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Single-atomic activation on ZnIn_(2)S_(4)basal planes boosts photocatalytic hydrogen evolution

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Nano Research 2024年第7期17卷 5949-5955页

作者： Jianpeng Cui Ying Wang Luxue Lin Xiaotian Yang Xuyu Luo Shiying Guo Xiaoyong Xu College of Physics Science and Technology and Center for Interdisciplinary ResearchYangzhou UniversityYangzhou 225002China

The use of single-atom cocatalysts plays a crucial role in enhancing artificial photocatalysis,where the precise construction of stable and efficient single-atom configuration is essential but remains ***,we report a simple one-step hydrothermal method for preparing single-atomic Mo modified ZnIn_(2)S_(4)(Mo-ZIS)nanosheets as a highly active photocatalytic hydrogen evolution(PHE)*** Mo substituting for portion of In atoms in ZIS nanosheets induces the spatial charge redistribution,which not only promotes the separation of photogenerated charge carriers but also optimizes the Gibbs free energy of adsorbing H*on S atoms at basal *** a result,Mo-ZIS exhibits an impressive PHE rate as high as 6.71 mmol·g^(−1)·h^(−1),over 10 times that of the pristine ZIS,with an apparent quantum efficiency(AQE)up to 38.8%at 420 *** study gains insights into the coordination configuration and electronic modulation resulting from single-atomic decoration,providing mechanistic cognitions for the development of advanced photocatalysts via non-precious metal atomic modification.

关键词： photocatalytic hydrogen evolution ZnIn_(2)S_(4) single-atom activation Gibbs free energy

Design of efficient thermoelectric generators

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Science China Materials 2024年第1期67卷 377-378页

作者： Min Liu Yanzhong Pei interdisciplinary Materials Research center School of Materials Science and EngineeringTongji UniversityShanghai 201804China

Thermoelectricity,which enables direct conversion between heat and electricity,undergoes impressive developments in recent decades,and is particularly promising for recovering low-grade heat of<600 K[1,2].Currently,only Bi2Te3-based thermoelectric devices are commercialized[3].However,the scarcity of tellurium(Te)(Fig.1a)is the main *** leads to numerous recent efforts on the development of efficient nonBi2Te3 thermoelectrics as potential alternatives,and successful examples(Fig.1b)include Mg3Sb2-alloys[2,3]and MgAgSb[1,2].

关键词： enable efficient electricity

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How Does Stacking Pressure Affect the Performance of Solid Electrolytes and All-Solid-State Lithium Metal Batteries?

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Energy & Environmental Materials 2024年第4期7卷 93-98页

作者： Junwu Sang Bin Tang Yong Qiu Yongzheng Fang Kecheng Pan Zhen Zhou interdisciplinary Research center for Sustainable Energy Science and Engineering (IRC4SE2) School of Chemical Engineering Zhengzhou University

All-solid-state lithium metal batteries (ASSLMBs) with solid electrolytes (SEs)have emerged as a promising alternative to liquid electrolyte-based Li-ion batteries due to their higher energy density and ***,since ASSLMBs lack the wetting properties of liquid electrolytes,they require stacking pressure to prevent contact loss between electrodes and SEs.

关键词： critical current density solid electrolyte solid-state lithium metal batteries stacking pressure

Close-packed layer spacing as a practical guideline for structure symmetry manipulation of IV-VI/I-V-VI_(2) thermoelectrics

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InfoMat 2024年第2期6卷 99-106页

作者： Tao Jin Long Yang Xinyue Zhang Wen Li Yanzhong Pei interdisciplinary Materials Research center School of Materials Science and EngineeringTongji UniversityShanghaithe People's Republic of China

The crystal-structure symmetry in real space can be inherited in the reciprocal space,making high-symmetry materials the top candidates for thermoelectrics due to their potential for significant electronic band degeneracy.A practical indicator that can quantitatively describe structural changes would help facilitate the advanced thermoelectric material *** face-centered cubic structures,the spatial environment of the same crystallographic plane family is isotropic,such that the distances between the close-packed layers can be derived from the atomic distances within the *** by this,the relationship between inter-and intra-layer geometric information can be used to compare crystal structures with their desired cubic *** close-packed layer spacing was found to be a practical guideline of crystal structure symmetry in IV-VI chalcogenides and I-V-VI_(2) ternary semiconductors,both of which are historically important *** continuous structural evolution toward high symmetry can be described by the layer spacing when temperature or/and composition change,which is demonstrated by a series of pristine and alloyed thermoelectric materials in this *** layerspacing-based guideline provides a quantitative pathway for manipulating crystal structures to improve the electrical and thermal properties of thermoelectric materials.

