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Highly efficient solution-processed organic photovoltaics enabled by improving packing behavior of organic semiconductors

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Science China Chemistry 2024年第3期67卷 890-897页

作者： Xinyue Cui Hongxiang Li Hao Lu Yuqiang Liu Guangliu Ran Rui Liu Huarui Zhang Xueqing Ma Dawei Li Yi Lin Jifa Yu Wenkai Zhang Lei Cai Yahui Liu Pei Cheng Andong Zhang Zaifei Ma Guanghao Lu Zhishan Bo College of textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China State key laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065China Department of Physics and Applied Optics Beijing Area Major laboratory Center for Advanced Quantum StudiesBeijing Normal UniversityBeijing 100875China Shandong Province key laboratory of Medical Physics and Image Processing Technology School of Physics and ElectronicsShandong Normal UniversityJinan 250014China Beijing key laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing 100875China Center for Advanced Low-Dimension Materials State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China Frontier Institute of Science and Technology Xi'an Jiaotong UniversityXi'an 710054China

Solution processability is a unique property of organic semiconductors. The compact and regular π-π stacking between molecules is paramount in the performance of organic optoelectronic devices. However, it is still a challenge to improve their stacking quality without sacrificing the solution-processability from the aspect of materials design. Here, delicately engineered additives are presented to promote the formation of ordered aggregation of conjugated molecules by regulating their nucleation and growth dynamics. Intriguingly, the long-chain BTP-eC9-4F molecules can realize ordered aggregation comparable to short-chain ones without sacrificing processability. The domain size of BTP-eC9-4F aggregation is enlarged from 24.2 to 32.2 nm in blend *** exciton diffusion and charge transport become faster, contributing to the suppression of recombination losses. As a result, a power conversion efficiency of 19.2% is achieved in D18:BTP-eC9-4F based organic photovoltaics. Our findings demonstrate a facile strategy to improve the packing quality of solution-processed organic semiconductors for high-efficiency photovoltaics and beyond photovoltaics.

关键词： organic semiconductor organic photovoltaic charge transport solution processability

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Antibonding orbital tailor and stress relief engineering for FeS2 complex toward superior sodium storage

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Rare Metals 2024年第10期43卷 5048-5059页

作者： You-Bin Zhang Zhen-Guo Qi Fu-Sheng Liu Guo-Hui Qin State key laboratory Base for eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and Technology Shandong Synergetic Innovation Center of ecological and Chemical Engineering

The sluggish kinetics behaviors and vast volume variations of Na+hosts to FeS2anode involved intercalation,and conversion reactions plague its applicability of sodium-ion batteries （SIBs）.Here,a significantly expedited kinetics via cation intercalation and considerably relieved stress accumulation by constructing the concave scaffold protector are approached for *** Mn2+intercalation into FeS2,a new stable Mn–FeS2was generated with distorted coordination;elevated antibonding orbital occupancy and lowed d band center to the release of more free Na+were achieved,which was further encapsulated by hollow bowl-like carbon spheres （BC）This cation intercalation and concave morphology strategies confer Mn–FeS2@BC significantly enhanced electron ion transport kinetics via reversed electron transfer to FeS2fast desolvation kinetics,and evidently depressed structural deformation during Na+insertion and ***,Mn–FeS2@BC delivers the longevity and stable Na+storage capacity in both half and full cell ***,Mn–FeS2@BC also displays excellen adaptability in a wider temperature *** work proposes new views into the deep regulation of electrochemical performance of transition metal anodes via intercalation chemistry and concave engineering.

关键词： Concave engineering FeS2 Intercalation chemistry Sodium capture

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NaBH4-induced phase transition of CoSe_(2) with abundant Se deficiency for acidic oxygen reduction to hydrogen peroxide

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Rare Metals 2024年第2期43卷 500-510页

作者： Cai-Di Han Yong-Chao Zhang Qian Zhang Jin-Ting Wu Jian Gao Ji-Jun Zou Xiao-Dong Zhu State key laboratory Base of eco-Chemical Engineering College of Chemical Engineering Qingdao University of Science and TechnologyQingdao266042China key laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China

Electrocatalytic oxygen reduction(ORR)via the 2e−pathway to form H_(2)O_(2) in acidic medium has attracted extensive ***,the low activity,insufficient selectivity and high cost of catalysts have been the ***,CoSe_(2) with abundant Se deficiency was synthesized by a simple hydrothermal method,and the addition of NaBH4-induced CoSe_(2) phase transition from orthorhombic to cubic phase with more Se *** cubic phase CoSe_(2) with abundant Se deficiency can effectively regulate the surface electronic structure with suitable binding energies of*OOH and*O,which shows high activity,selectivity and long-term stability for acidic ORR to H_(2)O_(2).The onset potential is as low as 0.73 V *** hydrogen electrode(RHE),the H_(2)O_(2) selectivity is 84%(0 V ***),and the average electron transfer number is about ***,the H_(2)O_(2) yield measured using a flow cell is as high as 115.92 mmol·gcat.^(−1)·h^(−1) and the Faradaic efficiency is 70%at 0 V ***,which presents high potential in electrocatalytic acidic ORR to H_(2)O_(2) and organic pollutant degradation using the electron-Fenton process.

