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Absorption mechanism of SO_(3)on various alkaline absorbents in the presence of SO_(2)

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Journal of Environmental Sciences 2025年第3期149卷 268-277页

作者： Junxiang Guo Jin Xiong Yuran Li Jirigele Qinggele Tingyu Zhu Shougang Group Research Institute of Technology Beijing 100043China Beijing key laboratory of Green Recyclable process for Iron&Steel Production Technology Beijing 100043China CAS key laboratory of Green process and engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China WISDRI City Environment Protection engineering Limited Company Wuhan 430205China

Sulfur trioxide(SO_(3))as a condensable particle matter has a significant influence on atmospheric visibility,which easily arouses formation of *** is imperative to control the SO_(3)emission from the industrial flue *** commonly used basic absorbents,including Ca(OH)_(2),MgO and NaHCO_(3)were selected to explore the effects of temperature,SO_(2)concentration on the SO_(3)absorption,and the reaction mechanism of SO_(3)absorption was further *** suitable reaction temperature for various absorbents were proposed,Ca(OH)_(2)at the high temperatures above 500°C,MgO at the low temperatures below 320°C,and NaHCO_(3)at the temperature range of 320–500°*** competitive absorption between SO_(2)and SO_(3)was found that the addition of SO_(2)reduced the SO_(3)absorption on Ca(OH)_(2)and NaHCO_(3),while had no effect on *** order of the absorption selectivity of SO_(3)follows MgO,NaHCO_(3)and Ca(OH)_(2)under the given conditions in this *** absorption process of SO_(3)on NaHCO_(3)follows the shrinking core model,thus the absorption reaction continues until NaHCO_(3)was exhausted with the utilization rate of nearly 100%.The absorption process of SO_(3)on Ca(OH)_(2)and MgO follows the grain model,and the dense product layer hinders the further absorption reaction,resulting in low utilization of about 50%for Ca(OH)_(2)and *** research provides a favorable support for the selection of alkaline absorbent for SO_(3)removal in application.

关键词： Alkali absorbent Sulfur trioxide Selectivity Shrinking core model Grain model

Adsorption removal of mercury from flue gas by metal selenide:A review

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Journal of Environmental Sciences 2025年第2期148卷 420-436页

作者： Yang Zheng Guoliang Li Yi Xing Wenqing Xu Tao Yue School of Energy and Environmental engineering University of Science and Technology BeijingBeijing 100083China State key laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China CAS key laboratory of Green process and engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China

Mercury(Hg)pollution has been a global concern in recent decades,posing a significant threat to entire ecosystems and human health due to its cumulative toxicity,persistence,and transport in the *** intense interaction between mercury and selenium has opened up a new field for studying mercury removal from industrial flue gas *** the advantages of good Hg0 capture performance and lowsecondary pollution of the mineral selenium compounds,the most noteworthy is the relatively low regeneration temperature,allowing adsorbent regeneration with low energy consumption,thus reducing the utilization cost and enabling recovery of mercury *** paper reviews the recent progress of mineral selenium compounds in flue gas mercury removal,introduces in detail the different types ofmineral selenium compounds studied in the field ofmercury removal,reviews the adsorption performance of various mineral selenium compounds adsorbents on mercury and the influence of flue gas components,such as reaction temperature,air velocity,and other factors,and summarizes the adsorption mechanism of different fugitive forms of selenium *** on the current research progress,future studies should focus on the economic performance and the performance of different carriers and sizes of adsorbents for the removal of Hg0 and the correlation between the gas-particle flow characteristics and gas phase mass transfer with the performance of Hg0 removal in practical industrial *** addition,it remains a challenge to distinguish the oxidation and adsorption of Hg0 quantitatively.