关键词： phase transition structure manipulation thermoelectric materials x-ray diffraction

High-performance wood-based thermoelectric sponges for thermal energy harvesting and smart buildings

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Nano Research 2024年第6期17卷 5349-5357页

作者： Ding Zhang Qi Li Yanjie Fang Peijia Bai Lili Liu Jiaqi Guo Guangfa Wang Yuetong Zhou Rujun Ma School of Materials Science and Engineering National Institute for Advanced MaterialsSmart Sensing Interdisciplinary Science CenterNankai UniversityTianjin 300350China

The development of renewable woods for power generation can help improve the energy efficiency of buildings,and promote the concept design and implementation of“smart buildings”.Here,with specific chemical treatment and hydrothermal synthesis,we demonstrated the practical value of natural wood for thermoelectric power generation in smart *** prepared wood-based thermoelectric sponges show high Seebeck coefficients of 320.5 and 436.6μV/K in the vertical and parallel directions of the longitudinal channel of *** 500 cycles of the compressive strain at 20%,the corresponding Seebeck coefficients increase up to 413.4 and 502.1μV/K,respectively,which is attributed to the improved contact and connection between tellurium thermoelectric *** Seebeck coefficients are much larger than those of most reported inorganic thermoelectric ***,the thermoelectric sponges maintain excellent thermoelectric and mechanical *** further modeled the application value of wood-based thermoelectric sponges in smart buildings for power *** high thermoelectric electricity can be obtained,such as in Beijing with over 1.5 million kWh every year,demonstrating the great potential in thermal energy harvest and energy supply.

关键词： wood thermoelectric effect thermal energy harvesting smart buildings energy supply

Design and Synthesis of NiO@Co_(3)O_(4)@ZSM-5 Heterogeneous Multitask Hollow Structures for Tandem Catalysis

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Chemical Research in Chinese Universities 2024年第3期40卷 529-535页

作者： Muhammad Waqas interdisciplinary Research center for Refining and Advanced Chemicals King Fahd University of Petroleum&MineralsDhahran 31261Saudi Arabia

Precipitation and impregnation procedures unevenly distribute metals on zeolite,limiting chemical transformation in Lewis-acid,Brönsted-acid and metal-catalyzed tandem ***,heterogeneous multitask transition metals oxides@zeolites are promising catalysts for sustainable processes;nevertheless,synthesis is fascinating and ***,the construction of purposely designed multitask materials segregated in selective shells reveals the remarkable spatial organization of metals-zeolite,resulting in them being suitable for a wide range of tandem *** synthesis of multi-site catalysts begins with a universal wet chemistry approach that yields nickel oxide(NiO)***,the NiO crystals are stabilized using cationic dodecyltrimethylammonium bromide,followed by achieving cross-linking carbon growth by emulsion polymerization of glucose in hydrothermal treatment to yield uniformed NiO@carbon spheres(NiO@CSs).Next,sequential adsorption of cobalt cations and colloidal ZSM-5(1%in H_(2)O,mass fraction),followed by calcination in air,yielded NiO@cobalt oxide@zeolite denoted as NiO@Co_(3)O_(4)@ZEO hollow *** hollowing mechanism and materials segregation within shells are revealed by scanning and transmission electron microscopy,thermogravimetric analysis,and X-ray *** finding advances the rational synthesis of heterogenous core-shell hollow structures for various gas phase catalytic tandem reactions to yield valuable chemicals.

