检索结果-南通市图书馆

Peroxidase-like nanozyme based microenvironment-responsive injectable hydrogel for bacteria-infected wound healing

在线全文

学校读者我要写书评

暂无评论

science China Technological sciences 2024年第10期67卷 3247-3260页

作者： ZHOU Wei LI XiaNan TANG MengCheng PAN LingFeng WANG BeiBei ZHANG Hao ZHANG Han WANG ShiBo KONG XiangDong institute of Smart Biomaterial Materials School of Materials Science and EngineeringZhejiang University of Science & Technology Zhejiang-Mauritius Joint Research Center for Biomaterials and Tissue engineering Zhejiang University of Science & Technology

Hydrogel stands out as one of the most attractive wound dressings due to its excellent moisturizing properties and capacity to absorb wound exudates. However, conventional hydrogel dressings often lack responsiveness to the microenvironment, merely acting as protective barriers for the wound. Consequently, they exhibit limited effectiveness in preventing infection and facilitating wound repair. To address these problems, we have developed a multifunctional injectable hydrogel, CF/MS@HG, based on peroxidase-like nanozymes, aiming at rapidly healing bacterial-infected wounds. The hydrogel is mainly composed of oxidized sodium alginate, aminated gelatin, and polylysine, encapsulating MIL-101(CuFe) NPs(CF) and manganese selenide nanoparticles(MnSe2NPs, or MS NPs). After injection, the complex rapidly gelatinizes at the infected wound site through a Schiff base reaction. In vitro experiments have demonstrated the hydrogel's strong adhesion and self-healing ***, CF exhibiting peroxidase(POD)-like activity, catalyzes in situ hydrogen peroxide(H2O2) to generate highly toxic hydroxyl radicals(·OH) within the wound microenvironment, inducing oxidative damage to bacteria. Meanwhile, MS decomposes into H2Se in the slightly acidic wound microenvironment, disrupting bacterial metabolism and inhibiting *** addition of polylysine further enhances the hydrogel's antibacterial properties. In vivo experiments have shown that the hydrogel exhibits excellent biological safety and significantly promotes wound healing. This multifunctional smart hydrogel holds great promise for the treatment of bacterial-infected wounds.

关键词： peroxidase-like nanozyme manganese selenide injectable hydrogel bacterial infection wound healing

A post-modification strategy to precisely construct dual-atom sites for oxygen reduction electrocatalysis

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第3期90卷 511-517,I0012页

作者： Juan Wang Xinyan Liu Chang-Xin Zhao Yun-Wei Song Jia-Ning Liu Xi-Yao Li Chen-Xi Bi Xin Wan Jianglan Shui Hong-Jie Peng Bo-Quan Li Jia-Qi Huang School of Materials science and engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research institute of Multidisciplinary science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction engineering and technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China institute of Fundamental and Frontier sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Materials science and engineering Beihang UniversityBeijing 100191China

Dual-atom catalysts(DACs) afford promising potential for oxygen reduction electrocatalysis due to their high atomic efficiency and high intrinsic ***,precise construction of dual-atom sites remains a *** this work,a post-modification strategy is proposed to precisely fabricate DACs for oxygen reduction ***,a secondary metal precursor is introduced to the primary single-atom sites to introduce direct metal-metal interaction,which ensures the formation of desired atom pair structure during the subsequent pyrolysis process and allows for successful construction of *** as-prepared FeCo-NC DAC exhibits superior oxygen reduction electrocatalytic activity with a half-wave potential of 0,91 V *** hydrogen ***-air batteries equipped with the FeCo-NC DAC demonstrate higher peak power density than those with the Pt/C *** importantly,this post-modification strategy is demonstrated universal to achieve a variety of dual-atom *** work presents an effective synthesis methodology for precise construction of catalytic materials and propels their applications in energy-related devices.

