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Facet-dependent transformation and toxicity of nanoscale zinc oxide in the synthetic saliva

Journal of Environmental Sciences 2024年第5期139卷 170-181页

作者： Xiang Zhang Yunpeng Huang Jikun Wang Jie Tang YangMei Nali Zhu Zhigang Li Lingxiangyu Li YaweiWang School of Environment Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China College of resources and Environment University of Chinese Academy of SciencesBeijing 100049China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Key Laboratory of Systems Health Science of Zhejiang Province Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China Department of Chemistry University of PennsylvaniaPhiladelphia 19104USA

The nanoscale zinc oxide(n-ZnO)was used in food packages due to its superior antibac terial activity,resulting in potential intake of n-ZnO through the digestive system,wherein n-ZnO interacted with *** recent,facet engineering,a technique for controlling the exposed facets,was applied to n-ZnO,whereas risk of n-ZnO with specific exposed facets in saliva was *** nanoflakes(ZnO-0001)and nanoneedles(ZnO-1010)with the pri mary exposed facets of{0001}and{1010}respectively were prepared in this study,investigat ing stability and toxicity of ZnO-0001 and ZnO-1010 in synthetic *** ZnO-0001 and ZnO-1010 partially transformed into amorphous Zn_(3)(PO_(4))_(2)within 1 hr in the saliva even containing orgnaic components,forming a ZnO-Zn_(3)(PO_(4))_(2)core-shell *** less,ZnO-1010 relative to ZnO-0001 would likely transform into Zn_(3)(PO_(4))_(2),being attributed to superior dissolution of{1010}facet due to its lower vacancy formation energy(1.15 eV than{0001}facet(3.90 eV)).The toxicity of n-ZnO to Caco-2 cells was also dependent on the primary exposed facet;ZnO-0001 caused cell toxicity through oxidative stress,whereas ZnO-1010 resulted in lower cells viability than ZnO-0001 through oxidative stress and mem brane *** functional theory calculations illustrated that·O_(2)^(-)was formed and released on{1010}facet,yet O_(2)^(2-)instead of·O_(2)^(-)was generated on{0001}facet,leading to low oxidative stress from *** findings demonstrated that stability and toxicity of n-ZnO were dependent on the primary exposed facet,improving our understanding o health risk of nanomaterials.

关键词： The exposed facet Nanoscale ZnO Chemical transformation Synthetic salica Nanotoxicity

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Triple the steady-state reaction rate by decorating the In_(2)O_(3)surface with SiO_(x)for CO_(2)hydrogenation

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Journal of Energy Chemistry 2024年第8期95卷 96-105,I0003页

作者： Hao Wang Chun Yang Xiaoyan Yu Mingrui Wang Runze Yang Xiaowa Nie Ben Hang Yin Alex C.K.Yip Chunshan Song Guanghui Zhang Xinwen Guo State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsPSU-DUT Joint Center for Energy ResearchSchool of Chemical EngineeringDalian University of TechnologyDalian 116024LiaoningChina Department of Chemistry the Chinese University of Hong KongHong Kong 999077China Paihau-Robinson Research institute the MacDiarmid Institute for Advanced Materials and NanotechnologyVictoria University of WellingtonWellington 6012New Zealand Department of Chemical and Process Engineering The University of CanterburyChristchurch 8041New Zealand

Indium oxide(In_(2)O_(3)),as a promising candidate for CO_(2)hydrogenation to C_(1) products,often suffers from sintering and activity decline,closely related to the undesirable structural evolution under reaction *** on the comprehension of the dynamic evolution,this study presents an efficient strategy to alleviate the agglomeration of In_(2)O_(3)nanoparticles by the surface decoration with highly dispersed silica species(SiO_(x)).Various structural characterizations combined with density functional theory calculations demonstrated that the sintering resulted from the over-reduction,while the enhanced stability originated from the anchoring effect of highly stable In-OSi bonds,which hinders the substantial formation of metallic In(In^(0))and the subsequent agglomeration.0.6Si/In_(2)O_(3)exhibited CO_(2)conversion rate of10.0 mmol g^(-1)h^(-1)at steady state vs.3.5 mmol g^(-1)h^(-1)on In_(2)O_(3)in CO_(2)*** steady-state activity was also achieved on Pd-modified *** to the traditional Pd/In_(2)O_(3)catalyst,the methanol production rate of Pd catalyst supported on 0.6Si/In_(2)O_(3)was enhanced by 23%,showing the potential of In_(2)O_(3)modified by SiO_(x)in serving as a platform *** work provides a promising method to design new In_(2)O_(3)-based catalysts with improved activity and stability in CO_(2)hydrogenation.