关键词： Non-conventional pollutants Adsorbents Metal selenides Flue gas Mercury removal

Dynamic event-triggered data-driven iterative learning bipartite tracking control for nonlinear MASs with prescribed performance

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Science China(Information Sciences) 2025年第1期68卷 292-305页

作者： Tao SHI Wei-Wei CHE School of Mechatronic engineering and Automation Shanghai University State key laboratory of Synthetical Automation for process Industries Northeastern University College of Information Science and engineering Northeastern University

This article proposes a distributed dynamic event-triggered data-driven iterative learning control(DET-DDILC)scheme under a predefined performance to tackle the bipartite tracking control problem for multiagent systems(MASs). An improved dynamic linearization technique is utilized to convert the nonlinear MASs into an iterative linear data model. First,a peer-to-peer mapping function is introduced to map the constrained distributed system output homeomorphism to an unconstrained one. In addition, a DET mechanism based on a time-iteration-varying function is devised to conserve network communication resources. Based on the unconstrained transformation and the designed DET mechanism, the DET-DDILC algorithm is devised to ensure that the bipartite tracking performance of MASs can be within the preset range. Finally, the effectiveness and feasibility of the designed control scheme are demonstrated via a simulation case by a comparison.

关键词： bipartite tracking control prescribed performance event-triggered iterative learning control multiagent systems

Selenate oxyanion-intercalated NiFeOOH for stable water oxidation via lattice oxygen oxidation mechanism

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Journal of Energy Chemistry 2025年第2期101卷 676-684页

作者： Yijie Zhang Weiyi Zhang Xiaowen Zhang Jinping Li Guang Liu Shanxi key laboratory of gas Energy Efficient and Clean Utilization College of Chemical Engineering and Technology Taiyuan University of Technology Shanxi Research Institute of Huai Rou laboratory

Transition metal-based compounds can serve as pre-catalysts to obtain genuine oxygen evolution reaction（OER） electrocatalysts in the form of oxyhydroxides through electrochemical ***,the role and existence form of leached oxygen anions are still ***,we selected iron selenite-wrapped hydrated nickel molybdate（denoted as NiMoO/FeSeO） as a pre-catalyst to study the oxyanion *** is surprising to find that SeO2-exists in the catalyst in the form of intercalation,which is different from previous studies that suggest that anions are doped with residual elements after electrochemical activation,or adsorbed on the catalyst *** experiment and theoretical calculations show that the existence of SeO42-intercalation effectively adjusts the electronic structure of NiFeOOH,promotes intramolecular electron transfer and O-O release,and thus lowers the reaction energy *** expected,the synthesized NiFeOOH-SeO only needs 202 and 285 mV to attain 100 and 1000 mA cm-2in 1 M ***,the anion exchange membrane water electrolyzer（AEMWE） consisting of NiFeOOHSeO anode and Pt/C cathode can reach 1 A cm-2at 1.70 V and no significant attenuation within 300 *** findings provide insights into the mechanism,by which the intercalated oxyanions enhance the OER performance of NiFeOOH,thereby facilitating large-scale hydrogen production through AEMWE.

关键词： Anion exchange membrane electrolyzer Industrial current densities Lattice oxygen oxidation Oxyanion intercalation Water splitting

Aerodynamic Optimization and Flow Mechanism for a Compressor Cascade at Low Reynolds Number

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Journal of Thermal Science 2025年第1期34卷 92-109页

作者： LI Lin ZHANG Jianshe CHEN Caiyan TAN Wei ZHANG Yanfeng key laboratory of Light-Duty gas-Turbine Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China National key laboratory of Science and Technology on Advanced Light-duty gas-turbine Beijing 100190China

Low-Reynolds-number effect is an important factor affecting the performance of compressors and other main components of high-altitude long-endurance unmanned aerial *** improve the flow condition and reduce flow loss under the condition of high altitude and low Reynolds number(Re),this paper proposes an optimization process based on a surrogate model,which combines the class-shape transformation method(CST),the Latin hypercube sampling(LHS)method,the light gradient-boosting machine algorithm(LightGBM),and a genetic algorithm(GA)to optimize a high-subsonic compressor *** surrogate model is verified to be accurate and can be used in the optimization *** accuracy of the GA is higher than the other algorithms under common test *** optimization results are verified by numerical simulation,and the flow differences before and after optimization are compared,especially the flow within the boundary *** changing the blade shape,the optimization process adjusts the loading distribution to delay the transition of the optimized blade on the suction surface,which changes the turbulent reattachment in the laminar separation bubble(LSB)into laminar ***,the mixing loss induced by the turbulent reattachment of the LSB and the wake loss of turbulent separation at the trailing edge are significantly reduced,and the performance of the compressor profile is finally *** addition,turbulent separation of the optimized profile is delayed reducing the range of the wake region on the suction *** this optimization process,the reduction of total pressure loss coefficient at Re of 2.5×10^(5),3.5×10^(5),and 4.5×10^(5) are 16.32%,20.76%,and 22.16%,respectively.

