检索结果-南通市图书馆

Phase field modeling of grain stability of nanocrystalline alloys by explicitly incorporating mismatch strain

Rare Metals 2024年第7期43卷 3370-3382页

作者： Min Zhou Hong-Hui Wu Yuan Wu Hui Wang Xiong-Jun Liu Sui-He Jiang Xiao-Bin Zhang Zhao-Ping Lu Beijing Advanced Innovation Center for materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083Cnina institute for carbon Neutrality University of Science and TechnologyBeijing 100083China institute of materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China

Ab st ra ct Nanocrystalline materials exhibit unique properties due to their extremely high grain boundary(GB) ***,this high-density characteristic induces grain coarsening at elevated temperatures,thereby limiting the widespread application of nanocrystalline *** experimental observations revealed that GB segregation and second-phase pinning effectively hinder GB migration,thereby improving the stability of nanocry stalline *** this study,a mouified phase-field model that integrates mismatch strain,solute segregation and precipitation was developed to evaluate the influence of lattice misfit on the thermal stability of nanocrystalline *** simulation results indicated that introducing a suitable mismatch strain can effectively enhance the microstructural stability of nanocrystalline *** synergizing precipitation with an appropriate lattice misfit,the formation of second-phase particles in the bulk grains can be suppressed,thereby facilitating solute segregation/precipitation at the *** concentrated solute segregation and precipitation at the GBs effectively hinders grain migration,thereby preventing grain *** findings provide a new perspective on the design and regulation of nanocrystalline alloys with enhanced thermal stability.

关键词： Phase field model Mismatch strain Second-phase precipitation Grain boundary segregation Nanocrystalline alloys

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Pyrrolic nitrogen coordinated Nidual-atom catalyst for boosting COelectroreduction

引用

Science China Chemistry 2024年

作者： Zhi-Wei Chen Hong-Juan Wang Chang Liu Xiu-Li Lu Tong-Bu Lu MOE International Joint Laboratory of materials Microstructure Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Nitrogen-doped carbon materials have been widely used for the constructions of single-atom catalysts,while the effect of different species of doped nitrogen on the catalytic activity of CO2electroreduction has rarely been *** we found that pyrrolic-N coordinated Ni2+catalysts display much higher electrocatalytic CO2-to-CO activity and selectivity than the corresponding pyridinic-N coordinated low valent Ni（0–+2）catalysts,and pyrrolic-N coordinated Ni2dual-atoms catalyst of Ni2/N-CNTs exhibits the best electrocatalytic performance,with over 90%Faradaic efficiencies in a broad potentials from-0.6 to-1.2 V *** hydrogen electrode,as well as an outstanding CO specific current of 56.2 A/mgNiand high turnover frequency of 6.2×10～4h-1,over 7-times higher than those of pyridinic-N coordinated Ni *** results indicate the weak electron-donor nature of pyrrolic-N facilitates the generation of a reduced active site at low overpotential for boosting *** functional theory calculations reveal that the reaction free energy for the*COOHformation on pyrrolic-N coordinated Ni catalysts are lower than those on pyridinic-N coordinated Ni catalysts,and a H2O-adsorbed Ni2/N-CNTs displays the optimized reaction free energy for both*COOH formation and CO desorption,which derive the best catalytic performance.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Integration of metal-organic layers with quantum dots for artificial photosynthesis

引用

Science China Chemistry 2024年

作者： Hong Yuan Min Zhang Ji-Hua Deng Tong-Bu Lu Di-Chang Zhong institute for new Energy materials and Low carbon Technologies School of Materials Science and Engineering School of Chemistry and Chemical Engineering Tianjin University of Technology

Metal-organic layers （MOLs）,a type of new-emerging two-dimensional ultrathin metal-organic framework materials with large surface areas and highly exposed active sites,have shown promising applications in photocatalytic ***,due to a lack of photosensitivity and photooxidation capability,photosensitizers and sacrificial reductants are usually necessary for MOLs-based photocatalytic CO2reduction *** this article,by integration of MOLs and quantum dots （QDs）,we constructed MOLs-based catalysts with multi-functions of photosensitivity,photoreduction and photooxidation,which thus can serve as photocatalysts for CO2reduction with H2O as an electron ***,by an electrostatic self-assembly approach,nickel（II）-based MOLs （Ni-MOLs） and CsPbBr3QDs have been assembled,constructing valid II-Scheme Ni-MOLs/CsPbBr3heterojunctions with close Ni-MOLs/*** a close heterointerface shortens the charge transfer distance,thus effectively boosting the charge separation and *** a result,upon illumination by visible light (λ≥400 nm,100 m W cm-2),the optimized photocatalyst shows high efficiency and stability in photochemical CO2reduction in the absence of any photosensitizers and sacrificial *** CO yield reaches as high as 124μmol g-1in 4 h,over 6 times higher than that achieved by ***,the selectivity reaches 100%.This work provides a new way to construct MOL-based catalysts for artificial photosynthesis.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Influence of pore structure on thermal stress distribution inside coal particles during primary fragmentation

