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Synthesis and optical properties of highly efficient Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+)blue phosphor for full-spectrum white-light-emitting diodes:The role of Li_(2)CO_(3)flux

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Journal of Rare Earths 2024年第7期42卷 1217-1223,I0001页

作者： Zihao Wang Sisi Liang Chenyang Zhan Kunyuan Xu Jie Hu Dejian Chen Liping Song Haomiao Zhu School of Physics and Materials Science Nanchang UniversityNanchang330000China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341000China CAS key laboratory of design and assembly of functional nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen Research Center of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China

Full-spectrum phosphor-converted white-light-emitting diodes(pc-WLED)are emerging as a mainstream technology in semiconductor ***,high-performance blue phosphor which can be excited efficiently by a 400 nm NUV diode chip is still ***,we present a blue-emitting Na_(3)KMg_(7)(PO_(4))6:Eu^(2+)phosphor synthesized by the solid-reaction ***,we find that the using of Li_(2)CO_(3)as flux can significantly improve the crystal quality and thus the emission efficiency of the ***,the excitation peak of the phosphor shifts from 365 to 400 nm,which is pivotal for efficient NUV(400 nm)diode chip *** practical Eu^(2+)concentration is also enhanced by using Li_(2)CO_(3)as flux,and the absorption efficiency is greatly *** phosphor exhibits superior PL thermal stability,namely retains 94%integrated photoluminescence intensity at 150℃of that at 25℃.As a result,the optimized phosphor shows an emission band peaked at 437 nm with a bandwidth of 40 nm and a high external photoluminescence quantum yield of 51.7%.Finally,a pc-WLED was fabricated by using NKMPO:Eu^(2+)blue,Sr_(2)SiO_(4):Eu^(2+)green,CaAlSiN_(3):Eu^(2+)red phosphors,and a 400 nm NUV diode *** shows a high color rendering index of R_(a)=96.4 and a correlated color temperature of 4358 *** results prove that NKMPO:Eu^(2+)is a promising blue phosphor for full-spectrum WLED based on NUV diode chips.

关键词： Eu^(2+) Blue phosphor Na_(3)KMg_(7)(PO_(4))_(6) Full-spectrum white LEDs Rare earths

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Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries

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Chinese Chemical Letters 2024年第7期35卷 473-479页

作者： Yan Wang Huixin Chen Fuda Yu Shanyue Wei Jinhui Song Qianfeng He Yiming Xie Miaoliang Huang Canzhong Lu Engineering Research Center of Environment-Friendly functional Materials Ministry of EducationInstitute of Materials Physical ChemistryHuaqiao UniversityXiamen 361021China CAS key laboratory of design and assembly of functional nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

Lithium-sulfur(Li-S)batteries with high theoretical capacity and energy density need to solve problems such as the high decomposition energy barrier of Li_(2)S and large volume change of sulfur in the charging process caused by the shuttle effect before practical ***,a green synthesis method is used to prepare polyacrylic acid(PAA)superabsorbent material,and then the pyrolyzed PAA(P/PAA)material is obtained as the positive electrode of Li-S *** functional calculation reveals that the oxygen self-doping pyrolyzed polyacrylic acid(P/PAA)delivered stronger binding energy toward Li2S species in carbonyl C=O than that of graphite powder(GP)which are-1.58 eV and-1.02 eV,*** with the distribution of relaxation time analysis and the in-situ electrochemical impedance approach,it is further demonstrated that the designed P/PAA as sulfur host plays a physical/chemical adsorption dual function in maintaining the stability and rate performance of *** an initial discharge capacity of 1258 mAh/g at 0.1 C and a minimal capacity decline of 0.05%per cycle even after 800 cycles at 0.5 C,the produced cathode demonstrated outstanding electrochemical *** average Coulombic efficiency is nearly 100%.The P/PAA electrodes may typically retain 96%of their capacity while declining on average only 0.033%per cycle after 130 cycles at 3 *** effort provides a new method for the future development of heteroatomic self-doping superabsorbent with promising adsorption properties for polysulfides as cathode materials of Li-S batteries.

