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Carboniferous integrative stratigraphy,biotas,and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年第4期67卷 1071-1106页

作者： keyi HU Xiangdong WANG Wenqi WANG Yingfan SONG Xunyan YE Lu LI Yukun SHI Sunrong YANG Ying LI State key Laboratory for mineral deposits Research School of Earth Sciences and Engineering and Frontiers Science Center for Critical Earth Material CyclingNanjing UniversityNanjing 210023China

During the Carboniferous Period,the Qinghai-Tibetan Plateau and its surrounding areas were located in quite different paleogeographic positions with various sedimentary and biological *** is important to systematically compile and summarize the Carboniferous strata and biotas of the Qinghai-Tibetan Plateau and its surrounding areas,to establish an integrated stratigraphic framework for correlation,and to reconstruct the paleogeography for correctly understanding the breakup of the Gondwana Continent and the evolution of the Paleo-Tethys Ocean in the Late *** Carboniferous of the Qinghai-Tibetan Plateau and its surrounding areas can be subdivided into the Gondwanan,Cimmerian,and Tethyan *** Gondwanan-type Carboniferous are distributed in the North Himalayan,Kangmar-Lhunze,and Zanda-Zumba regions of the South Tibet Subprovince and northern India-Pakistan Area,where only the Mississippian is developed and the biota is of Gondwanan *** Cimmerian-type Carboniferous,which are found in the Baoshan,Tengchong,Coqen-Xainza,LhasaZayu,Nagqu-Biru,and South Qiangtang regions,as well as Shan-Thai and South Afghanistan-Pamir areas,also represent only the Mississippian strata,but their biota is characterized by mixed characters of European,South China,Australian,and North American *** Tethyan-type Carboniferous are distributed in the Tanggula Mountains,Hoh Xil-Bayanhar,ChamdoHengduanshan,Tiekelike,West Kunlun,Karakorum,East Kunlun-Central Qinling,and Qilian regions,where the Carboniferous succession is well developed,and the biota is of warm-water Tethyan *** biostratigraphical correlation of the Gondwanan-type and Cimmerian-type Carboniferous is based mainly on conodonts and additionally on brachiopods and rugose *** Mississippian of the Tethyan-type Carboniferous is correlated mainly by using rugose corals and brachiopods,whereas in the Pennsylvanian foraminifera(fusuline)and conodonts are regarded as primary fossil groups,subord

关键词： Qinghai-Tibetan Plateau Carboniferous Lithostratigraphy Biota Stratigraphic correlation

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Zircon Hf Isotope Mapping for Understanding Crustal Architecture and Its Controls on mineralization during Early Cretaceous in the Southern Great Xing'an Range,NE China

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Journal of Earth Science 2024年第1期35卷 41-50页

作者： Feng Yuan Huanan Liu Shengjin Zhao Mingjing Fan State key Laboratory of Geological Processes and mineral Resources Collaborative Innovation Center for Exploration of Strategic Mineral ResourcesSchool of Earth ResourcesChina University of GeosciencesWuhan 430074China State key Laboratory of Geological Processes and mineral Resources School of Earth Sciences and ResourcesChina University of GeosciencesBeijing100083China No.10 Institute of Geological Exploration Inner Mongolia Bureau of Geology and Mineral ResourcesChifeng 024000China key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China

Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE *** on previously published geochronology and zircon Hf-isotope data,Hf isotope mapping is undertaken to improve our understanding of crustal architecture and its controls on ore *** ore-related Early Cretaceous granitoids were sourced predominantly from juvenile crust,with the involvement of variable proportions of ancient crustal *** crustal architecture,as inferred from Hf isotopic contour maps,indicates two distinct Hf isotopic domains in SGXR,including(1)a higher-ε_(Hf)(+7 to+11)juvenile crust containing minor ancient crustal material,and(2)a lower-ε_(Hf)(+2 to+6)juvenile crust containing a greater proportion of ancient crustal *** Hf isotopic maps identify links between crustal architecture and regional *** deposits and other deposits with significant Cu production are restricted mainly to the higher-ε_(Hf)juvenile crustal regions in the northern and eastern *** dominated by other metals(e.g.,Mo,Sn,W,Pb,Zn,and Ag)occur mainly in the lower-ε_(Hf)juvenile crustal regions in the southern and western *** between juvenile crust-derived melts and ancient crustal components played an important role on the distribution of various ore metals.

