory response in diabetic skin wounds leads to excessive production of reactive oxygen species,which cause a vicious circle of long-term *** the therapeutic research of metal nanoenzymes for healing diabetic ulcers,it still faces the challenges in poor nanoenzymes activity and low-efficient therapeutic ***,ultrasmall oxygen-deficient MoO_(3−X)quantum dots were fabricated and employed as nanoenzymes for healing fiabetic *** PEGylation,PEGylated MoO_(3−X)quantum dots(MoO_(3−X)/PEG)with oxygen vacancies exhibits excellent photothermal,peroxidase/catalase-like *** addition,these MoO_(3−X)/PEG showed superior properties in scavenging H_(2)O_(2)and effectively inhibiting the scavenging of reactive oxygen *** importantly,such an oxygen-defected MoO_(3−X)/PEG had obvious antibacterial and skin repairing effects on alleviating hypoxia and excessive oxidative stress even in a mouse model of diabetic ulcers,inhibiting proinflammatory cytokines and significantly accelerating the healing of infected wounds,which shows great application potential for promoting wound *** work highlights that the developed oxygen defected molybdenum oxide compounds capable of peroxidaselike and catalase-like activities show great application potential for healing diabetes wound.

关键词： oxygen-defected molybdenum-based nanoenzymes antioxidant anti-inflammatory diabetes ulcer wounds

Bioinspired mineral-in-shell nanoarchitectonics:Functional empowerment of mineral precursors for guiding intradentinal mineralization

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Nano Research 2024年第5期17卷 4338-4349页

作者： Xiaoran Zheng Yang Liu Mingjing Li Yuyan Li Wanshan Gao Rongmin Qiu Jiaqi Xing Jiaojiao Yang Yantao Chen Xinyuan Xu Mingming Ding Jun Luo Jianshu Li College of Polymer Science and engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065China College of Stomatology Hospital of Stomatology Guangxi Medical UniversityGuangxi Key Laboratory of Oral and Maxillofacial Rehabilitation and ReconstructionGuangxi Clinical Research Center for Craniofacial DeformityGuangxi Key Laboratory of Oral and Maxillofacial Surgery Disease TreatmentGuangxi Health Commission Key Laboratory of Prevention and Treatment for Oral Infectious DiseasesNanning 530021China State key laboratory of Oral Diseases West China Hospital of StomatologySichuan UniversityChengdu 610041China Shenzhen key laboratory of Environmental Chemistry and ecological Remediation College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhen 518060China Med-X Center for Material Sichuan UniversityChengdu 610041China

Effective mineralization of biological structures poses a significant challenge in hard tissue engineering as it necessitates overcoming geometric complexities and multistep biomineralization *** this regard,we propose“mineral-in-shell nanoarchitectonics”,inspired by the nanostructure of matrix vesicles,which can influence multiple mineralization *** nanostructural design empowers mineral precursors with tailorable properties through encapsulating amorphous calcium phosphate within a multifunctional tannic acid(TA)and silk fibroin(SF)*** bioinspired nanosystem facilitates efficient recruitment of mineral precursors throughout the dentin structures,followed by large-scale intradentinal mineralization both in vitro and in vivo,which provides persistent protection against external *** simulations combined with experimental studies attribute the success of intradentinal mineralization to the TA-SF nanoshell,which exhibits a strong affinity for the dentin structure,stabilizing amorphous precursors and thereby facilitating concomitant mineral ***,this bioinspired mineral-in-shell nanoarchitectonics shows a promising prospect for hard tissue repair and serves as a blueprint for next-generation biomineralization-associated materials.

关键词： mineral-in-shell nanohybrids self-assembly biomineralization dentinal tubule occlusion dental hypersensitivity

Highly Porous Yet Transparent Mechanically Flexible Aerogels Realizing Solar-Thermal Regulatory Cooling

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Nano-Micro Letters 2024年第7期16卷 231-243页

作者： Meng Lian Wei Ding Song Liu Yufeng Wang Tianyi Zhu Yue-EMiao Chao Zhang Tianxi Liu State key laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620People’s Republic of China key laboratory of Synthetic and biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122People’s Republic of China

