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New sustainable polymers with on-demand depolymerization property

Science China Chemistry 2024年第9期67卷 2803-2841页

作者： Yangyang Sun Zesheng An Yanshan Gao Rongrong Hu Ye Liu Hua Lu Xiao-Bing Lu Xuan Pang Anjun Qin Yong Shen Youhua Tao Yu-Zhong Wang Junpeng Wang Gang Wu Guang-Peng Wu Tie-Qi Xu Xing-Hong Zhang Yuetao Zhang Zhenbiao Zhang Jian-Bo Zhu Miao Hong Zhibo Li State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China State Key Laboratory Base of Eco-chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdao266042China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China State Key Laboratory of Fine chemicals Frontiers Science Center for Smart MaterialsDalian University of TechnologyDalian 116024China Beijing National Laboratory for Molecular Sciences Center for Soft Matter Science and EngineeringKey Laboratory of Polymer Chemistry and Physics of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)College of ChemistryState Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610064China School of Polymer Science and Polymer Engineering the University of AkronAkronOH 44325USA MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationSuzhou Key Laboratory of Macromolecular Design and Precision SynthesisCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable *** an emerging class of sustainable polymers,the development of chemically depolymerizable polymers(CDPs),which can undergo closed-loop depolymerization/repolymerization cycles to reproduce virgin polymers without the loss of properties from recovered monomers,offers an ideal solution to preserve finite natural resources,provides a feasible solution to the end-of-life issue of polymer waste,and thereby establishes a circular materials ***,two grand key challenges have been encountered in the establishment of practically useful CDPs:how to balance polymerization and depolymerization ability and how to unify conflicted depolymerizability and physical ***,this critical review article presents our vision for summarizing feasible strategies to overcome the above two significant challenges and the design principles for constructing an ideal CDP by highlighting selected major progress made in this rapidly expanding field.

关键词： chemically depolymerizable polymers sustainable polymers depolymerization monomer recovery degradation plastics

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Estimating the Operation Status of Steam Cracking Furnace Using Numerical Simulation with Combustion Models

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China Petroleum Processing & Petrochemical Technology 2012年第4期14卷 52-63页

作者： Zhou Xianfeng Yang Yuanyi Wang Guoqing Zhang Lijun Liu Yi College of chemical Engineering Beijing University of Chemical Technology Beijing Research institute of chemical industry SINOPEC

An accurate and complete geometric model was constructed to simulate the combustion, flow and temperature environment in the radiant section of the steam cracking furnace. Simulation of flow and radiation status has utilized the standard k-ε model and P1 model. The finite-rate/eddy-dissipation (finite-rate/ED) combustion model and non-premixed combustion model were both used to simulate accurately the combustion and the operation status of the steam cracking furnace. Three different surfaces of the steam cracking furnace were obtained from the simulation, namely:the flue gas temperature field of the entrance surface in long flame burners, the central surface location of tubes, and the crossover section surface. Detailed information on the flue gas temperature and the mass concentration fraction of these different surfaces in the steam cracking furnace can also be obtained by the simulation. This paper analyzed and compared the simulation results with the two combustion models, estimated the operation status of the steam cracking furnace, and reported that the finite-rate/ED model is appropriate to simulate the steam cracking furnace by comparing key simulation data with actual test data. This work has also provided a theoretical basis for simulating and operating the steam cracking furnace.

关键词： steam cracking furnace operation status combustion model numerical simulation flue gas

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Properties of oxide films grown on 25Cr20Ni alloy in air-H_2O and H_2-H_2O atmospheres

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Petroleum Science 2014年第1期11卷 147-154页

作者： Wang Shenxiang Cui Lishan Wang Guoqing Zheng Yanjun Wang Hongxia Jia Jingsheng College of Science China University of Petroleum Beijing Research institute of chemical industry

The oxidation kinetics,surface morphology and phase structure of oxide films grown on 25Cr20Ni alloy in air-H2O and H2-H2O atmospheres at 900 ℃ for 20 h were *** anti-coking performance and resistance to carburization of the two oxide films were compared using 25Cr20Ni alloy tubes with an inner diameter of 10 mm and a length of 850 mm in a bench scale naphtha steam pyrolysis *** oxidation kinetics followed a parabolic law in an air-H2O atmosphere and a logarithm law in a H2-H2O atmosphere in the steady-state *** oxide film grown in the air-H2O atmosphere had cracks where the elements Fe and Ni were enriched and the un-cracked area was covered with octahedral-shaped MnCr2O4 spinels and Cr1.3Fe0.7O3 oxide clusters,while the oxide film grown in the H2-H2O atmosphere was intact and completely covered with dense standing blade MnCr2O4 *** the pyrolysis tests,the anti-coking performance and resistance to carburization of the oxide film grown in the H2-H2O atmosphere were far better than that in the air-H2O *** mass of coke formed in the oxide film grown in the H2-H2O atmosphere was less than 10％ of that in the air-H2O *** Cr1.3Fe0.7O3 oxide clusters converted into Cr23C6 carbides and the cracks were filled with carbon in the oxide film grown in the air-H2O atmosphere after repeated coking and decoking tests,while the dense standing blade MnCr2O4 spinels remained unchanged in the oxide film grown in the H2-H2O *** ethylene,propylene and butadiene yields in the pyrolysis tests were almost the same for the two oxide films.

