检索结果-南通市图书馆

A comparative study on the formation of nitrogen-containing organic compounds in cloud droplets and aerosol particles

引用

Journal of environmental Sciences 2025年第3期149卷 456-464页

作者： Guohua Zhang TaoWang Qinhao Lin Kun Liu Wei Sun Duohong Chen Lei Li Xinming Wang Xinhui Bi State key laboratory of Organic Geochemistry and Guangdong Provincial key laboratory of environmental Protection and Resources Utilization Guangzhou Institute of GeochemistryChinese Academy of Sciences(CAS)Guangzhou 510640China Guangdong-Hong Kong-Macao Joint laboratory for environmental pollution and control Guangzhou Institute of GeochemistryCASGuangzhou 510640China University of Chinese Academy of Sciences Beijing 100049China School of environmental Science and Engineering Institute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China State environmental Protection key laboratory of Regional Air Quality monitoring Guangdong Environmental Monitoring CenterGuangzhou 510308China Institute of Mass Spectrometer and atmospheric Environment Jinan UniversityGuangzhou 510632China

Nitrogen-containing organic compounds(NOCs)may potentially contribute to aqueous secondary organic aerosols,yet the different formation of NOCs in aerosol particles and cloud droplets remains *** the in-situ measurements performed at a mountain site(1690 m a.s.l.)in southern China,we investigated the formation of NOCs in the cloud droplets and the cloud-free particles,based on their mixing state information of NOCscontaining particles by single particle mass *** relative abundance of NOCs in the cloud-free particles was significantly higher than those in cloud residual(cloud RES)*** were highly correlated with carbonyl compounds(including glyoxalate and methylglyoxal)in the cloud-free particles,however,limited correlation was observed for cloud RES *** of their mixing state and temporal variations highlights that NOCs was mainly formed from the carbonyl compounds and ammonium in the cloud-free particles,rather than in the cloud RES *** results support that the formation of NOCs from carbonyl compounds is facilitated in concentrated solutions in wet aerosols,rather than cloud *** addition,we have identified the transport of biomass burning particles that facilitate the formation of NOCs,and that the observed NOCs is most likely contributed to the light *** findings have implications for the evaluation of NOCs formation and their contribution to light absorption.

关键词： Nitrogen-containing organic compounds Individual particles Cloud Carbonyl compounds Mixing state

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Interpreting hourly mass concentrations of PM_(2.5)chemical components with an optimal deep-learning model

引用

Journal of environmental Sciences 2025年第5期151卷 125-139页

作者： Hongyi Li Ting Yang Yiming Du Yining Tan Zifa Wang State key laboratory of atmospheric Boundary Layer Physics and atmospheric Chemistry(LAPC) Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China Center for Excellence in Regional atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China Shenyang environmental monitoring Center Shenyang 110167China

PM_(2.5)constitutes a complex and diversemixture that significantly impacts the environment,human health,and climate ***,existing observation and numerical simulation techniques have limitations,such as a lack of data,high acquisition costs,andmultiple *** limitations hinder the acquisition of comprehensive information on PM_(2.5)chemical composition and effectively implement refined air pollution protection and control *** this study,we developed an optimal deep learning model to acquire hourly mass concentrations of key PM_(2.5)chemical components without complex chemical *** model was trained using a randomly partitioned multivariate dataset arranged in chronological order,including atmospheric state indicators,which previous studies did not *** results showed that the correlation coefficients of key chemical components were no less than 0.96,and the root mean square errors ranged from 0.20 to 2.11μg/m^(3)for the entire process(training and testing combined).The model accurately captured the temporal characteristics of key chemical components,outperforming typical machine-learning models,previous studies,and global reanalysis datasets(such asModern-Era Retrospective analysis for Research and Applications,Version 2(MERRA-2)and Copernicus Atmosphere monitoring Service ReAnalysis(CAMSRA)).We also quantified the feature importance using the random forest model,which showed that PM_(2.5),PM_(1),visibility,and temperature were the most influential variables for key chemical *** conclusion,this study presents a practical approach to accurately obtain chemical composition information that can contribute to filling missing data,improved air pollution monitoring and source *** approach has the potential to enhance air pollution control strategies and promote public health and environmental sustainability.