关键词： low Reynolds numbers compressor optimization boundary layer transition

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Adsorption and retention of fracturing fluid and its impact on gas transport in tight sandstone with different clay minerals

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Petroleum Science 2025年第1期22卷 370-383页

作者： Yi-Jun Wang Li-Jun You Jian Yang Yi-Li Kang Ming-Jun Chen Jia-Jia Bai Jian Tian State key laboratory of Oil and gas Reservoir Geology and Exploitation Southwest Petroleum University engineering Technology Research Institute of Southwest Oil & gas Field Company PetroChina School of Petroleum engineering Changzhou University State key laboratory of Coal Mine Disaster Dynamics and Control Chongqing University

To elucidate the adsorption characteristics and retention mechanisms of fracturing fluids in diverse clay minerals, we conducted on-line nuclear magnetic resonance(NMR) and atomic force microscopy(AFM)experiments. The depth and extent of solid phase damage are determined by the ratio between the size of fine fractions in fracturing fluid residue and the pore-throat size in experiments. Poor physical properties(K 0.5 m D) combined with a scattered distribution of retained fracturing fluid is associated with high gas phase recovery permeability, whereas a continuous sheet-like distribution results in low recovery permeability. The expansive surface area and presence of filamentous illite minerals facilitate the multiple winding and adsorption of fracturing fluids, demonstrating strong hydrogen-bonding, multi-layering and multiple adsorption properties. The geological characteristics of the main gas formations exhibit significant variation, and the severity of damage caused by fracturing fluids occurs in diverse sequences. To address this issue, a differentiated strategy for optimizing fracturing fluids has been proposed.

关键词： Clay minerals Formation damage Fracturing fluid retention distribution Adsorption morphology

Synthesis ofδ-MnO_(2)via ozonation routine for low temperature formaldehyde removal

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Journal of Environmental Sciences 2025年第1期147卷 642-651页

作者： Guijun Fan Yacong Guo Shaohua Chai Le Zhang Jian Guan Guojun Ma Ning Han Yunfa Chen State key laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China College of Chemical engineering University of Chinese Academy of SciencesBeijing 100049China key laboratory of Science and Technology on Particle Materials Institute of Process EngineeringChinese Academy of SciencesBeijing 361021China key laboratory for Mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Petrochemical engineering&Environment Zhejiang Ocean UniversityZhoushan 316022China

Nowadays,it is still a challenge to prepared high efficiency and low cost formaldehyde(HCHO)removal catalysts in order to tackle the long-living indoor air ***,δ-MnO_(2)is successfully synthesized by a facile ozonation strategy,where Mn^(2+)is oxidized by ozone(O_(3))bubble in an alkaline *** presents one of the best catalytic properties with a low 100%conversion temperature of 85℃for 50 ppm of HCHO under a GHSV of 48,000 mL/(g·hr).As a comparison,more than 6 times far longer oxidation time is needed if O3 is replaced by O_(2).Characterizations show that ozonation process generates a different intermediate of tetragonalβ-HMnO_(2),which would favor the quick transformation into the final productδ-MnO_(2),as compared with the relatively more thermodynamically stable monoclinicγ-HMnO_(2)in the O_(2)***,HCHO is found to be decomposed into CO_(2)via formate,dioxymethylene and carbonate species as identified by room temperature insitu diffuse reflectance infrared fourier transform *** these results show great potency of this facile ozonation routine for the highly activeδ-MnO_(2)synthesis in order to remove the HCHO contamination.

