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Constructing orthogonally structured graphene nanointerface on SiC nanowires reinforced carbon/carbon composites to boost mechanical strength and strength retention rate

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Journal of Materiomics 2024年第3期10卷 615-623页

作者： Yao Guo Shouyang Zhang Qiang Song Fei Zhao Longkang Cong Wei Li Ruimei Yuan State Key Laboratory of Solidification processing Shaanxi Key Laboratory of Fiber Reinforced Light Composite MaterialsNorthwestern Polytechnical UniversityXi'an 710072China Advanced interdisciplinary research Center for Flexible Electronics Academy of Advanced Interdisciplinary ResearchXidian UniversityXi'an 710072China

Carbon/carbon composites with higher mechanical strength and better reliability at elevated tempera-tures are urgently needed to satisfy the practical applications *** nanowires(SiCNWs)modified C/C(SC-CC)composites have attracted an abundance of attention for their excellent mechanical *** further boost the mechanical strengths of composites and maximize the reinforcing efficiency of SiCNWs,we introduce orthogonally structured graphene nanosheets(OGNs)into SC-CC composites,in which OGNs are grafted on the SiCNWs via chemical vapor deposition(CVD)method,forming SC-G-CC *** from the nano-interface effects,uniform stress distribution,strong SiCNWs/PyC interfacial bonding and elevated stress propagation efficiency in the PyC matrix are achieved,thus SC-G-CC composites accomplish brilliant mechanical properties before and after 1,600℃ heat *** temperature rises to 2,100℃,SiCNWs lose efficacy,whereas OGNs with excellent thermal stability continue to play the nano-interface role in the PyC ***,SC-G-CC com-posites show better mechanical performance after 2,100℃ heat treatment,and the mechanical strength retention rate(MSR)of interlaminar shear strength,out-of-plane and in-plane compressive strength of SC-G-CC composites reach 61.0%,55.7%and 55.3%,*** work proposes an alternative thought for maximizing the potentiality of nanomaterials and edifies the mechanical modification of composites.

关键词： SiC nanowires Orthogonally structured graphene nanosheets Carbon/carbon composites Mechanical properties Heat treatment

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Introduction of rare-earth element Sc in alloy design to modify wear features of dual-phase high-entropy alloy

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Rare Metals 2024年第2期43卷 817-828页

作者： Hao Ren Rui-Run Chen Xue-Feng Gao Tong Liu Gang Qin Yu-Lung Chiu Shi-Ping Wu Jing-Jie Guo Guo National Key Laboratory for Precision Hot processing of Metals School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin150001China School of Metallurgy and materials University of BirminghamBirminghamB152TTUK

Tailoring the alloy composition,which induces the hard secondary phase to increase hardness and strength to improve the wear features,is a feasible approach for developing wear-resistant metal ***,a group of(AlCoCrFeNi)_(100–x)Sc_(x)(x=0–2.0,at%)high-entropy alloys(HEAs)are designed and the phase compositions and wear behaviors are ***-doped HEA series contain the primary body-centered cubic(BCC)and eutectic phases,in which the eutectic phase is composed of the alternately grown BCC and Laves *** addition promotes the diffusion of Ni atoms from BCC phase to form the Sc-rich Laves phase at the grain *** hardness increases due to solid solution strengthening and second phase *** the second phase strengthening plays a more significant role relative to solid solution *** phase and the oxides caused by wear heating prevent the direct contact between friction pair and HEAs,thus inducing a decreased wear rate from 6.82×10^(−5) to 3.47×10^(−5)m^(3)·N^(−1)·m^(−1).Moreover,the wear mechanism changes from adhesive wear,abrasive wear and oxidative wear to abrasive wear and oxidative wear.

关键词： High entropy alloy(HEA) Laves phase Hardness Wear mechanism

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A Hf-doped dual-phase high-entropy alloy: phase evolution and wear features

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Rare Metals 2024年第1期43卷 324-333页

作者： Hao Ren Rui-Run Chen Xue-Feng Gao Tong Liu Gang Qin Yu-Lung Chiu Shi-Ping Wu Jing-Jie Guo National Key Laboratory for Precision Hot processing of Metals School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150001China School of Metallurgy and materials University of BirminghamEdgbastonBirmingham B152TTUK