关键词： Hf isotope mapping crustal architecture large-scale Early Cretaceous granitoids distribution of ore deposits southern Great Xing'an Range zircon

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Integrative Carboniferous stratigraphy, biotas and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年

During the Carboniferous Period, the Qinghai-Tibetan Plateau and its surrounding areas were located in quite different paleogeographic positions with various sedimentary and biological types. It is important to systematically compile and summarize the Carboniferous strata and biotas of the Qinghai-Tibetan Plateau and its surrounding areas, to establish an integrated stratigraphic framework for correlation, and to reconstruct the paleogeography for correctly understanding the breakup of the Gondwana Continent and the evolution of the Paleo-Tethys Ocean in the Late Paleozoic. The Carboniferous of the Qinghai-Tibetan Plateau and its surrounding areas can be subdivided into the Gondwanan, Cimmerian, and Tethyan types. The Gondwanan-type Carboniferous are distributed in the North Himalayan, Kangmar-Lhunze, and Zanda-Zumba regions of the South Tibet Subprovince and northern India-Pakistan Area, where only the Mississippian is developed and the biota is of Gondwanan affinity. The Cimmerian-type Carboniferous, which are found in the Baoshan, Tengchong, Coqen-Xainza, LhasaZayu, Nagqu-Biru, and South Qiangtang regions, as well as Shan-Thai and South Afghanistan-Pamir areas, also represent only the Mississippian strata, but their biota is characterized by mixed characters of European, South China, Australian, and North American types. The Tethyan-type Carboniferous are distributed in the Tanggula Mountains, Hoh Xil-Bayanhar, ChamdoHengduanshan, Tiekelike, West Kunlun, Karakorum, East Kunlun-Central Qinling, and Qilian regions, where the Carboniferous succession is well developed, and the biota is of warm-water Tethyan affinity. The biostratigraphical correlation of the Gondwanan-type and Cimmerian-type Carboniferous is based mainly on conodonts and additionally on brachiopods and rugose corals. The Mississippian of the Tethyan-type Carboniferous is correlated mainly by using rugose corals and brachiopods,whereas in the Pennsylvanian foraminifera(fusuline) and conodonts are reg

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Discovery and Significance of Layered Chromite mineralization in Mafic-Ultramafic Rocks from the Gayahe Area of the East Kunlun Orogenic Belt,Northwestern China

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Journal of Earth Science 2024年第4期35卷 1367-1372页

作者： Shao-Yong Jiang Hailin Xie Wenqi Ren Bin Wang Feng Yuan Xiufeng Liu Hui-Min Su State key Laboratory of Geological Processes and mineral Resources Collaborative Innovation Center for Exploration of Strategic Mineral ResourcesSchool of Earth ResourcesChina University of GeosciencesWuhan 430074China Qinghai Engineering Research center of Deep Exploration Technology for Large and Ultra-Large Gold deposits around Qaidam Basin First Geological Exploration Institute of Qinghai ProvinceHaidong 810600China

0 INTRODUCTION Chromium(Cr)is one of the most important strategic critical metals in *** primary chromite deposits can be divided into two types according to their geological setting and occurrences:podiform chromite and stratiform/layered chromite(Stowe,1994;Paktunc,1990).Podiform chromites mainly occur in ophiolites or mantle peridotites(Yang et al.,2022,2010;Bao et al.,1999).

