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A multi-mechanism numerical simulation model for CO_(2)-EOR and storage in fractured shale oil reservoirs

Petroleum Science 2024年第3期21卷 1814-1828页

作者： Yuan-Zheng Wang Ren-Yi Cao Zhi-Hao Jia Bin-Yu Wang Ming Ma Lin-Song Cheng College of Petroleum engineering China University of Petroleum(Beijing)Beijing102249China john&willie leone department of energy&mineral engineering The Pennsylvania State UniversityUniversity Park16802PA.USA

Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir *** multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale *** this paper,a multi-mechanism coupled model is developed by *** to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)***,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and *** model verification with the Eclipse300 and MRST is *** results show that the interaction between the mechanisms significantly affects the production performance and storage *** effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale *** well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity ***,the potential gas invasion risk is *** model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.

关键词： CO_(2)-EOR CO_(2)storage Shale oil reservoir Complex fracture model Multiple mechanisms

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A systematic review of occupational exposure to respirable coal mine dust(RCMD)in the *** industry

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International Journal of Coal Science & Technology 2023年第2期10卷 32-44页

作者： Younes Shekarian Elham Rahimi Mohammad Rezaee Pedram Roghanchi john and willie leone Family department of energy and mineral engineering Earth and Mineral Sciences(EMS)Energy InstituteThe Pennsylvania State UniversityUniversity ParkUSA department of mineral engineering New Mexico Institute of Mining and TechnologySocorroNMUSA

Cumulative inhalation of respirable coal mine dust(RCMD)can lead to severe lung diseases,including coal worker's pneu-moconiosis(CWP),silicosis,mixed dust pneumoconiosis,dust-related diffuse fibrosis(DDF),and progressive massive fibrosis(PMF).Statistics from the number of reported cases showed a significant decrease in the progression of respiratory diseases in the ***,an unexpected increase in the number of CWP cases was reported in the late *** date,there has been no comprehensive systematic review to assess all contributing factors to the resurgence of CWP *** study aims to investigate the effects of various mining parameters on the prevalence of CWP in coal mines.A systematic review using the preferred reporting items for systematic reviews and meta-analysis(PRISMA)method was conducted to investigate the health effects of RCMD exposure and identify the factors that may contribute to the recent resurgence of CWP *** systematic review yielded a total of 401 papers,which were added to the *** total number of 148 and 208 papers were excluded from the database in the process of screening and eligibility,***,18 papers were considered for data selection and full-text *** review revealed that factors including geographic location,mine size,mining operation type,coal-seam thickness,coal rank,changes in mining practices,technology advancement,and engi-neering dust control practices are contributing to the recent resurgence of CWP among coal ***,the evidence for root causes is limited owing to the methodological constraints of the studies;therefore,further detailed studies are needed.

关键词： Respirable coal mine dust Systematic review Coal worker's pneumoconiosis Respiratory diseases Exposure limit Occupational exposure

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An analysis of contributing mining factors in coal workers’pneumoconiosis prevalence in the United States coal mines,1986-2018

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International Journal of Coal Science & Technology 2021年第6期8卷 1227-1237页

作者： Younes Shekarian Elham Rahimi Naser Shekarian Mohammad Rezaee Pedram Roghanchi department of mineral engineering New Mexico Institute of Mining and TechnologySocorroNMUSA department of Information Systems Business SchoolUniversity of Colorado DenverDenverCOUSA john and willie leone Family department of energy and mineral engineering Earth and Mineral Sciences(EMS)Energy InstituteThe Pennsylvania State UniversityUniversity ParkPAUSA

