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Synthesis of reduced graphene oxide nanosheets from sugarcane dry leaves by two-stage pyrolysis for antibacterial activity

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Nano Materials Science 2024年第5期6卷 625-634页

作者： Baskar Thangaraj Pravin Raj Solomon Nutthapon Wongyao Mohamed I.Helal Ali Abdullah Sufian Abedrabbo Jamal Hassan Department of Physics Khalifa UniversityAbu Dhabi127788United Arab Emirates Molecular Epidemiological Diagnostic research Facility Department of ImmunologySchool of Biological SciencesMadurai Kamaraj UniversityMadurai625021Tamil NaduIndia fuel Cells and Hydrogen research and Engineering Center Pilot Plant Development and Training InstituteKing Mongkut's University of Technology ThonburiBangkok10140Thailand CORE Lab Specialist Electron Microscopy Core LabsKhalifa UniversityAbu Dhabi127788United Arab Emirates

Oxidative-exfoliation methods were in vogue in the production of rGO from *** of such synthetic graphite needs high temperatures(2500℃).Thus,such process is not *** present study is made on the dry leaves of sugarcane(Saccharum officinarum)as an alternative raw material so as to be economical and environmentally *** dry leaves are subjected to two-step pyrolysis without any catalyst or reducing agent in far divergent temperatures to produce as prepared and acid treated *** were evaluated by UV–Vis.,FTIR,XRD,Raman spectroscopy,TGA/DTG,BET,FESEM-EDS and *** as prepared rGO has few layers with irregular and folded architecture whereas acid-treated rGO has thinly stacked crumpled sheets with many wrinkles on its *** prepared rGOs have multilayered graphitic structure due to the unique ratio between G and D *** treated rGO has poor thermal stability as compared to that of as-prepared rGO at high temperatures due to the variation in the oxygen-containing functional *** treated rGO has low antibacterial activity as compared to that of the as-prepared rGO due to the paucity of the functional groups.

关键词： Biomass wastes Sugarcane dry leaves Pyrolysis Reduced graphene oxide Antibacterial activity

Honeycomb-like polyaniline for flexible and folding all-solid-state supercapacitors

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Frontiers of Materials Science 2019年第2期13卷 133-144页

作者： Ge JU Muhammad Arif KHAN Huiwen ZHENG Zhongxun AN Mingxia WU Hongbin ZHAO Jiaqiang XU Lei ZHANG Salma BILAL Jiujun ZHANG NEST Lab Department of Chemistry College of Sciences Shanghai University Shanghai 200444China School of Materials Science and Engineering Shanghai University Shanghai 200444 China National Engineering research Center for Supercapacitor for Vehicles Shanghai AOWEI Technology Development Co. Ltd. Shanghai 201203 China institute for fuel Cell Innovation National Research Council of Canada 4250 Wesbrook Mall Vancouver Canada National Centre of Excellence in Physical Chemistry University of Peshawar 25120 Peshawar Pakistan institute of Sustainable Energy Shanghai University Shanghai 200444 China

Porous polyaniline (PANI) was prepared through an efficient and costeffective method by polymerization of aniline in the NaCl solution at room temperature. The resulting PANI provided large surface area due to its highly porous structure and the intercrossed nanorod, resulting in good electrochemical performance. The porous PANI electrodes showed a high specific capacitance of 480 F·g^-1, 3 times greater than that of PANI without using the NaCl solution. We also make chemically crosslinked hydrogel film for hydrogel polymer electrolyte as well as the flexible supercapacitors (SCs) with PANI. The specific capacitance of the device was 234 F·g^-1 at the current density of 1 A·g^-1. The energy density of the device could reach as high as 75 W·h·kg^-1 while the power density was 0.5 kW·kg^-1, indicating that PANI be a promising material in flexible SCs.

