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Change in Grain-Size Composition of Lignite under Cyclic Freezing-Thawing and Wetting-Drying

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Natural Resources 2024年第1期15卷 17-27页

作者： Natalia S. Batugina Vladislav I. Fedorov Chersky institute of Mining of the North Siberian Branch russian academy of sciences Yakutsk Russia

The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.

关键词： Lignite Freezing-Thawing Cycle Wetting-Drying Cycle Grain Size Composition Dust Coal Storage Loss Quality

Plasma electrolytic formation and characterization of MnWO_(4)/WO_(3) film heterostructures

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ChemPhysMater

ChemPhysMater 2024年第3期3卷 293-302页

作者： M.S.Vasilyeva I.V.Lukiyanchuk Yu.B.Budnikova V.G.Kuryavyi D.H.Shlyk G.A.Zverev Department of Chemistry and Materials of institute of High Technology and Advanced Materials Far Eastern Federal UniversityFEFU CampusVladivostok 690922Russia institute of Chemistry Far Eastern BranchRussian Academy of SciencesVladivostok 690022Russia

MnWO_(4)/WO_(3) p-n heterojunction films were fabricated using a one-step method consisting of the plasma electrolytic oxidation(PEO)of titanium in homogeneous electrolytes containing paratungstate ions and stable watersoluble EDTA-chelated *** influences of the formation current density and W:Mn molar ratio of the electrolyte,which was varied from 1:2 to 2:1,on the composition,morphology,and optical and photocatalytic properties of the resulting coatings were studied.X-ray diffraction analysis,scanning electron microscopy,energy dispersive X-ray analysis,Raman spectroscopy,and ultraviolet diffuse reflectance spectroscopy were used to characterize the formed *** of the W:Mn ratio of the electrolyte,the coatings contained crystalline t-WO_(3) and m-MnWO_(4).Depending on the formation conditions,the optical band gap energies of the composites varied from 2.63 to 3.01 *** largest absorption red shift and lowest band gap energy were observed in the film composite formed in an electrolyte with W:Mn=2:1,at a current density of 0.2 A cm^(−2).Composites obtained in electrolytes with W:Mn ratios of 2:1 and 1:1 exhibited photocatalytic activity in the degradation of rhodamine C and methyl orange dyes in the presence of 10 mmol L^(–1) H_(2)O_(2) under ultraviolet and visible light *** role of hydrogen peroxide in this dye degradation on PEO-coated composites under light irradiation is discussed.

关键词： Plasma electrolytic oxidation Manganese tungstate Tungsten oxide Titanium Optical properties p-n heterojunction

Kaapvaal lamproite melts(aka orangeites):A new type of alkalicarbonate liquid?insights from olivine-hosted multiphase inclusions(Silvery Home,South Africa)

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Geoscience Frontiers 2024年第5期15卷 308-322页

作者： Adam Abersteiner Alexey Tarasov Alexander Golovin Geoffrey H.Howarth Vadim S.Kamenetsky Department of Geosciences and Geography Research Programme of Geology and Geophysics(GeoHel)University of HelsinkiFinland institute for Sustainability Energy and ResourcesThe University of AdelaideAdelaide SA-5005Australia Department of Earth sciences School of Physical SciencesThe University of AdelaideAdelaide SA-5005Australia V.S.Sobolev institute of Geology and Mineralogy Siberian Branch Russian Academy of SciencesRussia Department of Geological sciences University of Cape TownRondebosch 7701South Africa Center of Deep Sea Research Institute of OceanologyChinese Academy of Sciences266071 QingdaoChina