关键词： 25Cr20Ni alloy air-H2O H2-H2O oxide film anti-coking resistance to carburization

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Robust observer-based control for uncertain discrete-time piecewise affine systems

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控制理论与应用（英文版） 2012年第2期10卷 236-243页

作者： Yahui GAO 1 , Zhiyuan LIU 2 , Hong CHEN 3 1.AVIC (Aviation industry corporation of China) China Aviation Motor Control System institute, Wuxi Jiangsu 214063, China 2.Department of Control Science and Engineering, Harbin institute of Technology, Harbin Heilongjiang 150001, China 3.Department of Control Science and Engineering, jilin University, Changchun jilin 130025, China AVIC (Aviation industry corporation of China) China Aviation Motor Control System institute Wuxi Jiangsu China Department of Control Science and Engineering Harbin Institute of Technology Harbin Heilongjiang China Department of Control Science and Engineering Jilin University Changchun Jilin China

The main contribution of this paper is to present a novel robust observer-based controller design method for discrete-time piecewise affine systems with norm-bounded uncertainties. The key ideas are to construct a piecewise quadratic Lyapunov function to guarantee the stability of the closed-loop systems, approximate polytopic operating regions by ellipsoids, and use the singular value decomposition technique to treat the constraint of matrix equality. It is shown that the suggested control method can be formulated as linear matrix inequalities that are numerically feasible with commer- cially available software. A numerical example is also given to verify the proposed approach.

关键词： Piecewise affine systems Robust control Observer Linear matrix inequality

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Bimodal PE prepared with combined iron (II) and nickel (II) olefin polymerization catalysts

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Chinese Science Bulletin 2006年第1期51卷 115-116页

作者： WANG Shibo LIU Dongbing XU Renwei MAO Bingquan College of Science Beijing University of Chemical Technology Beijing 100029 China Polyolefins National Engineering and Research Center Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation Beijing 100013 China

Combined iron (II) and nickel (II) olefin polymerization catalysts could produce a kind of PE having the characters of ideal bimodal PE with ap- propriate conditions and catalysts. In the ethylene homopolymerization with triethylalkylaluminum (AlEt3) as the activator, the prepared bimodal PE contained not only branched PE of high molecular weight, but also linear PE of low molecular weight. And the amounts of both fractions were similar. Ideal bimodal PE resin was prepared in one polymerization reactor.

关键词：聚乙烯铁镍复合催化剂制备

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THE APPLICATION OF XPS FOR THE IDENTIFICATION OF ALLOTROPIC SINGLE CRYSTALS

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Chinese Science Bulletin 1982年第4期27卷 462-463页

作者：王殿勋李永津陈传正李少羽康炳杰 institute of Chemistry Academia Sinica institute of Physics Academia Sinica Research institute of jilin chemical industry corporation

As we know, chemical shift of XPS has been used for the identification of the atoms of a given element with non-equivalent lattice sites in a compound. Reports on the use of XPS for single crystal study have been very scanty and that on the use of technique for the identification of allotropic single crystal has been nil so *** single crystal is formed by thedifferent arrangements of the atoms in the cryatal which exhibit different X-ray diffraction data. By using these diffraction data, the fine valeuce-

关键词： identif anode feasible narrow

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YGS40, an active fraction of Yi-Gan San, reduces hydrogen peroxide-induced apoptosis in PC12 cells

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Chinese Journal of Natural Medicines 2015年第6期13卷 438-444页

作者： ZHAO Yu-Rong QU Wei LIU Wen-Yuan HONG Hao FENG Feng CHEN Han XIE Ning Department of Natural Medicinal Chemistry China Pharmaceutical University Department of Pharmaceutical Analysis China Pharmaceutical University Department of Pharmacology China Pharmaceutical University New Technology Center of chemical Pharmaceutical Shanghai institute of Pharmaceutical industry China State institute of Pharmaceutical industry Jiangxi Qingfeng Pharmaceutical corporation

In our previous study, we have elucidated the chemical profile ofYGS40, a fraction of Yi-Gan San （YGS）, used for the treatment of Alzheimer＇s disease （AD）. Oxidative stress-induced apoptosis is implicated in neurodegenerative disorders such as AD. The aim of the present study was to explore the protective effects of YGS40 against hydrogen peroxide （H202）-induced apoptosis in PC12 cells and the underlying mechanisms. PC12 cells were exposed to 100 μmol·L 1 of H202 for 12 h with or without YGS40 pretreatment. Cytotoxicity was determined by MTT （3, （4, 5-dimethylthiazole-2-yl） 2, 5-diphenyl-tetrazolium bromide） and lactate dehydrogenase （LDH） release assays; apoptosis was detected by Annexin V/propidium iodide coupled staining and by determining caspase-3 activity and Bax and Bcl-2 protein levels. Mitochondrial membrane potential （MMP） was assessed by the retention of rhodamine123; and the activities of superoxide dismutase （SOD） and malondialdehyde （MDA） were measured using commercially available enzymatic kits. Pretreatment with YGS40 significantly prevented H2O2-induced cytotoxicity and protected the cells against H2O2-triggered apoptosis characterized by extemalization of membrane phosphatidylserine and caspase-3 activation and the increased ratio of Bax/Bcl-2 in PC12 cells. Further studies showed that YGS40 suppressed H2O2-induced MMP loss, increased SOD activity, and decreased MDA level. These findings suggest that YGS40 may be beneficial for the prevention and treatment of oxidative stress-mediated disorders.