Initially defined high entropy alloys(HEAs)usually exhibit a single-phase solid-solution ***,two and/or more types of phases in HE As possibly induce the desired microstructure features,which contribute to improving the wear properties of HE ***,we prepare a series of(AlCoCrFeNi)_(100-x)Hf_(x)(x=0,2,4and 6;at%) HEAs and concern their phase compositions,micro structures and wear *** leads to the formation of(Ni,Co)_(2)Hf-type Laves phase and tailors the microstructure from a body-centered cubic(BCC) singlephase structure to a hypoeutectic *** increased hardness from~HV 512.3 to~HV 734.1 is due to solid-solution strengthening,grain refinement strengthening and precipitated phase *** a few oxides(Al_(2)O_(3)+Cr_(2)O_(3)) caused by the wear heating contribute to an 85.5% decrease in wear rate of the HEA system from6.71×10^(-5) to 0.97×10^(-5) m^(3)·N^(-1)·m^(-1).In addition,Hf addition changes the wear mechanism from abrasive wear,mild oxidative wear and adhesive wear to oxidative wear and adhesive wear.

关键词： High entropy alloy Laves phase Hardness Wear mechanism

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Multi-Time-Scale Variational Mode Decomposition-Based Robust Fault Diagnosis of Railway Point Machines Under Multiple Noises

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Chinese Journal of Electronics 2024年第3期33卷 814-822页

作者： Junqi LIU Tao WEN Guo XIE Yuan CAO Clive Roberts Shaanxi Key Laboratory of Complex System Control and Intelligent Information processing Xi'an University of Technology The School of Electronic and Information Engineering Beijing Jiaotong University birmingham centre for Railway research and Education University of Birmingham

The fault diagnosis of railway point machines(RPMs) has attracted the attention of engineers and *** have studies considered diverse noises along the *** fulfill this aspect,a multi-time-scale variational mode decomposition(MTSVMD) is proposed in this paper to realize the accurate and robust fault diagnosis of RPMs under multiple *** decomposes condition monitoring signals after coarse-grained processing in varying *** this manner,the information contained in the signal components at multiple time scales can construct a more abundant feature space than at a single *** the experimental validation,a random position,random type,random number,and random length(4R) noise-adding algorithm helps to verify the robustness of the *** adequate experimental results demoristrate the superiority of the proposed MTSVMD-based fault diagnosis.

关键词： Fault diagnosis Condition monitoring Noise Signal processing algorithms Aerospace electronics Rail transportation Robustness

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Polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode

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Nano research 2024年第6期17卷 5278-5287页

作者： Mengyu Shi Junlong Zhang Guochuan Tang Ben Wang Sen Wang Xiaoxian Ren Guojie Li Weihua Chen Chuntai Liu Changyu Shen State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002China College of Chemistry and Green Catalysis Center Zhengzhou UniversityZhengzhou 450001China research Institute of interdisciplinary Science and School of materials Science and Engineering Dongguan University of TechnologyDongguan 523808China

Zn metal anode suffers from dendrite issues and passive byproducts,which severely plagues the practical application of aqueous Zn metal ***,a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking(hyaluronic acid)and chemical crosslinking(synthetic zwitterionic monomer copolymerized with acrylamide)is introduced to overcome these *** the one hand,highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H_(2)O-poor interface to avoid side *** the other hand,the charged groups(sulfonic and imidazolyl)in chemical crosslinking structure build anion/cation transport channels to boost ions’kinetics migration and regulate the typical solvent structure[Zn(H_(2)O)_(6)]^(2+)to R-SO_(3)^(−)[Zn(H_(2)O)_(4)]^(2+),with uniform electric field distribution and significant resistance to dendrites and parasitic *** on the above functions,the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm^(−2),and Zn||MnO_(2)full cell has a reversible specific capacity of 150 mAh·g^(−1)after 1000 cycles at 2 C with this hydrogel ***,the pouch cell delivers impressive flexibility and cyclability for energy-storage applications.

关键词： Zn anode dendrites parasitic reactions polyzwitterion double network hydrogel electrolyte

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Spaceborne and ground-based sensor collaboration:Advancing resident space objects’orbit determination for space sustainability

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Astrodynamics 2024年第3期8卷 325-347页

作者： Niki Sajjad Mehran Mirshams Andreas Makoto Hein Space research Laboratory Department of Aerospace EngineeringK.N.Toosi University of TechnologyTehran16569-83911Iran interdisciplinary centre for Security Reliability and Trust(SnT)University of LuxembourgLuxembourg1855Luxembourg

The limited space around the Earth is getting cluttered with leftover fragments from old missions,creating a real *** more satellites are launched,even debris pieces as small as 5 mm must be tracked to avoid ***,it is an arduous and challenging task in *** paper presents a technical exploration of ground-based and in-orbit space debris tracking and orbit determination *** highlights the challenges faced during on-ground and in-orbit demonstrations,identifies current gaps,and proposes solutions following technological advancements,such as low-power pose estimation *** to the numerous atmospheric barriers to ground-based sensors,this study emphasizes the significance of spaceborne sensors for precise orbit determination,complemented by advanced data processing algorithms and collaborative *** ultimate goal is to create a comprehensive catalog of resident space objects(RSO)around the Earth and promote space environment *** exploring different methods and finding innovative solutions,this study contributes to the protection of space for future exploration and the creation of a more transparent and precise map of orbital objects.

