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Journal of Energy Chemistry 2024年第7期94卷 688-715页

作者： Amina Lahrichi Youness El Issmaeli Shankara S.Kalanur Bruno G.Pollet Green Hydrogen lab(GH2lab) Hydrogen Research Institute(HRI)Universitédu QuébecàTrois-Rivières(UQTR)3351 boulevard des ForgesTrois-RivièresQuébec G9A 5H7Canada

Solid oxide electrolysis cells(SOECs)represent a crucial stride toward sustainable hydrogen generation,and this review explores their current scientific challenges,significant advancements,and potential for large-scale hydrogen *** SOEC technology,the application of innovative fabrication tech-niques,doping strategies,and advanced materials has enhanced the performance and durability of these systems,although degradation challenges persist,implicating the prime focus for future *** we provide in-depth analysis of the recent developments in SOEC technology,including Oxygen-SOECs,Proton-SOECs,and ***,Hybrid-SOECs,with their mixed ionic conducting electrolytes,demonstrate superior efficiency and the concurrent production of hydrogen and *** with the capacity to harness waste heat,these advancements in SOEC technology present signif-icant promise for pilot-scale applications in *** review also highlights remarkable achieve-ments and potential reductions in capital expenditure for future SOEC systems,while elaborating on the micro and macro aspects of sOECs with an emphasis on ongoing research for optimization and *** concludes with the potential of SOEC technology to meet various industrial energy needs and its significant contribution considering the key research priorities to tackle the global energy demands,ful-fillment,and decarbonization efforts.

关键词： Solid oxide electrolysis cells Proton-SOECs Oxygen-SoECs Hybrid-SOECs Intermediate-high temperature electrolysers Hydrogenproduction

Grain size refinement of additive manufactured Ce-TZP ceramics by coupled two-step pre-sintering and HIP

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Journal of Advanced Ceramics 2024年第5期13卷 621-629页

作者： ruoshi Zhao Hongbing Yang Xintong Liu Hezhen Li Chang-An Wang Jing Ma Yanhao dong State Key lab of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

Ceria-stabilized tetragonal zirconia polycrystal(Ce-TZP)has exceptional fracture toughness and flaw tolerance due to facile t‒m phase transformation ***,its wider-range applications are limited by its relatively low strength due to its large grain size and low transformation stress,which results in yield-like ***,we combined additive manufacturing(AM),pressureless two-step sintering,and hot isostatic pressing(HIP),and addressed the challenging grain size refinement problem in *** successfully produced dense ultrafine-grained Ce-TZP ceramics with an average grain size below 500 nm,a three-point bending strength above 800 MPa,and a single-edge-notch-beam fracture toughness in the range of 11‒12 MPa·m^(1/2).The critical roles of processing design,mixed Ce valences,and ***-stabilization of tetragonal polymorphs were *** work offers insights and strategies for the future development of stronger and tougher Ce-TZP ceramics that can compete with tetragonal yttria-stabilized zirconia in various applications,including additive manufacturing.

关键词： zirconia additive manufacturing(AM) two-step sintering hot isostatic pressing(HIP) grain size refinement

Stability-enhanced rF signal transmission over long fiber-optic links

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Chinese Optics Letters 2024年第5期22卷 131-136页

作者：尹知谦郑满航张川博管世健周昕刘奕彤刚泽宇聂佳强张云山朱兴邦方涛陈向飞 Engineering research Center of Precision Photonics Integration and System Application Ministry of Education&Key Laboratory of Intelligent Optical Sensing and ManipulationMinistry of Education&National Laboratory of Solid State Microstructures&College of Engineering and Applied Sciences&Institute of Optical Communication Engineering&Nanjing University-Tongding Joint Lab for Large-scale Photonic Integrated CircuitsNanjing UniversityNanjing 210023China College of Electronics and Optical Engineering and College of Flexible Electronics(Future Technology) Nanjing University of Posts and TelecommunicationsNanjing 210023China The 41st research Institute of China Electronics Technology Group Corp Qingdao 266000China

We propose a method for optimizing the phase stability of microwave signal transmission over long ***,the design of the photon link was modified to reduce the radio frequency(rF)signal’s baseline noise and increase ***,a low-noise driver circuit was developed for a two-section distributed feedback(dFB)laser designed using reconstruction equivalent chirp(rEC)technology to create an ultra-stable laser,and its performance was characterized through linewidth *** results indicate that the dFB laser achieved narrower linewidth,improving system phase *** an injection current(30 mA)is applied to the reflection section of the two-section dFB laser,the laser linewidth will be narrower(1.38 MHz),further enhancing the system’s phase transmission *** a 1 Hz offset frequency,a residual phase noise of-88.65 dBc/Hz is *** short-term stability with an averaging time of 1 s is 1.60×10^(-14),and the long-term stability over a testing time of 60,000 s is 3.41×10^(-18).Even after incorporating temperature variations,the long-term stability reaches 8.37×10^(-18) at 22 h.

