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Journal of energy Chemistry 2024年第10期97卷 419-428页

作者： Yu Liu Kun Lang Huifang Han Huijing Liu Yao Fu Pengchen Zou Yinhui Lyu Jia Xu Jianxi Yao State key laboratory of Alternate Electrical Power System with renewable energy Sources Beijing Key Laboratory of Energy Safety and Clean Utilization North China Electric Power University

CsPbI2Br perovskite solar cell has been extensively studied due to its exceptional thermal stability and relatively stable perovskite phase ***,the presence of bromine leads to a rapid crystallization rate of CsPbI2Br films,resulting in small grain size and high defect ***,CsPbI2Br demonstrates poor light absorption due to its wide ***,it is crucial to control the crystallization rate and increase the film thickness to reduce defect density,enhance light absorption,and improve photovoltaic *** this study,we utilized a PbAc2-incorporated twice spincoating（PTS） process to address these ***,PbAc2was added to the CsPbI2Br precursor solution to form a CsPbI2Br film,which was then coated with the CsPbI2Br precursor solution to produce the PTS film,Ac-can delay the perovskite crystallization,leading to the formation of thicker and denser CsPbI2Br ***,lone-pair electrons of the oxygen atom provided by Ac-formed coordination bonds with under-coordinated Pb2+ions to fill halogen ion vacancies,thereby reducing the defect ***,the PTS CsPbI2Br device achieved a peak power conversion efficiency（PCE） of 16.19% and maintained 96.7% of its initial PCE over 1500 h at room temperature under 25% relative humidity without any encapsulation.

关键词： Crystallization management CsPbI2Br PbAc2 Perovskite solar cells Twice spin-coating process

Highly selective and eco-friendly dihydroisoquinoline synthesis via Cu/Co synergistic catalysis in Cu NPs@MOFs catalyst under mild conditions

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Science China Chemistry 2024年第5期67卷 1561-1568页

作者： Peng-Fei Guo Ze-Long Liang Yue-E Jiao Hang Xu Bin Zhao key laboratory of Advanced energy Material Chemistry Renewable Energy Conversion and Storage CenterDepartment of ChemistryNankai UniversityTianjin 300071China

3,4-Dihydroisoquinoline(DHIQ)is an important precursor used in the production of drugs for treating cancer,HIV,Alzheimer's disease,*** studies on DHIQ synthesis show low catalytic selectivity due to the susceptible over-oxidation feedstock of1,2,3,4-tetrahydroisoquinoline(THIQ),which often requires alkali ***,it is desirable yet challenging to explore a highly selective and efficient oxydehydrogenation capacity for DHIQ synthesis under eco-friendly reaction ***,a novel framework 1 was synthesized,exhibiting 1D channels with the size of 4.6 A×9.6 A and high solvent/p H/thermal stability.A stable framework allows it to encapsulate Cu nanoparticles(NPs)to form Cu NPs@1-x(x=1,2,3,and 4)with varying loading amounts of Cu NPs at 2.0 wt%,3.0 wt%,4.0 wt%,and 6.0 wt%,*** NPs@1-3 could selectively catalyze the reaction from THIQ to DHIQ with a high selectivity of 98%and a recorded turnover frequency(TOF)of 22.1 h-1under eco-friendly mild *** corresponding catalytic activity can maintain at least five recyclings and can be further applied to gram-scale ***,the efficient preparation of DHIQ catalyzed by Cu NPs@1-3 could be realized even under air ***,the anticancer molecule precursor synthesis of 6,7-dimethoxy-3,4-dihydroisoquinoline was also selectively catalyzed by Cu NPs@*** investigations revealed that high catalytic performance can be attributed to the stable framework and the synergistic catalytic effect of the loaded Cu NPs and Co metal *** importantly,this work represents the first example of MOF catalysts for selectively thermo-catalytic DHIQ synthesis and demonstrates a simple approach to obtain efficient catalysts for selective oxydehydrogenation in the production of unsaturated compounds.

