检索结果-南通市图书馆

Journal of Energy Chemistry 2025年第2期101卷 474-484页

作者： Yu Li Zhengrong Xu Quanxin Guo Qin Li Rui Liu key laboratory of Advanced Civil Engineering Materials of ministry of education School of Materials Science and Engineering Tongji University

By manipulating the distribution of surface electrons,defect engineering enables effective control over the adsorption energy between adsorbates and active sites in the CO2reduction reaction（CO2RR）.Herein,we report a hollow indium oxide nanotube containing both oxygen vacancy and sulfur doping（V_o-Sx-In2O3） for improved CO2-to-HCOOH electroreduction and *** componential synergy significantly reduces the*OCHO formation barrier to expedite protonation process and creates a favorable electronic micro-environment for*HCOOH *** a result,the CO2RR performance of Vo-Sx-In2O3outperforms Pure-In2O3and V_o-In2O3,where V_o-S53-In2O3exhibits a maximal HCOOH Faradaic efficiency of 92.4% at-1,2 V *** hydrogen electrode（RHE） in H-cell and above 92%over a wide window potential with high current density(119.1 mA cm-2at-1.1 V ***) in flow ***,the rechargeable Zn-CO2battery utilizing V_o-S53-In2O3as cathode shows a high power density of 2.29 mW cm-2and a long-term stability during charge-discharge *** work provides a valuable perspective to elucidate co-defective catalysts in regulating the intermediates for efficient CO2RR.

关键词： CO2 electroreduction In2O3 Intermediate Oxygen vacancy Sulfur doping Zn-CO2 battery

Structuring MoO3-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2025年第2期36卷 239-243页

作者： Bowen Li Ting Wang Ming Xu Yuqi Wang Zhaoxing Li Mei Liu Wenjing Zhang Ming Feng key laboratory of Functional Materials Physics and Chemistry of the ministry of education Jilin Normal University

Improving the surface atoms utilization efficiency of catalysts is extremely important for large-scale H2production by electrochemical water splitting,but it remains a great ***,we reported two kinds of Mo O3-polyoxometalate hybrid nanobelt superstructures (MoO3-POM HNSs,POM=PW12O40and Si W12O40) using a simple hydrothermal *** superstructure with highly uniform nanoparticles as building blocks can expose more surface atoms and emanate increased specific surface *** incorporated POMs generated abundant oxygen vacancies,improved the electronic mobility,and modulated the surface electronic structure of MoO3,allowing to optimize the H*adsorption/desorption and dehydrogenation kinetics of ***,the as-prepared MoO3-PW12O40HNSs electrodes not only displayed the low overpotentials of 108 mV at 10 mA/cm2current density in 0.5 mol/L H2SO4electrolyte but also displayed excellent long-term *** hydrogen evolution reaction （HER） performance of MoO3-POM superstructures is significantly better than that of corresponding bulk materials MoO3@PW12O40and Mo O3@Si W12O40,and the overpotentials are about 8.3 and 4.9 times lower than that of single Mo *** work opens an avenue for designing highly surface-exposed catalysts for electrocatalytic H2production and other electrochemical applications.

关键词： Electrocatalysis Hydrogen production Metal oxide Polyoxometalate Superstructure

Research progress on piperidine-containing compounds as agrochemicals

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2025年第1期36卷 58-67页

作者： Wei Sun Anjing Liao Li Lei Xu Tang Ya Wang Jian Wu State key laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityGuiyang 550025China

Piperidine is a crucial pharmacophore and a special scaffold in the realm of drug *** flexibility increases the molecule’s capability to bind to the *** piperidine-containing compounds are distinguished by their remarkable activity,and are increasingly becoming a vital category of *** this review,the research progress of piperidines in the discovery of pesticides was updated according to their active *** structure-activity relationships(SARs),and mechanisms of action of piperidine-containing compounds were also *** article is meant to enable readers to quickly understand piperidines,while providing ideas for creating piperidines with novel structures and unique mechanisms of action.