关键词： PANI honeycomb-like nanostructure all-solid-state SC electrochemical property

Improvement on hydrogen generation properties of Zr(BH4)4·8NH3

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Progress in Natural Science:Materials International 2021年第1期31卷 41-46页

作者： D.F.Wu L.Z.Ouyang J.M.Huang J.W.Liu H.Wang X.S.Yang H.Shao M.Zhu School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials South China University of Technology Guangdong research institute of Rare Metals Guangdong Key Laboratory of Rare Earth Development and Application China-Australia Joint Laboratory for Energy & Environmental Materials Key Laboratory of Fuel Cell Technology of Guangdong Province Advanced Manufacturing Technology research Centre Department of Industrial and Systems Engineering The Hong Kong Polytechnic University Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering (IAPME) University of Macau

Hydrolysis of Zr(BH4)4·8NH3in deionized water can generate high purity hydrogen at room ***, the sluggish hydrolysis kinetics of Zr(BH4)4·8NH3hinders its practical use. To improve its hydrogen generation properties, the effects of magnetic stirring, changing hydrolysis solution and tuning the ammonia coordination number on the hydrolysis properties of Zr(BH4)4·8NH3were investigated. Results show that both changing hydrolysis solution and tuning the ammonia coordination number can enhance the hydrolysis *** hydrolysis kinetics properties of Zr(BH4)4·8NH3were significantly improved in MgCl2and *** Zr(BH4)4·8NH3(x ≤ 8) samples were synthesized by a ball-milling method with different ammonization time(10, 60 and 180 min). Both the hydrolysis kinetics and hydrogen yield of Zr(BH4)4·8NH3(x ≤ 8) were enhanced as the ammonia coordination number(x) decreased. Thus, tuning ammonia coordination number is an effective way to control the hydrolysis properties of Zr(BH4)4·8NH3(x ≤ 8).

关键词： Hydrogen production Zr(BH 4 ) 4 ·8NH 3 Hydrolysis properties Ammonia coordination number

Progress and industrialization development trends of the anaerobic digestion technologies for bio-natural gas

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International Journal of Agricultural and Biological Engineering 2024年第4期17卷 1-12页

作者： Hongguang Zhu Fulu Lu Fanghui Pan School of Mechanical Engineering Tongji UniversityShanghai 201804China Bio-Energy research Center Institute of New Rural DevelopmentTongji UniversityShanghai 201804China

The production of bio-natural gas through anaerobic digestion not only realize the resource utilization and harmless treatment of urban and rural organic wastes,but also reduce the emission of methane and carbon ***,as an independently industry,bio-natural gas has some prominent challenges compared to household biogas and small-scale biogas *** the healthy development of the bio-natural gas industry,system analysis and planning have become particularly *** study reviews the current development status of the bio-natural gas industry and innovatively analyzes the development direction of industry from a multidimensional *** opinions are provided based on system *** major technological breakthroughs that have supported the success of regional bio-natural gas industry are *** completeness of industrial technology,the objectivity of industrial regional development and the inevitability of the comprehensive benefits of the industrial chain are the major development direction of the bio-natural ***,according to the three major demands of new energy fuel,electricity and energy storage,two new energy systems based on bio-natural gas and the synergistic development of multiple new energy sources are *** study provides theoretical and practical guidance for the bio-natural gas industry.

关键词： bio-natural gas anaerobic digestion technological progress industrialization sustainable development

Solar photocatalytic energy conversion

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Science Bulletin 2017年第9期62卷 597-598页

作者： Xuxu Wang Dengwei Jing Meng Ni State Key Laboratory of Photocatalysis on Energy and Environment Research Institute of HotocatalysisCollege of ChemistryFuzhou UniversityFuzhou 350l16China International research Center for Renewable Energy Xi'an Jiaotong UniversityXi'an 710049China Environmental Energy research Group Research Institute for Sustainable Urban Development(RISUD)The Hong Kong Polytechnic UniversityHong KongChina

development of clean and renewable energy sources is an inevitable choice of human society to address the energy shortage and environmental deterioration problems *** has been recognized as the most ideal and clean fu... 详细信息

关键词： BDD OER

Numerical simulation of a direct internal reforming solid oxide fuel cell using computational fluid dynamics method

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第7期9卷 961-969页

作者： Jun LI Ying-wei KANG Guang-yi CAO Xin-jian ZHU Heng-yong TU Jian LI institute of fuel Cell Department of Automalion Shanghai Jiao Tong University Shanghai 200240 China College of Materials Science and Engineering Huazhong University of Science and Technology Wuhan 430074 China

A detailed mathematical model of a direct internal reforming solid oxide fuel cell(DIR-SOFC) incorporating with simulation of chemical and physical processes in the fuel cell is presented. The model is developed based on the reforming and electrochemical reaction mechanisms,mass and energy conservation,and heat transfer. A computational fluid dynamics(CFD) method is used for solving the complicated multiple partial differential equations(PDEs) to obtain the numerical approximations. The resulting distributions of chemical species concentrations,temperature and current density in a cross-flow DIR-SOFC are given and analyzed in detail. Further,the influence between distributions of chemical species concentrations,temperature and current density during the simulation is illustrated and discussed. The heat and mass transfer,and the kinetics of reforming and electrochemical reactions have significant effects on the parameter distributions within the cell. The results show the particular characteristics of the DIR-SOFC among fuel cells,and can aid in stack design and control.

