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Journal of Energy Chemistry 2025年第1期100卷 215-225页

作者： Jiaye Li Shuang Pan Yihuang Chen Qiong Liu College of Chemistry and Materials Engineering Wenzhou University Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Technology (China) Institute of Analysis Guangdong Academy of Sciences (China National Analytical CenterGuangzhou)

Photocatalytic oxygen reduction for hydrogen peroxide （H2O2） synthesis presents a green and costeffective production ***,achieving highly selective H2O2synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative ***,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H2O2and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride（CNRb）.The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h-1for H2O2generation and photooxidation rate of 3.75 mM h-1for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion （SCC） efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical *** is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product *** study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H2O2coupled with biomass valorization.

关键词： Atomic economy Radical pathway regulation Rubidium atom coordination Biomass valorization

Prediction and optimization of flue pressure in sintering process based on SHAP

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 346-359页

作者： Mingyu Wang Jue Tang Mansheng Chu Quan Shi Zhen Zhang School of Metallurgy Northeastern UniversityShenyang 110819China Liaoning Low-Carbon Steelmaking Technology Engineering research center Northeastern UniversityShenyang 110819China Engineering research center of Frontier Technologies for Low-Carbon Steelmaking(Ministry of Education) Shenyang 110819China

Sinter is the core raw material for blast *** pressure,which is an important state parameter,affects sinter *** this paper,flue pressure prediction and optimization were studied based on the shapley additive explanation(SHAP)to predict the flue pressure and take targeted adjustment ***,the sintering process data were collected and processed.A flue pressure prediction model was then constructed after comparing different feature selection methods and model algorithms using SHAP+extremely random-ized trees(ET).The prediction accuracy of the model within the error range of±0.25 kPa was 92.63%.SHAP analysis was employed to improve the interpretability of the prediction *** effects of various sintering operation parameters on flue pressure,the relation-ship between the numerical range of key operation parameters and flue pressure,the effect of operation parameter combinations on flue pressure,and the prediction process of the flue pressure prediction model on a single sample were analyzed.A flue pressure optimization module was also constructed and analyzed when the prediction satisfied the judgment *** operating parameter combination was then *** flue pressure was increased by 5.87%during the verification process,achieving a good optimization effect.

关键词： sintering process flue pressure shapley additive explanation prediction optimization

Synthesis and Crystal Structure of Diethyl-2,6-dimethyl-3,5-diyl-(1-(2-chlorobenzoyl)-1H- pyrazole-3-diethyl-carboxylate)-pyridine

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Chinese Journal of Structural Chemistry 2008年第10期27卷 1163-1166页

作者：钱群张敏李志芬曹卫国张军邵敏夏义本 Department of Chemistry Shanghai University instrumental analysis and research center Shanghai University School of Materials Science and Engineering Shanghai University

The reaction of hydrazine hydrate with a new α,γ-diketone ester 3, derived from the reaction of 2,6-dimethyl-3,5-diacetyl-pyridine 2 with diethyl oxalate in the presence of sodium ethoxide, afforded the pyrazole derivative 4. Treatment of 4 with 2-chlorobenzoyl chloride gave diethyl 2,6-dimethyl-3,5-diyl-（1-2（chlorobenzoyl）-1H-pyrazole-3-diethyl-carboxylate） pyridine 5. Fine crystal of 5 suitable for XRD analysis was obtained form recrystalization in ethyl acetate. The crystal belongs to the triclinic system, space group P1^-, with a = 1.0342（11）, b = 1.2211（12）, c = 1.5013（15） nm, α = 82.5190（10）,β = 85.7960（10）,γ = 85.3150（10）°, V= 1.8697（3） nm^3, Dc= 1.173 g/cm^3, μ = 0.219 mm^-1, F（000） = 684, Z = 2, the final R = 0.0720 and wR = 0.2211.

