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Road sub-surface defect detection based on gprMax forward simulation-sample generation and Swin Transformer-YOLOX

Frontiers of Structural and Civil Engineering 2024年第3期18卷 334-349页

作者： Longjian LI Li YANG Zhongyu HAO Xiaoli SUN Gongfa CHEN School of Civil and Transportation Engineering Guangdong University of TechnologyGuangzhou 510006China JSTI Group Guizhou Engineering Survey and Design co. Ltd.Guangzhou 510800China Guangzhou Municipal Engineering Testing co. Ltd.Guangzhou 510520China

Training samples for deep learning networks are typically obtained through various field experiments,which require significant manpower,resource and time ***,it is possible to utilize simulated data to augment the training *** this paper,by comparing the actual experimental model with the simulated model generated by the gprMax[1]forward simulation method,the feasibility of obtaining simulated samples through gprMax simulation is ***,the samples generated by gprMax forward simulation are used for training the network to detect objects in existing real *** the same time,aiming at the detection and intelligent recognition of road sub-surface defects,the Swin-YOLOX algorithm is introduced,and the excellence of the detection network,which is improved by augmenting the simulated samples with real samples,is further *** comparing the prediction performance of the object detection models,it is observed that the model trained with mixed samples achieved a recall of 94.74%and a mean average precision(maP)of 97.71%,surpassing the model trained only on real samples by 12.95%and 15.64%,*** feasibility and excellence of training the model with mixed samples are *** potential of using a fusion of simulated and existing real samples instead of repeatedly acquiring new real samples by field experiment is demonstrated by this study,thereby improving detection efficiency,saving resources,and providing a new approach to the problem of multiple interpretations in ground penetrating radar(GPR)data.

关键词： ground penetrating radar gprMax forward modeling sample generation Swin-YOLOX object detection

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The structure–activity relationships of Rh/CeO_(2)-ZrO_(2) catalysts based on Rh metal size effect in the three-way catalytic reactions

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Nano Research 2024年第8期17卷 6870-6878页

作者： Dongming Chen Weixin Zhao Zihao Xu Zheng Zhao Juanyu Yang Yongke Hou Yongqi Zhang Zongyu Feng Meisheng Cui Xiaowei Huang National Engineering Research Center for Rare Earth Grirem Advanced Materials Co.Ltd.Beijing 100088China Grirem Hi-Tech co. Ltd.Sanhe 065201China General Research Institute for Nonferrous Metals Beijing 100088China

With the continuous tightening of automotive emission regulations and the increasing promotion of energy-efficient hybrid vehicles,new challenges have arisen for the low-temperature performance of three-way catalysts(TWCs).To guide the design of next-generation TWCs,it is essential to further develop our understanding of the relationships between microstructure and catalytic ***,Rh/CeO_(2)–ZrO_(2) catalysts were synthesized with different Rh metal dispersion by using a combination of the wet impregnation method and reduction *** catalysts included Rh single-atom catalysts,cluster catalysts,and nanoparticle *** results showed that the Rh nanoparticle catalyst,with an average size of 1.9 nm,exhibited superior three-way catalytic performance compared to the other *** on the catalytic activity in a series of simple reaction atmospheres such as co+O_(2),NO+co,and hydrocarbons(HCs)+O_(2) and operando infrared spectroscopy,we found that metallic Rh sites on Rh nanoparticles are the key factor responsible for the low-temperature catalytic performance.

关键词： Rh/CeO_(2)-ZrO_(2) catalyst Rh metal size effect Rh nanoparticles three-way catalytic performance

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A molecular insight into coke formation process of vacuum residue in thermal cracking reaction

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Petroleum Science 2024年第3期21卷 2130-2138页

作者： Ji-Guang Li Xin Guo Huan-Di Hou Heavy Oil Processing Department Sinopec Research Institute of Petroleum Processing Co.LtdBeijing100083China

Understanding the coking behaviors has been considered to be really essential for developing better vacuum residue processing technologies.A battery of thermal cracking tests of typical vacuum residue at 410℃ with various reaction time were performed to evaluate the coke formation *** total yields of ideal components including naphtha,atmospheric gas oil(AGO)and vacuum gas oil(VGO)of thermal cracking reactions increased from 10.89%to 40.81%,and the conversion ratios increased from8.05%to 43.33%with increasing the reaction time from 10 to 70 *** asphaltene content increased from 12.14%to a maximum of 22.39%and then decreased,and this maximum of asphaltene content occurred at the end of the coking induction *** asphaltenes during the coking induction period,at the end and after coking induction period of those tested thermal cracking reactions were characterized to disclose the structure changing rules for coke formation process,and the coke formation pathways were discussed to reveal the coke formation process at molecular level.