关键词： Piperidine Agrochemicals biological activity Structure-activity relationships Mechanism of action

Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang Wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan Shi Qun Yi Yao Liu Yi Huang key laboratory of Green Chemical Engineering Process of ministry of education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationHubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205HubeiChina key laboratory of Pesticide&Chemical biology of ministry of education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079HubeiChina College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108FujianChina

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction(OER).Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER ***,most of them undergo incomplete reconstruction with limited thickness of reconstruction layer,leading to low component utilization and arduous exploration of real catalytic ***,we identify the dynamic behaviors in complete reconstruction of Co-based complexes during *** hollow phytic acid(PA)cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability,in favor of the fast and complete reconstruction.A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co(Fe)(OH)xand subsequent potential-driven oxidation to Co(Fe)*** obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm^(-2)and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER *** work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction

Pristine/magnesium-loaded biochar and ZVI affect rice grain arsenic speciation and cadmium accumulation through different pathways in an alkaline paddy soil

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2025年第1期147卷 630-641页

作者： Chen Zhang Dong Shi Chao Wang Guoxin Sun Huafen Li Yanxia Hu Xiaona Li Yanhui Hou Ruilun Zheng Institute of Grassland Flowers and EcologyBeijing Academy of Agriculture and Forestry SciencesBeijing 100097China Beijing key laboratory of Farmland Soil Pollution Prevention and Remediation Key Laboratory of Plant-Soil Interactions of the Ministry of EducationCollege of Resources and Environmental SciencesChina Agricultural UniversityBeijing 100193China State key laboratory of Urban and Regional ecology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

Cadmium(Cd)and arsenic(As)co-contamination has threatened rice production and food *** is challenging to mitigate Cd and As contamination in rice simultaneously due to their opposite geochemical ***-loaded biochar with outstanding adsorption capacity for As and Cd was used for the first time to remediate Cd/As contaminated paddy *** addition,the effect of zero-valent iron(ZVI)on grain As speciation accumulation in alkaline paddy soils was first *** effect of rice straw biochar(SC),magnesiumloaded rice straw biochar(Mg/SC),and ZVI on concentrations of Cd and As speciation in soil porewater and their accumulation in rice tissueswas investigated in a pot *** of SC,Mg/SC and ZVI to soil reduced Cd concentrations in rice grain by 46.1%,90.3%and 100%,and inorganic As(iAs)by 35.4%,33.1%and 29.1%,respectively,and reduced Cd concentrations in porewater by 74.3%,96.5%and 96.2%,*** of 51.6%and 87.7%in porewater iAs concentrationswere observed with Mg/SC and ZVI amendments,but notwith *** acid(DMA)concentrations in porewater and grain increased by a factor of 4.9 and 3.3,respectively,with ZVI *** three amendments affected grain concentrations of iAs,DMA and Cd mainly by modulating their translocation within plant and the levels of As(Ⅲ),silicon,dissolved organic carbon,iron or Cd in *** three amendments(SC,Mg/SC and ZVI)have the potential to simultaneously mitigate Cd and iAs accumulation in rice grain,although the pathways are different.

关键词： Cadmium(Cd) Arsenic(As)speciation Co-contamination Magnesium-loaded biochar Zero-valent iron(ZVI) Rice

Interpretable Machine Learning-Based Spring Algal Bloom Forecast Model for the Coastal Waters of Zhejiang

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Ocean University of China 2025年第1期24卷 1-12页

作者： HUANG Guoqiang BAO Min ZHANG Zhao GU Dongming LIANG Liansong TAO Bangyi State key laboratory of Satellite Ocean environment Dynamics Second Institute of OceanographyMinistry of Natural ResourceHangzhou 310012China Wenzhou Marine Center Ministry of Natural ResourcesWenzhou 325000China Observation and Research Station of Yangtze River Delta Marine ecosystems Ministry of Natural ResourcesZhoushan 316000China key laboratory of Marine ecological Monitoring and Restoration Technologies Ministry of Natural ResourceShanghai 201206China