关键词： CO_(2)hydrogenation In_(2)O_(3)sintering Dynamic structural evolution Surface SiO_(x)modification DFT simulations

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Au nanoclusters anchored on TiO_(2) nanosheets for high-efficiency electroreduction of nitrate to ammonia

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Nano Research 2024年第3期17卷 1209-1216页

作者： Miaosen Yang Tianran Wei Jia He Qian Liu Ligang Feng Hongyi Li Jun Luo Xijun Liu School of Chemical Engineering Northeast Electric Power UniversityJilin 132012China Nanchang institute of Technology Nanchang 330044China State Key Laboratory of Chemistry and Utilization of Carbon Based Energy resources College of ChemistryXinjiang UniversityUrumqi 830017China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China institute for new Energy Materials and Low-Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China institute for advanced study Chengdu UniversityChengdu 610106China School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002China Guangzhou Panyu Polytechnic Guangzhou 511483China ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of ChinaLonghua DistrictShenzhen 518110China

Electrocatalytic nitrate reduction reaction(NO_(3)RR)offers a unique rationale for green NH_(3) synthesis,yet the lack of high-efficiency NO_(3)RR catalysts remains a great *** this work,we show that Au nanoclusters anchored on TiO_(2) nanosheets can efficiently catalyze the conversion of NO_(3)RR-to-NH_(3) under ambient conditions,achieving a maximal Faradic efficiency of 91%,a peak yield rate of 1923μg·h^(-1)·mgcat.-1,and high durability over 10 consecutive cycles,all of which are comparable to the recently reported metrics(including transition metal and noble metal-based catalysts)and exceed those of pristine TiO_(2).Moreover,a galvanic Zn-nitrate battery using the catalyst as the cathode was proposed,which shows a power density of 3.62 mW·cm^(-2) and a yield rate of 452μg·h^(-1)·mgcat.-*** simulations further indicate that the atomically dispersed Au clusters can promote the adsorption and activation of NO_(3)-species,and reduce the NO_(3)RR-to-NH_(3) barrier,thus leading to an accelerated cathodic *** work highlights the importance of metal clusters for the NH_(3) electrosynthesis and nitrate removal.

关键词： NH3 electrosynthesis Zn-nitrate battery Au nanoclusters nitrate reduction reaction(NRR) TiO_(2)nanosheets

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Genome-wide identification of the pectate lyase(PEL)gene family members in Malvaceae,and their contribution to cotton fiber quality

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Journal of Integrative Agriculture 2024年第10期23卷 3264-3282页

作者： Qian Deng Zeyu Dong Zequan Chen Zhuolin Shi Ting Zhao Xueying Guan Yan Hu Lei Fang Zhejiang Provincial Key Laboratory of Crop Genetic resources the Advanced Seed InstituteCollege of Agriculture andBiotechnologyZhejiang UniversityHangzhou 300058China Hainan institute Zhejiang UniversitySanya 572025China

Pectin is a major constituent of the plant cell *** lyase(PEL,EC 4.***.2.2)uses anti-β-elimination chemistry to cleave theα-1,4 glycosidic linkage in the homogalacturonan region of ***,limited information is available on the comprehensive and evolutionary analysis of PELs in the *** this study,we identified 597PEL genes from 10 Malvaceae *** and motif analyses revealed that these PELs are classified into six subfamilies:Clades I,II,III,IV,Va,and *** two largest subfamilies,Clades I and II,contained 237 and222 PEL members,*** members of Clades Va and Vb only contained four or five motifs,far fewer than the other *** duplication analysis showed that segmental duplication played a crucial role in the expansion of the PEL gene family in Gossypium *** PELs from Clades I,IV,Va,and Vb were expressed during the fiber elongation stage,but nearly all PEL genes from Clades II and III showed no expression in any of the investigated fiber developmental *** further performed single-gene haplotype association analysis in 2,*** accessions and 229 *** ***,14 PELs were significantly associated with fiber length and strength traits in *** with superior fiber quality,while only eight GhPEL genes were found to be significantly associated with fiber quality traits in *** findings provide important information for further evolutionary and functional research on the PEL gene family members and their potential use for fiber quality improvement in cotton.