关键词： Dual-atom catalysts Electrocatalysis Oxygen reduction reaction Post-modification Zinc–air batteries

Low-Volatile Binder Enables Thermal Shock-Resistant Thin-Film Cathodes for Thermal Batteries

在线全文

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第4期7卷 126-134页

作者： Yong Xie Yong Cao Xu Zhang Liangping Dong Xiaojiang Liu Yixiu Cui Chao Wang Yanhua Cui Xuyong Feng Hongfa Xiang Long Qie Laboratory of Electrochemical Power Sources Institute of Electronic Engineering China Academy of Engineering Physics School of Materials science and engineering Hefei University of Technology State Key Laboratory of Material Processing and Die & Mold technology School of Materials Science and Engineering Huazhong University of Science and Technology

Manufacturing thin-film components is crucial for achieving high-efficiency and high-power thermal batteries (TBs).However,developing binders with low-gas production at the operating temperature range of TBs (400-550℃)has proven to be a significant ***,we report the use of acrylic acid derivative terpolymer (LA136D) as a low-volatile binder for thin-film cathode fabrication and studied the chain scission and chemical bondbreaking mechanisms in pyrolysis.

关键词： gas production high-power low-volatile binder thermal battery thin-film cathode

A new fluorocarbon adhesive:Inhibiting agglomeration during combustion of propellant via efficient F-Al_(2)O_(3) preignition reaction

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Carbon Energy 2024年第6期6卷 292-305页

作者： Qifa Yao Min Xia Chao Wang Fanzhi Yang Wei Yang Yunjun Luo School of Materials science and engineering Beijing Institute of TechnologyBeijingChina Key Laboratory of High Energy Density Materials Ministry of EducationBeijing Institute of TechnologyBeijingChina School of Aerospace engineering Beijing Institute of TechnologyBeijingChina Advanced Research institute of Multidisciplinary science Beijing Institute of TechnologyBeijingChina

Inhibiting the agglomeration of molten aluminum particles packed in the binder network is a promising scheme to achieve efficient combustion of solid *** this investigation,the hydroxyl-terminated structured fluorinated alcohol compound(PFD)was introduced to modify the traditional polyethylene glycol/polytetrahydrofuran block copolymerization(HTPE)binder;that is,a unique fluorinated polyether(FTPE)binder was synthesized by embedding fluorinated organic segments into the HTPE binder via crosslinking *** FTPE was applied in aluminum-based propellants for the first *** to the complete release of fluorinated organic active segments in the range of 300℃to 400℃,the burning rate of FTPEbased propellant increased from 4.07(0%PFD)to 6.36 mm/s(5%PFD),increased by 56.27%under 1 *** reaction heat of FTPE propellants increased from 5.95(0%PFD)to 7.18 MJ/kg(5%PFD)under 3.0 MPa,indicating that HTPE binder modified with PFD would be conducive to inhibiting the D90 of condensed combustion products(CCPs)dropped by 81.84%from 75.46(0%PFD)to 13.71μm(5%PFD)under 3.0 MPa,in consistent with the significant reduction of aluminum agglomerates observed on the quenched burning surface of the *** results demonstrated that a novel FTPE binder with PFD can release fluorinated organic active segments,which motivate preignition reaction with the alumina shell in the early stage of aluminum combustion,and then enhance the melting diffusion effect of aluminum to inhibit the agglomeration.

关键词： agglomeration characteristics aluminum particles combustion fluorine alcohol compounds HTPE propellants

A Single-Layer Piezoelectric Composite Separator for Durable Operation of Li Metal Anode at High Rates

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第1期7卷 265-274页

作者： Yuanpeng Ji Botao Yuan Jiawei Zhang Zhezhi Liu Shijie Zhong Jipeng Liu Yuanpeng Liu Mengqiu Yang Changguo Wang Chunhui Yang Jiecai Han Weidong He National Key Laboratory of science and technology on Advanced Composites in Special Environments and Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080China MIIT Key Laboratory of Critical Materials technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150080China School of Petroleum engineering Chongqing University of Science and TechnologyChongqing 401331China State Key Laboratory of urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150080China Chongqing Research institute Harbin Institute of TechnologyChongqing 401151China School of Mechanical engineering Chengdu UniversityChengdu 610106China