The 2016–2022 monitoring data from three ecological buoys in the Wenzhou coastal region of Zhejiang Province and the dataset European Centre for Medium-Range Weather Forecasts were examined to clarify the elaborate relationship between variations in ecological parameters during spring algal bloom incidents and the associated changes in temperature and wind fields in this study.A long short-term memory recurrent neural network was employed,and a predictive model for spring algal bloom in this region was *** model integrated various inputs,including temperature,wind speed,and other pertinent variables,and chlorophyll concentration served as the primary output *** model training used chlorophyll concentration data,which were supplemented by reanalysis and forecast temperature and wind field *** model demonstrated proficiency in forecasting next-day chlorophyll concentrations and assessing the likelihood of spring algal bloom occurrences using a defined chlorophyll concentration *** historical validation from 2016 to 2019 corroborated the model's accuracy with an 81.71%probability of correct prediction,which was further proven by its precise prediction of two spring algal bloom incidents in late April 2023 and early May *** interpretable machine learning-based model for spring algal bloom prediction,displaying effective forecasting with limited data,was established through the detailed analysis of the spring algal bloom mechanism and the careful selection of input *** insights gained from this study offer valuable contributions to the development of early warning systems for spring algal bloom in the Wenzhou coastal area of Zhejiang Province.

关键词： spring algal bloom forecast LSTM interpretable

On-chip light control of semiconductor optoelectronic devices using integrated metasurfaces

在线全文

学校读者我要写书评

暂无评论

Opto-Electronic Advances 2025年第1期8卷 5-30页

作者： Cheng-Long Zheng Pei-Nan Ni Yi-Yang Xie Patrice Genevet Henan key laboratory of Diamond Optoelectronic Materials and Devices Key Laboratory of Materials PhysicsMinistry of EducationSchool of PhysicsZhengzhou UniversityZhengzhou 450052China key laboratory of Optoelectronics Technology Beijing University of TechnologyMinistry of EducationBeijing 100124China Colorado School of Mines 1523 Illinois St.GoldenCO 80401USA

Semiconductor optoelectronics devices,capable of converting electrical power into light or conversely light into electrical power in a compact and highly efficient manner represent one of the most advanced technologies ever developed,which has profoundly reshaped the modern life with a wide range of *** recent decades,semiconductor technology has rapidly evolved from first-generation narrow bandgap materials(Si,Ge)to the latest fourth-generation ultra-wide bandgap semiconductor(GaO,diamond,AlN)with enhanced performance to meet growing ***,merging semiconductor devices with other techniques,such as computer assisted design,state-of-the-art micro/nano fabrications,novel epitaxial growth,have significantly accelerated the development of semiconductor optoelectronics *** them,integrating metasurfaces with semiconductor optoelectronic devices have opened new frontiers for on-chip control of their electromagnetic response,providing access to previously inaccessible degrees of *** review the recent advances in on-chip control of a variety of semiconductor optoelectronic devices using integrated metasurfaces,including semiconductor lasers,semiconductor light emitting devices,semiconductor photodetectors,and low dimensional *** integration of metasurfaces with semiconductors offers wafer-level ultracompact solutions for manipulating the functionalities of semiconductor devices,while also providing a practical platform for implementing cuttingedge metasurface technology in real-world applications.

关键词： optoelectronics nanophotonics metasurfaces semiconductor

Magnitude, spatial patterns and drivers of methane fluxes from coastal salt marshes and mangrove forests in China

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2025年第3期68卷 850-866页

作者： Yixuan YU Derrick Y.F.LAI Minjie HU Chuan TONG key laboratory of Humid Subtropical eco-geographical Process of ministry of education Fujian Normal University School of Geographical Sciences Fujian Normal University Department of Geography and Resource Management The Chinese University of Hong Kong

Methane（CH4） is a highly potent greenhouse gas due to its high radiative forcing and global warming *** the magnitude, spatial patterns, and drivers of CH4emission from wetlands at the regional scale is crucial for formulating suitable strategies to mitigate future climate change. In this study, we synthesized the CH4flux data reported for major plant communities in the coastal salt marshes and mangrove forests in China and produced a spatial map of CH4fluxes from the mangrove sediments and salt marshes in China based on the results of machine learning models. Moreover, we examined the main drivers of CH4flux from these coastal wetlands and estimated the annual CH4emissions from the salt marshes and mangrove forests in different coastal provinces of China using a bottom-up approach. Our results showed that the mean CH4fluxes from the salt marsh and mangrove ecosystems in China were 2.22±0.29 and 2.26±0.55 mg m-2h-1, respectively. Across China, the total annual CH4emission from salt marshes was 31,179.75 Mg CH4a-1, while that from mangroves was 5,533.97 Mg CH4a-1with the sediments contributing to 12.7%(701.64 Mg CH4a-1) of the total efflux. The salt marshes and mangroves in China accounted for 2.75% and 0.14%–0.15% of the global annual CH4emissions from these two ecosystems,respectively. Moreover, we found that CH4emissions from the salt marshes and mangroves could offset the cooling impact arising from net carbon dioxide uptake by 88% and 53%, respectively, over a 100-year time scale. Mean annual temperature, soil moisture, and soil organic carbon content were the main factors controlling CH4emissions from these coastal ***, we found that CH4fluxes from the salt marshes in China decreased with latitude, which implied a possible increase in marsh CH4emission in response to global warming that should be considered carefully when developing nature-based climate solutions to achieve national goals for carbon neutrality.