关键词： Malvaceae pectate lyase(PEL) Gossypium species fiber quality

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Impacts of permafrost degradation on streamflow in the northern Himalayas

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Science China Earth Sciences 2024年第6期67卷 1990-2000页

作者： Linfeng FAN Fang JI Xingxing KUANG Zhilin GUO Rui ZHANG Chunmiao ZHENG State Key Laboratory of Mountain Hazards and Engineering Resilience Institute of Mountain Hazards and EnvironmentChinese Academy of SciencesChengdu 610299China Yangtze institute for Conservation and Development Hohai UniversityNanjing 210024China School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Eastern institute for advanced study Ningbo 315200China

The Himalayan water tower provides crucial water resources for *** degradation is deemed to exert important impacts on streamflow in the Himalayan ***,the magnitudes of such impacts remain poorly ***,we established a robust hydrological model that incorporated active layer deepening and ground ice melt for the drainage basin of the largest river in the northern Himalayas-the Yarlung Zangbo River(YZR).We estimated that permafrost degradation led to~0.65 km^(3)/yr decrease in surface runoff and~0.35 km^(3)/yr increase in baseflow and ground ice melt contributed~0.25% to the annual streamflow in the YZR for the period ***“fill-and-spill”mechanism helps explain the seeming contradiction of observed increasing versus decreasing baseflow in different permafrost regions *** propose that the dilution of riverine dissolved organic carbon(DOC)concentrations by baseflow may lead to the riverine DOC hysteresis *** study not only lays solid scientific basis for water resources management in the Himalayas,but also yields new insights into how to interpret measured river discharge and nutrient flux in permafrost regions over the globe.

关键词： Permafrost degradation Hydrology Streamflow Surface runoff Groundwater Himalayas

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Microwave shock motivating the Sr substitution of 2D porous GdFeO_(3) perovskite for highly active oxygen evolution

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Journal of Energy Chemistry 2024年第1期88卷 232-241,I0006页

作者： Jinglin Xian Huiyu Jiang Zhiao Wu Huimin Yu Kaisi Liu Miao Fan Rong Hu Guangyu Fang Liyun Wei Jingyan Cai Weilin Xu Huanyu Jin Jun Wan State Key Laboratory of new Textile Materials and advanced Processing Technologies Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing&FinishingWuhan Textile UniversityWuhan 430200HubeiChina Future Industries institute STEMUniversity of South AustraliaAdelaideSA 5095Australia institute for Sustainability Energy and ResourcesThe University of AdelaideAdelaideSA 5005Australia

The incorporation of partial A-site substitution in perovskite oxides represents a promising strategy for precisely controlling the electronic configuration and enhancing its intrinsic catalytic *** methods for A-site substitution typically involve prolonged high-temperature *** these processes promote the development of unique nanostructures with highly exposed active sites,they often result in the uncontrolled configuration of introduced ***,we present a novel approach for synthesizing two-dimensional(2D)porous GdFeO_(3) perovskite with A-site strontium(Sr)substitution utilizing microwave shock *** technique enables precise control of the Sr content and simultaneous construction of 2D porous structures in one step,capitalizing on the advantages of rapid heating and cooling(temperature~1100 K,rate~70 K s^(-1)).The active sites of this oxygen-rich defect structure can be clearly revealed through the simulation of the electronic configuration and the comprehensive analysis of the crystal *** electrocatalytic oxygen evolution reaction application,the synthesized 2D porous Gd_(0.8)Sr_(0.2)FeO_(3) electrocatalyst exhibits an exceptional overpotential of 294 mV at a current density of 10 mA cm^(-2)and a small Tafel slope of 55.85 mV dec^(-1)in alkaline *** study offers a fresh perspective on designing crystal configurations and the construction of nanostructures in perovskite.

