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Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable Zn‑Air Batteries

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Nano-Micro Letters 2025年第1期17卷 176-190页

作者： Xiaohong Zou Qian Lu Mingcong Tang Jie Wu Kouer Zhang Wenzhi Li Yunxia Hu Xiaomin Xu Xiao Zhang Zongping Shao Liang An Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China jiangsu key laboratory of atmospheric environment monitoring and pollution control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China Department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced Manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction Zn-air batteries

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Molten-salt synthesis and composition-dependent luminescent properties of barium tungsto-molybdate-based solid solution phosphors

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Chinese Physics B 2016年第2期25卷 482-488页

作者：贺香红叶招莲关明云连宁孙建华 School of Chemistry and environmental Engineering Jiangsu University of Technology jiangsu key laboratory of atmospheric environment monitoring and pollution control (AEMPC) School of Environment Science and EngineeringNanjing University of Information Science and Technology

Pr^（3＋）-activated barium tungsto-molybdate solid solution phosphor Ba（Mo_（1-z）W_z）O_4：Pr^（3＋）is successfully fabricated via a facile molten-salt approach. The as-synthesized microcrystal is of truncated octahedron and exhibits deep-red-emitting upon blue light excitation. Powder x-ray diffraction and Raman spectroscopy techniques are utilized to investigate the formation of solid solution phosphor. The luminescence behaviors depend on the resulting composition of the microcrystals with fixed Pr^（3＋）-doping concentration, while the host lattices remain in a scheelite structure. The forming solid solution via the substitution of [WO_4] for [MoO_4] can significantly enhance its luminescence, which may be due to the fact that Ba（Mo_（1-z）W_z）O_4：Pr^（3＋）owns well-defined facets and uniform morphologies. Owing to its properties of high phase purity,well-defined facets, highly uniform morphologies, exceptional chemical and thermal stabilities, and stronger emission intensity, the resulting solid solution phosphor is expected to find potential applications in phosphor-converted white lightemitting diodes（LEDs）.

关键词： molten-salt barium tungsto-molybdate microcrystals solid solution deep-red-emitting

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Theoretical insights of the pharmaceutical compound fluoxetine in water:Role in direct photolysis and indirect photolysis by free radicals

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Journal of environmental Sciences 2024年第8期142卷 269-278页

作者： Ying Lu Se Wang Yifan Shen School of environmental Science and Engineering Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologyJiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlNanjing University of Information Science and TechnologyNanjing 210044China

The frequent detection of pharmaceutical compounds in the environment has led to a growing awareness,which may pose a major threat to the aquatic *** this study,photodegradation(direct and indirect photolysis)of two different dissociation states of fluoxetine(FLU)was investigated in water,mainly including the determination of photolytic transition states and products,and the mechanisms of indirect photodegradation with·OH,CO_(3)^(*-)and NO_(3)^(*).The main direct photolysis pathways are defluorination and C–C bond *** addition,the indirect photodegradation of FLU in water is mainly through the reactions with·OH and NO_(3)^(*),and the photodegradation reaction with CO_(3)^(*-)is relatively difficult to occur in the water *** results provide a theoretical basis for understanding the phototransformation process of FLU in the water environment and assessing its potential risk.

关键词： Fluoxetine Photochemical mechanism Direct photolysis Free radical reaction DFT

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Crystal Structure and Theoretical Energy Gap of 2-(2-((4-(Pyridin-2-yl)pyrimidin-2-yl)disulfanyl)pyrimidin-4-yl)pyridinium Hexafluorophosphate

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Chinese Journal of Structural Chemistry 2017年第2期36卷 229-235页

作者：陶涛赵煚珖曹晖 jiangsu key laboratory of atmospheric environment monitoring and pollution control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and Engineering Nanjing University of Information Science &Technology

The crystal structure of 2-（2-（（4-（pyridin-2-yl）pyrimidin-2-yl）disulfanyl）pyrimidin-4-yl）pyridinium hexafluorophosphate was obtained by X-ray single-crystal diffraction. This molecule crystallizes in monoclinic P2/c space group with a=6.219（1）, b=13.103（2）, c=13.059（2） , β=97.567（2）°, Z=2, the final R=0.0525 and w R=0.1434. The title compound was prepared successfully from 1,2-bis（4-（pyridin-3-yl）pyrimidin-2-yl）disulfane（BPPD）. TD-DFT computational studies on energy gaps and UV-Vis spectra of BPPD and the title compound have been carried out for comparisons. The resultant HOMO-LUMO gap of the BPPD compound is 4.45 e V, while that for the corresponding hexafluorophosphate salt is much smaller at 2.46 e V, which are in agreement with their UV-Vis absorptions.