引用

Particuology 2024年第2期85卷 49-61页

作者： Kai Qiao Shan Zhong Siyang Tang Ke Yang Hairong Yue Kui Ma Lei Song Bin Liang School of Chemical Engineering Sichuan UniversityChengdu610065China institute of new Energy and Low-carbon Technology Chengdu610207China

Thermal stress is an important reason of coal particle primary fragmentation,during which the role of pore structure is *** stress induced fragmentation experiments were conducted with low volatile coal/char particles,and the results show that the fragmentation severity enhances with increasing *** porous thermal stress models were developed with finite element method,and the influences of the pore shape,size,position and porosity on the thermal stress were *** maximum thermal stress inside particle increases with pore curvature,the pore position affects the thermal stress more significantly at the particle center and *** expectation of the maximum tensile thermal stress linearly increases with porosity,making the particles with higher porosity easier to fragment,contrary to the conclusion deduced from the devolatilization *** obtained results are valuable for the analysis of different thermal processes concerning the thermal stresses of the solid feedstocks.

关键词： Coal particle Primary fragmentation Thermal stress Pore structure Porosity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Highly cycle-stable VOPO_(4)-based cathodes for magnesium ion batteries:Insight into the role of interlayer engineering in batteries performance

引用

Nano Research 2024年第7期17卷 6127-6138页

作者： Jiahe Zhang Jing Shang Xiaojun Zhang Ke Wang Yihe Zhang Engineering Research Center of Ministry of Education for Geological carbon Storage and Low carbon Utilization of Resources Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid WastesNational Laboratory of Mineral MaterialsSchool of Materials Science and TechnologyChina University of Geosciences(Beijing)Beijing 100083China

It is the sluggish ion migration kinetics that seriously affects the practical performance of the magnesium ion *** though an electrode material design using rational interlayer engineering method could effectively solve this issue,the optimal interlayer distance remains ***,various VOPO_(4)-based electrodes with expanded interlayer spacing were fabricated and the relationship between interlayer structure and battery performance was *** analysis combined with computations unveils the existence of an optimal interlayer structure,as inadequate expansion failed to fully utilization of the material performance,while excessive expansion degraded the electrode *** them,the electrode with triethylene glycol(TEG)intercalation exhibited optimized performance,maintaining excellent cycling stability(191.3 mAh·g^(−1)after 800 cycles).Density functional theory(DFT)demonstrated the effectiveness and limitations to lowering the migration energy barrier by expanding the interlayer *** addition,systematic mechanism research revealed the Mg^(2+)storage process:The stepwise shuttling of Mg^(2+)along the directions that lie in(001)plane triggers two pairs of redox processes,namely V^(5+)/V^(4+)and V^(4+)/V^(3+).This study,regulation of layer spacing to achieve the best integrated performance of electrodes,could deepen the understanding of interlayer engineering and guide the design of advanced multivalent-ion batteries.

关键词： magnesium ion batteries layered electrodes interlayer engineering energy storage mechanisms high kinetics

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Semi-quantitative analysis of the structural evolution of mesophase pitch-based carbon foams by Raman and FTIR spectroscopy

引用

新型炭材料（中英文） 2024年第4期39卷 668-680页

作者： LIU Yue CHANG Sheng-kai SU Zhan-peng HUANG Zu-jian QIN Ji YANG Jian-xiao Hunan Province Key Laboratory for Advanced carbon materials and Applied Technology College of Materials Science and EngineeringHunan UniversityChangsha410082China

Graphitized carbon foams(GFms)were prepared using mesophase pitch(MP)as a raw material by foaming(450℃),pre-oxidation(320℃),carbonization(1000℃)and graphitization(2800℃).The differences in structure and properties of GFms prepared from different MP precursors pretreated by ball milling or liquid phase extraction were investigated and compared,and semi-quantitative calculations were conducted on the Raman and FTIR spectra of samples at each preparation ***-quantitat-ive spectroscopic analysis provided detailed information on the structure and chemical composition changes of the MP and GFm de-rived from *** with microscopic observations,the change from precursor to GFm was *** results showed that ball milling concentrated the distribution of aromatic molecules in the pitch,which contributed to uniform foaming to give a GFm with a uniform pore distribution and good *** phase extraction helped remove light components while retaining large aromatics to form graphitic planes with the largest average size during post-treatment to produce a GFm with the highest degree of graphitization and the fewest open pores,giving the best compression resistance(2.47 MPa),the highest thermal conductivity(64.47 W/(m·K))and the lowest electrical resistance(13.02μΩ·m).Characterization combining semi-quantitative spectroscopic ana-lysis with microscopic observations allowed us to control the preparation of the MP-derived GFms.