Kaapvaal lamproites(aka orangeites)are a group of volatile-rich(H_(2)O,CO_(2)),micaceous,ultrapotassic igneous rocks that are unique to the Kaapvaal craton in southern ***,the composition of the melts that give rise to these rocks remains poorly understood due to overprinting effects of contamination by mantle and crustal material,volatile exsolution,fractional crystallisation and post-magmatic ***,this lack of reliable data on the initial composition of the Kaapvaal lamproite melts hampers our understanding of their source,petrogenesis and ascent *** is a common mineral comprising the Kaapvaal lamproites that has both xenocrystic(i.e.,mantle)and magmatic *** inclusions(melt/fluid)entrapped within olivine have been consistently demonstrated as an effective tool for gaining fundamental insights into the composition and evolution of melts that produce both kimberlites and lamproites,prior to processes,such as eruption,devolatization and syn-/post-magmatic *** this study,multiphase inclusions of both secondary and pseudosecondary origin hosted in olivine from a Kaapvaal lamproite(Silvery Home,South Africa)provide novel insights into the composition of the melt(s)that initially transported olivine to the surface and then crystallised after emplacement to form the lamproite *** inclusions in our study contain daughter mineral assemblages consisting of diverse Ca-Mg carbonates,including K-,Na-,Ba-,and Sr-bearing varieties,moderate K-rich silicates(phlogopite,tetraferriphlogopite),and subordinate oxides,phosphates,sulphides,sulphates,and *** on these daughter mineral assemblages,we suggest that the composition of the melt entrapped by olivine was SiO_(2)-poor,Ca-Mg carbonate-rich and contained elevated concentrations of K,Na,Ba,Sr,P and *** mineral and reconstructed melt compositions are in stark contrast to the mineral association of the groundmass and the bulk-rock composition

关键词： Lamproite Kaapvaal Multiphase inclusions Olivine Orangeite

Chlorogenic acid ameliorates heart failure by attenuating cardiomyocyte ferroptosis Author links open overlay panel

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Journal of Traditional Chinese Medical sciences 2024年第2期11卷 191-198页

作者： Kai Huang Fanghe Li Jiayang Tang Haiyin Pu Vasily Sukhorukov Alexander N.Orekhov Shuzhen Guo School of Traditional Chinese Medicine Beijing University of Chinese MedicineBeijing102488China Laboratory of Angiopathology Institute of General Pathology and PathophysiologyRussian Academy of Medical SciencesMoscow125315Russia

Objective To elucidate the effects of chlorogenic acid(CGA),a bioactive polyphenol compound prevalent in traditional Chinese medicine and various foods,including Lonicera japonica Thunb.(Jin Yin Hua),Eucommia ulmoides Oliv.(Du Zhong Ye),tea,and coffee,on cardiomyocyte ferroptosis and heart *** We assessed the effect of CGA on cardiac function using a mouse model of heart failure induced by transverse aortic constriction(TAC).These indicators included the left ventricular ejection fraction(LVEF),fractional shortening(LVFS),end-systolic volume(LVESV),end-diastolic volume(LVEDV),end-systolic diameter(LVESD),and end-diastolic diameter(LVEDD).An isoprenaline hydrochloride(ISO)-induced H9c2 cardiomyocyte cell model was also established,and the cells were treated with various concentrations of *** assess the effect of CGA on ferroptosis in cardiomyocytes,we measured cell viability and evaluated the levels of intracellular reactive oxygen species(ROS),ferrous ions(Fe^(2+)),and lipid peroxidation using fluorescent *** clarify the ferroptosis signaling pathway regulated by CGA,western blotting was used to examine the expression of ferroptosis biomarkers,specifically solute carrier family 7 member 11(SLC7A11)and glutathione peroxidase 4(GPX4),in H9c2 cardiomyocytes and mouse myocardial *** CGA significantly enhanced cardiac performance indices such as LVEF,LVFS,LVESV,LVEDV,LVESD,and LVEDD.H9c2 cardiomyocytes exposed to ISO showed decreased cell viability and increased ROS levels,Fe^(2+)content,and lipid peroxidation ***,CGA treatment significantly ameliorated these ***,in both H9c2 cardiomyocytes and myocardial tissue obtained from mice with TAC,CGA increased the expression of ferroptosis-related proteins,including SLC7A11 and *** CGA has the potential to enhance cardiac function and diminish lipid peroxidation and ROS levels in cardiomyocytes via the SLC7A11/GPX4 signaling *** process alleviat

关键词： Chlorogenic acid Heart failure Ferroptosis H9c2 cardiomyocyte Traditional Chinesemedicine

A progress review of black carbon deposition on Arctic snow and ice and its impact on climate change

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Advances in Polar Science 2024年第2期35卷 178-191页

作者： ZHANG Zilu ZHOU Libo ZHANG Meigen Department of Lower Atmosphere Observation Research(LAOR) Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Science University of Chinese Academy of SciencesBeijing 100049China State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China