关键词： resident space objects(RSO) space debris orbit determination tracking ground-based sensors spaceborne sensors

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In situ polymerization of water-induced 1,3-phenylene diisocyanate for enhanced efficiency and stability of inverted perovskite solar cells

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interdisciplinary materials 2024年第2期3卷 316-325页

作者： Shiyao Jia Jiabao Yang Tong Wang Xingyu Pu Hui Chen Xilai He Guangpeng Feng Xingyuan Chen Yijun Bai Qi Cao Xuanhua Li State Key Laboratory of Solidification processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi'anChina

In the realm of photovoltaics,organometallic hybridized perovskite solar cells(PSCs)stand out as promising contenders for achieving high-efficiency photoelectric conversion,owing to their remarkable performance ***,defects within the perovskite layer,especially at the perovskite grain boundaries and surface,have a substantial impact on both the overall photoelectric performance and long-term operational stability of *** mitigate this challenge,we propose a method for water-induced condensation polymerization of small molecules involving the incorporation of 1,3-phenylene diisocyanate(1,3-PDI)into the perovskite film using an antisolvent *** to this step,the introduction of water triggers the polymerization of[P(1,3-PDI)],thereby facilitating the in situ passivation of uncoordinated lead defects inherent in the perovskite *** passivation process demonstrates a notable enhancement in both the efficiency and stability of *** approach has led to the attainment of a noteworthy power conversion efficiency(PCE)of 24.66% in inverted ***,based on the P(1,3-PDI)modification,these devices maintain 90.15% of their initial efficiency after 5000 h of storage under ambient conditions of 25℃ and 50±5% relative ***,even after maximum power point tracking for 1000 h,the PSCs modified with P(1,3-PDI)sustain 82.05% of the initial *** molecules can rationally manipulate water and turn harm into benefit,providing new directions and methods for improving the efficiency and stability of PSCs.

关键词： antisolvent engineering defect passivation inverted perovskite solar cells

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Multifactor roadmap for designing low-power-consumed micro thermoelectric thermostats in a closed-loop integrated 5G optical module

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interdisciplinary materials 2024年第2期3卷 326-337页

作者： Dongwang Yang Yubing Xing Jiang Wang Kai Hu Yani Xiao Kechen Tang Jianan Lyu Junhao Li Yutian Liu Peng Zhou Yuan Yu Yonggao Yan Xinfeng Tang State Key Laboratory of Advanced Technology for materials Synthesis and processing Wuhan University of TechnologyWuhanChina Nanostructure research Center Wuhan University of TechnologyWuhanChina research Center for materials Genome Engineering Wuhan University of TechnologyWuhanChina Institute of Physics(IA) RWTH Aachen UniversityAachenGermany

As the core components of fifth-generation(5G)communication technology,optical modules should be consistently miniaturized in size while improving their level of *** inevitably leads to a dramatic spike in power consumption and a consequent increase in heat flow density when operating in a confined *** ensure a successful start-up and operation of 5G optical modules,active cooling and precise temperature control via the Peltier effect in confined space is essential yet *** this work,p-type Bi_(0.5)Sb_(1.5)Te_(3)and n-type Bi_(2)Te_(2.7)Se_(0.3)bulk thermoelectric(TE)materials are used,and a micro thermoelectric thermostat(micro-TET)(device size,2×9.3×1.1mm^(3);leg size,0.4×0.4×0.5mm^(3);number of legs,44)is successfully integrated into a 5G optical module with Quad Small Form Pluggable 28 *** a result,the internal temperature of this kind of optical module is always maintained at 45.7°C and the optical power is up to 7.4 ***,a multifactor design roadmap is created based on a 3D numerical model using the ANSYS finite element method,taking into account the number of legs(N),leg width(W),leg length(L),filling atmosphere,electric contact resistance(Rec),thermal contact resistance(Rtc),ambient temperature(Ta),and the heat generated by the laser source(QL).It facilitates the integrated fabrication of micro-TET,and shows the way to enhance packaging and performance under different operating *** to the roadmap,the micro-TET(2×9.3×1mm^(3),W=0.3 mm,L=0.4 mm,N=68 legs)is fabricated and consumes only 0.89W in cooling mode(Q_(L)=0.7W,T_(a)=80℃)and 0.36Win heating mode(T_(a)=0℃)to maintain the laser temperature of 50℃.This research will hopefully be applied to other microprocessors for precise temperature control and integrated manufacturing.

