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Transformation of leather waste into microwave-activated and N-doped carbon for Li-S batteries

新型炭材料(中英文) 2025年

作者： Carolina Pano-Azucena Roberto Rosas-Rangel Miguel Olvera-Sosa David Salvador González-González Rene Rangel-Mendez Luis Felipe Chazaro-Ruiz Miguel Avalos-Borja Javier Antonio Arcibar-Orozco CIATEC.Center for Applied Innovation in Competitive Technologies tecnologico de Monterrey School of Engineering and Sciences instituto Potosino de Investigación Científica y Tecnológica Universidad Autónoma de Coahuila Facultad de SistemasCiudad Universitaria

The use of carbon from waste biomass has the potential to buffer the drawbacks of Li-S batteries and improve their overall performance. Chrome-Tanned-LeatherShavings(CTLS) are undesirable wastes, highly available for transformation into porous carbon. Microwave activation is an efficient state-of-the-art procedure to obtain unique porous structures and nitrogen incorporation can improve the performance of porous carbons. This study proposes the transformation of CTLS into a microwave activated porous carbon, and then was modified to introduce nitrogen. A microporous activated carbon with a specific surface area of 556 m2g-1 with honeycomb-like structure was obtained. Both urea thermal decomposition and ethanolamine impregnation improves the nitrogen and amine presence of surface groups. However,the results indicated that only urea treatment was effective in improving the initial capacity of the cell(1363 mAhg-1), which is probably linked with the sorption of long-chain polysulfides. This investigation confirms that it is possible to obtain carbon materials from CTLS, for use as sulfur-host cathodes in Li-S batteries, and improve their performance with urea thermal decomposition. Furthermore, a Radial basis function neural network was fitted to provide statistical support to the experimental results. The trained model corroborated the importance of nitrogen content of the carbons in the discharge capacity of the cells.

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Cadmium sorption by sodium and thiourea-modified zeolite-rich tuffs

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Journal of Environmental Sciences 2017年第2期29卷 39-48页

作者： Perfecto Barragán P M.Guadalupe Macedo M Maria T.Olguín instituto tecnologico de toluca Laboratorio de Investigacion en Ingenieria Ambiental.Av.Tecnologico S/NColonia Ex-Rancho La VirgenMetepecEstado de Meico CP.52140Mexico instituto National de Investigaciones Nucleares Departamento de QuimicaA.P.18-1027Col.EseandonDelegacion Miguel Hidalgo C.P.11801Mexico

In the present investigation, two zeolite-rich tuffs from Guaymas and El Cajon（State of Sonora）, which were conditioned with a sodium chloride solution and subsequently modified with a thiourea solution, were chosen to evaluate the removal of Cd from aqueous systems. The zeolitic materials were characterized by scanning electron microscopy and X-ray diffraction. The surface area was also determined. The experiments were performed in a batch system, and the influences of p H, contact time between phases, and the concentration of Cd in the solution on the adsorption by sodium or thiourea-modified zeolite-rich tuff were investigated. It was found that the efficiency of Cd ion removal from aqueous solutions is influenced by the p H of the aqueous systems. The Cd adsorption kinetic data were well fitted to a pseudo-second-order model in all cases. The Langmuir and Langmuir–Freundlich isotherms adequately described the Cd sorption behavior by the zeolite from El Cajon pretreated with Na Cl and the zeolite from Guaymas modified with thiourea, respectively.

关键词： Cadmium Zeolite-rich-tuff Sorption Kinetics Isotherms

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Analysis and optimization of sustainable machining of AISI O1 tool steel by the wire-EDM process

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Advances in Manufacturing 2021年第2期9卷 304-317页

作者： Carmita Camposeco-Negrete School of Engineering and Science Tecnologico de MonterreyEduardo Monroy Cárdenas 200050110 TolucaEstado de MéxicoMexico

