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Boosting sodium-storage properties of hierarchical Na_(3)V_(2)(PO_(4))_(3)@C micro-flower cathodes by tiny Cr doping:The effect of“four ounces moving a thousand pounds”

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Nano Research 2024年第1期17卷 235-244页

作者： Yongjia Wang Guoshuai Su Xiaoying Li Linrui Hou Longwei Liang Changzhou Yuan School of Materials Science&Engineering University of JinanJinan 250022China

Na_(3)V_(2)(PO_(4))_(3)(NVP),as a great potential cathode candidate for Na-ion batteries(NIBs),has attracted enormous interest due to its three-dimensional(3D)large open framework for convenient Na+transport,yet its practical application is still limited by its inferior electron conductivity and sluggish Na+diffusion ***,the tiny Cr doped hierarchical NVP micro-flower cathodes(i.e.,Na_(3)V_(2-x)Crx(PO_(4))_(3)@C,x≤0.1),which are self-assembled with single-crystal nanoflake subunits in-situ coated with carbon nano-shell,are designed and fabricated via a scalable *** optimized cathode,i.e.,Na_(3)V_(1.94)Cr_(0.06)(PO_(4))_(3)@C(NVCP-6),was endowed with more electro-active Na(2)sites and higher electronic/ionic conductivity for efficient sodium *** from these competitive merits,the NVCP-6,when evaluated as a cathode towards NIBs,exhibits an ultrahigh-rate capability of 99.8 mAh·g^(-1)at 200 C and superior stability of 82.2%over 7300 cycles at 50 ***,the NVCP-6 based full NIBs display remarkable electrochemical properties in terms of both high-rate capacities and long-duration cycling properties at different temperatures(-20–50°C).The contribution,i.e.,the design of“four ounces can move a thousand pounds”,here will promote the practical industrial application of NVP towards advanced NIBs.

关键词： Na_(3)V_(2)(PO_(4))_(3)cathode tiny Cr doping active Na sites ultrahigh-rate capability Na-ion batteries

Electronic property and topological phase transition in a graphene/CoBr_(2) heterostructure

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Chinese Physics B 2024年第2期33卷 498-505页

作者：秦元秀李胜世纪维霄张昌文 School of Physics and Technology Institute of SpintronicsUniversity of JinanJinan 250022China

Recently,significant experimental advancements in achieving topological phases have been reported in van der Waals(vdW)heterostructures involving ***,using first-principles calculations,we investigate graphene/CoBr_(2)(Gr/CoBr_(2))heterostructures and find that an enhancement of in-plane magnetic anisotropy(IMA)energy in monolayer CoBr_(2) can be accomplished by reducing the interlayer distance of the vdW *** addition,we clarify that the enhancement of IMA energy primarily results from two factors:one is the weakness of the Co-d_(xy) and Co-d_(x^(2)-y^(2)) orbital hybridization and the other is the augmentation of the Co-d_(yz) and Co-d_(z)2 orbital ***,calculation results suggest that the Kosterlitz–Thouless phase transition temperature(TKT)of a 2D XY magnet Gr/CoBr_(2)(23.8 K)is higher than that of a 2D XY monolayer CoBr_(2)(1.35 K).By decreasing the interlayer distances,the proximity effect is more pronounced and band splitting ***,by taking into account spin–orbit coupling,a band gap of approximately 14.3 meV and the quantum anomalous Hall effect(QAHE)are attained by decreasing the interlayer distance by 1.0 *** by the above conclusions,we design a topological field transistor device *** results support that the vdW interlayer distance can be used to modulate the IMA energy and QAHE of materials,providing a pathway for the development of new low-power spintronic devices.

关键词： van der Waals heterostructure in-plane magnetic anisotropy energy quantum anomalous Hall effect

Wheat morphological and biochemical responses to copper oxide nanoparticles in two soils

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Pedosphere 2024年第4期34卷 814-825页

作者： Qian YANG Haipeng LI Yuqing ZHANG Yinghao LIU Helian LI School of Water Conservancy and Environment University of JinanJinan 250022China