关键词： Se defected CoSe_(2) Crystal phase transition Electrocatalysis Acidic oxygen reduction Hydrogen peroxide

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Numerical simulation on sand sedimentation and erosion characteristics around HDPE sheet sand barrier under different wind angles

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Journal of Mountain Science 2024年第2期21卷 538-554页

作者： ZHANG Kai ZHANG Peili ZHANG Hailong TIAN Jianjin WANG Zhenghui XIAO Jianhua College of Civil Engineering Lanzhou Jiaotong UniversityLanzhou 730000China key laboratory of Desert and Desertification Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China key laboratory of ecological Safety and Sustainable Development in Arid Lands Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China

For the safety of railroad operations,sand barriers are utilized to mitigate wind-sand disaster *** disasters,characterized by multi-directional wind patterns,result in diverse angles among the *** this study,using numerical simulations,we examined the behavior of High Density Polyethylene(HDPE)sheet sand barriers under different wind angles,focusing on flow field distribution,windproof efficiency,and sedimentation erosion *** study discovered that at a steady wind speed,airflow velocity varies as the angle between the airflow and the HDPE barrier ***,a 90°angle results in the widest low-speed airflow area on the barrier’s downwind *** the airflow is not perpendicular to the barrier,it prompts a lateral airflow movement which decreases as the angle *** windproof efficiency correlates directly with this angle but inversely with the wind’s ***,with a wind angle of 90°,wind speed drops by 81%.The minimum wind speed is found at 5.1H(the sand barrier height)on the barrier’s downwind *** the angle grows,the barrier’s windproof efficiency improves,extending its protective *** is most prominent on the barrier’s downwind side,as the wind angle shifts from 30°to 90°,the sand sedimentation area on the barrier’s downwind side enlarges by *** the angle grows,sedimentation intensifies,eventually overtakes the forward erosion and enlarges the sedimentation area.

关键词： Multi-wind direction HDPE sheet sand barrier Numerical simulation Windproof efficiency Sedimentation erosion

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Effects of Poria cocos polysaccharide on growth performance,physiological parameters,and lipid metabolism of spotted sea bass Lateolabrax maculatus

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Journal of Oceanology and Limnology 2024年第1期42卷 316-331页

作者： Jing LU Zhangfan HUANG Youling YE Anle XU Zhongbao LI Fisheries College Jimei UniversityXiamen 361021China Fujian Provincial key laboratory of Marine Fishery Resources and eco-environment Xiamen 361021China

The aquaculture industry has developed significantly over the past few decades and has had a substantial impact on the global food supply and marine fisheries ***,some problems arise behind the scenes due to excessive intensive farming,such as slow animal growth,frequent disease,and lipid metabolism *** problems have limited the sustainable development of the aquaculture industry,and a continuable solution is *** use of fungal polysaccharide appears to provide a solution to these ***,different supplemented levels of Poria cocos polysaccharide(PCP)(0,0.4,0.8,1.2,1.6,and 2.0 g/kg,respectively)were fed to spotted sea bass(Lateolabrax maculatus)in similar size(30.28±0.18 g)in current *** effects of PCP on growth,physiological parameters,and lipid metabolism of spotted sea bass were investigated after a 4-week rearing *** showed,fish with PCP intake presented a significantly higher weight gain,specific growth rate,and a significantly lower feed conversion *** higher trypsin activity in liver and intestine were observed in fish with PCP *** superoxide dismutase activity in serum and liver of fish with PCP intake were significantly improved,while significantly higher serum total antioxidant capacity and hepatic catalase activity were also ***,no significant differences in lysozyme and alkaline phosphatase activity were evident among *** with PCP intake showed a significantly lower total cholesterol,but no noteworthy change in triglyceride and lipid-metabolismrelated genes expression were observed among *** indicated that intake of PCP has a positive effect on growth and antioxidant capacity of spotted sea bass,but seems to have a limited effect on the non-specific immunity and lipid metabolism of spotted sea *** on the regression analysis results,1.4 g/kg of PCP is the optimal dose for spotted sea bass in size(30.28±0.18 g).