In the United States,an unexpected and severe increase in coal miners’lung diseases in the late 1990s prompted researchers to investigate the causes of the disease *** study aims to scrutinize the effects of various mining parameters,including coal rank,mine size,mine operation type,coal seam height,and geographical location on the prevalence of coal worker’s pneumoconiosis(CWP)in surface and underground coal mines.A comprehensive dataset was created using the *** Safety and Health Administration(MSHA)Employment and Accident/Injury *** information was merged based on the mine ID by utilizing SQL data management software.A total number of 123,589 mine-year observations were included in the statistical *** Estimating Equation(GEE)model was used to conduct a statistical analysis on a total of 29,707,and 32,643 mine-year observations for underground and surface coal mines,*** results of the econometrics approach revealed that coal workers in underground coal mines are at a greater risk of CWP comparing to those of surface coal ***,underground coal mines in the Appalachia and Interior regions are at a higher risk of CWP prevalence than the Western *** coal mines in the Appalachian coal region are more likely to CWP development than miners in the Western *** analysis also indicated that coal workers working in smaller mines are more vulnerable to CWP than those in large mine ***,coal workers in thin-seam underground mine operations are more likely to develop CWP.

关键词： Respirable coal mine dust Respiratory diseases Coal worker’s pneumoconiosis(CWP) Occupational exposure

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Cost and Emissions Implications of Coupling Wind and Solar Power

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Smart Grid and Renewable energy 2012年第4期3卷 308-315页

作者： Seth Blumsack Kelsey Richardson john and willie leone Family department of energy and mineral engineering Pennsylvania State University University Park USA.

We assess the implications on long-run average energy production costs and emissions of CO2 and some criteria pollutants from coupling wind, solar and natural gas generation sources. We utilize five-minute meteorological data from a US location that has been estimated to have both high-quality wind and solar resources, to simulate production of a coupled generation system that produces a constant amount of electric energy. The natural gas turbine is utilized to provide fill-in energy for the coupled wind/solar system, and is compared to a base case where the gas turbine produces a constant power output. We assess the impacts on variability of coupled wind and solar over multiple time scales, and compare this variability with regional demand in a nearby load center, and find that coupling wind and solar does decrease variability of output. The cost analysis found that wind energy with gas back-up has a lower levelized cost of energy than using gas energy alone, resulting in production savings. Adding solar energy to the coupled system increases levelized cost of energy production;this cost is not made up by any reductions in emissions costs.

关键词： Wind energy Solar energy Air Emissions

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Selective oxidation of ethane to aldehydes over SBA-15 supported molybdenum catalyst

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Journal of energy Chemistry 2014年第5期23卷 609-616页

作者： Jianmei Li Jian Liu Liwei Ren Qinglong Liu Zhen Zhao Yongsheng Chen Pengyu Zhu Yuechang Wei Aijun Duan Guiyuan Jiang State Key Laboratory of Heavy Oil College of Science China University of Petroleum EMS energy Institute and john and willie leone Family department of energy and mineral engineering The Pennsylvania State University University Park PA 16802 USA

SBA-15 supported Mo catalysts （Moy/SBA-15） were prepared by an ultrasonic assisted incipient-wetness impregnation method. The physical and chemical properties of the catalysts were characterized by means of N2-adsorption-desorption, XRD, TEM, UV-Vis, Raman, XANES and H2-TPR. The results showed that a trace amount of MoO3 was produced on high Mo content samples. Tum-over frequency （TOF） and product selectivity are dependent on the molybdenum content. Both Mo0.75/SBA-15 and Mo1.75/SBA-15 catalysts give the higher catalytic activity and the selectivity to the total aldehydes for the selective oxidation of C2H6. At the reaction temperature of 625℃, the maximum yield of aldehydes reached 4.2% over Mo0.75/SBA-15 catalyst. The improvement of the activity and selectivity was related with the state of MoOx species.

关键词： selective oxidation of ethane supported oxides catalysts Mo aldehydes SBA-15

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Using yttrium as an indicator to estimate total rare earth element concentration:a case study of anthracite-associated clays from northeastern Pennsylvania

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International Journal of Coal Science & Technology 2020年第4期7卷 652-661页

作者： Xiaojing Yang Daniel Kozar Daniel Gorski Anthony Marchese James Pagnotti Rusty Sutterlin Mohammad Rezaee Mark S.Klima Sarma V.Pisupati john and willie leone Family department of energy and mineral engineering and the EMS energy Institute Center for Critical MineralsThe Pennsylvania State University110 Hosier BuildingUniversity ParkPA 16802USA Texas mineral Resources Corporation.539 El Paso St Sierra BlancaTX 79851USA Pagnotti Enterprises 46 Public SquareWilkes-BarrePA 18701USA Inventure Renewables Inc161625th Avenue.TuscaloosaAL 35401USA