The rapid warming of the Arctic,accompanied by glacier and sea ice melt,has significant consequences for the Earth’s climate,ecosystems,and *** carbon(BC)deposition on snow and ice can trigger a significant reduction in snow albedo and accelerate melting of snow and ice in the *** reviewing the published literatures over the past decades,this work provides an overview of the progress in both the measurement and modeling of BC deposition and its impact on Arctic climate *** summary,the maximum value of BC deposition appears in the western russian Arctic(26 ng·g^(–1)),and the minimum value appears in Greenland(3 ng·g^(–1)).BC records in the Arctic ice core already peaked in 1920s and 1970s,and shows a regional difference between Greenland and Canadian *** different temporal variations of Arctic BC ice core records in different regions are closely related to the large variability of BC emissions and transportation processes across the Arctic *** simulations usually underestimate the concentration of BC in snow and ice by 2–3 times,and cannot accurately reflect the seasonal and regional changes in BC *** deposition is the main removal mechanism of BC in the Arctic,and observations show different seasonal variations in BC wet deposition in Ny-Ålesund and *** discrepancy may result from varying contributions of anthropogenic and biomass burning(BB)emissions,given the strong influence by BC from BB emissions at *** BC deposition significantly influences regional climate change in the Arctic,increasing fire activities in the Arctic have made BB source of Arctic BC more *** average,BC in Arctic snow and ice causes an increase of+0.17 W·m^(–2)in radiative forcing and 8 Gt·a^(–1)in runoff in *** stressed in the latest Arctic Monitoring and Assessment Programme report,reliable source information and long-term and high-resolution observations on Arctic BC deposition will be crucial for a more comp

关键词： Arctic climate black carbon albedo snow deposition

Water Photomolecular Evaporation Due to Light-Mediated Ortho-Para Spin Transitions

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Open Journal of Applied sciences 2024年第8期14卷 2201-2206页

作者： Sergey Pershin Irina Bjørnø Michael Grishin Prokhorov General Physics institute of the russian academy of sciences Moscow Russia RKMD Copenhagen Denmark

Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis that this effect can be explained by ortho-para magnetic spin interactions in water molecules within the water-air interface layer. Water molecules, consisting of hydrogen and oxygen, exhibit different nuclear spin states: ortho-(triplet) and para-(singlet). The interaction of polarized light with these spin states may induce transitions between the rotational levels of ortho- and para-forms due to catalysts like triplet oxygen (O2) in its inhomogeneous magnetic field. Resonance pumping at 532 nm (~18,797 cm−1) due to the transition v1-v2-v3 ~ 0-8-2 (~18,796 cm−1) results in an increase in molecular energy sufficient to overcome intermolecular forces at the water surface, thereby causing evaporation. The proposed ortho-para conversion mechanism involves spin-orbit coupling and specific resonance conditions. This theory provides a quantum mechanical perspective on the photomolecular effect, potentially offering insights into natural processes such as cloud formation and climate modeling, as well as practical applications in solar desalination and industrial drying. Further experimental validation is required to confirm the role of spin interactions in light-induced water evaporation.

关键词： Ortho-Para Spin Transition Water Structure Evaporation Theory Photo Molecular Effect

Gut Microbiota and Cytokine Profile in Cirrhosis

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Journal of Clinical and Translational Hepatology 2024年第8期12卷 689-700页

作者： Irina Efremova Roman Maslennikov Anna Kudryavtseva Anastasia Avdeeva George Krasnov Mikhail Diatroptov Vyacheslav Bakhitov Salekh Aliev Natalia Sedova Maria Fedorova Elena Poluektova Oxana Zolnikova Nariman Aliev Anna Levshina Vladimir Ivashkin Department of Internal Medicine Gastroenterology and HepatologySechenov UniversityMoscowRussia Post-Genomic Research Laboratory Engelhardt Institute of Molecular BiologyRussian Academy of SciencesMoscowRussia V.A.Nasonova Research institute of Rheumatology MoscowRussia Consultative and Diagnostic Center 2 of the Moscow Health Department MoscowRussia First Hospital Surgery Department Pirogov Russian National Research Medical UniversityMoscowRussia Department of Clinical Laboratory Diagnostics FGBOU DPO“Russian Medical Academy of Continuing Professional Education of the Ministry of Health of the Russian Federation”MoscowRussia The Interregional Public Organization“Scientific Community for the Promotion of the Clinical Study” MoscowRussia