关键词： spotted sea bass Poria cocos polysaccharide growth lipid metabolism

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Intelligent laser-induced graphene sensor for multiplex probing catechol isomers

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Chinese Chemical Letters 2024年第7期35卷 227-234页

作者： Tian Cao Xuyin Ding Qiwen Peng Min Zhang Guoyue Shi School of Chemistry and Molecular Engineering Shanghai Key Laboratory for Urban Ecological Processes and Eco-RestorationEast China Normal UniversityShanghai 200241China

Herein,we unveil the intelligent detection of multiple catechol isomers in complex environments utilizing both laser-induced graphene(LIG)and artificial neural network(ANN).The large scale-up manufacturing of LIG-based sensors(LIGS)with three-electrode configuration on polyimide(PI)is achieved by direct laser-writing and screen-printing *** LIGS shows excellent electrochemical performance toward catechol isomers,i.e.,hydroquinone(1,4-dihydroxybenzene,HQ),catechol(1,2-dihydroxybenzene,CT),and resorcinol(1,3-dihydroxybenzene,RC),with a low limit of detection(LOD)(CC,0.079μmol/L;HQ,0.093μmol/L;RC,1.18μmol/L).Moreover,the ANN model is developed for machine-intelligent to predict concentrations of catechol isomers under an interfering environment via a single *** six unique parameters extracted from the differential pulse voltammetry(DPV)response,the machine learning-based regression provides a coefficient of correlation with 0.998 and is able to correctly predict the total and individual concentrations in complex river ***,this work provides a guide for the preparation and application of LIGS via facile and cost-efficient mass production and the development of an intelligent sensing platform based on the ANN model.

关键词： Laser-induced graphene Phenolic pollutants Electrochemical detection Artificial neural network

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Airflow Analytical Toolkit(AAT):A MATLAB-based analyzer for holistic studies on the dynamic characteristics of airflows

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Building Simulation 2024年第7期17卷 1137-1159页

作者： Zuoyu Xie Junhui Fan Bin Cao Yingxin Zhu Department of Building Science School of ArchitectureTsinghua UniversityBeijingChina key laboratory of eco Planning&Green Building Ministry of Education(Tsinghua University)BeijingChina

The dynamic characteristics of different airflows on micro-scales have been explored from many perspectives since the late *** the one hand,most analytical tools and research subjects in previous contributions vary significantly:some only focus on fluctuant velocity features,while others pay attention to directional *** the other hand,despite the wide variety of existing analytical methods,they are not systematically classified and *** paper aims to establish a system including state-of-the-art tools for airflow analysis and to further design a holistic toolkit named Airflow Analytical Toolkit(AAT).The AAT contains two tools,responsible for analyzing the velocity and direction characteristics of airflows,each of which is integrated with multiple analytical *** assess the performance of the developed toolkit,we further take typical natural and mechanical winds as cases to show its excellent analytical *** the help of this toolkit,the great differences in velocity and directional characteristics among different airflows are *** comparative results reveal that not only is the velocity of natural wind more fluctuating than that of mechanical wind,but its incoming flow direction is also more *** AAT,serving as a powerful and user-friendly instrument,will hopefully offer great convenience in data analysis and guidance for a deeper understanding of the dynamic characteristics of airflows,and further remedy the gap in airflow analytical tools.

关键词： airflow analysis dynamic characteristic wind velocity wind direction thermal comfort wind comfort

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Total-factor energy efficiency of ten major global energy-consuming countries

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Journal of Environmental Sciences 2024年第3期137卷 41-52页

作者： Xuan Wang Yonglong Lu Chunci Chen Xiaojie Yi Haotian Cui State key laboratory of Urban and Regional ecology Research Centre for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China State key laboratory of Marine Environmental Science and key laboratory of the Ministry of Education for Coastal Wetland ecosystems College of the Environment and EcologyXiamen UniversityFujian 361102China University of Chinese Academy of Sciences Beijing 100049China

Improving energy efficiency is regarded as a key path to tackling global warming and achieving the Sustainable Development Goals(SDGs).In 2020,the energy consumption of the world's ten major energy-consuming countries accounted for 66.8%of the global *** paper applied data envelopment analysis(DEA)to calculate these ten major energyconsuming countries'total-factor energy efficiency(TFEE)at national and sectoral levels from 2001-2020,and explored the infuencing factors of total-factor energy efficiency with the Tobit regression *** results showed significant difference in the ten countries'energy *** United States and Germany topped the list for total-factor energy efficiency,while China and India were at the ***,the energy efficiency of the industrial subsector has increased significantly over the past two decades,while that of the other subsectors has been relatively *** industrial structure upgrading,per capita GDP,energy consumption structure,and foreign direct investment had significant impacts on energy efficiency with national *** consumption structure and GDP per capita were determinative factors of energy efficiency.