关键词： Pm2.5 chemical composition Hourly mass concentration Deep learning Bayesian optimization Feature importance

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chemical characteristics and sources apportionment of volatile organic compounds in the primary urban area of Shijiazhuang,North China Plain

引用

Journal of environmental Sciences 2025年第3期149卷 465-475页

作者： Xiao Zhang Junfeng Wang Jiangwei Zhao Junliang He Yali Lei Kai Meng RuiWei Xue Zhang Miaomiao Zhang Shuangying Ni Eleonora Aruffo College of geographical sciences and Environment Shijiazhuang UniversityShijiazhuang 050035China jiangsu key laboratory of atmospheric Environment monitoring and pollution control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China Hebei Province Ecology environmental monitoring Center Shijiazhuang 050037China key Lab of Geographic Information Science of the Ministry of Education School of Geographic SciencesEast China Normal UniversityShanghai 200241China Hebei Provincial Institute of Meteorological Sciences Shijiazhuang 050021China key laboratory of Meteorology and Ecological Environment of Hebei Province Shijiazhuang 050021China Hebei Provincial Academy of Ecological environmental Science Shijiazhuang 050037China Department of Advanced Technologies in Medicine&Dentistry University“G.d’Annunzio”of Chieti-PescaraChieti 66100Italy Center for Advanced Studies and Technology-CAST Chieti 66100Italy

VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effective implementation of measures aimed at preventing and controlling atmospheric *** to October 2020,onlinemonitoringwas conducted in the main urban area of Shijiazhuang to collect data on VOCs and analyze their concentrations and ***,the PMF(positive matrix factorization)method was utilized to identify the VOCs *** indicated that the TVOCs(total VOCs)concentration was(96.7±63.4μg/m^3),with alkanes exhibiting the highest concentration of(36.1±26.4μg/m^3),followed by OVOCs(16.4±14.4μg/m^3).The key active components were alkenes and aromatics,among which xylene,propylene,toluene,propionaldehyde,acetaldehyde,ethylene,and styrene played crucial roles as reactive *** sources derived from PMF analysis encompassed vehicle emissions,solvent and coating sources,combustion sources,industrial emissions sources,as well as plant sources,the contribution of which were 37.80%,27.93%,16.57%,15.24%,and 2.46%,***,reducing vehicular exhaust emissions and encouraging neighboring industries to adopt low-volatile organic solvents and coatings should be prioritized to mitigate VOCs levels.

关键词： Volatile organic compounds pollution characteristics Ozone formation potential OH radical loss rate Source apportionment

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Structure-performance relationship between denitration performance and catalytic interface morphologies of MnCeOx/P84 catalytic filters

引用

Journal of Rare Earths 2025年第3期 516-525页

作者： Bo Yang Yujie Lei Maosen Ni Liuying Wang Qiong Huang Mindong Chen jiangsu Collaborative Innovation Center of atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science&Technology

MnCeOx/P84 catalytic filters with spherical,flower-like,cubic and rod-like catalytic interfaces were synthesized respectively,and their catalytic activities in the NH3-SCR reaction were *** MnCeOx/P84 catalytic filter with spherical catalytic interfaces（recorded as S-MnCeOx/P84） exhibits the best catalytic denitration *** NOxremoval efficiency of S-MnCeOx/P84 reaches the highest value of 98.6% at 160℃ when the catalyst loading is 100 g/*** the same time,S-MnCeOx/P84 exhibits good SO2resistance and stability,achieving a NOxremoval rate of 83% at 190℃ with 30 ppm *** characterization results illustrate that the MnCeOxactive component in S-MnCeOx/P84 is present in weak crystalline states,tightly wrapped around the surface of the filter fiber,and uniformly dispersed,and the mesopore is the main pore structure of the S-MnCeOx/P84,which can provide a channel for the catalytic reaction to *** the same time,transmission electron microscopy（TEM） characterization shows that y-MnO2is the main form of MnO2in the S-MnCeOx/*** analysis of H2temperature programmed reduction（H2-TPR）.NH3temperature programmed desorption（NH3-TPD） and in-situ diffuse reflectance infrared spectra（DRIFTS） show that S-MnCeOx/P84 has good redox ability at 100-200℃ and has abundant Lewis acid sites and Br?nsteds acid sites,which provides an important guarantee for its superior low-temperature NH3-SCR denitration performance.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

An improved GCN−TCN−AR model for PM_(2.5) predictions in the arid areas of Xinjiang,China

引用

Journal of Arid Land 2025年第1期17卷 93-111页

作者： CHEN Wenqian BAI Xuesong ZHANG Na CAO Xiaoyi School of Information and control Engineering Qingdao University of TechnologyQingdao 266520China key laboratory for Semi-Arid Climate Change of the Ministry of Education College of Atmospheric SciencesLanzhou UniversityLanzhou 730000China