This study demonstrated using yttrium(Y)as an indicator to estimate the total rare earth element and Y contents(REY)in coal-associated samples and to facilitate selection of samples with high REY assays in a fast and inexpensive *** than 10 anthracite-associated samples were collected from each of three Pennsylvanian sites(sites B,J and C)based on Thorium gamma ray logging suggesting high REY *** samples from each site were analyzed by ICP-MS to determine the rare earth distribution patterns and to establish the site-specific linear equations of Y and *** Y contents of the remaining samples were measured by a portable X-ray fluorescence analyzer,and the REY values were estimated based on the site-specific linear equation developed earlier.R-squared values above 0.70 were obtained for all the estimation equations from all three sites on both a whole sample basis and an ash ***,ash content has been widely used as an indicator of high REY *** may not be applicable for a specific *** B in this study is an example where ash contents could not be statistically correlated with REY,so using Y for estimation is more *** demonstrated sample screening process is suitable for samples from sites that share more similar distribution patterns(either MREY or LREY or HREY)as well as for samples from sites that share multiple distribution patterns(LREY/MREY/HREY)depending on the desirable *** demonstrated process lowers the analytical cost from$70 to 80 dollars per sample to$10-15 per sample while significantly reducing the processing time and acid consumption for ICP *** is particularly true when a relatively large sample size is involved,for example,100 samples from one site analyzed by ICP-MS/OES.

关键词： Rare earth elements XRF analysis Correlations Prediction ICP analysis

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Characterization of Size and Density Separated Fractions of a Bituminous Coal as a Feedstock for Entrained Slagging Gasification

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International Journal of Clean Coal and energy 2013年第4期2卷 58-67页

作者： Nari Soundarrajan Nandakumar Krishnamurthy Sarma V. Pisupati john and willie Leonie Family department of energy and mineral engineering and EMS energy Institute The Pennsylvania State University University Park USA National energy Technology Laboratory US Department of Energy Morgantown USA

Coal is one of the main sources of energy in many parts of the world and has one of the largest reserves/production ratios amongst all the non-renewable energy sources. Gasification of coal is one among the advanced technologies that has potential to be used in a carbon constrained economy. However, gasification availability at several commercial demonstrations had run into problems associated with fouling of syngas coolers due to unpredictable flyash formation and unburnt carbon losses. Computer models of gasifiers are emerging as a powerful tool to predict gasifier performance and reliability, without expensive testing. Most computer models used to simulate gasifiers tend to model coal as a homogenous entity based on bulk properties. However, coal is a heterogeneous material and comminution during feedstock preparation produces particle classes with different physical and chemical properties. It is crucial to characterize the heterogeneity of the feedstocks used by entrained flow gasifiers. To this end, a low ash US bituminous coal that could be used as a gasifier feedstock was segregated into density and size fractions to represent the major mineral matter distributions in the coal. Float and sink method and sieving were employed to partition the ground coal. The organic and inorganic content of all density fractions was characterized for particle size distribution, heating value, ultimate analysis, proximate analysis, mineral matter composition, ash composition, and petrographic components, while size fractions were characterized for heating value, ash composition, ultimate and proximate analysis. The proximate, ultimate and high heating value analysis showed that variation in these values is limited across the range of size fractions, while the heterogeneity is significant over the range of density fractions. With respect to inorganics, the mineral matter in the heavy density fractions contribute significantly to the ash yield in the coal while contributing ver

关键词： Slag Fly-Ash Entrained-Flow Gasifier Clean Coal Technology mineral Transformations Partioning

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Emerging contaminants:A One Health perspective

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The Innovation 2024年第4期5卷 140-170,139页