关键词： Multifunctional Core-shell hollow spheres Gas-phase reaction Valuable chemical

The pseudospectrum and spectrum (in)stability of quantum corrected Schwarzschild black hole

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Science China(Physics,Mechanics & Astronomy) 2024年第10期Mechanics & Astronomy) .卷 59-79页

作者： Li-Ming Cao Jia-Ning Chen Liang-Bi Wu Libo Xie Yu-Sen Zhou Peng Huanwu center for Fundamental Theory interdisciplinary center for Theoretical Study and Department of Modern Physics University of Science and Technology of China School of Fundamental Physics and Mathematical Sciences Hangzhou Institute for Advanced StudyUCAS

In this study, we investigate the pseudospectrum and spectrum(in)stability of quantum corrected Schwarzschild black ***, we use the hyperboloidal framework to cast the quasinormal mode(QNM) problem into an eigenvalue problem associated with a non-selfadjoint operator, and then the spectrum and pseudospectrum are depicted. Besides, the invariant subspace method is exploited to improve the computational efficiency for pseudospectrum. The investigation into the spectrum(in)stability entails two main aspects. On the one hand, we calculate the spectra of the quantum corrected black hole, then by the means of the migration ratio, the impact of the quantum correction effect on the Schwarzschild black hole has been *** results indicate that the so-called “migration ratio instability” will occur for small black holes with small angular momentum number l. In the eikonal limit, the migration ratios remain the same for each overtone. On the other hand, we study the spectrum(in)stability of the quantum corrected black hole by directly adding some particular perturbations into the effective potential,where perturbations are located at the event horizon and null infinity, respectively. There are two interesting observations under the same perturbation energy norm. First, perturbations at infinity are more capable of generating spectrum instability than those at the event horizon. Second, we find that the peak distribution can lead to the instability of QNM spectrum more efficiently than the average distribution.

关键词： quasinormal modes pseudospectrum hyperboloidal coordinate

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Q-BioLiP:A Comprehensive Resource for Quaternary Structure-based Protein-ligand Interactions

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Genomics, Proteomics & Bioinformatics 2024年第1期22卷 151-159页

作者： Hong Wei Wenkai Wang Zhenling Peng Jianyi Yang School of Mathematical Sciences Nankai UniversityTianjin 300071China MOE Frontiers Science center for Nonlinear Expectations Research Center for Mathematics and Interdisciplinary SciencesShandong UniversityQingdao 266237China

Since its establishment in 2013,BioLiP has become one of the widely used resources for protein-ligand ***,several known issues occurred with it over the past *** example,the protein-ligand interactions are represented in the form of single chain-based tertiary structures,which may be inappropriate as many interactions involve multiple protein chains(known as quaternary structures).We sought to address these issues,resulting in Q-BioLiP,a comprehensive resource for quaternary structure-based protein-ligand *** major features of Q-BioLiP include:(1)representing protein structures in the form of quaternary structures rather than single chain-based tertiary structures;(2)pairing DNA/RNA chains properly rather than separation;(3)providing both experimental and predicted binding affinities;(4)retaining both biologically relevant and irrelevant interactions to alleviate the wrong justification of ligands’biological relevance;and(5)developing a new quaternary structure-based algorithm for the modelling of protein-ligand complex *** these new features,Q-BioLiP is expected to be a valuable resource for studying biomolecule interactions,including protein-small molecule interaction,protein-metal ion interaction,protein-peptide interaction,protein-protein interaction,protein-DNA/RNA interaction,and RNA-small molecule interaction.Q-BioLiP is freely available at https://***/Q-BioLiP/.

关键词： Protein-ligand interaction Quaternary structure Protein-ligand binding site Protein-protein interaction Binding affinity

The Role of Corticotropin-Releasing Factor Receptor 1 in the Stress-Induced Alteration of Visual Properties in Primary Visual Cortex:Insights from the Single Prolonged Stress Model

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Neuroscience Bulletin 2024年第7期40卷 1012-1016页

作者： Qianhui Xia Xi Kuang Wei Meng Fei Yin Chenchen Ma Yupeng Yang center for Advanced interdisciplinary Science and Biomedicine of IHM Division of Life Sciences and MedicineUniversity of Science and Technology of ChinaHefei 230027China

Dear Editor,Stress initiates a cascade of hormonal and behavioral responses that enable an organism to adapt to new environmental *** unbalanced stress response can lead to dysregulation of the hypothalamic-pituitary-... 详细信息

关键词： Corti Receptor Cortex