关键词： Vacuum residue Thermal cracking Asphaltene coking induction period Sulfur Nitrogen

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FSS: algorithm and neural network accelerator for style transfer

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Science China(Information Sciences) 2024年第2期67卷 253-266页

作者： Yi LING Yujie HUANG Yujie CAI Zhaojie LI Mingyu WANG Wenhong LI Xiaoyang ZENG State Key Laboratory of ASIC & System Fudan University Shanghai Explore X Technology co. Ltd.

Neural networks(NNs), owing to their impressive performance, have gradually begun to dominate multimedia processing. For resource-constrained and energy-sensitive mobile devices, an efficient NN accelerator is necessary. Style transfer is an important multimedia application. However, existing arbitrary style transfer networks are complex and not well supported by current NN accelerators, limiting their application on mobile devices. Moreover, the quality of style transfer needs improvement. Thus, we design the Fast Style system(FSS), where a novel algorithm and an NN accelerator are proposed for style transfer. In FSS, we first propose a novel arbitrary style transfer algorithm, Fast Style. We propose a light network that contributes to high quality and low computational complexity and a prior mechanism to avoid retraining when the style changes. Then, we redesign an NN accelerator for Fast Style by applying two improvements to the basic NVIDIA deep learning accelerator(NVDLA) architecture. First, a flexible dat FSM and wt FSM are redesigned to enable the original data path to perform other operations(including the GRAM operation)by software programming. Moreover, statistics and judgment logic are designed to utilize the continuity of a video stream and remove the data dependency in the instance normalization, which improves the accelerator performance by 18.6%. The experimental results demonstrate that the proposed Fast Style can achieve higher quality with a lower computational cost, making it more suitable for mobile devices. The proposed NN accelerator is implemented on the Xilinx VCU118 FPGA under a 180-MHz clock. Experimental results show that the accelerator can stylize 512×512-pixel video with 20 FPS, and the measured performance reaches up to 306.07 GOPS. The ASIC implementation in TSMC 28 nm achieves about 22 FPS in the case of a 720-p video.

关键词： neural network accelerator style transfer neural network deep learning

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High-efficiency co_(2) sequestration through direct aqueous carbonation of carbide slag: determination of carbonation reaction and optimization of operation parameters

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 157-167页

作者： Zhiqiang Wang Longpeng Cui Yanfang Liu Jili Hou Hongwei Li Liang Zou Fuxia Zhu Department of coal and Syngas conversion Sinopec Research Institute of Petroleum Processing Co.Ltd.Beijing 100083China

Under the dual-carbon target, co_(2) mineralization through solid wastes presents a mutually beneficial approach for permanent carbon emission reduction at a low material cost, while also enabling the resource utilization of these wastes. However, despite its potential, a comprehensive understanding about the effect of industrial solid waste properties and operating parameters on the carbonation process, and the mechanism of direct aqueous carbonation is still lacking. A series of experiments were conducted to compare the carbonation performance of fly ash, steel slag, and carbide slag. Subsequently, co_(2) mineralization by carbide slag was systematically studied under various operating parameters due to its high co_(2) sequestration capacity. Results showed the reactivity of CaO and Ca(OH)2 was higher than that of CaO·SiO_(2) and 2CaO·SiO_(2). Carbide slag demonstrated a sequestration capacity of 610.8 g co_(2)/kg and carbonation efficiency ζCa of 62.04% under the conditions of 65 ℃, 1.5 MPa initial co_(2) pressure, 15 mL/g liquid-to-solid ratio, and 200 r/min stirring speed. Moreover, the formation of carbonates was confirmed through XRD, SEM-EDS, TG, and FTIR. A mechanism analysis revealed that initially, the rate of the carbonation process was primarily controlled by the mass transfer of co_(2) in the gas–liquid interface. However, the rate-determining step gradually shifted to the mass transfer of Ca2+ in the solid–liquid interface as the reaction time increased. This study lays the foundation for the large-scale implementation of co_(2) sequestration through carbide slag carbonation.