关键词： Total-factor energy efficiency SBM-UN model Major energy-consuming country Carbon emission reduction

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Experimental demonstration of a quantum downstream access network in continuous variable quantum key distribution with a local local oscillator

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Photonics Research 2024年第6期12卷 1262-1273页

作者： DENGKE QI XIANGYU WANG ZHENGHUA LI JIAYU MA ZIYANG CHEN YUEMING LU SONG YU State key laboratory of Information Photonics and Optical Communications Beijing University of Posts and TelecommunicationsBeijing 100876China key laboratory of Trustworthy Distributed Computing and Service(MoE) Beijing University of Posts and TelecommunicationsBeijing 100876China State key laboratory of Advanced Optical Communication Systems and Networks School of Electronicsand Center for Quantum Information TechnologyPeking UniversityBeijing 100871China

Quantum networks provide opportunities and challenges across a range of intellectual and technical frontiers,including quantum computation,communication,and *** traditional communication networks,quantum networks utilize quantum bits rather than classical bits to store and transmit *** key distribution(QKD)relying on the principles of quantum mechanics is a key component in quantum networks and enables two parties to produce a shared random secret key,thereby ensuring the security of data *** this work,we propose a cost-effective quantum downstream access network structure in which each user can get their corresponding key information through terminal *** on this structure,we demonstrate the first four-end-users quantum downstream access network in continuous variable QKD with a local local *** contrast to point-to-point continuous variable QKD,the network architecture reevaluates the security of each user and accounts for it accordingly,and each user has a lower tolerance for excess noise as the overall network expands with more ***,the feasibility of the experiment is based on the analysis of the theoretical model,noise analysis,and multiple techniques such as the particle filter and adaptive equalization algorithm used to suppress excess *** results show that each user can get a low level of excess noise and can achieve secret key rates of 546 kbps,535 kbps,522.5 kbps,and 512.5 kbps under a transmission distance of 10 km,respectively,with the finite-size block of 1×10~*** not only verifies the good performance but also provides the foundation for the future multi-user quantum downstream access networks.

关键词： quantum oscillator local

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Changes in global land surface frozen ground and freeze-thaw processes during 1950-2020 based on ERA5-Land data

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Advances in Climate Change Research 2024年第2期15卷 265-274页

作者： Yong YANG Ren-Sheng CHEN Yong-Jian DING Hong-Yuan LI Zhang-Wen LIU Qilian Alpine ecology and Hydrology Research Station Key Laboratory of Ecological Safety and Sustainable Development in Arid LandsNorthwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 73000China State key laboratory of Cryospheric Sciences Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 73000China Shandong Provincial key laboratory of Water and Soil Conservation and Environmental Protection College of Resources and EnvironmentLinyi UniversityLinyi 276000China

Frozen ground(FG)plays an important role in global and regional climates and environments through changes in land freeze-thaw processes,which have been conducted mainly in different ***,the changes in land surface freeze-thaw processes under climate change on a global scale are still *** on ERA5-Land hourly land skin temperature data,this study evaluated changes in the global FG area,global land surface first freeze date(FFD),last freeze date(LFD)and frost-free period(FFP)from 1950 to *** results show that the current FG areas(1991-2020 mean)in the Northern Hemisphere(NH),Southern Hemisphere(SH),and globe are 68.50×10^(6),9.03×10^(6),and 77.53×10^(6)km^(2),which account for 72.4%,26.8%,and 60.4%of the exposed land(excluding glaciers,ice sheets,and water bodies)in the NH,SH and the globe,respectively;further,relative to 1951-1980,the FG area decreased by 1.9%,8.8%,and 2.8%,*** FG at lower latitudes degrades to intermittently FG,and intermittently FG degrades to non-frozen ground,which caused the global FG boundary to retreat to higher latitudes from 1950 to *** annual FG areas in the NH,SH,and globe all show significant decreasing trends(p<0.05)from 1950 to 2020 at-0.32×10^(6),-0.22×10^(6),and-0.54×10^(6)km^(2)per decade,*** FFP prolongation in the NH is mainly influenced by LFD advance,while in the SH it is mainly controlled by FFD *** prolongation trend of FFP in the NH(1.34 d per decade)is larger than that in the SH(1.15 d per decade).

关键词： Frozen ground Freeze-thaw processes Frost-free period First freeze date Global warming

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