关键词： 2D materials Perovskite Microwave Electrocatalysis Oxygen evolution reaction

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Toward to agricultural green development by multi-objective zoning and nitrogen nutrient management:a case study in the Baiyangdian Basin,China

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Frontiers of Agricultural Science and Engineering 2024年第1期11卷 140-154页

作者： Xiaomeng ZHANG Xiangwen FAN Wenqi MA Zhaohai BAI Jiafa LUO Jing YANG Ling LIU Jianjie ZHANG Lin MA College of resources and Environmental Sciences Hebei Agricultural UniversityBaoding 071000China Center for Agricultural resources Research Institute of Genetic and Developmental BiologyChinese Academy of SciencesShijiazhuang 050022China Ruakura Research Centre AgResearch LimitedHamilton 3240New Zealand

Although China has achieved great advancements toward national food security,the country is still confronted with a range of challenges,including natural resource stress,imbalanced diets and environmental *** management of crop–livestock systems is the key measure to realize agricultural green ***,optimized management of crop–livestock systems that use multi-objective zoning is *** study employed a multi-objective zoning management approach to comprehensively analyze four indicators:ammonia volatilization,nitrogen surplus,soil carrying capacity and ecological red line *** its significant ecological integrity and a strong emphasis on sustainability,the Baiyangdian Basin serves as a unique and suitable test case for conducting analyses on multi-objective nutrient optimization management,with the aim to facilitate the agricultural green *** study finds that less than 8%of the area in the Baiyangdian Basin meet the acceptable environmental indicator standard,whereas around 50%of the area that had both nitrogen surplus and ammonia volatilization exceeded the *** of unified management,that is,the same management technique across the study areas,could result in an increase of areas meeting environmental indicator thresholds to 21.1%.This project developed a novel multi-indicator partition optimization method,in which distinct measures are tailored for different areas to satisfy multiple environmental *** of this method,could potentially bring more than 50%area below the threshold,and areas with ammonia emissions and nitrogen surplus could be reduced to 15.8%.The multi-indicators partition optimization method represents a more advanced and efficiency-oriented management approach when compared to unified *** approach could be regarded as the best available option to help China achieve agricultural transformation to improve efficient production and reduce e

关键词： Agricultural green development Baiyangdian Basin environmental emission threshold partition management

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Dealloyed TiCuMn efficiently catalyze the NO reduction and Zn-NO batteries

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Frontiers of Chemical Science and Engineering 2024年第9期18卷 51-59页

作者： Lang Zhang Tong Hou Weijia Liu Yeyu Wu Tianran Wei Junyang Ding Qian Liu Jun Luo Xijun Liu State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China Education Department of Guangxi Zhuang Autonomous Region Key Laboratory of Applied Analytical ChemistryGuangxi Collaborative Innovation Center for Chemistry and Engineering of Forest ProductsGuangxi Key Laboratory of Chemistry and Engineering of Forest ProductsKey Laboratory of Chemistry and Engineering of Forest ProductsState Ethnic Affairs CommissionSchool of Chemistry and Chemical EngineeringGuangxi Minzu UniversityNanning 530006China institute for new Energy Materials&Low-Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China institute for advanced study Chengdu UniversityChengdu 610106China ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of ChinaShenzhen 518110China

Electrocatalytic NO reduction reaction offers a sustainable route to achieving environmental protection and NH3 production targets as *** this work,a class of dealloyed Ti_(60)Cu_(33)Mn_(7)ribbons with enough nanoparticles for the high-efficient NO reduction reaction to NH_(3)is fabricated,reaching an excellent Faradaic efficiency of 93.2%at–0.5 V vs reversible hydrogen electrode and a high NH3 synthesis rate of 717.4μmol·h^(-1)·mgcat.-1 at–0.6 V vs reversible hydrogen *** formed nanoparticles on the surface of the catalyst could facilitate the exposure of active sites and the transportation of various reactive ions and ***,the Mn content in the TiCuMn ribbons modulates the chemical and physical properties of its surface,such as modifying the electronic structure of the Cu species,optimizing the adsorption energy of N^(*)atoms,decreasing the strength of the NO adsorption,and eliminating the thermodynamic energy barrier,thus improving the NO reduction reaction catalytic ***,a Zn-NO battery was fabricated using the catalyst and Zn plates,generating an NH3 yield of 129.1µmol·h^(-1)·cm^(-2)while offering a peak power density of 1.45 mW·cm^(-2).