关键词： YGS40 Yi-Gan San Hydrogen peroxide Antioxidant effects Apoptosis

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Applied catalysis for sustainable development of chemical industry in China

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National Science Review 2015年第2期2卷 167-182页

作者： Zaiku Xie Zhicheng Liu Yangdong Wang Zhonghao Jin China Petroleum & chemical corporation Sinopec Shanghai Research institute of Petrochemical Technology

Progressing green chemical technologies is signiicant to the sustainable development of chemical industry in China, as the energy and environment problems increasingly became great challenges to the whole society. he scientiic connotation of sustainable energy chemical engineering can be generalized as green carbon/hydrogen science which means optimization of carbon/hydrogen atom economics based on high eicient catalysis and low-carbon emission. his review illustrated recent advances in developing sustainable technologies for applied catalysis in chemical industry of China, including the ields of high eicient conversion of heavy oil, green petrochemical catalytic technologies, clean utilization of coal and natural gas, promoting sustainable resources and clean energy, etc. Moreover, from the view of industrial point, some important common scientiic problems were discussed and summarized, such as the relation between molecular difusion and catalyzing eiciency, homogeneous catalysis in heterogeneous catalysts,in situ or operando characterization of industrial catalysis, etc., aiming to supplying a forward roadmap to academia and/or industry.

关键词： applied catalysis catalytic eiciency green carbon/hydrogen science green petrochemical technology coal chemical technology bioma

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An air-stable single-crystal layered oxide cathode based on multifunctional structural modulation for high-energy-density sodium-ion batteries

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Science China Chemistry 2024年

作者： Yi-Feng Liu Hai-Yan Hu Jia-Yang Li Hongrui Wang Yi Zhao Jingqiang Wang Yuan-Bo Wu Yan-Jiang Li Guang-Yu Zhang Qing-Qun Sun Yan-Fang Zhu Rui-Ren Tang Xiong-Wei Wu Jia-Zhao Wang Shi-Xue Dou Shu-Lei Chou Yao Xiao Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University School of Chemistry and Materials Science Hunan Agricultural University institute of Energy Materials Science University of Shanghai for Science and Technology Wenzhou Key Laboratory of Sodium-Ion Batteries Wenzhou University Technology Innovation Institute for Carbon Neutralization institute for Carbon Neutralization College of Chemistry and Materials Engineering Wenzhou University College of Chemistry and chemical Engineering Central South University

P2-type layered oxide, Na2/3Ni1/3Mn2/3O2, has drawn particular interest as a promising cathode material for sodium-ion batteries(SIBs) due to its fast sodium-ion transport channels with low migration potential. However, some catastrophic flaws, such as air instability, complicated multiphase evolution, and irreversible anionic redox, limit its electrochemical performance and hinder its application. Here, an air-stable single-crystal P2-type Na2/3Ni1/3Mn1/3Ti1/3O2is proposed based on the multifunctional structural modulation of Ti substitution that could alleviate the issues for practical SIBs. As a result, the cathode with high energy density shows excellent air stability and highly reversible phase transitions(P2–OP4), and delivers faster kinetics and stable anion redox chemistry. Meanwhile, a thorough investigation of the relationship between structure, function, and properties is demonstrated,emphasizing formation processes, electrochemical behavior, structural evolution, and air stability. Overall, this study provides the direction of multifunctional structural modulation for the development of high-performance sodium-based layered cathode materials for practical applications.

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STUDY ON STYRENE-BUTADIENE BLOCK COPOLYMER FOR THE MODIFICATI0N OF TIRE TREAD

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Chinese Journal of Polymer Science 1996年第1期14卷 34-40页

作者：王岩陈伟洁穆瑞凤王用威余丰年刘青 Department of Polymer Science College of Chemical Engineering Dalian University of Technology Dalian 116012 chemical Engineering Research institute of Yanshan chemical industry corporation Beijing 102400

This paper mainly deals with the design and synthesis of a novel styrene-butadieneblock copolymer. When this copolymer is used in the tread portion of tyres, it can improvewet skid resistance and reduce rolling resistance without sacrificing its general physical-mechanical properties. The visco-elastic curve of tire tread using the novel copolymer asits rubber portion was showed. Reactivity ratios for two monomers in the polymerizingsystem were calculated. The diagrams of differelitial, integral and finite difference calculithroughout the whole molecular chain were presented. The influence of the micro- andmacro-structure of the copolymer chain on wet skid resistance and rolling resistance wasdiscussed

关键词： Anionic solution polymerization Diblock copolymer of styrene and butadiene Rolling resistance Wet skid resistance Visco-elastic property

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