关键词： resultant monoclinic pyrimidine torsion assembly conjugated octahedral salts heterocyclic tetra

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Seasonal variations, temperature dependence, and sources of size-resolved PM components in Nanjing, east China

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Journal of environmental Sciences 2022年第11期34卷 175-186页

作者： Mingjie Xie Wei Feng Shuyan He Qin’geng Wang Collaborative Innovation Center of atmospheric environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China State key laboratory of pollution control and Resources Reuse School of the EnvironmentNanjing UniversityNanjing 210023China

Size-segregated ambient particulate matter(PM) samples were collected seasonally in suburban Nanjing of east China from 2016 to 2017 and chemically speciated. In both fine( 2.1 μm, PM>2.1) PM, organic carbon(OC) accounted for the highest fractions(26.9% ± 10.9% and 23.1% ± 9.35%) of all measured species, and NO3-lead in average concentrations of water-soluble inorganic ions(WSIIs). The size distributions of measured components were parameterized using geometric mean diameter(GMD). GMD values of NO_(3)^(-), Cl^(-), OC, and PM for the whole size range varied from 2.1μm in warm seasons, which was due to the fact that the size distributions of semi-volatile components(e.g., NH4NO3, NH4Cl, and OC) had a dependency on the ambient *** OC, elemental carbon(EC), and elements, NH_(4)^(+), NO_(3)^(-), and SO_(4)^(2-)exhibited an increase trend in GMD values with relative humidity, indicating that the hygroscopic growth might also play a role in driving seasonal changes of PM size distributions. Positive matrix factorization was performed using compositional data of fine and coarse particles, respectively. The secondary formation of inorganic salts contributing to the majority(> 70%) of fine PM and 20.2% ± 19.9% of speciated coarse PM. The remaining coarse PM content was attributed to a variety of dust sources. Considering that coarse and fine PM had comparable mass concentrations, more attention should be paid to local dust emissions in future air quality plans.

关键词： Particulate matter Size distribution Seasonal variation Semi-volatility Source apportionment

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^(18)F-Labeling techniques for positron emission tomography

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Science China Chemistry 2013年第12期56卷 1682-1692页

作者： LI Ying jiangsu key laboratory of atmospheric environment monitoring & pollution control Chemistry Department School of Environmental Science & Engineering Nanjing University of Information Science & Technology

Much research effort has been made to understand various biological processes at levels of molecules using molecular imaging techniques. Because of great sensitivity, high resolution, and rapid detection, positron emission tomography （PET） imaging is becoming one of the most used imaging techniques for medical diagnose and pre-clinical studies. Here we provide a review on molecular imaging and PET imaging. An introduction is also provided on ~SF-fluorine labeling techniques for the preparation of PET imaging probes. A summary and comparison of currently available ~SF-fluorine labeling methods is provided. The per- spectives for 18F-fluorine labeling techniques are also given.

关键词： molecular imaging positron emission tomography 18F-fluorine/fluoride specific activity radiochemical yield

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Effect of sulfate on Cu(Ⅱ)sorption to polymer-supported nano-hydrated ferric oxides:Experimental and modeling studies

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Chinese Journal of Chemical Engineering 2021年第5期34卷 319-326页

作者： Wenxiang Ni Luyang Yang Xiaolin Zhang Hui Qiu Collaborative Innovation Center of atmospheric environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and PollutionControlSchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China State key laboratory of pollution control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China

Incorporating of hydrous ferric oxide(HFO)inside porous supports with large sizes has become an effective way to decontaminate the water from heavy *** anions like sulfate are usually present in high concentrations in water,and might greatly affect adsorption behavior of hybrid ***,a polymer-based HFO-CPS was fabricated by encapsulating nano-HFO inside a chloromethylated polystyrene polymer(CPS)and the reactivity of HFO-CPS with Cu(Ⅱ)was evaluated in the presence of sulfate *** complexation theory was firstly employed to describe the effect of sulfate on Cu(Ⅱ)adsorption edges of hybrid HFO-CPS,where constant capacitance model(CCM)was *** available weak adsorption site Fe_((2))OH of hybrid HFO-CPS was found to decrease from 20% Fe to 5% Fe,which might be caused by the pore plugging effect after HFO *** the assumption that a ternary complex was formed,the effect of sulfate on Cu(Ⅱ)adsorption by HFO-CPS were successfully described by CCM using the optimized Fe_((2))OH site under different sulfate concentrations(1 or 10 mmol·L^(-1))and Cu/Fe ratios(0.0042 or 0.0252).It is confirmed that the formation of FeOHCuSO4 ternary surface complexes played an important role in enhancing Cu(Ⅱ)adsorption on HFO-CPS in the presence of sulfate.

关键词： Iron oxides Polymer Sulfate Adsorption Ternary complex

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Microphysical Characteristics of Sea Fog over the East Coast of Leizhou Peninsula, China

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Advances in atmospheric Sciences 2013年第4期30卷 1154-1172页

作者：赵丽娟牛生杰张羽徐峰 jiangsu key laboratory of atmospheric environment monitoring and pollution control School of Atmospheric Physics Nanjing University of Information Science and Technology Zhanjiang Meteorological Bureau Guangdong Ocean University