关键词： Polyacrylic acid Oxygen self-doping Green synthetic Pore mesh polymer cathodes Lithium-sulfur batteries

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Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries

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Chinese Chemical Letters 2024年第5期35卷 434-440页

作者： Haodong Wang Xiaoxu Lai Chi Chen Pei Shi Houzhao Wan Hao Wang Xingguang Chen Dan Sun CAS key laboratory of design and assembly of functional nanostructures and Fujian Provincial key laboratory of Nanomaterials Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Fujian Normal UniversityFuzhou 350007China Xiamen Institute of Rare Earth Materials Haixi InstitutesChinese Academy of SciencesXiamen 361021China School of Microelectronics Hubei UniversityWuhan 430062China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen 361021China

The detrimental“shuttle effect”of lithium polysulfides(LiPSs)together with sluggish multi-order reaction kinetics are the main drawbacks hindering lithium-sulfur(Li-S)batteries from commercial ***,we first propose the implementability of layered rare-earth hydroxides(LREHs)in Li-S batteries to optimize electrochemical *** this work,a two-dimensional(2D)rare-earth-based composite constructed by the layered gadolinium hydroxy chloride[Gd_(2)(OH)_(5)(H_(2)O)_(n)]Cl nanoplates(LGdH NPs)and graphene oxide(GO)was designed as a sulfur immobilizer for Li-S *** the experimental results and density functional theory(DFT)calculations,it is revealed that the LGdH@GO composite not only provides a strong anchoring of the intermediates during cycling,but also acts as an effective catalyst to accelerate the liquid-solid conversion of *** Li-S batteries assembled by LGdH@GO modified separators delivered a superior rate performance with a specific capacity of 605.34 mAh/g at 5 C,as well as excellent cycle stability with a decay rate of 0.087%over 500 cycles at 2 *** study provided a deep understanding of the mechanism to suppress the“shuttle effect”by the LREHs,and a guide to design effective functional interlayers for high-performance Li-S batteries with excellent electrocatalytic activity.

关键词： Lithium-sulfur batteries functional separator Layered rare-earth hydroxides Shuttle effect Adsorption Catalysis

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Advancing microarray fabrication:One-pot synthesis and highresolution patterning of UV-crosslinkable perovskite quantum dots

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Nano Research 2024年第9期17卷 8600-8609页

作者： Linfeng Yuan Dejian Chen Kun He Jiamin Xu Kunyuan Xu Jie Hu Sisi Liang Haomiao Zhu CAS key laboratory of design and assembly of functional nanostructures and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science&Technology Innovation laboratory for Optoelectronic Information of China Fuzhou 350108China University of Chinese Academy of Sciences Beijing 100049China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen Research Center of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021China

The development of highly efficient,solution-processable,and environmentally stable perovskite quantum dots(PQDs)is crucial for their accurate high-resolution patterning and subsequently enabling the practical deployment of PQD based emissive display *** study presents an innovative strategy for integrating all-inorganic PQDs and ultraviolet(UV)crosslinkable acrylate polymer at a structural and functional *** achievement is accomplished by meticulous design and one-pot synthesis of UV-crosslinkable CsPbX_(3)(X=Cl,Br,I)PQDs solution,which exhibit outstanding environmental *** the solution-processable characteristics of the resulting UV-crosslinkable PQDs,precise patterning of high-resolution(2μm,7608 pixels·in.^(-1))and colorful PQDs microarrays can be readily achieved through inkjet printing and high-throughput photolithography(~2μm in pitch line/space patterning).The UV cross-linked process guarantees a homogeneous distribution of PQDs,effectively mitigating coffee ring effect and improving the overall quality of stereoscopic *** photo-cured PQDs film,which undergoes free radical photopolymerization,displays an impressive photoluminescence quantum yield(PL QY)of up to 89.2%,reaching 98%of the value observed in the solution *** approach outlined in this research is both cost-effective and pragmatic,exhibiting tremendous promise for diverse system-level integrated optoelectronic devices,such as ultra-high-resolution micro-light-emitting device(micro-LED)displays.

关键词： perovskite quantum dots microarrays cross-linking strategy Inkjet printing photolithography

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Protective layer for stable lithium-metal anodes at 60 mA·h/cm^(2) and 60 mA/cm^(2) with ion channel and inductive effect

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Journal of Materiomics 2024年第6期10卷 1252-1260页

作者： Xiao Zhang Zhiwei Chen Jiaojiao Han Qiang Wang Jinshan Wang Juhua Luo Jianguang Xu Chi Chen Wei Yao School of Materials Science and Engineering Jiangsu Provincial Key Laboratory of Eco-Environmental MaterialsYancheng Institute of TechnologyYancheng 224051China School of Materials and Energy Shanghai Key Laboratory of Engineering Materials Application and EvaluationShanghai Polytechnic UniversityShanghai 201209China CAS key laboratory of design and assembly of functional nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen key laboratory of Rare Earth Photoelectric functional Materials and Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021China