Piezoelectric ceramic and polymeric separators have been proposed to effectively regulate Li deposition and suppress dendrite growth,but such separators still fail to satisfactorily support durable operation of lithium metal batteries owing to the fragile ceramic layer or low-piezoelectricity polymer as ***,by combining PVDF-HFP and ferroelectric BaTiO_(3),we develop a homogeneous,single-layer composite separator with strong piezoelectric effects to inhibit dendrite growth while maintaining high mechanical *** squeezed by local protrusion,the polarized PVDF-HFP/BaTiO_(3)composite separator generates a local voltage to suppress the local-intensified electric field and further deconcentrate regional lithium-ion flux to retard lithium deposition on the protrusion,hence enabling a smoother and more compact lithium deposition morphology than the unpoled composite separator and the pure PVDF-HFP separator,especially at high ***,the homogeneous incorporation of BaTiO_(3)highly improves the piezoelectric performances of the separator with residual polarization of 0.086 pC cm^(-2)after polarization treatment,four times that of the pure PVDF-HFP separator,and simultaneously increases the transference number of lithium-ion from 0.45 to *** from the prominent piezoelectric mechanism,the polarized PVDF-HFP/BaTiO_(3)composite separator enables stable cyclic performances of Li||LiFePO_(4)cells for 400 cycles at 2 C(1 C=170 mA g^(-1))with a capacity retention above 99%,and for 600 cycles at 5 C with a capacity retention over 85%.

关键词： composite separator Li metal anodes piezoelectric materials PVDF-HFP uniform Li deposition

Fe-Induced Electronic Transfer and Structural Evolution of Lotus Pod-Like CoNiFePx@P,N-C Heterostructure for Sustainable Oxygen Evolution

在线全文

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第3期7卷 186-193页

作者： Xiaojun Zeng Qingqing Zhang Chulong Jin Hui Huang Yanfeng Gao Advanced Ceramic Materials Research institute School of Materials Science and EngineeringJingdezhen Ceramic University Singapore institute of technology School of Materials science and engineering Shanghai University

Transition metal phosphides with metallic properties are a promising candidate for electrocatalytic water oxidation,and developing highly active and stable metal phosphide-based oxygen evolution reaction catalysts is still ***,we present a facile ion exchange and phosphating processes to transform intestine-like CoNiPx@P,N-C into lotus pod-like CoNiFePx@P,N-C heterostructure in which numerous P,N-codoped carboncoated CoNiFePxnanoparticles tightly anchors on the 2D carbon ***,the as-prepared CoNiFePx@P,N-C enables a core-shell structure,high specific surface area,and hierarchical pore structure,which present abundant heterointerfaces and fully exposed active ***,the incorporation of Fe can also induce electron transfer in CoNiPx@P,IM-C,thereby promoting the oxygen evolution ***,CoNiFePx@P,IM-C delivers a low overpotential of 278 mV （vs RHE） at a current density of10 mA cm-1and inherits excellent long-term stability with no observable current density decay after 30 h of chronoamperometry *** work not only highlights heteroatom induction to tune the electronic structure but also provides a facile approach for developing advanced and stable oxygen evolution reaction electrocatalysts with abundant heterointerfaces.

