检索结果-南通市图书馆

Prominent cycling reversibility and kinetics enabled by CaTiO3 protective layer on Zn metal for aqueous Zn-ion batteries

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 245-258页

作者： Gaeun Lee Yong Nam Ahn Seongjoon So Chanwoo Park Jong-Seong Bae Taehyun Park Il Tae Kim Jaehyun Hur School of Chemical Biological and Battery Engineering Gachon University Seongnam Busan Center Korea Basic Science Institute

Aqueous Zn-ion batteries （AZIBs） have received considerable attention owing to their various advantages such as safety,low cost,simple battery assembly conditions,and high ionic ***,they still suffer from serious problems,including uncontrollable dendrite growth,corrosion,hydrogen evolution reaction （HER） from water decomposition,electrode passivation,and unexpected *** creation of a uniform artificial nanocrystal layer on the Zn anode surface is a promising strategy for resolving these ***,we propose the use of a perovskite CaTiO3（CTO） protective layer on Zn（CTO@Zn） as a promising approach for improving the performance of *** CTO artificial layer provides an efficient pathway for Zn ion diffusion towards the Zn metal because of the high dielectric constant （εr=180） and ferroelectric characteristics that enable the alignment of dipole moments and redistribute the Zn2+ions in the CTO *** avoiding the direct contact of the Zn anode with the electrolyte solution,the uneven dendrite growth,corrosion,parasitic side reactions,and HER are mitigated,while CTO retains its mechanical and chemical robustness during ***,CTO@Zn demonstrates an improved lifespan in a symmetric cell configuration compared with bare ***@Zn shows steady overpotential （～68 m V） for 1500 h at 1 mA cm-2/0.5 mA h cm-2,excelling bare ***,when paired with the V2O5-C cathode,the CTO@Zn//V2O5-C full battery delivers 148.4 mA h g-1（based on the mass of the cathode） after 300 *** study provides new insights into Zn metal anodes and the development of high-performance AZIBs.

关键词： Artificial layer Dielectric constant Zn metal anode Zinc aqueous battery

Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 509-521页

作者： Xinyuan Wang Fan Zhang Xingyu Zhou Qian Wang Changyu Liu Yangyang Liu Hui Wang Xiaojie Liu Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University

Na3V2（PO4）2O2F （VP） is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific *** functional theory （DFT） and finite element simulations show that incorporating SO42-into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge ***,the average Na+diffusion coefficient of Na3V2（PO4）1.95（SO4）0.05O2F（VPS-1） is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g-1) and cycling stability (111.0 mAh g-1capacity after 1000 cycles at 10 C current density) for ***-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 *** assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.

关键词： Anionic group modulation Polarization behavior Fast-charging Sodium-ion battery Fluorophosphate Cathode

ON THE ALMOST EVERYWHERE CONVERGENCE FOR ARBITRARY STOCHASTIC SEQUENCE

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Acta Mathematica Scientia 2014年第5期34卷 1634-1642页

作者：杨卫国陶林零程小军 Faculty of science Jiangsu University

The purpose of this paper is to establish a class of strong limit theorems for arbitrary stochastic sequences. As corollaries, we generalize some known results.

关键词： strong limit theorem stochastic sequence martingale

Transforming Education with Photogrammetry:Creating Realistic 3D Objects for Augmented Reality Applications

在线全文

学校读者我要写书评

暂无评论

Computer Modeling in Engineering & sciences 2025年第1期142卷 185-208页

作者： Kaviyaraj Ravichandran Uma Mohan Department of Computational Intelligence School of ComputingSRM Institute of Science and TechnologyKattankulathur603203India