关键词： metal-organic frameworks Cu NPs@MOFs 3 4-dihydroisoquinoline selective oxydehydrogenation synergistic catalysis

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A review on the chemo-catalytic conversion of cellulose to bio-ethanol

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Green Chemical Engineering 2024年第03期5卷 276-289页

作者： Xiuzheng Zhuang Haiyong Wang Shugen Jiang Xiaohong Hu Tong Su Xinghua Zhang Longlong Ma key laboratory of energy Thermal Conversion and Control of Ministry of Education School of Energy and Environment Southeast University key laboratory of renewable energy Guangzhou Institute of Energy Conversion Chinese Academy of Sciences Wuzhou Refrigeration Group Co.Ltd.

While the industry has produced sugar-derived ethanol from the conventional method of fermentation for hundreds of years, other effective routes involving the direct transformation of carbohydrates still remain extremely rare. Very recently, an innovative chemo-catalytic method driven by the aqueous-phase catalysis was created for the synthesis of cellulosic ethanol, making a great breakthrough in the common ways as it can theoretically utilize all of the carbon atoms in sugars with faster kinetics; up to now, results from the relevant studies have been accumulated to a certain extent, but the periodic conclusions in this field are unfortunately absent. For this reason,this work tries to offer an overview of the cellulosic ethanol produced by chemo-catalytic routes, highlighting the present knowledge in relation to the technical efficiency, catalytic mechanisms as well as practical applications. At first, the advanced progress on the increasing efficiency from a varied type of catalytic systems are extensively discussed, which involves the specific functions of hybrid components from different strategies; meanwhile, the general influences of processing conditions, such as the hydrothermal severity and aqueous environments, are also identified. Subsequently, possible mechanisms behind the chemo-catalytic processes are widely elaborated by analyzing a number of experimental cases associated with the reaction network and its kinetic models. After that,the actual effects of this technique on the real biomass are collected to identify the positive/negative interactions between multiple components, together with the potential solutions on the semi-continuous processes of pilot scale application. The techno-economic analysis(TEA) is also calculated and compared with other similar methods, such as fermentation and gasification. Finally, several proposals aimed at upgrading the whole chain of chemo-catalytic processes are clearly provided, which may function as a guideline f

关键词： Cellulosic ethanol Chemo-catalytic method Influencing factors Catalytic mechanism Techno-economic analysis

Insulation Design Rule for a Spacer in SF_(6)/N_(2)-filled DC Gas Insulated Apparatus

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CSEE Journal of Power and energy Systems 2024年第2期10卷 727-735页

作者： Hongyang Zhou Guoming Ma Meng Zhang Cong Wang Youping Tu Chengrong Li State key laboratory of Alternate Electrical Power System with renewable energy Sources and the Beijing key laboratory of High Voltage and EMC North China Electric Power UniversityBeijing 102206China

A recurring challenge of a DC SF_(6)/N_(2)-filled GIS/GIL apparatus is the charge accumulation at DC *** conventional design rules and knowledge of AC spacers may not be applicable for this new type of apparatus.A novel design rule is proposed considering the effect of accumulated charge on the threshold of electric field strength being resistant to the superposed voltage.A surface charge accumulation simulation model is introduced,and the key parameters in the simulation model are *** addition,an experimental platform for a 100 kV spacer flashover test is *** flashover tests under superimposed voltage with opposing polarities are carried out,and the withstanding voltage of the spacer is ***,based on the proposed model,the threshold of the surface electric field strength(tangential component)on the DC spacer in SF_(6)/N_(2) mixed gases is *** a reliable insulation design of a DC GIS/GIL apparatus filled with 0.7 MPa SF_(6)/N_(2),the threshold of surface electric field strength on the DC spacer is 12 kV/*** insulation design rule can be referenced in the design of a high-voltage DC SF_(6)/N_(2)-filled GIS/GIL apparatus.

关键词： Charge accumulation DC spacer flashover voltage SF_(6)/N_(2) threshold of surface electric field strength

Charge Accumulation Characteristics of SF6-Epoxy Interface Under Negative Repetitive Nanosecond Pulses

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CSEE Journal of Power and energy Systems 2024年第4期10卷 1808-1815页

作者： Shaocong Wu Geng Chen Yuming Shao Hao Xu Xuanning Zhang Yanyu Liang Youping Tu State key laboratory of Alternate Electrical Power System with renewable energy Sources and the Beijing key laboratory of High Voltage and EMC North China Electric Power UniversityBeijing 102206China