Wire electrical discharge machining(wire-EDM)is an energy-intensive process,and its success relies on a correct selection of cutting *** is vital to optimize energy consumption,along with productivity and *** experimental study optimized three parameters in wire-EDM:pulse-on time,servo voltage,and voltage concerning machining time,electric power,total energy consumption,surface roughness,and material removal *** different plate thicknesses(15.88 mm and 25.4 mm)were *** orthogonal array,signal-to-noise ratio,and means graphs,and an analysis of vari-ance(ANOVA),determine the effects and contribution of cutting parameters on ***-on time is the most significant factor for almost all variables,with a percentage of contribution higher than 50%.Multi-objective optimization is conducted to accomplish a concurrent decrease in all variables.A case study is proposed to compute carbon dioxide(CO_(2))tons and electricity cost in wire-EDM,using cutting parameters from multi-objective optimization and starting values commonly employed to cut that tool steel.A sustainable manufacturing approach reduced 5.91%of the electricity cost and CO_(2)tons when machining the thin plate,and these responses were diminished by 14.09%for the thicker ***,it is possible to enhance the sustainability of the process without decreasing its productivity and quality.

关键词： Wire electrical discharge machining(wire-EDM) Optimization Taguchi desirability analysis Sustainability

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CLT Fabricated with Gmelina arborea and Tectona grandis Wood from Fast-Growth Forest Plantations: Physical and Mechanical Properties

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Journal of Renewable Materials 2022年第1期10卷 1-17页

作者： Freddy Munoz Carolina Tenorio Roger Moya Angel Navarro-Mora Escuela de Ingenieria Forestal Instituto Tecnologico de Costa RicaCartago159-7050Costa Rica Escuela de Ingenieria en Construccion Instituto Tecnologico de Costa RicaCartago159-7050Costa Rica

Fabrication and use of Cross Laminated Timber(CLT)using tropical woods is still limited at *** objective of the present study aims to determine the possibility of using CLT panels of 3 and 5 layers,fabricated withTectona grandis and Gmelina arborea wood using adhesive of isocyanate polymer emulsion system catalyzed with polymeric ***,water absorption,density,flexure test,compression and glue-line shear were evaluated using ANSI/APA PRG320-2012 ASTM D198 and ASTM D4761 *** results showed that CLT panels of *** presented higher values of density,less water absorption and lower delamination,with no evident differences between the CLT of 3 and 5 *** high density of *** resulted in higher values of the mechanical *** flatwise and edgewise flexure tests in 5-layer CLT panels of both species pre-sented higher values of bending stiffness compared to those of 3-layer CLT *** the bending stress values in 3-layer CLT panels were higher than for 5-layer CLT *** for shear stress in bending flatwise,in both species,3-layer CLT surpassed 5-layer CLT panels,but in the edgewise test no differences were *** MOE and Fc in the compression test were superior in relation to the edgewise *** and Fc in compres-sion flatwise in 3-layer CLT was greater than in 5-layer CLT in both species,but edgewise these values were higher in 5-layer CLT *** most common failures were stress and delamination in the flexure test,whereas in the compression test these were:shearing,splitting and *** the glue-line shear test no differences were observed between CLT panels of 3 and 5 layers for both species.

关键词： Structural elements sustainable material building material tropical wood wood of plantation

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Ethyl Methanesulfonate as Inductor of Somaclonal Variants in Different Crops

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Phyton-International Journal of Experimental Botany 2020年第4期89卷 835-850页

作者： Jose Gregorio Joya-Davila F.A.Gutierrez-Miceli Plant Biotechnology Laboratory Tecnologico Nacional de MexicoInstituto Tecnologico de Tuxtla GutierrezTuxtla Gutierrez29050Mexico

Ethyl methanesulfonate is a chemical mutagen,which is currently being used in plant breeding,to increase genetic variability in genes of agronomic interest,of species useful in *** primarily causes single base point mutations by inducing guanine alkylation,resulting in GC to AT *** effect is different between clones of a genotype and between genotypes of the same *** review presents the results obtained in recent research,where its effect on plant tissues,callus,and cells in suspension has been *** in the phenotypic expression of somaclonal variants were reported,involving morphology,production of secondary metabolites,changes in metabolic routes of resistance,tolerance to stress,increased seed yield,among *** addition,this review compiles the doses and guidelines to consider before using this mutagen,which can serve as a guide for future trials in deciding the response variables,the type of plant explants and the selection of the study *** lines have allowed plant breeders to have a collection of plants with different characteristics,in places where the cultivar does not have its center of *** is important to note that it is still necessary to continue evaluating the heritability of mutations and their behaviour in the environment where they will be established,in order to obtain new varieties of plants that can be cultivated with uniformity in their genetic response.