As one of the main characteristics of atmospheric pollutants,PM_(2.5) severely affects human health and has received widespread attention in recent *** to predict the variations of PM_(2.5) concentrations with high accuracy is an important *** PM_(2.5) monitoring stations in Xinjiang Uygur Autonomous Region,China,are unevenly distributed,which makes it challenging to conduct comprehensive analyses and ***,this study primarily addresses the limitations mentioned above and the poor generalization ability of PM_(2.5) concentration prediction models across different monitoring *** chose the northern slope of the Tianshan Mountains as the study area and took the January−December in 2019 as the research *** the basis of data from 21 PM_(2.5) monitoring stations as well as meteorological data(temperature,instantaneous wind speed,and pressure),we developed an improved model,namely GCN−TCN−AR(where GCN is the graph convolution network,TCN is the temporal convolutional network,and AR is the autoregression),for predicting PM_(2.5) concentrations on the northern slope of the Tianshan *** GCN−TCN−AR model is composed of an improved GCN model,a TCN model,and an AR *** results revealed that the R2 values predicted by the GCN−TCN−AR model at the four monitoring stations(Urumqi,Wujiaqu,Shihezi,and Changji)were 0.93,0.91,0.93,and 0.92,respectively,and the RMSE(root mean square error)values were 6.85,7.52,7.01,and 7.28μg/m^(3),*** performance of the GCN−TCN−AR model was also compared with the currently neural network models,including the GCN−TCN,GCN,TCN,Support Vector Regression(SVR),and *** GCN−TCN−AR outperformed the other current neural network models,with high prediction accuracy and good stability,making it especially suitable for the predictions of PM_(2.5)*** study revealed the significant spatiotemporal variations of PM_(2.5)***,the PM_(2.5) concentrations exhibited cle

关键词： air pollution PM_(2.5) concentrations graph convolution network(GCN)model temporal convolutional network(TCN)model autoregression(AR)model northern slope of the Tianshan Mountains

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effectiveness of Precursor Emission Reductions for the control of Summertime Ozone and PM2.5 in the Beijing–Tianjin–Hebei Region under Different Meteorological Conditions

引用

Advances in atmospheric Sciences 2025年第4期42卷 653-669页

作者： Jing QIAN Hong LIAO jiangsu key laboratory of atmospheric Environment monitoring and pollution control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044JiangsuChina

We used observed concentrations of air pollutants,reanalyzed meteorological parameters,and results from the Goddard Earth Observing System Chemical Transport Model to examine the relationships between concentrations of maximum daily 8-h average ozone(MDA8 O_(3)),PM_(2.5)(particulate matter with diameter of 2.5μm or less),and PM_(2.5)components and 2-m temperature(T2)or relative humidity(RH),as well as the effectiveness of precursor emission reductions on the control of O_(3) and PM_(2.5) in Beijing–Tianjin–Hebei(BTH)under different summertime temperature and humidity *** observed(simulated)MDA8 O_(3) and PM_(2.5) concentrations increased as T2 went up,with linear trends of 4.8(3.2)ppb℃^(−1) and 1.9(1.5)μg m^(−3)℃^(−1),*** results showed that the decreases in MDA8 O_(3) from precursor emission reductions were more sensitive to T2 than to *** a larger proportion of volatile organic compound(VOC)emissions at higher T2 was more effective for the control of summertime O_(3) in *** the control of summertime PM_(2.5) in BTH,reducing nitrogen oxides(NOx)combined with a small proportion of VOCs was the best *** magnitude of reduction in PM_(2.5) from reducing precursor emissions was more sensitive to RH than to T2,with the best efficiency at high *** from this study are helpful for formulating effective policies to tackle O_(3) and PM_(2.5) pollution in BTH.

关键词： ozone PM_(2.5) emission reductions meteorological conditions

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Enhanced removal of I^- on hierarchically structured layered double hydroxides by in suit growth of Cu/Cu2O

引用

Journal of environmental Sciences 2020年第2期32卷 338-348页

作者： Jiuyu Chen Junyi Wang Qianhong Gao Xiaomei Zhang Ying Liu Peng Wang Yan Jiao Zongxiang Zhang Yi Yang jiangsu key laboratory of Chemical pollution control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China Collaborative Innovation Center of atmospheric Environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC)Nanjing University of Information Science&TechnologyNanjing 210044China jiangsu environmental Protection key laboratory of monitoring for Organic Pollutants in Soil Taizhou Environmental Monitoring CenterTaizhou 225300China