作者： Fang Wang Leilei Xiang Kelvin Sze-Yin Leung Martin Elsner Ying Zhang Yuming Guo Bo Pan Hongwen Sun Taicheng An Guangguo Ying Bryan WBrooks Deyi Hou Damian EHelbling Jianqiang Sun Hao Qiu Timothy MVogel Wei Zhang Yanzheng Gao Myrna JSimpson Yi Luo Scott XChang Guanyong Su Bryan MWong Tzung-May Fu Dong Zhu Karl JJobst Chengjun Ge Frederic Coulon Jean Damascene Harindintwali Xiankui Zeng Haijun Wang Yuhao Fu Zhong Wei Rainer Lohmann Changer Chen Yang Song Concepcion Sanchez-Cid Yu Wang Ali El-Naggar Yiming Yao Yanran Huang Japhet Cheuk-Fung Law Chenggang Gu Huizhong Shen Yanpeng Gao Chao Qin Hao Li Tong Zhang Natàlia Corcoll Min Liu Daniel SAlessi Hui Li Kristian KBrandt Yolanda Pico Cheng Gu Jianhua Guo Jianqiang Su Philippe Corvini Mao Ye Teresa Rocha-Santos Huan He Yi Yang Meiping Tong Weina Zhang Fidèle Suanon Ferdi Brahushi Zhenyu Wang Syed AHashsham Marko Virta Qingbin Yuan Gaofei Jiang Louis A.Tremblay Qingwei Bu Jichun Wu willie Peijnenburg Edward Topp Xinde Cao Xin Jiang Minghui Zheng Taolin Zhang Yongming Luo Lizhong Zhu Xiangdong Li DamiàBarceló Jianmin Chen Baoshan Xing Wulf Amelung Zongwei Cai Ravi Naidu Qirong Shen Janusz Pawliszyn Yong-guan Zhu Andreas Schaeffer Matthias C.Rillig Fengchang Wu Gang Yu James M.Tiedje State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China University of Chinese Academy of Sciences Beijing 100049China department of Chemistry Hong Kong Baptist UniversityHong KongChina HKBU Institute of Research and Continuing Education Shenzhen Virtual University ParkShenzhenChina Technical University of Munich TUM School of Natural SciencesInstitute of Hydrochemistry85748 GarchingGermany School of Resources&Environment Northeast Agricultural UniversityHarbin 150030China Climate Air Quality Research UnitSchool of Public Health and Preventive MedicineMonash UniversityMelbourneVICAustralia Faculty of Environmental Science&engineering Kunming University of Science&TechnologyKunming 650500China Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria College of Environmental Science and EngineeringNankai UniversityTianjin 300350China Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control School of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Ministry of Education Key Laboratory of Environmental Theoretical Chemistry South China Normal UniversityGuangzhouGuangdong 510006China department of Environmental Science Baylor UniversityWacoTXUSA Center for Reservoir and Aquatic Systems Research(CRASR) Baylor UniversityWacoTXUSA School of Environment Tsinghua UniversityBeijing 100084China School of Civil and Environmental engineering Cornell UniversityIthacaNY 14853USA Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province Zhejiang University of TechnologyHangzhou 310014China School of Environmental Science and engineering Shanghai Jiao Tong UniversityShanghai 200240China Laboratoire d’Ecologie Microbienne Universite Claude Bernard Lyon 1UMR CNRS 5557UMR INRAE 1418VetAgro Sup69622 VilleurbanneFrance department of Pla

Environmental pollution is escalating due to rapid global development that often prioritizes human needs over planetary *** global efforts to mitigate legacy pollutants,the continuous introduction of new substances remains a major threat to both people and the *** response,global initiatives are focusing on risk assessment and regulation of emerging contaminants,as demonstrated by the ongoing efforts to establish the UN’s Intergovernmental Science-Policy Panel on Chemicals,Waste,and Pollution *** review identifies the sources and impacts of emerging contaminants on planetary health,emphasizing the importance of adopting a One Health *** for monitoring and addressing these pollutants are discussed,underscoring the need for robust and socially equitable environmental policies at both regional and international *** actions are needed to transition toward sustainable pollution management practices to safeguard our planet for future generations.

关键词： pollution planet contaminants

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