关键词： Geneticvariability plantbreeding pointmutation guaninealkylation chemical mutagen

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Geodesic Vulnerability Approach for Identification of Critical Buses in Power Systems

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Journal of Modern Power Systems and Clean Energy 2021年第1期9卷 37-45页

作者： Jesus Beyza Eduardo Garcia-Paricio Hector F.Ruiz Jose M.Yusta instituto tecnologico de Morelia Avenida Tecnologico 1500Lomas de Santiaguito58120Mexico the department of Electrical Engineering University of ZaragozaC/Maria de Luna 350018Spain

One of the most critical issues in the evaluation of power systems is the identification of critical buses. For this purpose, this paper proposes a new methodology that evaluates the substitution of the power flow technique by the geodesic vulnerability index to identify critical nodes in power *** methods are applied comparatively to demonstrate the scope of the proposed approach. The applicability of the methodology is illustrated using the IEEE 118-bus test system as a case study. To identify the critical components, a node is initially disconnected, and the performance of the resulting topology is evaluated in the face of simulations for multiple cascading faults. Cascading events are simulated by randomly removing assets on a system that continually changes its structure with the elimination of each component. Thus, the classification of the critical nodes is determined by evaluating the resulting performance of 118 different topologies and calculating the damaged area for each of the disintegration curves of cascading failures. In summary, the feasibility and suitability of complex network theory are justified to identify critical nodes in power systems.

关键词： Power system critical node complex network theory cascading failure load flow

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Tribological performance of uncoated and TiCN-coated D2,M2 and M4 steels under lubricated condition

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Journal of Iron and Steel Research International 2017年第8期24卷 823-829页

作者： Luis Daniel Aguilera Camacho Santos García Miranda Karla Judith Moreno instituto tecnologico de Celaya/TNM Apartado Postal 5738010-CelayaGuanajuatoMexico

Hard coatings are used to improve the wear resistance of metals which largely depends on adhesion between substrate and *** wear and friction behavior of uncoated and TiCN-coated D2,M2 and M4 steels were evaluated by apin-on-disk test under lubricated *** order to evaluate the influence of lubricant on wear performance,dry friction tests were also *** results showed that friction coefficients were very similar for both uncoated and TiCN-coated *** lubricated conditions,the uncoated D2 tool steel exhibited the lowest friction coefficient,but the TiCN-coated D2 steel presented the smallest wear *** was the main wear mechanism in all the ***,microhardness measurements were carried out,finding an influence of the steel substrate on the hardness of the ***,adhesion test was conducted,suggesting agood adhesion of class 1 between substrates and TiCN coatings.

关键词： D2 tool steel M2 high speed steel M4 high speed steel TiCN coating Friction Wear

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Non-linear modeling of kinetic and equilibrium data for the adsorption of hexavalent chromium by carbon nanomaterials:Dimension and functionalization

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Chinese Journal of Chemical Engineering 2019年第4期27卷 912-919页

作者： Miguel de la Luz-Asunción Eduardo E.Pérez-Ramírez Ana L.Martínez-Hernández Victor M.Castano Víctor Sánchez-Mendieta Carlos Velasco-Santos Facultad de Quimica Universidad Autonoma del Estado de Mexico Km. 12 de la carretera Toluca-Atlacomulco C.P. 50200 San Cayetano Toluca Estado de Mexico Mexico tecnologico Nacional de Mexico-instituto tecnologico de Queretaro Division de Estudios de Posgrado e Investigacion Av. Tecnologico s/n esq. GraL Mariano Escobedo Col. Centro Historico C.P. 76000 Santiago de Queretaro Queretaro Mexico Centro de Fisica Aplicada y Tecnologia Avanzada Universidad Nacional Autonoma de Mexico Boulevard Juriquilla 3001 Queretaro 76230 Mexico