关键词： nitric oxide reduction NH3 electrosynthesis TiCuMn alloy Mn modulation Zn-NO battery

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Fine mapping of the powdery mildew resistance gene PmXQ-0508 in bread wheat

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The Crop Journal 2024年第4期12卷 1176-1184页

作者： Zejun Qian Guohao Han Ningning Yu Cheng Liu Ran Han Paula E.Jameson Jiaojiao Wang Ya Zhao Bei Xiao Ruishan Liu Jiadong Zhang Yuli Jin Hongjie Li Pengtao Ma Yantai Key Laboratory of Characteristic Agricultural Biological resources Conservation and Germplasm Innovative Utilization College of Life SciencesYantai UniversityYantai 264005ShandongChina Center for Agricultural resources Research Institute of Genetics and Developmental BiologyChinese Academy of SciencesShijiazhuang 050021HebeiChina Crop Research institute Shandong Academy of Agriculture SciencesJinan 250100ShandongChina School of Biological Sciences University of CanterburyChristchurch 8140CanterburyNew Zealand The National Engineering Laboratory of Crop Molecular Breeding Institute of Crop SciencesChinese Academy of Agricultural SciencesBeijing 100081China

In a wheat breeding line XQ-0508 showing consistent resistance to powdery mildew disease,a recessive gene,designated PmXQ-0508,was identified and mapped to a distal region on chromosome arm *** three resistance-associated genes in this region,one encoding a protein kinase was selected as the primary candidate for *** closely linked DNA markers developed in the study could be used for marker-assisted selection for powdery-mildew resistance in breeding programs.

关键词： Wheat powdery mildew PmXQ-0508 BSR-Seq Fine mapping Marker-assisted selection

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Analysis of Sea Surface Temperature Cooling in Typhoon Events Passing the Kuroshio Current

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Journal of Ocean University of China 2024年第2期23卷 287-303页

作者： HU Yuyi SHAO Weizeng SHEN Wei ZUO Juncheng JIANG Tao HU Song College of Marine Sciences Shanghai Ocean UniversityShanghai 201306China East China Sea Environment Monitoring Ministry of Natural ResourcesShanghai 201206China China Waterborne Transport Research institute Ministry of TransportBeijing 100088China

The aim of this study is to investigate the sea surface temperature(SST) cooling as typhoons pass the Kuroshio Current.A numerical circulation model,denoted as the Stony Brook Parallel Ocean Model(sbPOM),was used to simulate the SST,which includes four wave-induced effect terms(i.e.,radiation stress,nonbreaking waves,Stokes drift,and breaking waves) simulated using the third-generation wave model,called WAVEWATCH-Ⅲ(WW3).The significant wave height(SWH) measurements from the Jason-2 altimeter were used to validate the WW3-simulated results,yielding a root mean square error(RMSE) of less than 0.50 m and a correlation coefficient(COR) of approximately *** water temperature measured from the advanced Research and Global Observation Satellite was applied to validate the model ***,the RMSE of the SST is 0.92℃ with a COR of approximately *** revealed in the sbPOM-simulated SST fields,a reduction in the SST at the Kuroshio Current region was observed as a typhoon passed,although the water temperature of the Kuroshio Current is relatively *** variation of the SST is consistent with that of the current,whereas the maximum SST lagged behind the occurrence of the peak ***,the Stokes drift plays an important role in the SST cooling after analyzing four wave-induced terms in the background of the Kuroshio *** sensitivity experiment also showed that the accuracy of the water temperature was significantly reduced when including breaking waves,which play a negative role in the inside part of the *** variation in the mean mixing layer depth(MLD) showed that a typhoon could enhance the mean MLD in the Kuroshio Current area in September and October,whereas a typhoon has little influence on the mean MLD in the Kuroshio Current area in ***,the mean MLD rapidly decreased with the weakening of the strong wind force and wave-induced effects when a typhoon crossed the Kuroshio Current.

关键词： typhoon wave sea surface temperature Kuroshio Current

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