检索结果-南通市图书馆

Application of Optical Hydrogels in Environmental Sensing

在线全文

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第3期7卷 311-336页

作者： Shuo Yang Shruti Sarkar Xing Xie Dan Li Jianmin Chen Shanghai Key Laboratory of Atmospheric particle Pollution and Prevention(LAP3) Department of Environmental Science and EngineeringFudan UniversityShanghai 200438China School of Civil and Environmental engineering Georgia Institute of TechnologyAtlanta Georgia 30332USA

The ever-increasing complexity of environmental pollutants urgently warrants the development of new detection *** based on the optical properties of hydrogels enabling fast and easy in situ detection are attracting increasing *** this paper,the data from 138 papers about different optical hydrogels(OHs)are extracted for statistical *** detection performance and potential of various types of OHs in different environmental pollutant detection scenarios were evaluated and compared to those obtained using the standard detection *** on this analysis,the target recognition and sensing mechanisms of two main types of OHs are reviewed and discussed:photonic crystal hydrogels(PCHs)and fluorescent hydrogels(FHs).For PCHs,the environmental stimulus response,target receptors,inverse opal structures,and molecular imprinting techniques related to PCHs are reviewed and ***,the different types of fluorophores(i.e.,compound probes,biomacromolecules,quantum dots,and luminescent microbes)of FHs are ***,the potential academic research directions to address the challenges of applying and developing OHs in environmental sensing are proposed,including the fusion of various OHs,introduction of the latest technologies in various fields to the construction of OHs,and development of multifunctional sensor arrays.

关键词： environmental sensors fluorescent hydrogel optical hydrogel photonic crystal hydrogel pollution detection

Dynamic recrystallization mechanism, texture evolution development and mechanical characteristics of a Mg–8.7Gd–4.18Y–0.42Zr magnesium alloy by ECAP

在线全文

学校读者我要写书评

暂无评论

Progress in Natural science:Materials International 2024年第2期34卷 376-388页

作者： Ling Zhang Yinglong Li School of Materials science and engineering Northeastern University School of Mechanical and engineering Ningxia Institute of Science and Technology

Equal channel angle pressing is recognized for its ability to refine alloy grains and alter grain orientation, thereby achieve better mechanical performance of the magnesium alloy. This study investigates the microstructures,dynamic recrystallization mechanism, texture development, and mechanical performance of GW94K(Mg–8.7Gd–4.18Y–0.42Zr wt. %) Mg alloy following ECAP-4 passes at 400°C and 3 mm/min. Results show that when high-temperature deformation is undertaken, twin formation is suppressed while dislocation slip is facilitated, increasing dislocation density during deformation. Following ECAP deformation, the sample displayed higher fracture elongation, TYS, and UTS than the as-solutioned GW94K alloy. In particular, the GW94K alloy performed well mechanically after ECAP-4 passes, with an ultimate TYS of 231 MPa, an UTS of 290 MPa, and an elongation of 14.8 %. DDRX and shear bands induce CDRX, both of which are important in plastic deformation. as well as in modifying microstructure and grain orientation during ECAP deformation.

关键词： Dynamic recrystallization mechanism Equal channel angular pressing Magnesium alloy Mechanical performance Mg-Gd-Y-Zr alloy Texture development

Rational design and energy catalytic application of high-loading single-atom catalysts

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第10期43卷 4844-4866页

作者： Zi-Wei Deng Yue Liu Jie Lin Wen-Xing Chen Energy and Catalysis Center School of Materials Science and EngineeringBeijing Institute of Technology Ningbo institute of Materials Technology and engineering Chinese Academy of Science

It is well known that single-atom catalysts(SACs)have become a hot topic in the field of catalysis due to their advantages such as 100% metal atom utilization efficiency,high catalytic activity and selectivity compared with conventional catalysts and nanocatalysts. However, the isolated metal atoms on SACs have thermodynamic instability and tend to agglomerate, which limit their catalytic ***, it is of great significance to synthesize stable and high-loading single-atom catalysts(HLSACs). In this paper,we review the research progress of HLSACs from two aspects:design and application. Firstly, we comprehensively introduce the synthesis strategies of HLSACs, namely, top-down and bottom-up methods. Secondly, we overview the application status of HLSACs in three fields: electrocatalysis, thermal catalysis and photocatalysis. Finally, we summarize the development prospects and challenges of HLSACs.