Augmented reality(AR)is an emerging dynamic technology that effectively supports education across different *** increased use of mobile devices has an even greater *** the demand for AR applications in education continues to increase,educators actively seek innovative and immersive methods to engage students in ***,exploring these possibilities also entails identifying and overcoming existing barriers to optimal educational ***,this surge in demand has prompted the identification of specific barriers,one of which is three-dimensional(3D)*** 3D objects for augmented reality education applications can be challenging and time-consuming for the *** address this,we have developed a pipeline that creates realistic 3D objects from the two-dimensional(2D)*** for augmented and virtual reality can then utilize these created 3D *** evaluated the proposed pipeline based on the usability of the 3D object and performance ***,with 117 respondents,the co-creation team was surveyed with openended questions to evaluate the precision of the 3D object created by the proposed photogrammetry *** analyzed the survey data using descriptive-analytical methods and found that the proposed pipeline produces 3D models that are positively accurate when compared to real-world objects,with an average mean score above *** study adds new knowledge in creating 3D objects for augmented reality applications by using the photogrammetry technique;finally,it discusses potential problems and future research directions for 3D objects in the education sector.

关键词： Augmented reality education immersive learning 3D object creation photogrammetry and StructureFromMotion

MoS_(2)Lubricate‑Toughened MXene/ANF Composites for Multifunctional Electromagnetic Interference Shielding

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2025年第2期17卷 358-371页

作者： Jiaen Wang Wei Ming Longfu Chen Tianliang Song Moxi Yele Hao Zhang Long Yang Gegen Sarula Benliang Liang Luting Yan Guangsheng Wang School of Physical science and Engineering Beijing Jiaotong UniversityBeijing 100044People’s Republic of China Key Laboratory of Bio‑Inspired Smart Interfacial science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191People’s Republic of China

The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution *** MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite *** introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal *** the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,*** toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)*** the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 *** MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial *** work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.

关键词： MXene-MoS_(2) Lubrication toughening EMI shielding Photothermal conversion Electric heating performance

Epitaxial growth triggered core-shell Pd@RuP nanorods for high-efficiency electrocatalytic hydrogen evolution

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2023年第11期86卷 510-517,I0011页

作者： Jiaqian Ding Xian Jiang Caikang Wang Zhuoya Zhu Chang Xu Yi Zhou Xuan Wang Qicheng Liu Zhenyuan Liu Yawen Tang Jun Lin Gengtao Fu jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Center of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023JiangsuChina School of New Energy Nanjing University of Science and TechnologyJiangyin 214443JiangsuChina School of Materials science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212100JiangsuChina

Ru with Pt-like hydrogen bond strength,knockdown cost(~1/3 of Pt),and eximious stability is a competitive replacement for Pt-based catalysts towards the hydrogen evolution reaction(HER)in water *** design of Ru-based catalysts via interface construction,crystal phase control,and specific light element doping to realize the impressive promotion of limited activity and stability remains ***,we report the fabrication of Pd@RuP core-shell nanorods(NRs)via an epitaxial growth method,where ultrathin RuP shells extend the face-centered cubic(fcc)crystal structure and(111)plane of the Pd NRs *** functio nal theory results confirm that the core-s hell interface engineering and P doping synergistically accelerate electron transfer and moderate the d-band center to generate a suitable affinity for H*,thus optimizing HER *** with Pd@Ru NRs and Pt/C,the Pd@RuP NRs exhibit preferable electrocatalytic stability and superior activity with a low overpotential of 18 mV at 10 mA cm-2in the alkaline HER ***,the integrated Pd@RuP//RuO2-based electrolyzer also displays a low operation potential of 1.42 V to acquire 10 mA cm-2,demonstrating great potential for practical water *** work presents an efficient avenue to design Ru-based electrocatalysts via epitaxial growth for extraordinary HER performance.

关键词： Pd@RuP Epitaxial growth Interface engineering Hydrogen evolution Electrocatalyst

SUPERPLASTICITY OF A SiC_w/2024 Al COMPOSITE MADE BY PRESSURE INFILTRATION

在线全文

学校读者我要写书评

暂无评论

Acta Metallurgica Sinica(English Letters) 2002年第5期15卷 425-430页

作者： X. J. Xu , W. Wang and L. Caijiangsuuniversity of science and Technology, Zhenjiang 212013, China jiangsu university of science and Technology

The superplastic characteristics of the β-SiC whisker reinforced 2024 aluminum composite, fabricated by pressure infiltration and hot-rolling after extrusion, were investigated. The composite has a fine grain size of about 1μm, and exhibits a maximum tensile elongation of 370% in the initial strain rate of 3.3×10-3 s-1 at *** superplastic deformation mechanism of the composite is thought to be grain boundary (interface) sliding accommodated by grain boundary diffusion of aluminum atom and an appropriate amount of liquid phase.