Contradiction between ultrafast nucleation and deposition rates of lithium(Li)crystals at high rate and heterogeneity of Li^(+)flux resulting from concentration polarization has compromised the performance of Li metal anodes especially at high areal capacity and current ***,multifunctional protective layer consisting of MoO_(3) nanobelt films(MoO_(3)-NF)is introduced on the surface of Li by a simple rolling *** strong binding energy between Li and MoO_(3) guides the homogeneous nucleation and deposition of Li,while the nanobelt networks provide effective ion channels for uniform distribution of the Li+*** of the novel multifunctional protective layer,the MoO_(3)-NF@Li anodes demonstrate a remarkable stability for 800 h with ultralow overpotential of 159 mV at extreme harsh conditions of 60 mA·h/cm^(2) and 60 mA/cm^(2).MoO_(3)-NF@Li||LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2) full-cells can run 100 cycles with a superior capacity retention of 84.2%under practical test conditions,demonstrating great potential for high output and energy-density metal batteries.

关键词： Multifunctional protective layer Ion channel Inductive effect High areal capacity Li metal anodes

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Synergic catalysis of W and Ni originating from substitution of trivacant phosphotungstate for the selective oxidation of aniline to azoxybenzene

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Chinese Chemical Letters 2024年第2期35卷 558-563页

作者： Sheng Cai Xiao-Yuan Wu Weiming Wu Sa-Sa Wang Can-Zhong Lu CAS key laboratory of design and assembly of functional nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350117China Xiamen Institute of Rare Earth Materials Chinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China

Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal *** this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_(2)}{[Ni_(6)Cl(μ-OH)_(3)(H_(2)O)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))][Ni_(6)(μ-OH)_(3)(H_(2)O)_(2)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))]}Cl·27H_(2)O,(1,Dach=1,2-diaminocyclohexane)was *** 1 shows excellent catalytic performance in the selective oxidation of aniline to azoxybenzene(AOB)in *** apparently different results from that with the matrix{PW_(9)O_(34)}({PW9})suggest the successful regulation of the catalytic property of{PW9}by the introduction of the{Ni6}cluster into the *** experimental results indicate that the highlighted performance of 1 is contributed by the synergy of W and Ni sites,which are respectively responsible for the oxidation and condensation steps in the production of *** good selectivity to AOB is essentially attributed to the effective modulation of the reaction rates of oxidation and condensation steps by W and Ni sites,respectively.

关键词： Polyoxometalate {Ni_(6)}cluster Modulated catalytic property Aniline oxidation Azoxybenzene

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High-brightness near-infrared luminescent bioprobes based on lanthanide-doped NaCrFnanoparticles

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Science China Materials 2024年

作者： Yun Xing Shiqi Yu Datao Tu Xueyuan Chen State key laboratory of Structural Chemistry Fujian Key Laboratory of Nanomaterials and CAS Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fujian Science & Technology Innovation laboratory for Optoelectronic Information of China University of Chinese Academy of Sciences

Over the past decade, near-infrared （NIR） luminescent materials have emerged as a frontier in photonics and material science, finding diverse applications in bioimaging, encryption,and photodetection[1]. Particularly, NIR nanoprobes are widely utilized in life science and clinical medicine because of their high spatial resolution, deep tissue penetration, low optical absorption and scattering, and minimal autofluorescence[2,3].

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Recent Advances in Mechanistic Understanding of Metal-Free Carbon Thermocatalysis and Electrocatalysis with Model Molecules

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Nano-Micro Letters 2024年第7期16卷 74-97页

作者： Wei Guo Linhui Yu Ling Tang Yan Wan Yangming Lin CAS key laboratory of design and assembly of functional nanostructures Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002People’s Republic of China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021People’s Republic of China State key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002People’s Republic of China Institute of Urban Environment Chinese Academy of SciencesXiamen 361021People’s Republic of China

Metal-free carbon,as the most representative heterogeneous metal-free catalysts,have received considerable interests in electro-and thermo-catalytic reac-tions due to their impressive performance and *** the past decade,well-designed carbon catalysts with tunable structures and heteroatom groups coupled with various characterization techniques have proposed numerous reaction ***,active sites,key intermediate species,precise structure-activity relationships and dynamic evolution processes of carbon catalysts are still rife with controversies due to the monotony and limitation of used experimental *** this Review,we sum-marize the extensive efforts on model catalysts since the 2000s,particularly in the past decade,to overcome the influences of material and structure limitations in metal-free carbon *** both nanomolecule model and bulk model,the real contribution of each alien species,defect and edge configuration to a series of fundamentally important reactions,such as thermocatalytic reactions,electrocatalytic reactions,were systematically *** with in situ techniques,isotope labeling and size control,the detailed reaction mechanisms,the precise 2D structure-activity relationships and the rate-determining steps were revealed at a molecular ***,the outlook of model carbon catalysis has also been proposed in this work.