关键词： frequency dissemination two-section distributed feedback laser phase stability

MACF1 deficiency suppresses tooth mineralization through IGF1 mediated crosstalk between odontoblasts and ameloblasts

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Genes & diseases 2024年第5期11卷 9-12页

作者： Wuxia Qiu Xiao Lin Shaoqing Yang Zhihao Chen Kewen Zhang Chaofei Yang Yu Li Zhiping Miao Xiaoni deng Xiaohong duan Airong Qian lab for Bone Metabolism Xi’an Key Laboratory of Special Medicine and Health EngineeringKey Lab for Space Biosciences and BiotechnologyResearch Center for Special Medicine and Health Systems EngineeringNPU-UAB Joint Laboratory for Bone MetabolismSchool of Life SciencesNorthwestern Polytechnical UniversityXi’anShaanxi 710072China State Key laboratory of Military Stomatology National Clinical Research Center for Oral DiseasesDepartment of Oral BiologyClinic of Oral Rare and Genetic DiseasesSchool of StomatologyThe Fourth Military Medical UniversityXi’anShaanxi 710032China School of Chemical Engineering Sichuan University of Science&EngineeringZigongSichuan 643000China research&development Institute of Northwestern Polytechnical University in Shenzhen ShenzhenGuangdong 518063China Puyang Institute of Technology Henan UniversityPuyangHenan 457000China

Tooth mineralization is a ubiquitous and tightly regulated process involving complicated interactions between dental epithelium and *** molecules in tooth mineralization remain poorly *** actin cross-linking factor 1(MACF1)is a spectraplakin protein that plays pivotal roles in the brain,muscle,lung,and bone developmental process.^(1-3) To study the specific functions of MACF1 in bone formation,we established Macf1 conditional knockout mice using the Cre-LoxP system driven by Osxterix promoter(Osx-Cre;Macf1^(f/f)).^(2) Not surprisingly,Osx-Cre;Macf1^(f/f) mice displayed the phenotypes of delayed ossification and decreased bone ***,the OsxCre;Macf1^(f/f) mice unexpectedly showed a white and opaque appearance of incisors,contrary to the normal yellowbrown and transparent *** Osxterix is expressed in dental mesenchyme during tooth development,the abnormal tooth appearance might imply a new function of MACF1 in odontoblasts,or even ***,the present study aimed to investigate the role of MACF1 during tooth development.

关键词： mineralization linking transparent

Full-Scale Isogeometric Topology Optimization of Cellular Structures Based on Kirchhoff-Love Shells

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Computer Modeling in Engineering & Sciences 2024年第6期139卷 2479-2505页

作者： Mingzhe Huang Mi Xiao Liang Gao Mian Zhou Wei Sha Jinhao Zhang State Key lab of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and TechnologyWuhan430074China

Cellular thin-shell structures are widely applied in ultralightweight designs due to their high bearing capacity and strength-to-weight *** this paper,a full-scale isogeometric topology optimization(ITO)method based on Kirchhoff-Love shells for designing cellular tshin-shell structures with excellent damage tolerance ability is *** method utilizes high-order continuous nonuniform rational B-splines(NUrBS)as basis functions for Kirchhoff-Love shell *** geometric and analysis models of thin shells are unified by isogeometric analysis(IGA)to avoid geometric approximation error and improve computational *** topological configurations of thin-shell structures are described by constructing the effective density field on the *** volume constraints are imposed in the proximity of each control point to obtain bone-like cellular *** facilitate numerical implementation,the p-norm function is used to aggregate local volume constraints into an equivalent global *** numerical examples are provided to demonstrate the effectiveness of the proposed *** simulation and comparative analysis,the results indicate that the cellular thin-shell structures optimized by the proposed method exhibit great load-carrying behavior and high damage robustness.