关键词： δ-MnO_(2) Ozone oxidation HCHO oxidation In-situ DRIFTS

Density functional theory studies of Pt-based catalysts for CO oxidation

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Science China Technological Sciences 2025年第3期68卷 58-75页

作者： Xue LI Yang ZOU Yongqi ZHAO Xiaolong LIU Tingyu ZHU CAS key laboratory of Green process and engineering Institute of Process Engineering Chinese Academy of Sciences key laboratory of Green and High-value Utilization of Salt Lake Resources Chinese Academy of Sciences

CO is highly toxic and seriously harmful to human health, so it is meaningful to control CO emissions, especially from industrial plants. Catalytic oxidation is regarded to be an effective method for CO removal, in which Pt-based catalysts show excellent performance. Studies of catalytic CO oxidation employing Pt-based catalysts often encounter challenges such as CO poisoning, challenges in activating O2, significant temperature sensitivity, and inadequate tolerance to water and sulfur species. These experimental hurdles have been corroborated by density functional theory（DFT） computations, which model adsorption, reaction pathways, and electronic structures at catalyst surfaces. DFT analysis has elucidated the underlying mechanisms behind these limitations, laying the foundation for enhancing the efficacy of Pt-based catalysts within the scope of academic discourse. DFT has been used intensively in recent years to study the reaction mechanism and functioning characteristics of Pt-based catalysts in CO oxidation. Consequently, advancements in research on DFT experiments on Pt-based catalysts are described. This review provides a comprehensive overview and insights into the mechanism of CO adsorption on the surface of single-atom and multi-atom Pt-based catalysts, its effect on CO oxidation performance, and reaction pathways of CO oxidation in the hope of providing theoretical guidance for the structural design of most effective catalysts.

关键词： platinum catalytic oxidation carbon monoxide density functional theory

Structure-phase transformation of bismuth oxide to Ta-Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder heterojunctions for efficient photocatalytic removal of antibiotic

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Journal of Environmental Sciences 2025年第3期149卷 149-163页

作者： Man Yang Zhenzhen Shi Shaodong Sun Bian Yang Jie Cui Jianing Li Daqin Yun Nian Lei engineering Research Center of Conducting Materials and Composite Technology Ministry of EducationShaanxi Engineering Research Center of Metal-Based Heterogeneous Materials and Advanced Manufacturing TechnologyShaanxi Province Key Laboratory for Electrical Materials and Infiltration TechnologySchool of Materials Science and EngineeringXi’an University of TechnologyXi’an 710048China College of Energy Xiamen UniversityXiamen 361005China Beijing key laboratory of Ionic Liquids Clean process Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Developing heterojunction photocatalyst with well-matched interfaces andmultiple charge transfer paths is vital to boost carrier separation efficiency for photocatalytic antibiotics removal,but still remains a great *** present work,a new strategy of chloride anion intercalation in Bi_(2)O_(3)via one-pot hydrothermal process is *** as-prepared Ta-BiOCl/Bi_(24)O_(31)Cl_(10)(TBB)heterojunctions are featured with Ta-Bi_(24)O_(31)Cl_(10)and Ta-BiOCl lined shoulder-by-shouleder via semi-coherent *** this TBB heterojunctions,the well-matched semi-coherent interfaces and shoulder-by-shoulder structures provide fast electron transfer andmultiple transfer paths,respectively,leading to enhanced visible light response and improved photogenerated charge ***,a type-II heterojunction for photocharge separation has been obtained,in which photogenerated electrons are drove from the CB(conduction band)of Ta-Bi_(24)O_(31)Cl_(10)to the both of bilateral empty CB of Ta-BiOCl and gathered on the CB of Ta-BiOCl,while the photogenerated holes are left on the VB(valence band)of Ta-Bi_(24)O_(31)Cl_(10),effectively hindering the recombination of photogenerated electron-hole ***,the separated electrons can effectively activate dissolved oxygen for the generation of reactive oxygen species(·O_(2)^(−)).Such TBB heterojunctions exhibit remarkably superior photocatalytic degradation activity for tetracycline hydrochloride(TCH)solution to Bi_(2)O_(3),Ta-BiOCl and Ta-Bi_(24)O_(31)Cl_(10).This work not only proposes a Ta-BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder micro-ribbon architectures with semi-coherent interfaces and successive type-Ⅱheterojunction for highly efficient photocatalytic activity,but offers a new insight into the design of highly efficient heterojunction through phasestructure synergistic transformation strategy.

关键词： Heterojunction Bismuth oxide Charge separation/transfer Photocatalytic degradation Catalytic mechanism