Repetitve nanosecond impulses in gas-insulated metal-enclosed switchgear (GIS) are likely to trigger inside flashover. Interface charges on the spacer in GIS are considered one of the main factors damaging insulation performance and may be induced by overvoltage. For good understanding of insulation failures, accumulation characteristics of charges between SF6 and epoxy spacers under repetitive nanosecond impulses are investigated. It can be found under nanosecond impulses, the charge source in gas volume contributes to interface charge accumulation predominantly. Interface charges will be promoted by impulse number and amplitude. Accumulation processes are analyzed based on runaway electrons mechanism. When impulse amplitude exceeds a threshold value, discharge in the gas volume turns to a runaway mode. A runaway electron leads to the interface charge accumulation. Affected by motion of the runaway electrons, the potential peak gradually moves close to the grounded electrode when impulse amplitude is raised. Meanwhile, increasing impulse number can enhance surface potential. Surface potential will reach saturation eventually. However, memory effect of the repetitive impulse discharge makes the half-peak width of the surface potential at the interface change little. Design of GIS gas-solid insulations can refer to this research.

关键词： GIS interface charge repetitive nano-second pulse SF6

Assessment and Enhancement of FRC of Power Systems Considering Thermal Power Dynamic Conditions

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CSEE Journal of Power and energy Systems 2024年第4期10卷 1371-1383页

作者： Feng Hong Yalei Pang Weiming Ji Lu Liang Fang Fang Junhong Hao Jizhen Liu State key laboratory of Alternate Electric Power System with renewable energy Sources and School of Control and Computer Engineering North China Electric Power UniversityBeijing 102206China State key laboratory of Alternate Electric Power System with renewable energy Sources School of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China

Frequency stability and security have been a vital challenge as large-scale renewable energy is integrated into power *** contrast,the proportion of traditional thermal power units decreases during the decarbonization transformation process,resulting in poor frequency *** paper aims to explore the potential of frequency regulation support,dynamic assessment,and capacity promotion of thermal power plants in the transition *** the dynamic characteristics of the main steam working fluid under different working conditions,a nonlinear observer is constructed by extracting the main steam pressure and valve opening degree *** real-time frequency modulation capacity of thermal power units can provide a dynamic state for the power grid.A dynamic adaptive modification for primary frequency control(PFC)of power systems,including wind power and thermal power,is proposed and *** power dynamic allocation factor is adaptively optimized by predicting the speed droop ratio,and the frequency modulation capability of the system is improved by more than 11%under extreme ***,through the Monte Carlo simulation of unit states of the system under various working conditions,the promotion of the frequency regulation capacity with high wind power penetration(WPP)is verified.

关键词： Dynamic evaluation frequency regulation power system predictive modeling wind penetration

Framework for Preventive Control of Power Systems to Defend Against Extreme Events

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CSEE Journal of Power and energy Systems 2024年第2期10卷 856-870页

作者： Yuwei Xiang Tong Wang Zengping Wang State key laboratory of Alternate Electrical Power System with renewable energy Sources North China Electric Power UniversityBeijing 102206China

Enhancing power system resilience against extreme events is becoming increasingly critical. This paper discusses a unified framework for preventive control of power systems to enhance system resilience, which includes three parts: resilience assessment, resilience grading, and resilience enhancement. First, the resilience assessment contains facility-level and system-level resilience assessment. The concept of fragility curve is used in the facility-level resilience assessment. Various resilience indices are developed in system-level resilience assessment to roundly depict the impacts of extreme events on power systems and determine the system resilience. On this basis, the resilience is divided into different levels by resilience grading strategy, which can efficiently quantify the severity of the impact of extreme events and provide decision-making for the resilience enhancement strategies. Then, control strategies for enhancing power system resilience are also divided according to different resilience levels. A controlled islanding based preventive control is proposed to enhance system resilience, which aims to strengthen the first defensive line of power systems to deal with extreme events. Finally, taking the typhoon disaster in extreme events as an example, two tests carried out with two typhoons demonstrate the efficiency of the proposed method.