关键词： Design Electrocatalysis High-loading single-atom catalysts Photocatalysis Thermal catalysis

Growth,optical dispersion and magnetic behavior of Dy^(3+) doped yttrium iron garnet crystals

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第6期42卷 1110-1117,I0004页

作者： Yating Fang Hui Shen Yudie Ma Shijie Liao Shuang Xia Tian Tian Ding Zhou Yunfeng Ma Jiayue Xu institute of Crystal Growth School of Materials Science and EngineeringShanghai Institute of Technology National engineering Center of Electromagnetic Radiation Control Materials School of Electronic Science and EngineeringUniversity of Electronic Science and Technology of China

Y_(3)Fe_(5)O_(12)(YIG)crystals are highly desirable for the fabrication of mid-infrared isolators with the rapid growth of optical communications,although it is rather challenging to grow large size and high-quality single ***^(3+)doping is expected to improve the optical and magneto-optical prope ***,high quality Dy:YIG crystals and the adjustment of Dy^(3+)on the structure and optical behavior of YIG crystal remain unclear,impeding its practical ***,a series of Y_(3-x)Dy_(x)Fe_(5)O_(12)(x=0,0.5,1.0,1.5,3)solid solution crystals was grown by the flux-Bridgman method and single crystals up to 25 mm were *** the introduction of Dy^(3+),lattice parameters are gradually enlarged from 1.2379 nm(YIG)to 1.2420 nm(DyIG).Typical Dy^(3+)absorption peaks are observed around 1070,1265 and 1670 *** refractive index decreases from 2.37(500 nm)to 2.10(2500 nm)for YIG crystal,and it reduces from 2.47(500 nm)to 2.16(2500 nm)for DyIG *** optical bandgaps remain almost unchanged for Dy:YIG *** optical dispersion of the refractive indices was finely fitted by the Wemple and DiDomenico(WDD)and the Sellmeier models,*** the increase of Dy^(3+)content,the saturation magnetization(Ms)decreases significantly from 23.62 emu/g(YIG)to 5.33 emu/g(DyIG).Small coercive field is persisted for this system,endowing small external magnetic *** results provide valuable references for the manipulation of rare earths on the properties of magnetooptical crystals,which is beneficial to the design of high-performance garnet crystals for the application of optical switching and non-reciprocal related devices.

关键词： Magneto-optical crystal Yttrium iron garnet Dy^(3+)doping Crystal growth Optical dispersion Rare earths

Integrated high-performance and accurate shaping technology of low-cost powder metallurgy titanium alloys: A comprehensive review

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2024年第3期31卷 413-426页

作者： Xuemeng Gan Shaofu Li Shunyuan Xiao Yafeng Yang State Key Laboratory of Mesoscience and engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of Chinese Academy of sciences Beijing 100049China Key Laboratory of science and Technology on particle Materials Chinese Academy of SciencesBeijing 100190China

The practical engineering applications of powder metallurgy (PM) Ti alloys produced through cold compaction and pressure-less sintering are impeded by poor sintering densification, embrittlement caused by excessive O impurities, and severe sintering deforma-tion resulting from the use of heterogeneous powder mixtures. This review presents a summary of our previous work on addressing the above challenges. Initially, we proposed a novel strategy using reaction-induced liquid phases to enhance sintering densification. Near- complete density (relative density exceeding 99%) was achieved by applying the above strategy and newly developed sintering aids. By focusing on the O-induced embrittlement issue, we determined the onset dissolution temperature of oxide films in the Ti matrix. On the basis of this finding, we established a design criterion for effective O scavengers that require reaction with oxide films before their dissol-ution. Consequently, a ductile PM Ti alloy was successfully obtained by introducing 0.3wt% NdB6 as the O scavenger. Lastly, a powder- coating strategy was adopted to address the sintering deformation issue. The ultrafine size and shell-like distribution characteristics of coating particles ensured rapid dissolution and homogeneity in the Ti matrix, thereby facilitating linear shrinkage during sintering. As a result, geometrically complex Ti alloy parts with high dimensional accuracy were fabricated by using the coated powder. Our fundament-al findings and related technical achievements enabled the development of an integrated production technology for the high-performance and accurate shaping of low-cost PM Ti alloys. Additionally, the primary engineering applications and progress in the industrialization practice of our developed technology are introduced in this review.

关键词： powder metallurgy titanium sintering densification oxygen scavenging accurate shaping

Enhancing CO_(2) transport with plasma-functionalized ionic liquid membranes

在线全文

学校读者我要写书评

暂无评论

Plasma science and Technology 2024年第7期26卷 74-81页

作者：舒茹晨许卉裴晨霄王楠刘新刚侯剑源袁圆张仁熙 Shanghai Key Laboratory of Atmospheric particle Pollution and Prevention(LAP) Institute of Environmental ScienceFudan UniversityShanghai 200433People’s Republic of China

The ionic liquid(IL) 1-butyl-3-methylimidazolium tetrafluoroborate treated with radiofrequency plasma is proposed for functionalization and immobilization on polyethersulfone supports to form supported ionic liquid membranes for CO_(2) *** effects of treatment time and transmembrane pressure difference on CO_(2) permeance were *** best gas permeation performance was obtained with a treatment time of 10 min and the transmembrane pressure difference was 0.25 *** of the materials by Fourier transform infrared spectroscopy,x-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy demonstrates that the IL is grafted with carboxyl groups and deprotonated through plasma treatment.A preliminary mechanism for the plasma treatment and facilitated transport of CO_(2)has been proposed on this basis.