关键词： China mantle setting

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Natural marmatite photocatalyst for treatment of mineral processing wastewater to help zero wastewater discharge

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Journal of Environmental Sciences 2024年第8期142卷 83-91页

作者： Meirong Wu Wei Sun Xiangsong Meng Jianhua Kang Yue Yang School of minerals Processing and Bioengineering Central South UniversityChangsha 410083China key Laboratory of Hunan Province for Clean and Efficient Utilization of strategic Calcium-containing mineral Resources Central South UniversityChangsha 410083China

mineral processing wastewater(MPW)with large discharge and high toxicity affects environmental safety,and the realizing zero discharge of MPW is of great significance for reducing environmental pollution,saving water resources,and promoting the sustainable development of the mining *** this study,we reported natural marmatite(NM)as a low-cost and efficient photocatalyst for the treatment of MPW to help zero wastewater *** photocatalytic activity of NM was evaluated by the removal of total organic carbon(TOC)from MPW under visible-light illumination,and the optimal degradation conditions were *** showed that superoxide free radicals(^(·)O_(2)^(-))were the dominant active species responsible for organic pollutants degradation,and 74.25%TOC removal was obtained after 120 min reaction under the optimum treatment ***,the wastewater treated by NM photocatalysis can be reused in the flotation system without adverse impact on the product *** on these findings,a model of zero wastewater discharge for flotation with the help of photocatalytic treatment was established,it indicated that the water of the whole system can be balanced without affecting the ore dressing index,which showed that visible light-driven photocatalyst has a promising application prospect in the treatment and recycling of industrial wastewater.

关键词： Natural mineral Photocatalysis Industrial wastewater Wastewater recycling Water balance

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Preparation of Kω-g-C_(3)N_(4) composite loaded on magnetic attapulgite and its degradation performance for malachite green

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Chinese Journal of Chemical Engineering 2024年第7期71卷 110-121页

作者： Aishun Ma Hanlin Qian Hongxia Liu Sili Ren Jiangxi key Laboratory of Mining&Metallurgy Environmental Pollution Control Jiangxi University of Science and TechnologyGanzhou 341000China Jiangxi Provincial key Laboratory of Low-Carbon Processing and Utilization of strategic Metal mineral Resources Jiangxi University of Science and TechnologyGanzhou 341000China

Visible-light-driven photocatalysis is a promising technology for the treatment of dye *** this work,a novel photocatalyst of Kω-g-C_(3)N_(4) loaded on magnetic attapulgite(ATP)(K-g-C_(3)N_(4)@ATP-Fe_(3)O_(4))with excellent visible light photocatalytic properties and stability were successfully prepared and *** removal efficiency of K-g-C_(3)N_(4)@ATP-Fe_(3)O_(4) for malachite green(MG)was studied,and the degradation mechanism was analyzed and *** was found that the K_(5)-g-C_(3)N_(4)@ATP-Fe_(3)O_(4) photocatalyst possessed excellent degradation efficiency of over 98.0%for the MG dye wastewater under optimal ***,the K_(5)-g-C_(3)N_(4)@ATP-Fe_(3)O_(4) materials possessed good recyclability with a removal rate over 82%after 4 *** visible light condition,the K_(5)-g-C_(3)N_(4)@ATP-Fe_(3)O_(4) photocatalyst produce radicals of·OH and O_(2)^(-)to degrade the MG dyes,which was supported by electron paramagnetic resonance(EPR)and radical trapping *** addition,the LC-MS analysis interpreted the degradation pathways and intermediates of MG in the *** findings in this work indicate that the prepared photocatalytic material has excellent degradation efficiency for MG and can be applied in dye wastewater treatment.

关键词： Photocatalyst Malachite green Kω-g-C_(3)N_(4) Degradation

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Ore Geology,H-O-C Isotopes and 40Ar-39Ar Dating of the Wutonggou Iron Deposit,Eastern Tianshan,NW China:Implications for the Source,Timing,and Genesis of Hydrothermal mineralization in a Sedimentary Iron Deposit

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Journal of Earth Science 2024年第4期35卷 1170-1185页

作者： Chun-Long Wang Yi-Tian Wang State key Laboratory of Geological Processes and mineral Resources Collaborative Innovation Center for Exploration of Strategic Mineral ResourcesSchool of Earth ResourcesChina University of GeosciencesWuhan430074China MNR key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing100037China