关键词： pyridine pyrazole N-acylation crystal structure

Magnetic force microscope study on anisotropic NdFeB permanent magnets

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中国有色金属学会会刊：英文版 2003年第6期13卷 1410-1414页

作者：刘薇蒋建华吴建生李刚 Key Laboratory of State Education Ministry for High Temperature Materials and Testing instrumental analysis center

NdFeB permanent magnets prepared by powder metallurgy were investigated using magnetic force microscopy (MFM). The excellent MFM images of sample along the surfaces parallel and perpendicular to the alignment axis were collected respectively. The results show the necessity of annealing procedure in the preparation of the samples to remove the polishing surface stress and to illustrate the real magnetic domain structure, so that the much information about both the magnetic structure and the topographic microstructure is obtained. The hard MFM tip is verified to be effective for this material especially for the sample with the examined surface parallel to alignment axis. By analyzing these well-captured magnetic force images, magnetic domains and alignment degree as well as the topographic information such as grain size and the nonmagnetic phases at the grain boundaries were demonstrated.

关键词： NdFeB 永磁体永磁材料磁力显微镜各向异性

The emerging role of mesenchymal stem cell-derived extracellular vesicles to ameliorate hippocampal NLRP3 inflammation induced by binge-like ethanol treatment in adolescence

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Neural Regeneration research 2025年第4期20卷 1153-1163页

作者： Susana Mellado María JoséMorillo-Bargues Carla Perpiñá-Clérigues Francisco García-García Victoria Moreno-Manzano Consuelo Guerri María Pascual Department of Physiology School of Medicine and DentistryUniversity of ValenciaValenciaSpain Bioinformatics and Biostatistics Unit Príncipe Felipe Research CenterValenciaSpain Neuronal and Tissue Regeneration Laboratory Príncipe Felipe Research CenterValenciaSpain

Our previous studies have reported that activation of the NLRP3(NOD-,LRR-and pyrin domain-containing protein 3)-inflammasome complex in ethanol-treated astrocytes and chronic alcohol-fed mice could be associated with neuroinflammation and brain *** stem cell-derived extracellular vesicles(MSC-EVs)have been shown to restore the neuroinflammatory response,along with myelin and synaptic structural alterations in the prefrontal cortex,and alleviate cognitive and memory dysfunctions induced by binge-like ethanol treatment in adolescent *** the therapeutic role of the molecules contained in mesenchymal stem cell-derived extracellular vesicles,the present study analyzed whether the administration of mesenchymal stem cell-derived extracellular vesicles isolated from adipose tissue,which inhibited the activation of the NLRP3 inflammasome,was capable of reducing hippocampal neuroinflammation in adolescent mice treated with binge *** demonstrated that the administration of mesenchymal stem cell-derived extracellular vesicles ameliorated the activation of the hippocampal NLRP3 inflammasome complex and other NLRs inflammasomes(e.g.,pyrin domain-containing 1,caspase recruitment domain-containing 4,and absent in melanoma 2,as well as the alterations in inflammatory genes(interleukin-1β,interleukin-18,inducible nitric oxide synthase,nuclear factor-kappa B,monocyte chemoattractant protein-1,and C–X3–C motif chemokine ligand 1)and miRNAs(miR-21a-5p,miR-146a-5p,and miR-141-5p)induced by binge-like ethanol treatment in adolescent *** analysis further revealed the involvement of miR-21a-5p and miR-146a-5p with inflammatory target genes and NOD-like receptor signaling *** together,these findings provide novel evidence of the therapeutic potential of MSC-derived EVs to ameliorate the hippocampal neuroinflammatory response associated with NLRP3 inflammasome activation induced by binge drinking in adolescence.