关键词： superplasticity aluminum matrix composites pressure infiltra-tion

Interfacial fusion-enhanced 11 μm-thick gel polymer electrolyte for high-performance lithium metal batteries

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第11期98卷 58-66页

作者： Ying Jiang Xinyue Hong Peng Huang Jing Shi Wen Yan Chao Lai School of Chemistry and Materials science Jiangsu Normal UniversityXuzhou 221116JiangsuChina

In the pursuit of ultrathin polymer electrolyte(<20 μm) for lithium metal batteries, achieving a balance between mechanical strength and interfacial stability is crucial for the longevity of the ***, 11 μm-thick gel polymer electrolyte is designed via an integrated electrode/electrolyte structure supported by lithium metal anode. Benefiting from an exemplary superiority of excellent mechanical property, high ionic conductivity, and robust interfacial adhesion, the in-situ formed polymer electrolyte reinforced by titanosiloxane networks(ISPTS) embodies multifunctional roles of physical barrier, ionic carrier, and artificial protective layer at the interface. The potent interfacial interactions foster a seamless fusion of the electrode/electrolyte interfaces and enable continuous ion transport. Moreover, the built-in ISPTS electrolyte participates in the formation of gradient solid-electrolyte interphase(SEI) layer, which enhances the SEI's structural integrity against the strain induced by volume fluctuations of lithium ***, the resultant 11 μm-thick ISPTS electrolyte enables lithium symmetric cells with cycling stability over 600 h and LiFePO_(4) cells with remarkable capacity retention of 96.6% after 800 *** study provides a new avenue for designing ultrathin polymer electrolytes towards stable, safe,and high-energy–density lithium metal batteries.

关键词： Ultrathin gel polymer electrolyte Integrated electrode/electrolyte structure Quasi-solid-state lithium metal battery Solid-electrolyte interphase

Synthesis and electrochemical performances of spherical LiFePO_4 cathode materials for Li-ion batteries

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2006年第z1期25卷 19-24页

作者： ZHOU Jianxin SHEN Xiangqian JING Maoxiang ZHAN Yun School of Materials science and Engineering Jiangsu University Zhenjiang 212013 China School of Materials Science and Engineering Jiangsu University Zhenjiang 212013 China School of Materials Science and Engineering Jiangsu University Zhenjiang 212013 China School of Materials Science and Engineering Jiangsu University Zhenjiang 212013 China

Spherical LiFePO4 and LiFePO4/C composite powders for lithium ion batteries were synthesized by a novel processing route of co-precipitation and subsequent calcinations in a nitrogen and hydrogen atmosphere. The precursors of LiFePO4, LiFePO4/C composite and the resultant products were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and the electrochemical performances were investigated by galvanostatic charge and discharge tests. The precursors composed of amorphous Fe3(PO4)2·xH2O and crystalline Li3PO4 obtained in the co-precipitation processing have a sphere-like morphology. The spherical LiFePO4 derived from the calcinations of the precursor at 700 ℃ for 10 h in a reduction atmosphere shows a discharge capacity of 119 mAh·g-1 at the C/10 rate, while the LiFePO4/C composite with 10wt.% carbon addition exhibits a discharge capacity of 140 mAh·g-1. The electrochemical performances indicate that the LiFePO4/C composite has a higher specific capacity and a more stable cycling performance than the bare olivine LiFePO4 due to the carbon addition enhancing the electronic conductivity.

关键词： spherical LiFePO4 LiFePO4/C composite co-precipitation cathode material Li-ion battery