关键词： Industrial by-products Direct aqueous carbonation co_(2)sequestration Mass transfer

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Influence of stearic acid surface modification on flowability and agglomeration of battery grade Li_(2)co_(3)powder

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Particuology 2024年第9期92卷 263-277页

作者： Ming Zhou Lithium Industry Center Zhejiang New Era Zhongneng Technology Co.Ltd.Shaoxing312000China

This work investigates the flow and agglomeration behaviors of battery grade Li_(2)co_(3)powder and the influence of stearic acid surface *** degree of agglomeration is directly related to the uniformity of Li_(2)co_(3)and its powder *** to the Chinese National Nonferrous Metal Industry Standard,battery grade Li_(2)co_(3)powder has D50 equal to 3–8μm which belongs to a micron-sized superfine ***,with the extension of storage time,the serious agglomeration phenomenon occurs due to the large specific surface area and rough and irregular powder *** Hausner ratio(HR)of the unmodified sample increases from 1.14 to 1.41,and the corresponding flowability is classified as good to ***,among samples with doping stearic acid,the optimum amount of it is 0.10 wt%which exhibits an extremely stable HR value from 1.14 to ***,after 156 days,the repose angle(AR)obtained for samples without surface modification and using 0.10 wt%stearic acid are calculated to be 49°and 28°,*** on the values of HR and AR,the flowability of the unmodified sample is poor while the sample modified with 0.10 wt%of stearic acid still maintain excellent powder flow ***,The LiMn_(2)O_(4)cathode material synthesized from modified Li_(2)co_(3)powder with a stearic acid content of 0.10 wt%exhibits good crystallinity and comparable electrochemical performance to that prepared by commercial Li_(2)co_(3).These results indicate that stearic acid has the potential to be an ideal modifier for battery grade Li_(2)co_(3)powder that needs to be kept for a long time.

关键词： Battery grade Li_(2)co_(3)powder Flowability Surface modification Stearic acid

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Chemical composition and pharmacological activities of Atractylodes lancea:A review

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Asian Journal of Traditional Medicines 2024年第3期19卷 159-171页

作者： Shuo Wanga Yunpeng Yang Yibo Wang Wenhan Wang Meng Zhang Yu Chen School of Life Science and Biopharmaceutics Shenyang Pharmaceutical UniversityShenyang 110016China jiangxi Alpha Hi-Tech Pharmaceutical co. LtdWuxi 214422China

Atractylodes lancea(called Cangzhu in China)is a medicinal plant that has long been used as tonic agent in various ethno-medical systems in East Asia,especially in China,for the treatment of gastrointestinal dysfunction,cancer,osteoporosis,obesity and fetal *** used the TCMSP database to search for the main active ingredients and traditional Chinese medicine targets of Atractylodes *** are a total of 38 related articles,of which 27 are closely related to chemical composition and *** study reviews the chemical components and pharmacological effects of ***,aiming to provide reference for its further research and development.

关键词： Atractylodes lancea chemical composition pharmacological activities

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convenient room-temperature synthesis of sulfur and nitrogen co-doped Nico-LDH coupled with CNTs on Nico foam as battery-type electrode for high performance hybrid supercapacitor

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Rare Metals 2024年第9期43卷 4286-4301页

作者： Li Song Xiao-Hong Zhong Fang-Lin Wang Zhi-Hui Huang Zhe Hong Yun-Fang Gao Hai-Dong Wang Jian-Wei Ren Sheng-Jie Peng Lei Li college of Biological Chemical Sciences and EngineeringJiaxing UniversityJiaxing 314001China college of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China college of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 210016China Research and Development Department Jiangxi Ganfeng LiEnergy Technology Co.Ltd.Xinyu 338000China Department of Mechanical Engineering Science University of JohannesburgAuckland ParkJohannesburg 2092South Africa