Background and Aims:Gut dysbiosis and abnormal cytokine profiles are common in *** study aimed to evaluate the correlations between ***:In the blood plasma of cirrhosis patients and controls,27 cytokines were examined using a multiplex *** plasma levels of nitrites(stable metabolites of the endothelial dysfunction biomarker nitric oxide)and lipopolysaccharide(LPS)were *** fecal microbiota was assessed by 16S rRNA gene ***:Levels of IL-1b,IL-2,IL-6,IL-13,IP-10,IFN-g,TNF-a,LPS,and nitrites were higher in cirrhosis patients than in controls,while levels of IL-4,IL-7,and PDGF-BB were *** LPS level was directly correlated with the levels of IL-1b,IL1-Ra,IL-9,IL-17,PDGF-BB,IL-6,TNF-a,and *** nitrite level was significantly directly correlated with the levels of TNF-a,GM-CSF,IL-17,and IL-12,and inversely correlated with the IL-7 ***-a levels were directly correlated with ascites severity and the abundance of Negativicutes,Enterobacteriaceae,Veillonellaceae,and Klebsiella,while inversely correlated with the abundance of Firmicutes,Clostridia,and ***-g levels were directly correlated with the abundance of Bacteroidaceae,Lactobacillaceae,Bacteroides,and Megasphaera,and inversely correlated with the abundance of Verrucomicrobiota,Akkermansiaceae,Coriobacteriaceae,Akkermansia,Collinsella,and ***-1b levels were directly correlated with the abundance of Comamonadaceae and Enterobacteriaceae and inversely correlated with the abundance of Marinifilaceae and ***-6 levels were directly correlated with the abundance of Enterobacteriaceae,hepatic encephalopathy,and ascites severity,and inversely correlated with the abundance of Peptostreptococcaceae,Streptococcaceae,and ***:The abundance of harmful gut microbiota taxa and endotoxinemia directly correlates with the levels of proinflammatory cytokines.

关键词： Endotoxin Leaky gut Gut microbiome Systemic inflammation Gut-liver axis Endotoxemia

Low Gilbert damping in Bi/In-doped YIG thin films with giant Faraday effect

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Chinese Physics B 2024年第10期33卷 419-426页

作者： Jin Zhan Yi Wang Xianjie Wang Hanxu Zhang Senyin Zhu Lingli Zhang Lingling Tao Yu Sui Wenqing He Caihua Wan Xiufeng Han V.I.Belotelov Bo Song School of Physics Harbin Institute of TechnologyHarbin 150001China Beijing National Laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of SciencesBeijing 100190China russian Quantum Center Moscow 119991Russia National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China Zhengzhou Research institute Harbin Institute of TechnologyZhengzhou 450046China Frontiers Science Center for Matter Behave in Space Environment Harbin Institute of TechnologyHarbin 150001China

Magnetic films with low Gilbert damping are crucial for magnonic devices,which provide a promising platform forrealizing ultralow-energy *** this study,low Gilbert damping and coercive field were observed in Bi/In-dopedyttrium iron garnet(BiIn:YIG)thin *** BiIn:YIG(444)films were deposited onto different substrates using pulsedlaser *** coercivity(<1 Oe)with saturation magnetization of 125.09 emu/cc was achieved along the in-planedirection of BiIn:YIG *** values of Gilbert damping and inhomogeneous broadening of ferromagnetic resonance inBiIn:YIG films were obtained to be as low as 4.05×10^(-4)and 5.62 Oe,*** addition to low damping,the giantFaraday rotation angles(up to 2.9×10^(4)deg/cm)were also observed in the BiIn:YIG *** modifying the magneticstructure and coupling effect between Bi^(3+)and Fe^(3+)of Bi:YIG,doped In^(3+)plays a key role on variation of the *** low damping and giant Faraday effect made the BiIn:YIG film an appealing candidate for magnonic andmagneto-optical devices.

关键词： magnonic device Gilbert damping Faraday effect

Economic and Strategic Synergy

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Beijing Review 2024年第22期67卷 18-19页

作者： Sun Zhuangzhi the institute of russian Eastern European and Central Asian Studies at the Chinese Academy of Social Sciences

russian President Vladimir Putin visited China on May 16-17,his 23rd trip to the country for state visits or international *** the visit,he engaged in extensivediscussion with Chinese President Xi Jinping,focusing on ... 详细信息

关键词： mutual visit Strategic