关键词： Salt marsh Mangrove Methane flux Spatial pattern Driving factors China

同方期刊数据库

Extracting ship and heading from Sentinel-2 images using convolutional neural networks with point and vector learning

在线全文

学校读者我要写书评

暂无评论

Journal of Oceanology and Limnology 2025年第1期43卷 16-28页

作者： Xiunan LI Peng CHEN Jingsong YANG Wentao AN Dan LUO Gang ZHENG Aiying LU Ocean College Zhejiang UniversityZhoushan 316021China State key laboratory of Satellite Ocean environment Dynamics Second Institute of OceanographyMinistry of Natural ResourcesHangzhou 310012China National Satellite Ocean Application Service Ministry of Natural ResourcesBeijing 100081China

Obtaining accurate ship positions and headings in remote sensing images plays a crucial role in various ***,current deep learning-based methods primarily focus on ship position detection,while the detection of ship wakes relies on traditional non-deep learning approaches,which often underperform in complex marine *** proposed a novel,simple,and efficient method called Point-Vector *** proposed method leverages convolutional neural networks(CNN)for feature extraction and subsequently integrates multi-scale features to generate high-resolution feature *** the final stage,ship positions and headings are represented using a combination of points and *** experiments with results from automatic identification system(AIS)reports demonstrate that our method achieved impressive performance in two-class ship target detection,with an average precision of 96.4%,recall rate of 94.3%,and an F 1 score of 95.2%.Notably,the average heading error was 3.3°.The proposed model achieved a practical inference speed(FPS>30),and the average processing time for inferring a large-scale Sentinel-2 remote sensing image was 11.4 s.

关键词： deep learning ship detection heading remote sensing Sentinel-2

MoS2 synaptic transistor with one-step manufacture

在线全文

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2025年第1期68卷 357-365页

作者： Yihao GUO Yang WANG Wenjie DENG Yi WU Jingtao LI Kexin LI Yuehui ZHAO Songlin YU Xiaoting WANG Yongzhe ZHANG Hui YAN key laboratory of Optoelectronics Technology of education ministry of China Faculty of Information TechnologyBeijing University of Technology key laboratory of Advanced Functional Materials Ministry of Education Faculty of Materials and ManufacturingBeijing University of Technology The 11th Research Institute of Electronics Technology Group Corporation

The synaptic transistor,which is a neuromorphic device with brain-like functions,has garnered significant attention due to characteristics such as low energy consumption,high integration,multiple functions,and high computational ***,the current synaptic transistor possesses a complicated structure and involves complex manufacturing steps,which is not conducive to low-cost,large-scale bionic ***,we introduce a simple MoS2synaptic transistor exhibiting robust synaptic *** transistor utilizes magnetron sputtering manufacture to combine the process of device metal electrode deposition and the introduction of defect states,which helps streamline the manufacturing process into a single *** long-term potentiation and long-term depression in photoelectric coordination are initially ***,biological functions,such as double pulse facilitation and the transformation behavior of short-term memory to long-term memory,are thoroughly evaluated,along with learning-forgetting-relearning ***,the device exhibits robust synaptic plasticity until incident light angles down to 30° to imitate the multi-to-one axon-cellular ***,a classical simulation of Pavlov's dog conditioned reflex is demonstrated along with the multiview extraction *** experimental results demonstrate a promising synaptic transistor with a simple structure,manufacturing technique,and excellent *** further indicates the potential for large-scale integration of bionic neuromorphic systems.

关键词： process optimization artificial synaptic device one-stepmanufacture synaptic plasticity bionic simulation

同方期刊数据库