The widespread application of copper oxide nanoparticles(CuO NPs)in agricultural production has caused growing concerns about their impact on *** this study,wheat root elongation was used to evaluate the toxic effect concentrations of CuO NPs in two soils with differing properties,collected from farmlands in Guangdong(GD)and Shandong(SD)provinces,*** morphological and biochemical properties were also assessed to explore the toxicity mechanism of CuO NPs on wheat *** root elongation results revealed lower toxic effect concentration values in the plants grown in GD soil than in SD ***,the treatment with CuO NPs at 200 mg Cu kg^(-1) significantly reduced wheat root and shoot biomass by 35.8%and 15.8%,respectively,in GD *** microscopy showed that CuO NPs deformed wheat roots and entered leaf cells,causing deformation and damaging the cell *** CuO NP treatments also decreased chlorophyll content,increased antioxidant enzyme activity,and increased membrane lipid peroxidation in wheat *** addition of CuO NPs significantly reduced the Zn(by 17.3%)and Fe(by 26.9%)contents in the leaves of plants grown in GD and SD soils,***,the contents of Cu,Mg,and Mn were increased by 27.4%–52.5%in GD soil and by 17.9%–71.6%in SD *** results suggested that CuO NPs showed greater toxicity to wheat plants grown in acidic soil than in alkaline soil and that the adverse effects of CuO NP treatments on wheat seedlings were due to a combination of CuO NPs and released Cu^(2+).

关键词： antioxidant enzyme activity chlorophyll content CuO nanoparticles element accumulation membrane lipid peroxidation root elongation toxic effectconcentration

Self-Powered Flexible Multicolor Electrochromic Devices for Information Displays

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Research 2024年第2期2023卷 529-540页

作者： Wenzhao Xue Yun Zhang Feng Liu Yao Dou Mei Yan Wenshou Wang School of Chemistry and Chemical Engineering University of JinanJinan 250022P.R.China

The development of self-powered flexible multicolor electrochromic(EC)systems that could switch different color without an external power supply has remained extremely ***,a new trilayer film structure for achieving self-powered flexible multicolor EC displays based on self-charging/discharging mechanism is proposed,which is simply assembled by sandwiching an ionic gel film between 2 cathodic nickel hexacyanoferrate(NiHCF)and Prussian blue(PB)nanoparticle films on indium tin oxide *** display exhibits independent self-powered color switching of NiHCF and PB films with fast responsive time and high reversibility by selectively connecting the Al wire as anodes with the 2 EC *** switching is thus achieved through a color overlay effect by superimposing the 2 EC films,including green,blue,yellow,and *** bleaching/coloration process of the displays is driven by the discharging/self-charging mechanism for NiHCF and PB films,respectively,ensuring the self-powered color switching of the displays reversibly without an external power *** is further demonstrated that patterns can be easily created in the self-powered EC displays by the spray-coating method,allowing multicolor changing to convey specific ***,a self-powered ionic writing board is demonstrated based on the self-powered EC displays that can be repeatedly written freehand without the need of an external power *** believe that the design concept may provide new insights into the development of self-powered flexible multicolor EC displays with self-recovered energy for widespread applications.

关键词： connecting repeatedly powered

A Parameter Adaptive Method for Image Smoothing

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Tsinghua Science and Technology 2024年第4期29卷 1138-1151页

作者： Suwei Wang Xiang Ma Xuemei Li School of Computer Science and Technology Shandong UniversityJinan 250101China School of Software Shandong UniversityJinan 250101China

Edge is the key information in the process of image smoothing. Some edges, especially the weak edges, are difficult to maintain, which result in the local area being over-smoothed. For the protection of weak edges, we propose an image smoothing algorithm based on global sparse structure and parameter adaptation. The algorithm decomposes the image into high frequency and low frequency part based on global sparse structure. The low frequency part contains less texture information which is relatively easy to smoothen. The high frequency part is more sensitive to edge information so it is more suitable for the selection of smoothing parameters. To reduce the computational complexity and improve the effect, we propose a bicubic polynomial fitting method to fit all the sample values into a surface. Finally, we use Alternating Direction Method of Multipliers (ADMM) to unify the whole algorithm and obtain the smoothed results by iterative optimization. Compared with traditional methods and deep learning methods, as well as the application tasks of edge extraction, image abstraction, pseudo-boundary removal, and image enhancement, it shows that our algorithm can preserve the local weak edge of the image more effectively, and the visual effect of smoothed results is better.

关键词： image smoothing parameter adaptation bicubic interpolation polynomial fitting

Input-to-State Stability for Impulsive Switched Singular Systems with Mismatched Disturbances

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Journal of Systems Science & Complexity 2024年第3期37卷 924-946页

作者： YANG Anqing MA Shuping School of Information Engineering Shandong Management UniversityJinan 250357China School of Mathematics Shandong UniversityJinan 250100China

This work investigates the input-to-state stability(ISS)problem for impulsive switched singular systems(ISSSs)with mismatched *** this paper,‘disturbance’is a general concept that includes model uncertainty,unknown system dynamic,external disturbance,*** modified uncertainty and disturbance estimator(UDE)-based control method is presented for singular systems and ISSSs,a virtual control is introduced to offset the effects of mismatched *** the basis of a discontinuous multiple Lyapunov functional and admissible edge-dependent average dwell time(AED-ADT)method,several sufficient conditions in terms of linear matrix inequalities(LMIs)are obtained to ensure that the closed-loop systems are regular,impulse-free and ***,two examples are given to demonstrate the effectiveness of the proposed results.