To further improve the removal ability of layered double hydroxide(LDH) for iodide(I^-) anions from wastewater, we prepared hierarchically porous Cu5Mg10Al5-LDH and used as a matrix for in suit growth of Cu/Cu2O on its surface, forming Cu/Cu2O-LDH, which was characterized and applied as an *** displayed high I^-saturation uptake capability(137.8 mg/g) of Cu/Cu2O-LDH compared with Cu5Mg10Al5-LDH(26.4 mg/g) even thermal activated LDH(76.1 mg/g).Thermodynamic analysis showed that the reaction between I^-anions and Cu/Cu2O-LDH is a spontaneous and *** kinetics analysis exhibited that adsorption equilibrium can be reached after 265 ***, the adsorbent showed satisfactory selectivity in the presence of competitive anions(e.g., SO4^2-), and could achieve good adsorption performance in a wide pH range of 3–8.A cooperative adsorption mechanism was proposed on the basis of the following two aspects:(1) ion exchange between iodide and interlayer anions;(2) the adsorption performance of Cu, Cu(Ⅱ) and Cu2O for I^-.Meanwhile, the difference between the adsorption mechanism of Cu/Cu2O-LDH, Cu5Mg10Al5-LDH and Cu5Mg10Al5-CLDH adsorbents was also elaborated and verified.

关键词： Layered double hydroxide Cu/Cu2O Iodide adsorption Hierarchical structure In suit growth

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable Zn‑Air Batteries

引用

Nano-Micro Letters 2025年第1期17卷 176-190页

作者： Xiaohong Zou Qian Lu Mingcong Tang Jie Wu Kouer Zhang Wenzhi Li Yunxia Hu Xiaomin Xu Xiao Zhang Zongping Shao Liang An Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China jiangsu key laboratory of atmospheric Environment monitoring and pollution control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China Department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced Manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction Zn-air batteries

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

^(18)F-Labeling techniques for positron emission tomography

引用

Science China Chemistry 2013年第12期56卷 1682-1692页

作者： LI Ying jiangsu key laboratory of atmospheric Environment monitoring & pollution control Chemistry Department School of Environmental Science & Engineering Nanjing University of Information Science & Technology

Much research effort has been made to understand various biological processes at levels of molecules using molecular imaging techniques. Because of great sensitivity, high resolution, and rapid detection, positron emission tomography （PET） imaging is becoming one of the most used imaging techniques for medical diagnose and pre-clinical studies. Here we provide a review on molecular imaging and PET imaging. An introduction is also provided on ~SF-fluorine labeling techniques for the preparation of PET imaging probes. A summary and comparison of currently available ~SF-fluorine labeling methods is provided. The per- spectives for 18F-fluorine labeling techniques are also given.

关键词： molecular imaging positron emission tomography 18F-fluorine/fluoride specific activity radiochemical yield

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Molten-salt synthesis and composition-dependent luminescent properties of barium tungsto-molybdate-based solid solution phosphors

引用

Chinese Physics B 2016年第2期25卷 482-488页

作者：贺香红叶招莲关明云连宁孙建华 School of Chemistry and environmental Engineering Jiangsu University of Technology jiangsu key laboratory of atmospheric Environment monitoring and pollution control (AEMPC) School of Environment Science and EngineeringNanjing University of Information Science and Technology

Pr^（3＋）-activated barium tungsto-molybdate solid solution phosphor Ba（Mo_（1-z）W_z）O_4：Pr^（3＋）is successfully fabricated via a facile molten-salt approach. The as-synthesized microcrystal is of truncated octahedron and exhibits deep-red-emitting upon blue light excitation. Powder x-ray diffraction and Raman spectroscopy techniques are utilized to investigate the formation of solid solution phosphor. The luminescence behaviors depend on the resulting composition of the microcrystals with fixed Pr^（3＋）-doping concentration, while the host lattices remain in a scheelite structure. The forming solid solution via the substitution of [WO_4] for [MoO_4] can significantly enhance its luminescence, which may be due to the fact that Ba（Mo_（1-z）W_z）O_4：Pr^（3＋）owns well-defined facets and uniform morphologies. Owing to its properties of high phase purity,well-defined facets, highly uniform morphologies, exceptional chemical and thermal stabilities, and stronger emission intensity, the resulting solid solution phosphor is expected to find potential applications in phosphor-converted white lightemitting diodes（LEDs）.

关键词： molten-salt barium tungsto-molybdate microcrystals solid solution deep-red-emitting

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：