关键词： adolescence binge-like ethanol treatment extracellular vesicles hippocampus mesenchymal stem cells neuroinflammation NOD-,LRR-and pyrin domain-containing protein 3(NLRP3)

Variation of passivation behavior induced by sputtered energetic particles and thermal annealing for ITO/SiO_x/Si system

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Chinese Physics B 2017年第4期26卷 261-269页

作者：高明杜汇伟杨洁赵磊徐静马忠权 SHU-SOEN's research and Development Laboratory Department of PhysicsShanghai UniversityShanghai 200444China instrumental analysis and research center Shanghai UniversityShanghai 200444China

The damage on the atomic bonding and electronic state in a SiO_x（1.4-2.3 nm）/c-Si（150 μm） interface has been *** occurred in the process of depositing indium tin oxide（ITO） film onto the silicon substrate by magnetron *** observe that this damage is caused by energetic particles produced in the plasma（atoms,ions,and UV light）.The passivation quality and the variation on interface states of the SiO_x/c-Si system were mainly studied by using effective minority carrier lifetime（τ_（eff）） measurement as a potential *** results showed that the samples＇ τ_（eff）was reduced by more than 90%after ITO formation,declined from 107 μs to 5 μ*** vacuum annealing at 200 ℃,the τ_（eff） can be restored to 30 μ*** components of Si to O bonding states at the SiO_x/c-Si interface were analyzed by x-ray photoelectron spectroscopy（XPS） coupled with depth *** amorphous phase of the SiO_x layer and the ＂atomistic interleaving structure＂ at the SiO_x/c-Si interface was observed by a transmission electron microscope（TEM）.The chemical configuration of the Si-O fraction within the intermediate region is the main reason for inducing the variation of Si dangling bonds（or interface states） and effective minority carrier *** an appropriate annealing,the reduction of the Si dangling bonds between SiO_x and near the c-Si surface is helpful to improve the passivation effect.

关键词： sputtered damage SiO_x/c-Si interface effective minority carrier lifetime XPS

Synthesis of morphology-controlled silver nanostructures by electrodeposition

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Nano-Micro Letters 2010年第1期2卷 6-10页

作者： C.L.Liang K.Zhong M.Liu L.Jiang S.K.Liu D.D.Xing H.Y.Li Y.Na W.X.Zhao Y.X.Tong P.Liu instrumental analysis & research center Sun Yat-sen University School of Chemistry and Chemical Engineering Sun Yat-sen University

Nanostructured silver was obtained by potentiostatic *** effects of ionized surfactant(sodium dodecanesulphonate)and the substrate(Cu and Ti)on the morphology of depositions were *** is found that morphologies of silver nanostructures can be simply controlled via change of the *** Ag nanoparticles with narrow size distribution were obtained by electrodeposition in Ag NO3-SDS aqueous solution on copper *** the case of titanium substrate,silver dendrite structures were *** of different morphologies,XRD and TEM results showed that the as-prepared samples belong to face-centered cubic silver structure with good *** formation mechanism of different silver nanostructures was discussed.

关键词： Electrodeposition Silver nanopartilces Silver nano dentrites

STUDY ON SOME BIOLOGICALLY ACTIVE CO-ORDINATION COMPOUNDS OF METAL IONS (Ⅰ)——SYNTHESIS,CHARACTERIZATION,STRUCTURE AND ANTITUMOR ACTIVITY OF COMPLEX OF 3,6-DI-(DIMETHYLAMINO)-DIBENZOPY-RIODONIUM LANTHANUM EDTA

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Science China Chemistry 1989年第8期32卷 918-926页

作者：陈淑英王初华李笃王欣 Department of Chemistry Lanzhou University instrumental analysis and research Centre Lanzhou University