关键词： ionic liquids carbon dioxide supported ionic liquid membranes facilitated transport radiofrequency plasma

Comprehensive tensile properties improved by deep cryogenic treatment prior to aging in friction-stir-welded 2198 Al–Li alloy

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第10期43卷 5403-5409页

作者： Jian-Qiu Sun Yue Ma Chong Gao Hong-Yun Luo School of Materials science and engineering Beihang University Chinalco Research institute of science and Technology

In order to improve the comprehensive mechanical properties,deep cryogenic treatment （DCT）prior to aging was carried out on friction-stir-welded（FSW） 2198 Al-Li alloy;afterward,the microstructure and tensile properties were characterized by means of optical microscopy （OM）,transmission electron microscopy（TEM） and tensile *** results show that FSW 2198 alloy through DCT prior to aging （DAT） possesses superior tensile properties than conventional aging treatment （AT）The microstructural analysis reveals that DAT alloy exhibits a finer grain structure,since DCT might effectively alleviate the residual stress in FSW 2198 alloy and thus decrease the driving force for grain coarsening in subsequent aging ***,DCT generates dislocation multiplication,which provides more preferential nucleation sites for T1 （Al2CuLi） phase during subsequent aging treatment,resulting in high-density fine T1 phases and thin precipitate-free zone within DAT *** reasonable microstructure leads to DAT alloy possessing better strength-ductility combination compared to AT alloy.

关键词： Al–Li alloy Deep cryogenic treatment Friction stir welding Tensile properties

Revisiting the spin effects induced by thermal vorticity

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chinese Physics C 2024年第5期48卷 194-208页

作者：高建华杨诗正 Shandong Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment School of Space Science and PhysicsShandong UniversityWeihai 264209China institute of Frontier and Interdisciplinary science Key Laboratory of Particle Physics and Particle Irradiation(MOE)Shandong UniversityQingdao 266237China

We revisit the spin effects induced by thermal vorticity by calculating them directly from the spin-dependent distribution *** spin-1/2 particles,we provide the polarization up to the first order of thermal vorticity and compare it with the usual results calculated from the spin *** spin-1 particles,we show that all the non-diagonal elements vanish and there is no spin alignment up to the first order of thermal *** present the spin alignment at second-order contribution from thermal *** also show that the spin effects for both Dirac and vector particles receive an extra contribution when the spin direction is associated with the momentum of the particle.

关键词： relativistic heavy ion collisions global polarization quark gluon plasma

A new portable open-path instrument for ambient NH_(3) and on-road emission measurements

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental sciences 2024年第2期136卷 606-614页

作者： Wenhao Dai Shanshan Wang Sanbao Zhang Jian Zhu Chuanqi Gu Zhibin Sun Ruibin Xue Bin Zhou Shanghai Key Laboratory of Atmospheric particle Pollution and Prevention(LAP3) Department of Environmental Science and EngineeringFudan UniversityShanghai 200438China institute of Eco-Chongming(IEC) Shanghai 202162China institute of Atmospheric sciences Fudan UniversityShanghai 200433China

Increased attentions to vehicle emission of NH_(3)have been paid since it is generally regarded as an important source in urban ***,we developed a movable instrument based on Differential Optical Absorption Spectroscopy(DOAS)principle for detecting on-road NH_(3),which can avoid the losses in the sampling process attributed to the non-sampling *** this mobile DOAS,the temporal resolution,detection limit and relative error for NH_(3)were 1 min,2.29 ppbv and 4.57%±2.44%,*** employed to the on-road measurements along the arterial highway in Shanghai,the spatial distributions of NH_(3)and NO were obtained,and their dependence of traffic and road conditions were *** slopes of linear regression between NH_(3)and NO were 0.40,0.02 and 0.07 on the Middle Ring Road,Outer Ring Road and Chongming Island Ring *** indicates that light gasoline vehicles(LGVs)were found to be the main contributor to NH_(3)emissions,while heavy-duty diesel vehicles(HDVs)mainly emitted *** on the measured NH_(3)in the tunnel,the mileagebased NH_(3)emission factor per vehicle was estimated to be 17.9±6.3 mg/*** reported open-path instrument can be broadly used in on-road pollutant monitoring or vehicle emissions,and the measurements can reveal the real situation of emission characteristics,even find the abnormal operations of vehicle catalyst system.

关键词： Ammonia Traffic emissions DOAS Emission factor Mobile measurements