The adsorption capacities for the removal of hexavalent chromium from aqueous solutions by six carbon nanomaterials have been evaluated. Single-walled and multi-walled carbon nanotubes as received and after oxidation treatment, graphene oxide and reduced graphene oxide are the materials with different dimension and functionalization compared in this research. Carbon nanotubes have been modified using hydrogen peroxide as oxidizing agent under microwave radiation. The oxidation treatment on carbon nanotubes has a positive effect increasing the adsorbent–adsorbate interaction. Rate-controlling mechanisms and equilibrium data are analyzed using non-linear models. Non-linear method is proposed as the most suitable method for determining the kinetic and equilibrium parameters. The values of adsorption energy(E) obtained from the Dubinin–Radushkevich isotherm,have been found around 0.371 and 0.870 k J·mol-1, indicating physical adsorption. Therefore, the pseudo-second order model represents better the kinetic experimental data. The results show that the Langmuir isotherm provides a slightly better fit to the experimental data compared with the Freundlich isotherm, indicating homogeneous distribution of active sites on carbon nanomaterials and monolayer adsorption. The separation factors RLare found in the range of 0–1, suggesting that the adsorption process is suitable for all adsorbents. The mechanisms for hexavalent chromium removal have been proposed as electrostatic interactions and hydrogen bonding.

关键词： Carbon nanotubes Graphene Adsorption Hexavalent chromium Kinetic

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Non-thermal plasma for exhaust gases treatment

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Frontiers of Mechanical Engineering 2015年第3期10卷 301-305页

作者： Elvia ALVA R. Marquidia PACHECO P.l Fernando GOMEZ B. Joel PACHECO P. Arturo COLIN C Victor SANCHEZ-MENDIETA Ricardo VALDIVIA B Alfredo SANTANA D. Jose HUERTAS C Hilda FRIAS P. instituto Nacional de Investigaciones Nucleates Ocoyoacac 52750Mexico Universidad Autonoma del Estado de Mexico Toluca 50000 Mexico instituto tecnologico y de Estudios Superiores de Monterrey CampusToluca 50110 Mexico

This article describes a study on a non-thermal plasma device to treat exhaust gases in an internal combustion engine. Several tests using a plasma device to treat exhaust gases are conducted on a Honda GX200- 196 cm3 engine at different rotational speeds. A plasma reactor could be efficient in degrading nitrogen oxides and particulate matter. Monoxide and carbon dioxide treatment is minimal. However, achieving 1%-3% degradation may be interesting to reduce the emission of greenhouse gases.

关键词： plasma treatment NOx CO CO2 particulatematter vehicle

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Thorough Validation of a Rotor Fault Diagnosis Methodology in Laboratory and Field Soft-Started Induction Motors

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Chinese Journal of Electrical Engineering 2018年第3期4卷 66-72页

作者： Jesus A.Corral-Hernandez Jose A.Antonino-Daviu instituto tecnologico de la Energia Universitat Politecnica de ValenciaValencia 46022Spain

Induction motors are the most widespread rotating electrical machines in *** maintenance of the motors is of crucial importance due to the fact that unexpected faults in those machines can lead to huge economic losses for the corresponding *** recent years,there is an increasing use of industrial induction motors operated by different types of drives,which have different *** them,the use of soft-starters has proliferated due to the inherent benefits provided by these drives:they damp the high starting currents,enabling the soft startup of the motors and avoiding undesirable commutation transients introduced by other starting *** spite of these advantages,they do not avoid the possible occurrence of rotor damages,one of the most common faults in this type of *** works have proposed predictive maintenance techniques that are aimed to diagnose the rotor condition in soft-started machines and even fewer have demonstrated the validity of their methods in real *** work presents,for the first time,the massive validation of a rotor fault diagnosis methodology in soft-started induction *** and laboratory and induction motors started under different types of soft-starters and with diverse rotor fault conditions are considered in the *** results prove the potential of the approach for the reliable assessment of the rotor condition in such machines.

关键词： Induction motors soft-starter fault diagnosis transient analysis rotor reliability fault detection wavelet

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