关键词： 5G optical module finite element simulation micro thermoelectric thermostat Peltier effect

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Stable sodium metal anode enabled by interfacial room-temperature liquid metal engineering for high-performance sodium–sulfur batteries with carbonate-based electrolyte

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interdisciplinary materials 2024年第3期3卷 425-436页

作者： Kangdong Tian Chuanliang Wei Zhengran Wang Yuan Li Baojuan Xi Shenglin Xiong Jinkui Feng Key Laboratory for Liquid-Solid Structural Evolution&processing of materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinanChina School of Chemistry and Chemical Engineering Shandong UniversityJinanChina

Sodium(Na)metal is a competitive anode for next-generation energy storage applications in view of its low cost and high-energy ***,the uncontrolled side reactions,unstable solid electrolyte interphase(SEI)and dendrite growth at the electrode/electrolyte interfaces impede the practical application of Na metal as ***,a heterogeneous Na-based alloys interfacial protective layer is constructed in situ on the surface of Na foil by self-diffusion of liquid metal at room temperature,named“HAIP Na.”The interfacial Na-based alloys layer with good electrolyte wettability and strong sodiophilicity,and assisted in the construction of NaF-rich *** means of direct visualization and theoretical simulation,we verify that the interfacial Na-based alloys layer enabling uniform Na^(+)flux deposition and suppressing the dendrite *** a result,in the carbonate-based electrolyte,the HAIP Na||HAIP Na symmetric cells exhibit a remarkably enhanced cycling life for more than 650 h with a capacity of 1mAh cm^(−2)at a current density of 1mAcm^(−2).When the HAIP Na anode is paired with sulfurized polyacrylonitrile(SPAN)cathode,the SPAN||HAIP Na full cells demonstrate excellent rate performance and cycling stability.

关键词： interfacial Na-based alloy layer liquid metal Na dendrite Na metal anode Na–S battery

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Biomimetic porous silicon oxycarbide ceramics with improved specific strength and efficient thermal insulation

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Journal of materials Science & Technology 2024年第1期168卷 185-193页

作者： Zhuoqing Zhang Jinghan Li Lei Cao Yu Shi Huajie Yang Rui Yang Fan Xie Xing Zhang Shi-changxu Innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of materials Science and Engineering University of Science and Technology of ChinaHefei 230026China School of materials Science and Engineering Shenyang Ligong UniversityShenyang 110159China Shenyang Aircraft Design and research Institute Shenyang 110035China

Considering the challenge of aerodynamic heating,the development of high-performance insulating ce-ramic materials with lightweight and low thermal conductivity is crucially important for aerospace vehi-cles to achieve flight at high speed for a long *** this work,macro-porous silicon oxycarbide(SiOC)ceramics with directional pores(DP-SiOC)(mean pore size of 88.1μm)were prepared using polysiloxane precursors via freeze casting and photocrosslinking,followed by *** DP-SiOC samples were lightweight(density∼0.135 g cm^(-3))with a porosity of 90.4%,which showed good shapability through the molding of polysiloxane *** DP-SiOC samples also exhibited an ultra-low thermal con-ductivity of 0.048 W(m K)^(-1)at room temperature,which can also withstand heat treatment at 1200°C for 1 *** addition,scaffolds with triply periodic minimal surfaces(TPMS)were fabricated using digital light processing(DLP)printing,which was further filled with polysiloxane precursors for increasing the strength of *** TPMS scaffolds filled with macro-porous SiOC ceramics(TPMS-DP-SiOC)showed good integration between TPMS and macro-pore structures,which had a porosity∼75%and high specific strength of 9.73×10^(3)N m kg^(-1).The thermal conductivity of TPMS-DP-SiOC samples was 0.255 W(m K)^(-1)at room *** biomimetic TPMS-DP-SiOC ceramics developed in this study are likely used for thermal protection systems.

关键词： Thermal insulation Light weight Macro-porous ceramics SiOC

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