关键词： electronic transfer Fe exchange multi-metal phosphides OER electrocatalysts structural evolution

Deep Guided Attention Network for Joint Denoising and Demosaicing in Real Image

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Electronics 2024年第1期33卷 303-312页

作者： Tao ZHANG Ying FU Jun ZHANG School of Computer science and technology Beijing Institute of Technology Advanced Reasearch institute of Multidisciplinary science Beijing Institute of Technology

Denoising(DN) and demosaicing(DM) are the first crucial stages in the image signal processing pipeline. Recently, researches pay more attention to solve DN and DM in a joint manner, which is an extremely undetermined inverse problem. Existing deep learning methods learn the desired prior on synthetic dataset, which limits the generalization of learned network to the real world data. Moreover, existing methods mainly focus on the raw data property of high green information sampling rate for DM, but occasionally exploit the high intensity and signalto-noise(SNR) of green channel. In this work, a deep guided attention network(DGAN) is presented for real image joint DN and DM(JDD), which considers both high SNR and high sampling rate of green information for DN and DM, respectively. To ease the training and fully exploit the data property of green channel, we first train DN and DM sub-networks sequentially and then learn them jointly, which can alleviate the error accumulation. Besides, in order to support the real image JDD, we collect paired raw clean RGB and noisy mosaic images to conduct a realistic dataset. The experimental results on real JDD dataset show the presented approach performs better than the state-of-the-art methods, in terms of both quantitative metrics and qualitative visualization.

关键词： Training Visualization Inverse problems Green products Noise reduction Pipelines Signal processing

A porous Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) light color adjustable phosphor:Luminescent property and application of warm white LED

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第8期42卷 1421-1428,I0001页

作者： Yunxiao Ma Chao Linghu Ming Yang Hui Yu Xiangting Dong Long Xia School of Chemistry and Environmental engineering Changchun University of Science and TechnologyChangchun130022China School of Materials science and engineering Harbin Institute of Technology(Weihai)Weihai264209China

Light emitting diode(LED) is the fourth generation lighting source,but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time *** this study,a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO_(2)/ZnZrO_(3)(Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3))phosphor with warm white light emission properties was prepared,and the warm white light LED(wWLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) phosphors together with 270 nm *** ZrO_(2)/ZnZrO_(3),Tb-SSA/ZrO_(2)/ZnZrO_(3) and Eu-PTA/ZrO_(2)/ZnZrO_(3) samples show blue emission,green emission and red emission under deep ultraviolet(UV,270 nm) excitation,*** Tb-SSA and Eu-PTA are co-doped into ZrO_(2)/ZnZrO_(3) matrix with blue emission to achieve the warm white light emission,and the light color can be adjusted by controlling the doping amount of Eu^(3+)-and Tb^(3+).Through the excitation method of single-component phosphor by the single chip,the complex chip packaging process of w-LED can be *** doping rare earth organic complexes into porous ZrO_(2)/ZnZrO_(3) matrix,the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.

关键词： Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) Luminescence material Light color adjustable phosphor Warm white emission W-WLEDs Rare earths

Autonomous multi-drone racing method based on deep reinforcement learning

在线全文

学校读者我要写书评

暂无评论

science China(Information sciences) 2024年第8期67卷 35-48页

作者： Yu KANG Jian DI Ming LI Yunbo ZHAO Yuhui WANG Department of Automation University of Science and Technology of China institute of Advanced technology University of Science and Technology of China institute of Artificial Intelligence Hefei Comprehensive National Science Center College of Automation engineering Nanjing University of Aeronautics and Astronautics

Racing drones have attracted increasing attention due to their remarkable high speed and excellent maneuverability. However, autonomous multi-drone racing is quite difficult since it requires quick and agile flight in intricate surroundings and rich drone interaction. To address these issues, we propose a novel autonomous multi-drone racing method based on deep reinforcement learning. A new set of reward functions is proposed to make racing drones learn the racing skills of human experts. Unlike previous methods that required global information about tracks and track boundary constraints, the proposed method requires only limited localized track information within the range of its own onboard sensors. Further, the dynamic response characteristics of racing drones are incorporated into the training environment, so that the proposed method is more in line with the requirements of real drone racing scenarios. In addition, our method has a low computational cost and can meet the requirements of real-time racing. Finally, the effectiveness and superiority of the proposed method are verified by extensive comparison with the state-of-the-art methods in a series of simulations and real-world experiments.

关键词： racing drone autonomous multi-drone racing sim-to-real deep reinforcement learning Markov game