关键词： Cellular thin-shell structures isogeometric analysis full-scale topology optimization Kirchhoff–Love shells

Anisotropic alignments of hierarchical Li2SiO3/TiO2@nano-C anode//LiMnPO4@nano-C cathode architectures for full-cell lithium-ion battery

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National Science review 2020年第5期7卷 863-880页

作者： Hesham Khalifa Sherif A. El-Safty Abdullah reda Mohamed A. Shenashen Alaa I.Eid research Center for Functional Materials National Institute for Materials Science department of Petrochemical Egyptian Petroleum Research Institute Composite lab Advanced Materials Division Central Metallurgical R&D Institute

We report on low-cost fabrication and high-energy density of full-cell lithium-ion battery (LIB) ***-hierarchical electrode architectures of Li2SiO3/TiO2@nano-carbon anode (***@nano-C) and high-voltage olivine LiMnPO4@nano-carbon cathode (LMPO@nano-C) are designed for half-and full-system LIB-Cr2032 coin cell *** the basis of primary architecture-power-driven LIB geometrics,the structure keys including three-dimensional (3d) modeling superhierarchy,multiscale micro/nano architectures and anisotropic surface heterogeneity affect the buildup design of anode/cathode LIB *** hierarchical electrode surface topologies enable continuous in-/out-flow rates and fast transport pathways of Li+-ions during charge/discharge *** stacked layer configurations of pouch LIB-types lead to excellent charge/discharge rate,and energy density of237.6 Wh *** the most promising LIB-configurations,the high specific energy density of hierarchical pouch battery systems may improve energy storage for long-driving range of electric ***,the anisotropic alignments of hierarchical electrode architectures in the large-scale LIBs provide proof of excellent capacity storage and outstanding durability and *** full-system LIB-Cr2032 coin cell models maintain high specific capacity of～89.8%within a long-term life period of2000 cycles,and average Coulombic efficiency of99.8%at 1C rate for future configuration of LIB manufacturing and commercialization challenges.

关键词： lithium-ion batteries micro/nano architectures LiMnPO4@nano-carbon cathode Li2SiO3/TiO2@nano-carbon anode LIB-Cr2032 coin cell models

Cooperative User-Scheduling and resource Allocation Optimization for Intelligent reflecting Surface Enhanced LEO Satellite Communication

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China Communications 2024年第2期21卷 227-244页

作者： Meng Meng Bo Hu Shanzhi Chen Jianyin Zhang State Key lab of Networking and Switching Technology Beijing University of Posts and TelecommunicationsBeijing 100876China State Key lab of Wireless Mobile Communication China Academy of Telecommunication TechnologyBeijing 100191China research Institute of China Mobile Beijing 100053China

Lower Earth Orbit(LEO) satellite becomes an important part of complementing terrestrial communication due to its lower orbital altitude and smaller propagation delay than Geostationary satellite. However, the LEO satellite communication system cannot meet the requirements of users when the satellite-terrestrial link is blocked by obstacles. To solve this problem, we introduce Intelligent reflect surface(IrS) for improving the achievable rate of terrestrial users in LEO satellite communication. We investigated joint IrS scheduling, user scheduling, power and bandwidth allocation(JIrPB) optimization algorithm for improving LEO satellite system *** optimization problem of joint user scheduling and resource allocation is formulated as a non-convex optimization problem. To cope with this problem, the nonconvex optimization problem is divided into resource allocation optimization sub-problem and scheduling optimization sub-problem firstly. Second, we optimize the resource allocation sub-problem via alternating direction multiplier method(AdMM) and scheduling sub-problem via Lagrangian dual method ***, we prove that the proposed resource allocation algorithm based AdMM approaches sublinear convergence theoretically. Finally, we demonstrate that the proposed JIrPB optimization algorithm improves the LEO satellite communication system throughput.

关键词： convex optimization intelligent reflecting surface LEO satellite communication OFdM

Improving the operational stability of perovskite solar cells with cesium-doped graphene oxide interlayer

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Journal of Energy Chemistry 2024年第9期96卷 483-490页