关键词： Controlled islanding extreme events power system resilience preventive control

Micro-mechanism Study on the Different Antioxidants Protective Effect of Vegetable Oil by ReaxFF Molecular Dynamics

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CSEE Journal of Power and energy Systems 2024年第3期10卷 1269-1279页

作者： Haoxi Cong Xuefeng Hu Hao Pan Qingmin Li State key laboratory of Alternate Electrical Power System With renewable energy Sources North China Electric Power UniversityBeijing 102206China

The aging problem of vegetable oil has severely restricted the popularization and application of vegetable oil *** antioxidants is the most recommended *** present,there is insufficient research on the micromechanism application of the protective effect of antioxidants on vegetable *** this paper,multiple vegetable oil models with different types and concentrations of antioxidants are *** the molecular dynamics simulation based on ReaxFF is carried out at different temperatures and oxygen *** show that the protective mechanism of antioxidants is to release H and combine this with free radicals generated by the decomposition of unsaturated fatty acids(UFA)in the *** addition,the protective effects of four antioxidants show different *** stronger ones are tert-butyl hydroquinone(TBHQ)and butylated hydroxytoluene(BHT),while the weaker ones are butylated hydroxyanisole(BHA)and propyl gallate(PG).TBHQ has a better protective effect at lower concentrations,but the decomposition of UFA is promoted at higher *** the temperature rises,the decomposition of UFA is *** the addition of oxygen,smaller molecular compounds are easily oxidized,and the decomposition of UFA is *** above research could reveal the microscopic mechanism of antioxidant protection on vegetable oil,providing theoretical references for further exploration of effective vegetable oil aging protection technology.

关键词： Antioxidant molecular dynamics transformer vegetable oil

Particles attrition of binary mixtures in the coal-fueled chemical looping system based on fluidized bed

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Particuology 2024年第3期86卷 281-290页

作者： Heyu Li Zhe Sun Yan Cao Guangzhou Institute of energy Conversion Chinese Academy of SciencesGuangzhou 510640China University of Chinese Academy of Sciences Bejing 100049China CAS key laboratory of renewable energy Guangzhou 510640China Guangdong Provincial key laboratory of New and renewable energy Research and Development Guangzhou 510640China College of Chemistry and Chemical Engineering Anhui UniversityHefei230601China

In this work,a reactive air jet attrition device with auto-recording and collection of elutriated fines was *** established insights into the physiochemical interaction and further correlated attrition behaviors between char and oxygen carriers under various operation *** attrition rate increased by over 110% upon the introduced CO_(2),which brought in the significant effect of thermo-chemical stress,similarly in effects of the increased char addition ratio and the decreased sizes of char or hematite in different *** the char-hematite co-attrition process,the elutriated carbon loss of char with poor mechanical strength was found to be over 10%,while the reactive iron loss of hematite was found to be 6.3%,and was enriched in elutriated *** reaction-derived thermochemical stress and the collision-derived mechanical stress jointly controls the particle attrition during the cyclic transformation of oxygen carrier particles in coal-fueled chemical looping fluidization,especially sig-nificant in its reduction stage.

关键词： Attrition Binary species Chemical looping Oxygen carrier CO_(2)capture

Enhanced properties of stone coal-based composite phase change materials for thermal energy storage

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 206-215页

作者： Baoshan Xie Huan Ma Chuanchang Li Jian Chen key laboratory of renewable energy Electric-Technology of Hunan Province School of Energy and Power EngineeringChangsha University of Science and TechnologyChangsha 410114China State key laboratory of Disaster Prevention and Reduction for Power Grid Changsha University of Science and TechnologyChangsha 410114China

Phase change materials (PCMs) can be incorporated with low-cost minerals to synthesize composites for thermal energy storage in building *** coal (SC) after vanadium extraction treatment shows potential for secondary utilization in composite *** prepared SC-based composite PCMs with SC as a matrix,stearic acid (SA) as a PCM,and expanded graphite (EG) as an *** combined roasting and acid leaching treatment of raw SC was conducted to understand the effect of vanadium extraction on promoting loading *** showed that the combined treatment of roasting at 900℃ and leaching increased the SC loading of the composite by 6.2%by improving the specific surface *** loading capacity and thermal conductivity of the composite obviously increased by 127%and 48.19%,respectively,due to the contribution of 3wt% *** data were supported by the high load of 66.69%and thermal conductivity of 0.59 W·m^(-1)·K-1of the designed *** obtained composite exhibited a phase change temperature of 52.17℃,melting latent heat of 121.5 J·g^(-1),and good chemical *** SC-based composite has prospects in building applications exploiting the secondary utilization of minerals.

关键词： thermal energy storage phase change material stone coal vanadium extraction secondary utilization

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