The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but ***,a delaminated aerogel film(DAF)is fabricated through filtration-induced delaminated gelation and ambient *** delaminated gelation process involves the assembly of fluorinated cellulose nanofiber(FCNF)at the solid-liquid interface between the filter and the filtrate during filtration,resulting in the formation of lamellar FCNF hydrogels with strong intra-plane and weak interlayer hydrogen *** exchanging the solvents from water to hexane,the hydrogen bonding in the FCNF hydrogel is further enhanced,enabling the formation of the DAF with intra-layer mesopores upon ambient *** resulting aerogel film is lightweight and ultra-flexible,which pos-sesses desirable properties of high visible-light transmittance(91.0%),low thermal conductivity(33 mW m^(-1) K^(-1)),and high atmospheric-window emissivity(90.1%).Furthermore,the DAF exhibits reduced surface energy and exceptional hydrophobicity due to the presence of fluorine-containing groups,enhancing its durability and UV ***,the DAF has demonstrated its potential as solar-thermal regulatory cooling window materials capable of simultaneously providing indoor lighting,thermal insulation,and daytime radiative cooling under direct ***,the enclosed space protected by the DAF exhibits a temperature reduction of 2.6℃ compared to that shielded by conventional architectural glass.

关键词： Transparent aerogel Cellulose nanofiber aerogel Delaminated gelation Thermal insulation Passive daytime radiative cooling

Solar evaporation for simultaneous oil-water separation and electricity generation with Janus wood-based absorbers

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Frontiers of Environmental Science & engineering 2024年第2期18卷 13-23页

作者： Yue Yang Ze Fu Qi Zhang Jiangsu key laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science&TechnologyNanjing 210094China key laboratory of Industrial Ecology and Environmental engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresCollege of Engineering and Applied SciencesKey Laboratory of Intelligent Optical Sensing and Manipulation(Ministry of Education)Jiangsu Key Laboratory of Artificial Functional MaterialsNanjing UniversityNanjing 210093China

Oily wastewater from ocean oil spills endangers marine ecosystems and human health. Therefore, developing an effective and sustainable solution for separating oil-water mixtures is urgent. Interfacial solar photothermal evaporation is a promising approach for the complete separation of two-phase mixtures using only solar energy. Herein, we report a carbonized wood-based absorber with Janus structure of comprising a hydrophobic top-layer and an oleophobic bottom-layer for simultaneous solar-driven oil-water separation and electricity generation. Under sunlight irradiation, the rapid evaporation of seawater will induce a separation of oil-water mixtures, and cause a high salt concentration region underlying the interface, while the bottom “bulk water” maintains in a low salt concentration, thus forming a salinity gradient. Electricity can be generated by salinity gradient power. Therefore, oil-water separation efficiency of > 99% and derived extra electricity power of ~0.1 W/m2 is achieved under solar radiation, demonstrating the feasibility of oil-water separation and electricity production synchronously directly using solar energy. This work provides a green and cost-effective path for the separation of oil-water mixtures.

关键词： Oily wastewater Carbonized wood Salinity gradient Electricity generation Solar irradiation

Challenges and opportunities in Quaternary palynology

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Science China Earth Sciences 2024年第7期67卷 2148-2161页

作者： Qinghai XU Houyuan LU Zhuo ZHENG College of Geographical Sciences Hebei Key Laboratory of Environmental Change and Ecological ConstructionHebei Normal UniversityShijiazhuang 050024China key laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China School of Earth Sciences and engineering Sun Yat-sen UniversityZhuhai 519082China

Quaternary palynology plays a pivotal role in investigating global climate change and various other research fields,serving as an essential tool for the quantitative analysis of paleoenvironment ***,due to the vast diversity of terrestrial ecosystems and intricate interactions between vegetation,climate,and human activities,further advancements are required in the following aspects within this discipline.(1)The accuracy of classification in pollen morphology and fossil pollen identification needs improvement,particularly at the species *** represents a significant challenge in present Quaternary ***-aided intelligent recognition holds promise as a solution for species identification based on more detail pollen morphology.(2)Most pollen-based vegetation and climate reconstructions overlook the significance of bare *** bare ground can lead to substantial inaccuracies when quantitatively reconstructing past vegetation and climate.(3)While pollen records provide reliable information on paleoclimate changes,current quantitative climate reconstruction models heavily rely on modern pollen datasets derived from present-day vegetation disturbed more or less by human *** introduces bias and uncertainties into paleoclimate reconstruction.(4)Although pollen can serve as an indicator of human activities,accurately quantifying the intensity of human influence remains *** accurate identification of crop pollen,reconstructing reliable land cover/use data,and integrating multidisciplinary data may enhance the identification and quantification of signals related to human activity in pollen records.

关键词： Quaternary palynology Paleoclimate Paleovegetation Human activity