关键词： Metal-free carbon catalysts Model catalyst Electrocatalysis Active site Reaction mechanisms

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Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries

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Energy Reviews 2024年第3期3卷 102-128页

作者： Ming Zhang Xiaocao Cao Yaowei Hao Haodong Wang Jian Pu Bo Chi Zhongrong Shen CAS key laboratory of design and assembly of functional nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Xiamen key laboratory of Rare Earth Photoelectric functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen361021China College of Chemical Engineering Fuzhou UniversityFuzhouFujian350116China School of Materials Science and Engineering State Key Laboratory of Material Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan430074China

In the development of new electrochemical concepts for the fabrication of high-energy-density batteries,fluorideion batteries(FIBs)have emerged as one of the valid candidates for the next generation electrochemical energy storage technologies,showing the potential to match or even surpass the current lithium-ion batteries(LIBs)in terms of energy density,safety without dendritic grains,and elimination of dependence on scarce lithium and cobalt ***,the development of FIBs is still in its infancy and their performance is far from satisfactory,with issues such as the lower fluoride-ion conductivity of the electrolytes and the reversibility of the electrodes hindering their *** reviews have mainly focused on inorganic solid electrolytes with a brief emphasis on the development of various fluoride-ion conductors and their ion-conducting ***,this review summarizes the current developments in various electrolytes,a systematic overview of the current progress for various fluoride-ion electrolytes is presented by beginning with the history,structure and classification of FIBs,ion-transport mechanisms are briefly *** advances in different classes of fluoride-ion electrolytes are *** methods for optimizing the ionic conductivity characteristics of the fluoride-ion electrolytes are ***,an outlook on the future research direction of FIBs is given by highlighting some critical issues,challenges and prospects of fluoride-ion electrolytes.

关键词： Solid electrolyte Liquid electrolyte Composited electrolyte Fluoride-ion Conductivity

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Selective recovery of Th(Ⅳ) from radioactive rare earth waste residue by utilizing MoS_(2)-modified ion-absorbed type rare earth tailings

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Journal of Rare Earths 2024年第9期42卷 1782-1791,I0005页

作者： Xirong Chen Xinyu Fu Yun Gao Zhiyuan Zeng Bin Huang Xiaoqi Sun Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou341000China CAS key laboratory of design and assembly of functional nanostructures Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Fujian Research Center for Rare Earth Engineering Technology Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China Fujian College University of Chinese Academy of SciencesFuzhou350002China Jiangxi Province key laboratory of Cleaner Production of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhouJiangxi341000China

In the process of extracting ion-absorbed rare earth ore(IREO),the production of radioactive waste is a major environmental *** address this issue,MoS_(2) was used to modify ion-absorbed rare earth tailings(RET) to synthesize a novel MoS_(2)@RET composite material for the effective handling of radioactive waste generated in IREO separation *** composite material was thoroughly characterized using various analytical techniques,including X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),thermogravimetry(TG),Fourier-transform infrared(FTIR),scanning electron microscopy(SEM),Brunaue r-Emmett-Teller(BET) and energy dispersive spectroscopy(EDS).By optimizing the operating parameters,the optimal experimental conditions were determined to be pH=3,contact time=60 min,liquid-solid ratio=6 g/L,and initial concentration=150 mg/*** adsorption data fitted well with the pseudo second-order rate *** thermodynamic parameters concerning the adsorption of Th(Ⅳ) were analyzed and *** isotherm model is a more fitting choice for the adsorption process compared to the Freundlich isotherm ***_(2)@RET was used in the acid leachate of IREO waste residue,achieving the separation of Th and rare earth *** mechanism of Th(Ⅳ) adsorption by MoS_(2)@RET was investigated,revealing that the adsorption process involves electrostatic interactions,chemical bonding,and redox *** above research results indicate that MoS_(2)@RET composite materials have application potential in the sustainable treatment of IREO radioactive waste.

关键词： Rare earths Thorium Radioactive waste residue Adsorption Separation

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