The Wutonggou iron deposit is located in the well-known iron metallogenic belt in the eastern Tianshan,NW China,and has been regarded as a sedimentary iron *** hydrothermal overprinting could play indispensable roles in the formation of high-grade iron ores in sedimentary iron deposits,previous studies mainly focused on sedimentary-related iron mineralization,while the nature and contribution of hydrothermal fluids are poorly ***,an integrated study of ore geology,H-O-C isotopes and^(40)Ar-^(39)Ar dating,is conducted on the Wutonggou deposit,in order to reveal the features,source,and timing of hydrothermal *** studied deposit includes two mining sections namely the Jianshan and ***δ^(18)O values of early magnetite from the Jianshan section range from+3.0‰to+5.8‰that nearly consistent with classic magmatic magnetite,while increase to 6.3‰-8.0‰in the late *** from the two sections shows comparable H-O isotopic compositions and identical fractionation trends,and is plotted in or periphery to the primary magmatic water *** from the two sections are broadly similar in carbon and oxygen isotopic compositions,and siderite from the Wutonggou section is plotted in the same ***,comparable stable isotopic compositions and evolution trends indicate similar magmatic fluids contributed hydrothermal iron mineralization in the two mining ***,water-rock interactions of varying degrees generated distinct mineralization styles in the Jianshan and Wutonggou sections,and caused the isotopic fractionation in late *** extracted from a hydrothermal siderite ore yielded a^(40)Ar-^(39)Ar plateau age of 299.5±2.0 Ma,indicates the timing of hydrothermal iron mineralization is corresponding to the emplacement of vicinity *** together,the hydrothermal mineralization in the Wutonggou iron deposit was the product of remobilization and upgrading of early sedimentary iron ores,a

关键词： iron deposits H-O-C isotopes 40Ar-39Ar dating sedimentary iron deposits Wutonggou iron deposit eastern Tianshan

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Advances in depressants for flotation separation of Cu–Fe sulfide minerals at low alkalinity:A critical review

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International Journal of minerals,Metallurgy and Materials 2024年第1期31卷 1-17页

作者： Qicheng Feng Wenhang Yang Maohan Chang Shuming Wen Dianwen Liu Guang Han State key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Faculty of Land Resource EngineeringKunming University of Science and TechnologyKunming 650093China Yunnan key Laboratory of Green Separation and Enrichment of strategic mineral Resources Kunming University of Science and TechnologyKunming 650093China

The flotation separation of Cu–Fe sulfide minerals at low alkalinity can be achieved using selective *** the flotation system of Cu–Fe sulfide minerals,depressants usually preferentially interact with the pyrite surface to render the mineral surface hydrophilic and hinder the adsorption of the *** review summarizes the advances in depressants for the flotation separation of Cu–Fe sulfide minerals at low *** advances include use of inorganic depressants (oxidants and sulfur–oxygen compounds),natural polysaccharides (starch,dextrin,konjac glucomannan,and galactomannan),modified polymers (carboxymethyl cellulose,polyacrylamide,lignosulfonate,and tricarboxylate sodium starch),organic acids (polyglutamic acid,sodium humate,tannic acid,pyrogallic acid,salicylic acid,and lactic acid),sodium dimethyl dithiocarbamate,and *** potential application of specific inorganic and organic depressants in the flotation separation of Cu–Fe sulfide minerals at low alkalinity is *** advances in the use of organic depressants with respect to the flotation separation of Cu–Fe sulfide minerals are comprehensively ***,the depression performances and mechanisms of different types of organic depressants on mineral surfaces are ***,several perspectives on depressants vis-à-vis flotation separation of Cu–Fe sulfide minerals at low alkalinity are proposed.