The title coordination compound has been synthesized by the reaction of HLaEDTA·7H_2Owith (CH_3)_2N-?-N(CH_3)_2·HCOO^- in ethanol aqueous solution. Thesingle crystal has grown from aqueous solution and has been characterized by IR, TG-DTA,X-ray powder diffraction, molar conductance, UV and ~1H-NMR. The determination of itscrystal and molecular structure shows that it crystallizes in space group P2_(1/n) with latticeparameters: a = 14.735A, b = 29.335A, c = 16.409A, β = 99.24°, v = 7009.30A^3, z = 4,F(000) = 3488, molecular weight M = 1756.90, D_C = 1.665g/cm^3. It has been refined by thefull matrix least squares method to final discrepancy factor R = 0.096. The anion [La2(EDTA)_2(H_2O)_4]^(2-) turns out to be a dimer, in which each of the twoEDTA^(4-) ions is coordinated to a La^(3+) ion with five of its six coordinating sites and the re-maining sixth one-the oxygen atom of carboxylis bridged to two La^(3+) ions, thus forming aparallelogrammic four-membered ring La_2O_2. The nine coordinations about each metal arecompleted by two water molecules. The average bond length is 2.560A for La-O and 2.833Afor La-N. Approximately, the dimer belongs to point group Ci with the centre of inversionat the centre of La_2O_2 parallelogram. The antitumor activity of the coordination compound was studied by observing its effecton the incorporation of ~3H-TdR into DNA of leukemia (L7712) cells in vitro. The degree ofinhibition reached 83.9% after exposing 2×10~5 cells per millilitre to 4×10^(-5) mol/L of thecompound for 24 h, being higher than those of its precursors.

关键词： coordination compounds metal ions

Effect of Ball Milling Time on Microstructure and Hydrogen Storage Properties of Nd_(5)Mg_(41)Ni Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1201-1214页

作者： Zeming Yuan Chenxu Liu Xiaoming Li Yongqi Sui Zhonggang Han Tingting Zhai Dianchen Feng Yanghuan Zhang instrumental analysis center Inner Mongolia University of Science and TechnologyBaotou014010China Department of Functional Material research Central Iron and Steel Research InstituteBeijing100081China

Mg-based alloys must be dehydrogenated at high pressure and temperatures, limiting their practical application. In this paper, Nd_(5)Mg_(41)Ni alloy was prepared by vacuum melting, and the as-cast alloy was ball milled for 5 h, 10 h, 15 h, and 20 h. The effect of ball milling time on the microstructure and hydrogen storage properties of the alloy was systematically studied. The alloy comprises Nd_(5)Mg_(41), NdMg_(12), NdMg_(3), and Mg_(2)Ni phases. The Nd_(5)Mg_(41)Ni alloy milling for 10 h can reach 95% of the saturated hydrogen absorption at 553 K by 40 s, and the alloy can desorb hydrogen only by 20 min. The dehydrogenation activation energy is only 99.9 kJ/mol H_(2). Ball milling makes the alloy produce many nanocrystalline and amorphous structures. The nano-grain boundary provides a channel for the diffusion of hydrogen atoms, and the high energy at the grain boundary provides energy for the phase deformation nucleus. Ball milling leads to the refinement of alloy particles and shortens the diffusion distance of hydrogen atoms to the interior of alloy particles. Defects such as twins and dislocations generated by milling provide energy for the phase deformation nucleus during the hydrogen absorption and desorption.

关键词： Hydrogen storage materials Magnesium-base alloy Ball milling Nanocrystal Kinetics

Microstructure and Magnetic Properties of Nd_(8.5)Fe_(77.1)B_(6.4)Co_4Zr_3Nb_(0.5)V_(0.5) Ribbons

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Journal of Rare Earths 2007年第S1期25卷 218-220页

作者：王占勇刘文庆周邦新倪健森徐晖王现英金鸣林 Department of Materials Engineering Shanghai Institute of Technology instrumental analysis and research center Shanghai University Institute of Materials Shanghai University

Microstructure and magnetic properties of Nd8.5Fe77.1B6.4Co4Zr3Nb0.5V0.5 nanocomposite ribbons were investigated. A fine and uniform grain with 30 nm in average size was achieved for the ribbons annealed at 710 ℃ for 4 min, which enhanced the interaction coupling between grains and improved the magnetic properties. The results of three-dimensional atom probe (3DAP) revealed that V-enriched intergranular phase existed at the grain boundaries, suppressing the grain growth during crystallization process. The remanence and coercivity for annealed ribbons reached to 80 emu·g-1 and 567 kA·m-1, respectively.

关键词： Nd_2Fe_(14)B/α-Fe nanocomposite magnet 3DAP magnetic properties rare earths