关键词： Mesophase pitch carbon foams Raman FTIR Graphitization

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Organic near-infrared optoelectronic materials and devices:an overview

引用

Advanced Photonics 2024年第1期6卷 17-42页

作者： Zong-Lu Che Chang-Cun Yan Xue-Dong Wang Liang-Sheng Liao Soochow University Institute of Functional Nano and Soft Materials(FUNSOM)Jiangsu Key Laboratory for Carbon-Based Functional Materials and DevicesSuzhouChina Soochow University College of ChemistryChemical Engineering and Materials ScienceJiangsu Engineering Laboratory of Novel Functional Polymeric MaterialsSuzhouChina Macao University of Science and Technology Macao Institute of Materials Science and EngineeringMacaoChina

Near-infrared(NIR)light has shown great potential for military and civilian applications owing to its advantages in the composition of sunlight,invisibility to human eyes,deeper penetration into biological tissues,and low optical loss in optical ***,organic optoelectronic materials that can absorb or emit NIR light have aroused great scientific interest in basic science and practical *** on these NIR organic optoelectronic materials,NIR optoelectronic devices have been greatly improved in performance and *** this review,the representative NIR organic optoelectronic materials used in organic solar cells,organic photodetectors,organic light-emitting diodes,organic lasers,and organic optical waveguide devices are briefly introduced,and the potential applications of each kind of device are briefly ***,we summarize and take up the development of NIR organic optoelectronic materials and devices.

关键词： near-infrared organic optoelectronic materials organic solar cells organic light-emitting devices organic optical waveguides

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Identifying the origin of porous evolution of microsized bismuth in potassium-ion batteries

引用

Science China Chemistry 2024年第7期67卷 2234-2239页

作者： Shenxu Chu Kaixiang Lei Qian Yang Jiaxin Li Yuqing Zhao Mengjia Gu Lin Li Xing Hu Yu Zhang Zhuo Chen Shuo Shi Shulei Chou Shijian Zheng Tianjin Key Laboratory of materials Laminating Fabrication and Interface Control Technology School of Materials Science and EngineeringHebei University of TechnologyTianjin 300401China institute for carbon Neutralization Technology College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China

Microsized bismuth(Bi)with in-situ constructed three-dimensional(3D)porous network has been considered as a promising anode for high-performance potassium-ion batteries(PIBs).However,the mechanism of the in-situ porous evolution of microsized Bi during the charge/discharge process is still ***,various electrolytes are employed to disclose the origin of porous evolution of microsized Bi in *** and theoretically,the 3D porous network originates from the uniform interfacial charge distribution on the Bi surface in the linear ether-based *** addition,the universality of the interfacial charge distribution mechanism was verified by microsized Sn and *** in-situ constructed 3D porous network of Bi enables a superior potassium storage performance in a wide temperature range from-40 to 40℃.More importantly,the K_(0.9)Mn_(0.7)Ni_(0.3)O_(2)||Bi full cell delivers excellent cycling stability(a high capacity retention of 88.44%even after 2,000 cycles)and good temperature *** work gives a distinct clarification of the origin of the porous evolution of microsized Bi during cycling,which is critical for developing high-performance PIBs.

关键词： potassium-ion batteries microsized Bi porous evolution linear ether-based electrolyte interfacial charge distribution

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Chelation strategy induced blue-shift for efﬁcient deep-blue perovskite light-emitting diodes

引用

Science Bulletin 2024年第15期69卷 2332-2336页

作者： Yu Xia Zhipeng Zhang Yu-Hang Zhou Yu-Han Li Bin Wang Kai-Li Wang Chun-Hao Chen Jing Chen Ilhan Yavuz Guichuan Xing Zhao-Kui Wang institute of Functional Nano&Soft materials(FUNSOM) Jiangsu Key Laboratory of Advanced Negative Carbon TechnologiesJiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou 215123China Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials EngineeringUniversity of MacaoMacao 999078China Department of Physics Marmara UniversityZiverbeyIstanbul 34722Turkey

Metal halide perovskite, regarded as a potential material for next-generation display and lighting applications, has attracted great attention [1,2]. The development of blue perovskite light-emitting diodes (Pe LEDs) ... 详细信息

关键词： diodes emitting perovskite

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Single-wall carbon nanotube fiber non-woven fabrics with a high electrothermal heating response

引用

Nano Research 2024年第6期17卷 5621-5628页

作者： Xinyu Jiao Lele Xu Xinyang Sun Chao Shi Peng-Xiang Hou Chang Liu Hui-Ming Cheng Shenyang National Laboratory for materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of materials Science and Engineering University of Science and Technology of ChinaHefei 230026China Faculty of materials Science and Engineering/institute of Technology for carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China

carbon nanotube(CNT)fibers have great promise for constructing multifunctional fabrics with high electrical conductivity,good electro-heating ability,excellent flexibility,and a low ***,the inter-fiber contacts in the fabric greatly reduce these advantages and limit their ***,a simple pressure-fusing method to fabricate single-wall CNT(SWCNT)fiber non-woven fabrics(NWFs)that are composed of interconnected SWCNT fibers with fused joints is reported,which have good flexibility,a low density of 0.46 g/cm^(3),a high electrical conductivity of 3.7×10^(5)S/m,and a record high specific electrical conductivity of 803(S·m^(2))/*** also showed excellent electrical heating ability,so that a temperature of~160℃was rapidly reached at a low voltage of 2 *** with their low density,the SWCNT fiber NWFs are promising for use as a heating unit for low temperature battery protection and de-icing applications.

关键词： carbon nanotube fiber nonwoven fabrics fusing electrothermal heating

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：