Microphysical properties of sea fog and correlations of these properties were analyzed based on the measurements from a comprehensive field campaign carried out from 15 March to 18 April 2010 on Donghai Island （21°35″N, 110°32″5′E） in Zhanjiang, Guangdong Province, China. There were four types of circula- tion pattern in favor of sea fog events in this area identified, and the synoptic weather pattern was found to influence the microphysical properties of the sea fogs. Those influenced by a warm sector in front of a cold front or the anterior part of low pressure were found to usually have a much longer duration, lower visibility, greater liquid water content, and bigger fog droplet sizes. A fog droplet number concentration of N≥1 cm-a and liquid water content of L≥0.001 g m-a can be used to define sea fogs in this area. The type of fog droplet size distribution of the sea fog events was mostly monotonically-decreasing, with the spectrum width always being 〉20 μm. The significant temporal variation of N was due in large part to the number concentration variation of fog droplets with radius 〈3 μm. A strong collection process appeared when droplet spectrum width was 〉10 μm, which subsequently led to the sudden increase of droplet spectrmn width. The doln- inant physical process during the sea fog events was activation with subsequent condensational growth or reversible evaporation processes, but turbulent mixing also played an important role. The collection process occurred, but was not vital.

关键词： microphysical property microphysical correlation fog droplet size distribution the South China Sea

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Enhanced removal of I^- on hierarchically structured layered double hydroxides by in suit growth of Cu/Cu2O

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Journal of environmental Sciences 2020年第2期32卷 338-348页

作者： Jiuyu Chen Junyi Wang Qianhong Gao Xiaomei Zhang Ying Liu Peng Wang Yan Jiao Zongxiang Zhang Yi Yang jiangsu key laboratory of Chemical pollution control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China Collaborative Innovation Center of atmospheric environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC)Nanjing University of Information Science&TechnologyNanjing 210044China jiangsu environmental Protection key laboratory of monitoring for Organic Pollutants in Soil Taizhou Environmental Monitoring CenterTaizhou 225300China

To further improve the removal ability of layered double hydroxide(LDH) for iodide(I^-) anions from wastewater, we prepared hierarchically porous Cu5Mg10Al5-LDH and used as a matrix for in suit growth of Cu/Cu2O on its surface, forming Cu/Cu2O-LDH, which was characterized and applied as an *** displayed high I^-saturation uptake capability(137.8 mg/g) of Cu/Cu2O-LDH compared with Cu5Mg10Al5-LDH(26.4 mg/g) even thermal activated LDH(76.1 mg/g).Thermodynamic analysis showed that the reaction between I^-anions and Cu/Cu2O-LDH is a spontaneous and *** kinetics analysis exhibited that adsorption equilibrium can be reached after 265 ***, the adsorbent showed satisfactory selectivity in the presence of competitive anions(e.g., SO4^2-), and could achieve good adsorption performance in a wide pH range of 3–8.A cooperative adsorption mechanism was proposed on the basis of the following two aspects:(1) ion exchange between iodide and interlayer anions;(2) the adsorption performance of Cu, Cu(Ⅱ) and Cu2O for I^-.Meanwhile, the difference between the adsorption mechanism of Cu/Cu2O-LDH, Cu5Mg10Al5-LDH and Cu5Mg10Al5-CLDH adsorbents was also elaborated and verified.

关键词： Layered double hydroxide Cu/Cu2O Iodide adsorption Hierarchical structure In suit growth

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Ozone pollution characteristics and sensitivity analysis using an observation-based model in Nanjing,Yangtze River Delta Region of China

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Journal of environmental Sciences 2020年第7期32卷 13-22页

作者： Ming Wang Wentai Chen Lin Zhang Wei Qin Yong Zhang Xiangzhi Zhang Xin Xie Collaborative Innovation Center of atmospheric environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjingJiangsuChina jiangsu environmental monitoring Center NanjingJiangsuChina Department of Ecology and environment of jiangsu Province NanjingJiangsuChina Nanjing environmental monitoring Center Jiangsu ProvinceNanjingJiangsuChina

Ground-level ozone(O3)has become a critical pollutant impeding air quality improvement in Yangtze River Delta region of *** this study,we present O3 pollution characteristics based on one-year online measurements during 2016 at an urban site in Nanjing,jiangsu ***,the sensitivity of O3 to its precursors during 2 O3 pollution episodes in August was analyzed using a box model based on observation(OBM).The relative incremental reactivity(RIR)of hydrocarbons was larger than other precursors,suggesting that hydrocarbons played the dominant role in O3 *** RIR values for NOX ranged from–0.41%/%to 0.19%/%.The O3 sensitivity was also analyzed based on relationship of simulated O3 production rates with reductions of VOC and NOX derived from scenario *** results illustrate that O3 formation was between VOCs-limited and transition *** and light alkenes were found to be key species in O3 formation according to RIR values,and their sources were determined using the Positive Matrix Factorization(PMF)*** and solvent use was the largest contributor to xylenes(54%),while petrochemical industry was the most important source to propene(82%).Discussions on VOCs and NOX reduction schemes suggest that the 5%O3 control goal can be achieved by reducing VOCs by 20%.To obtain 10%O3 control goal,VOCs need to be reduced by 30%with VOCs/NOX larger than 3:1.

关键词： Ozone sensitivity OBM VOCs Yangtze River Delta

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