The convenient synthesis of the composite electrode with high supercapacitance performance plays an important role in practical application but is ***,the carbon nanotubes(CNTs)coupled with lowcrystalline sulfur and nitrogen co-doped Ni co-LDH(denoted as SN-Ni co-LDH)nanosheets array are grown on Ni co foam(NCF)substrate by two convenient steps of metal induced self-assembly and corrosion engineering,which present the advantages of operating at roomtemperature and low preparation *** from the S–N co-doping and low-crystallinity of Ni co-LDH,the prepared SN-Ni co-LDH@CNTs@NCF electrode presents a topping charge capacity of 2470 C·g^(-1)(4.94 C·cm^(-2))at 5 m A·cm^(-2).Furthermore,the fabricated asymmetry supercapacitor(ASC)achieves an extraordinary energy density of 77 Wh·kg^(-1)(0.617 m Wh·cm^(-2))at a power density of 438 W·kg^(-1)(3.5 m W·cm^(-2))and outstanding stability(91%capacity retention after 5000 cycles at20 m A·cm^(-2)).Impressively,the structure evolution of Ni co-LDH during the charge/discharge processes has been thoroughly elucidated by in-situ Raman ***,this work verifies a powerful strategy and practical value for preparing composite electrodes with high supercapacitance performance,and also provides guidance for the rational design of the smart electrodes.

关键词： Supercapacitor Nico-LDH Carbon nanotubes Sulfur and nitrogen co-doped convenient synthesis

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Modeling Method of Multi-Energy Systems Based on LSTM Algorithm

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1701-1709页

作者： Di Qiu Fei Chen Dong Liu Min Cao Siyang Liu Shanghai Jiao Tong University Shanghai 200240China Yunnan Power Grid co. Ltd

The development of the Energy Internet has improved the efficiency of energy utilization and promoted sustainable development of power and energy *** multi-energy system modeling considering the dynamic process of transmission line is one of the key research points of Energy Internet operation *** the energy circuit theory,the lumped parameter model of natural gas pipelines is built and the dynamic characteristic parameters under the control instruction are *** with dynamic characteristic parameters,the long short-term memory(LSTM)neural network is designed to fit the natural gas pipeline dynamic process into discrete linear time-varying(LTV)*** with the equations,an energy hub method is used to build a control model of industrial parks with multi-energy distribution *** the rolling optimal control strategy given in this paper,the model is solved by the Matlab-Yalmip solver and rolling control instructions of each energy conversion unit are ***,the case study demonstrates that the LSTM neural network-based modeling method presented in this paper can accurately fit the dynamic process of a natural gas pipeline *** rolling control model of the multi-energy system can improve the efficiency of energy utilization,exhibit the transmission line status constraints during the optimization control process and improve reliability of the multi-energy system operation.

关键词： Energy hub LSTM multi-energy supply system pipeline system modeling

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Sulfur and carbon co-doped g-C_(3)N_(4)microtubes with enhanced photocatalytic H2 production activity

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Frontiers in Energy 2024年第1期18卷 110-121页

作者： Yang GE Quanhao SHEN Qi ZHANG Naixu LI Danchen LU Zhaoming ZHANG Zhiwei FU Jiancheng ZHOU School of Chemistry and Chemical Engineering Southeast UniversityNanjing 211189China Shangdong Yellow Triangle Biotechnology Industry Research Institute co. Ltd.Dongying 257091China Xuzhou B&C Chemical co. Ltd.Xuzhou 221300China

Metal-free graphitic carbon nitride(g-C_(3)N_(4))has captured significant attention as a low-cost and efficient hydrogen production photocatalyst *** regulating the microstructure and accelerating the separation of photogenerated carriers remain crucial strategies for promoting the photocatalytic performance of this ***,a novel sulfur–carbon co-doped g-C_(3)N_(4)(SCCN)hierarchical microtubules filled with abundant nanosheets inside by thermal polymerization is *** nanosheets create abundant pores and cavities inside the SCCN microtubes,thereby increasing the specific surface area of g-C_(3)N_(4)and providing sufficient reactant attachment ***,the hierarchical structure of SCCN microtubules strengthens the reflection and scattering of light,and the utilization of visible light is favorably *** importantly,co-doping S and C has greatly improved the photocatalytic performance of graphitic carbon nitride,optimized the band gap structure and enhanced the photogenerated carrier ***,the SCCN exhibits a remarkable photocatalytic H_(2)evolution rate of 4868μmol/(g·h).This work demonstrates the potential of multi-nonmetal doped g-C_(3)N_(4)as the ideal photocatalyst for H2 evolution.

关键词： carbon nitride photocatalysis hydrogen production

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