关键词： Cu–Fe sulfide minerals flotation separation selective depressants depression mechanism

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Enhancing Geological Understanding and Identifying Gold Anomalies in the Ailaoshan Orogen

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Acta Geologica Sinica(English Edition) 2024年第2期98卷 441-453页

作者： ZHAO Shiyu YANG Lin SONG Yiwei DONG Yuntao FENG Lihao LI Huajian WU Junyu WANG Qingfei State key Laboratory of Geological Processes and mineral Resources China University of GeosciencesBeijing 100083China Xi’an center of mineral Resources Survey China Geological SurveyXi’an 710010China Yunnan Gold Mining Industry Group Kunming 650299China Jiangxi Provincial key Laboratory of Genesis and Prospect for strategic minerals East China University of TechnologyNanchang 330013China Frontiers Science center for Deep-time Digital Earth China University of Geosciences(Beijing)Beijing 100083China

The Ailaoshan Orogen in the southeastern Tibet Plateau,situated between the Yangtze and Simao blocks,underwent a complex structural,magmatic,and metamorphic evolution resulting in different tectonic subzones with varying structural lineaments and elemental *** elements can conceal or reduce anomalies due to the mutual effect between different anomaly *** the whole zone into subzones based on tectonic settings,ore cluster areas,or sample catchment basins(Scb),geochemical and structural anomalies associated with gold(Au)mineralization have been identified utilizing mean plus twice standard deviations(Mean+2STD),factor analysis(FA),concentration-area(CA)modeling of stream sediment geochemical data,and lineament density in both the Ailaoshan Orogen and the individual *** FA in the divided 98 Scbs with 6 Scbs containing Au deposits can roughly ascertain unknown rock types,identify specific element associations of known rocks and discern the porphyry or skarn-type Au *** with methods of Mean+2STD and C-A model of data in the whole orogen,which mistake the anomalies as background or act the background as anomalies,the combined methods of FA and C-A in the separate subzones or Scbs works well in regional metallogenic potential *** of lineament densities with a 10-km circle diameter is not suitable to locate Au deposits because of the delineated large areas of medium-high lineament *** contrast,the use of circle diameters of 1.3 km or 1.7 km in the ore cluster scale delineates areas with a higher concentration of lineament density,consistent with the locations of known Au *** analyzing the map of faults and Au anomalies,two potential prospecting targets,Scbs 1 and 63 with a sandstone as a potential host rock for Au,have been identified in the Ailaoshan *** use of combined methods in the divided subzones proved to be more effective in improving geological understanding and identifying

关键词： minerology geochemistry gold stream sediment sample catchment basin concentration-area model lineament density Ailaoshan Orogen

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Factors controlling the metal fertilization of granitic magma: Constraints from amphibole and biotite geochemistry of the Shangcheng pluton， Dabie orogen， Central China

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Journal of Earth Science 2024年

作者： Cheng-Lai Deng Hui-Min Su Wu Li Wen-Tian Li State key Laboratory of Geological Processes and mineral Resources Collaborative Innovation center for Exploration of strategic mineral Resources School of Earth Resources China University of Geosciences Wuhan School of Resources and Geosciences China University of Mining and Technology

It is very common for similar granitoids to be emplaced in the same tectonic region， with some being metal-fertilized while others are barren. The reasons for this are still not clear. Here， we take the Shangcheng pluton as an example. This pluton occurs close to the giant Shapinggou porphyry Mo deposit， and we use amphibole and biotite geochemistry as sensitive tracers to explore this issue. The Shangcheng granitoids comprise the Sigudun （SGD） and Shiguwa （SGW） units， with emplacement ages ranging from 140 ± 3 Ma to 134 ± 2.4 Ma， as revealed by titanite U-Pb dating. The geochemical data of amphibole and biotite indicate that the magma intruded from depths of ～3.3 km to ～2.3 km with increasing oxygen fugacity. The modeled results indicate that water content is an essential factor for metal fertilization， as the Shangcheng pluton has a lower water content than the Shapinggou Mo-bearing granite. The Shangcheng pluton is also characterized by fluorine-poor conditions， with lower halogen fugacity values of IV（F） and log (f H2O/f HF)fluid. In contrast， the increasing Y/Ho and Nb/Ta ratios of the Shapinggou Mo-bearing granite indicate the F-rich nature of the fertilized Shapinggou magma， and its lower Zr/Hf and K/Rb ratios suggest a greater magma differentiation. Therefore， water-poor and F-poor magma， in combination with low-degree fractional crystallization， may be the major controlling factors responsible for the Mo-barren nature of the Shangcheng pluton.

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