作者： Masaud Almalki Katerina Anagnostou Konstantinos rogdakis Felix T.Eickemeyer Mostafa Othman Minas M.Stylianakis dimitris Tsikritzis Anwar Q.Alanazi Nikolaos Tzoganakis Lukas Pfeifer rita Therisod Xiaoliang Mo Christian M.Wolff Aïcha Hessler-Wyser Shaik M.Zakeeruddin Hong Zhang Emmanuel Kymakis Michael Grätzel laboratory of Photonics and Interfaces École Polytechnique Fédérale de Lausanne(EPFL)Lausanne 1015Switzerland department of Electrical and Computer Engineering Hellenic Mediterranean UniversityHeraklionCrete 71410Greece Institute of Electrical and Microengineering(IEM)Photovoltaics and Thin-Film Electronics laboratory(PV-lab) École Polytechnique Fédérale de Lausanne(EPFL)Neuchâtel 2000Switzerland department of Nursing Faculty of Health SciencesHellenic Mediterranean UniversityCrete 71410Greece Centre Interdisciplinaire de Microscopie Electronique École Polytechnique Fédérale de Lausanne(EPFL)Lausanne 1015Switzerland Future Energy Technology Institute King Abdulaziz City for Science and Technology(KACST)P.O.Box 6086Riyadh 11442Saudi Arabia State Key laboratory of Photovoltaic Science and Technology Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and PerceptionInstitute of OptoelectronicsDepartment of Materials ScienceFudan UniversityShanghai 200433China

Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their *** interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of *** this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting *** GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.

关键词： Perovskite solar cells doped graphene oxide Graphene related material Long-term operational stability

3d-shaped 3d-continuously graphene cellulose(3d^(2)GC)architecture

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Nano research 2024年第7期17卷 6695-6699页

作者： Abdelrahman Brakat Hongwei Zhu State Key lab of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

In the endeavor to develop three-dimensional(3d)-architected sophisticated hierarchical structures,the synergy between inplane and out-of-plane interactions at interfaces offers new *** interplay,governed by van der Waals(vdW)interfacial nanoarchitectonics,facilitates the design of efficient thermally conductive *** work delves into the kinetics underlying a dual-templating strategy,seamlessly integrating two-dimensional(2d)-graphene sheets with one-dimensional(1d)-cellulose chains at heterointerfaces,thereby transforming into 3d-shaped and 3d-continuously anisotropic structures,termed as(3d^(2)GC)***,we designed and fabricated an anisotropic graphene cellulose scaffold(GCS)employing a nickel *** as-grown GCS replicates the 3d-shaped and configuration of the *** 3d-continuously interconnected fibrous-porous network of the GCS,combined with its anisotropic thermal properties(λ_(axial)/λ_(radial)),not only is promising for advanced thermal technologies but also offers advantages in cost-effectiveness and eco-effectiveness.

关键词： two-dimensional(2d)-graphene one-dimensional(1d)-cellulose heterointerface anisotropic three-dimensional(3d)-architecture

Chiral phonon activated spin Seebeck effect in chiral materials

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Science China(Physics,Mechanics & Astronomy) 2024年第3期67卷 149-155页

作者： Xiao Li Jinxin Zhong Jinluo Cheng Hao Chen Huiqian Wang Jun Liu dali Sun Lifa Zhang Jun Zhou Phonon Engineering research Center of Jiangsu Province Center for Quantum Transport and Thermal Energy ScienceSchool of Physics and TechnologyNanjing Normal UniversityNanjing 210023China Center for Phononics and Thermal Energy Science China-EU Joint Lab for NanophononicsSchool of Physics Science and EngineeringTongji UniversityShanghai 200092China Changchun Institute of Optics Fine Mechanics and PhysicsChinese Academy of ScienceChangchun 130033China department of Mechanical and Aerospace Engineering North Carolina State UniversityRaleigh NC 27606USA department of Physics North Carolina State UniversityRaleigh NC 27695USA Organic and Carbon Electronics laboratories(OraCEL) North Carolina State UniversityRaleigh NC 27606USA

Efficient generation of spin polarization is very important for spintronics and quantum computation. In chiral materials without magnetic order nor spin-orbit coupling, we find a new spin selectivity effect—chiral phonon activated spin Seebeck(CPASS)effect. Starting with the nonequilibrium distribution of chiral phonons under a temperature gradient, the CPASS coefficients are computed based on the Boltzmann transport theory. With both the phonon-drag and band transport contributions, the spin accumulations generated by the CPASS effect exhibit quadratic dependence on the temperature gradient. The strength of the CPASS effect and the relative magnitude of both contributions are tunable by the chemical potential modulation. The CPASS effect, which gives a promising explanation on the traditional chiral-induced spin selectivity effect, provides opportunities for the exploration of advanced spintronic devices based on chiral materials even in the absence of any magnetic order and spin-orbit coupling.

关键词： spin Seebeck effect chiral phonon phonon-drag contribution efficient spin generation