关键词： Impulsive switched singular systems input-to-state stability UDE-based control

Unconventional Fluorescent and Multi-responsive Polyethyleneimine with LCST and UCST Behavior:Synthesis,Characterization and Biological Applications

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Chinese Journal of Polymer Science 2024年第6期42卷 826-837页

作者： Feng-Ming Yin Li-Li Wu Shu-Sheng Li Xiao-Na Pan Xiao-Li Zhu Xu-Bao Jiang Xiang Zheng Kong College of Chemistry and Chemical Engineering University of JinanJinan250022China Shandong Institute for Product Quality Inspection Jinan250102China College of Chemical Engineering Tianjin UniversityTianjin300072China

Non-aromatic fluorescent and multi-responsive materials,exhibiting inherent fluorescence emission and controlled phase change,have garnered significant attention in recent ***,the underlying interaction between their fluorescent properties and phase transition remains *** this study,we synthesized a series of catalyst-free aza-Michael addition-based polyethyleneimine(RFPEI)materials by reacting polyethyleneimine(PEI)with N-isopropyl acrylamide(NIPAM).The resulting RFPEI was comprehensively characterized,and demonstrated dual-phase transition behavior(LCST and UCST)in water,which could be finely tuned by adjusting its composition or external factors such as ***,upon UV irradiation(365 nm),RFPEI exhibited strong fluorescence *** further investigated the effects of NIPAM grafting percentage to PEI,polymer concentration,and pH on the LCST/UCST and fluorescent properties of RFPEI aqueous ***,we showcased the great potential of RFPEI as a versatile tool for physiological cell imaging,trace detection,and controlled release of *** study presents a novel class of stimuli-responsive fluorescent materials with promising applications in the field of biomedicine.

关键词： Polyethyleneimine Multi-responsiveness Intrinsic fluorescence emission Cell imaging Controlled drug release

PVP/PAN-derived porous carbon fiber for zinc-ion hybrid supercapacitors

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Rare Metals 2024年第7期43卷 3066-3073页

作者： Shu-Hua Yang Wen-Qing Fu Yan-Wei Cui Bing-Qiang Cao Materials Center for Energy and Photoelectrochemical Conversion School of Material Science and EngineeringUniversity of JinanJinan 250022China

Porous carbon fibers are promising cathodes for zinc-ion hybrid supercapacitors(ZHSs)owing to their abundant active sites,great conductivity,and stable physical and chemical ***,designing a proper preparation technique to regulate the microstructure of carbon fibers still remains a great ***,a poly vinylpyrrolidone/po-lyacry lonitrile(PVP/PAN)-derived porous carbon fiber is developed via the PVP/PAN blend electrospinning and hydrothermal selective PVP removal *** hydrothermal selective PVP removal strategy can effectively avoid a cross-linking between PVP and PAN during the traditional stabilization at air *** PVP/PAN-derived porous carbon fiber,the sufficient micropores provide abundant space for the Zn^(2+)storage,whereas the proper mesopores contribute to the fast ion *** hierarchical porous structures endow ZHSs with high specific capacity and high-rate *** ZHS assembled with the optimal PVP/PAN-derived porous carbon fiber(PVP-PANC-0.8)displays an outstanding specific capacity of 208 mAh·g^(-1),high rate capability(49.5%)from 0.5 to 5 A·g^(-1),and 72.25%capacity retention after 10,000 cycles at 0.5 A·g^(-1).

关键词： Zinc-ion hybrid supercapacitors Porous carbon fibers Hierarchical porous structures Electrospinning

Entropy of deterministic trajectory via trajectories ensemble

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Chinese Physics B 2024年第6期33卷 347-354页

作者：彭勇刚冉翠平郑雨军 School of Physics Shandong UniversityJinan 250100China

We present a formulation of the single-trajectory entropy using the trajectories ensemble. The single-trajectory entropy is affected by its surrounding trajectories via the distribution function. The single-trajectory entropies are studied in two typical potentials, i.e., harmonic potential and double-well potential, and in viscous environment by interacting trajectory method. The results of the trajectory methods are in agreement well with the numerical methods(Monte Carlo simulation and difference equation). The single-trajectory entropies increasing(decreasing) could be caused by absorption(emission) heat from(to) the thermal environment. Also, some interesting trajectories, which correspond to the rare evens in the processes, are demonstrated.

关键词： trajectory entropy trajectories ensemble