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Influencing factors of infrared surveying in roadway

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Journal of Coal Science & Engineering(China) 2006年第1期12卷 49-51页

作者：蔡康旭郭达 College of Resource and Safety Engineering Hunan University of Science and Technology Xiangtan 411201 China kailuan group Limited Responsibility company Tangshan 063018 China

The main factors that affect infrared surveying in roadway include that property of rock, electromechanical equipments running, environmental temperature, hydrogeology and support material etc. This paper sums up the expression features of these disturbing factor through theoretical analysis and actual measurement contrasts and considers that some tunnel section does not suit to go on infrared survey, for instance, soft rock meets water to expanse, and surround rock has obviously pouring water. The basic methods had made evading disturbing of electromechanical equipments, environmental temperature and protect material etc to become possible. It is helpful that offers infrared surveying technical service for production safety better in roadway.

关键词： roadway infrared survey influencing factor analysis

Conversion and reaction kinetics of coke oven gas over a commercial Fe-Mo/Al_2O_3 catalyst

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Journal of Central South University 2016年第2期23卷 293-302页

作者：屈一新徐贺明赵见峰王志彦王亚涛 College of Chemical Engineering Beijing University of Chemical TechnologyBeijing 100029China Coal Chemical Research and Development Center of kailuan group Tangshan 063611China

Producing methanol from coke oven gas(COG) is one of the important applications of COG. Removal of sulfur from COG is a key step of this process. Conversion and reaction kinetics over a commercial Fe-Mo/Al2O3 catalyst(T-202) were studied in a continuous flow fixed bed reactor under pressures of 1.6-2.8 MPa, space time of 1.32-3.55 s and temperatures of 240-360 °C. Though the COG contains about 0.6 mol/mol H2, hydrogenation of CO and CO2 is not significant on this catalyst. The conversions of unsaturated hydrocarbons depend on their molecular structures. Diolefins and alkynes can be completely hydrogenated even at relatively low temperature and pressure. Olefins, in contrast, can only be progressively hydrogenated with increasing temperature and pressure. The hydrodesulfurization(HDS) of CS2 on this catalyst is easy. Complete conversion of CS2 was observed in the whole range of the conditions used in this work. The original COS in the COG can also be easily converted to a low level. However, its complete HDS is difficult due to the relatively high concentration of CO in the COG and due to the limitation of thermodynamics. H2 S can react with unsaturated hydrocarbons to form ethyl mercaptan and thiophene, which are then progressively hydrodesulfurized with increasing temperature and pressure. Based on the experimental observations, reaction kinetic models for the conversion of ethylene and sulfur-containing compounds were proposed; the values of the parameters in the models were obtained by regression of the experimental data.

关键词： coke oven gas conversion Fe-Mo/Al2O3 catalyst sulfur-containing compound kinetics

Separation occurring during the drop weight tear test of thick-walled X80 pipeline steels

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International Journal of Minerals,Metallurgy and Materials 2013年第8期20卷 741-747页

作者： Qing-yun Sha Da-hang Li Guo-jian Huang Ju Guan Technology Center Anshan Iron and Steel Group Company

A separation phenomenon occurring during the drop weight tear test of commercial thick-walled API （American Petroleum Institute） X80 strip steel was investigated in this work. Microstructural analysis showed that the band structure of bainite elongated along the rolling direction works as the initiation sites of separation. The propagation of separation can be promoted not only by the occurrence of the band structure of martensite/austenite constituent, prior austenite grain boundaries, and elongated bainite, but also by fine acicular ferrite and bainite. Wide separation formed in the former case, while the narrow one appeared in the latter case. acicular ferrite in thick-walled X80 pipeline steel in order Some methods were proposed to obtain fine and homogeneous to minimize the occurrence of separation.

关键词： pipeline steel drop weight tear test separation cracking band structure

Conversion of carbon dioxide to valuable petrochemicals:An approach to clean development mechanism

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Journal of Natural Gas Chemistry 2011年第3期20卷 219-231页

作者： Farnaz Tahriri Zangeneh Saeed Sahebdelfar Maryam Takht Ravanchi Catalyst Research group Petrochemical Research and Technology Company (NPC-RT) National Petrochemical Company

The increase of atmospheric carbon dioxide and the global warming due to its greenhouse effect resulted in worldwide concerns. On the other hand, carbon dioxide might be considered as a valuable and renewable carbon source. One approach to reduce carbon dioxide emissions could be its capture and recycle via transformation into chemicals using the technologies in C1 chemistry. Despite its great interest, there are difficulties in CO2 separation on the one hand, and thermodynamic stability of carbon dioxide molecule rendering its chemical activity low on the other hand. Carbon dioxide has been already used in petrochemical industries for production of limited chemicals such as urea. The utilization of carbon dioxide does not necessarily involve development of new processes, and in certain processes such as methanol synthesis and methane steam reforming, addition of CO2 into the feed results in its utilization and increases carbon efficiency. In other cases, modifications in catalyst and/or processes, or even new catalysts and processes, are necessary. In either case, catalysis plays a crucial role in carbon dioxide conversion and effective catalysts are required for commercial realization of the related processes. Technologies for CO2 utilization are emerging after many years of research and development efforts.

关键词： carbon dioxide utilization C1 chemistry clean development mechanism catalysis greenhouse effects

Cleaning IF molten steel with dispersed in-situ heterophases induced by the composite sphere explosive reaction in RH ladles

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International Journal of Minerals,Metallurgy and Materials 2011年第2期18卷 144-149页

作者： Fu-ping Tang Zhen Li Xiao-feng Wang Ben-wen Chen Peng Fei Anshan Iron ＆ steel group company Anshan 114014 China

A novel fine inclusion removal technology was put forward with dispersed in-situ heterophases induced by the composite sphere explosive reaction. A composite sphere with this function was designed and prepared using a laboratory scale batch-type balling disc （at 12 r/min）, and the composite sphere was fed at the end of the RH refining process. The results indicate that inclusions in the IF molten steel can be removed effectively by feeding composite spheres in RH ladle. Compared with conventional inclusion removal technology, using this novel technology, the amount of oxide inclusions can be decreased to a lower level and the inclusion size becomes finer, the total oxygen content in the as-cast slab can approach 5×10？6, and the cost per ton of steel produced can be reduced by 5-12 Yuan RMB.

关键词： IF steel refining bubbles slags filtration inclusions

Study and application of plasticity plaster-slurry for preventing coal spontaneous combustion

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Journal of Coal Science & Engineering(China) 2003年第2期9卷 74-78页

作者：刘爱华蔡康旭郭达张复胜 Dept.of Mineral Resources Engineering kailuan group Limited Responsibility company

Introduced the modulation scheme, function and mechanism of plasticity plaster slurry preventing coal spontaneous combustion. The applications show that the plasticity plaster slurry has good hygroscopicity and adsorptivity. To spray it on the coal wall of tunnel can shut off leakage wind fast and effectively. To press it into the coal body can absorb the heat and descend the temperature, surround the coal pieces, eliminate the possibility of the fiery district resuming combustion.

关键词： plasticity plaster slurry coal spontaneous combustion prevention and cure

Effects of Rare Earth on Behavior of Precipitation and Properties in Microalloyed Steels

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Journal of Rare Earths 2003年第2期21卷 167-171页

作者：林勤陈邦文唐历李联生朱兴元王怀斌 Department of Physical Chemistry University of Science and Technology Beijing National Enterprise Technology Center Wuhan Iron and Steel(Group)Company Panzhihua Iron and Steel (group) company

The influence of rare earths on the behavior of precipitation of 14MnNb,X60 and 10MnV steels was studied by STEM, XRD, ICP and thermal simulation method. The main carbonitride precipitates are Nb(C, N),(Nb, Ti)(C, N)and V(C, N). In austenite RE delays the beginning of precipitation, and decreases the rate of precipitation. In ferrite RE promotes precipitation and increases the amount of equilibrium carbonitride precipitation. RE can make precipitates fine, globular and dispersed in the microalloyed steels. With the increase of the amount of RE in steel, the amount of precipitation increases. The promotion effect is weakened with excessive RE. RE has only little influence on the strength of microalloyed steel, but it can improve impact toughness effectively.

关键词： metal materials microalloyed steel precipitation properties rare earths

Preparation and Application of C60 High Performance Concrete

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International Journal of Minerals,Metallurgy and Materials 1998年第4期12卷 241-244页

作者： Jizhong Li(Concrete company of Beijing Urban Construction group, Heijing 100039, China) Concrete company Beijing Urban Construction Group Beijing 100039 China

C60 High Performance Concrete (HPC) was prepared by limiting cement content and adopting compositesuperplasticizer, low-alkalinity expansive agent and high-quality line mixture. The results showed that the performance of the prepared C60 HPC was excellent. By adopting some advanced construction techniques such as usingsecondary vibration and secondary face compaction, controlling temperature difference and paying special attentionto early curing in the construction process, the prepared C60 HPC had been successfully applied in the monolithicstructure of huge building.

关键词： concrete performance construction techniques application of C60 high performance concrete

晶格畸变增强卤化锑晶体团簇的自陷激子发射（英文）

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Science China Materials 2025年第1期 132-140页

作者：刘达何敬敬孙玉婷刘心翊彭玉李庆杨化桂牛强杨双侯宇 Key Laboratory for Ultrafine Materials of Ministry of Education Shanghai Engineering Research Center of Hierarchical Nanomaterials School of Materials Science and Engineering East China University of Science and Technology China National Enterprise Technology Center Inner Mongolia Erdos Electric Power and Metallurgy Group Company Limited

零维钙钛矿材料以自陷激子引起的宽带发射为特征,是一种很有前途的刺激响应和光加密材料.然而,现有的研究主要集中在结构相变对光物理性质的影响上,对自陷激子的发射机制缺乏深入了解.本文证明了零维卤化锑单晶中的脱水反应,在不诱导结...

零维钙钛矿材料以自陷激子引起的宽带发射为特征,是一种很有前途的刺激响应和光加密材料.然而,现有的研究主要集中在结构相变对光物理性质的影响上,对自陷激子的发射机制缺乏深入了解.本文证明了零维卤化锑单晶中的脱水反应,在不诱导结构相变的基础上显著增强了自陷激子的发射,导致光致发光量子产率从3.5%大幅提高到91.4%.利用原位X射线衍射和光致发光技术揭示了晶体结构和光致发光强度之间的定性关系,证明了在脱水过程中引入了丰富的晶格畸变.温度依赖的荧光光谱和瞬态吸收光谱表明,晶格畸变导致中等的电子-声子耦合强度和更高的激子结合能,加速了自陷激子从非辐射复合单重态弛豫到辐射复合三重态,进而表现出增强的光致发光.作为概念验证,在防伪、可重写发光纸和湿度传感等多重场景中实现了应用.这一发现阐明了自陷激子的发射机制,并为设计可切换发光材料提供了一条新途径.

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