关键词： Direct internal reforming (DIR) Solid oxide fuel cell (SOFC) Computational fluid dynamics (CFD) Numerical simulation

Deep Learning-Based Robust Morphed Face Authentication Framework for Online Systems

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Computers, Materials & Continua 2023年第10期77卷 1123-1142页

作者： Harsh Mankodiya Priyal Palkhiwala Rajesh Gupta Nilesh Kumar Jadav Sudeep Tanwar Osama Alfarraj Amr Tolba Maria Simona Raboaca Verdes Marina Department of Computer Science and Engineering Institute of TechnologyNirma UniversityAhmedabad382481India Computer Science Department Community CollegeKing Saud UniversityRiyadh11437Saudi Arabia Doctoral School University Politehnica of BucharestBucharest060042Romania Department of Hydrogen and fuel Cell National Research and Development Institute for Cryogenics and Isotopic TechnologiesRamnicu Valcea240050Romania Department of Building Services Faculty of Civil Engineering and Building ServicesTechnical University of Gheorghe AsachiIasi700050Romania

The amalgamation of artificial intelligence(AI)with various areas has been in the picture for the past few *** has enhanced the functioning of several services,such as accomplishing better budgets,automating multiple tasks,and data-driven *** hassle-free polling has been one of ***,at the onset of the coronavirus in 2020,almost all worldly affairs occurred online,and many sectors switched to digital *** allows attackers to find security loopholes in digital systems and exploit them for their lucrative *** paper proposes a three-layered deep learning(DL)-based authentication framework to develop a secure online polling *** provides a novel way to overcome security breaches during the face identity(ID)recognition and verification process for online polling *** verification is done by training a pixel-2-pixel Pix2pix generative adversarial network(GAN)for face image reconstruction to remove facial objects present(if any).Furthermore,image-to-image matching is done by implementing the Siamese network and comparing the result of various metrics executed on feature embeddings to obtain the outcome,thus checking the electorate credentials.

关键词： Artificial intelligence discriminator generator Pix2pix GANs Kullback-Leibler(KL)-divergence online voting system Siamese network

High-performance and robust high-temperature polymer electrolyte membranes with moderate microphase separation by implementation of terphenyl-based polymers

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Journal of Energy Chemistry 2024年第5期92卷 572-578页

作者： Jinyuan Li Congrong Yang Haojiang Lin Jicai Huang Suli Wang Gongquan Sun Division of fuel Cells and Battery Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Key Laboratory of fuel Cells&Hybrid Power Sources Chinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of Sciences Beijing 100039China

Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel *** overcome these barriers,poly(terphenyl piperidinium)s constructed from the m-and p-isomers of terphenyl were synthesized to regulate the microstructure of the *** rigid p-terphenyl units prompt the formation of moderate PA aggregates,where the ion-pair interaction between piperidinium and biphosphate is reinforced,leading to a reduction in the plasticizing *** a result,there are trade-offs between the proton conductivity,mechanical strength,and PA retention of the membranes with varied m/p-isomer *** designed PA-doped PTP-20m membrane exhibits superior ionic conductivity,good mechanical strength,and excellent PA retention over a wide range of temperature(80–160°C)as well as satisfactory resistance to harsh accelerated aging *** a result,the membrane presents a desirable combination of performance(1.462 W cm^(-2) under the H_(2)/O_(2)condition,which is 1.5 times higher than that of PBI-based membrane)and durability(300 h at 160°C and 0.2 A cm^(-2))in the fuel *** results of this study provide new insights that will guide molecular design from the perspective of microstructure to improve the performance and robustness of HT-PEMs.

关键词： fuel cell High-temperature polymer electrolyte membranes Microphase separation Poly(terphenyl piperidinium)s Phosphoric acid

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沸石催化甘蔗渣裂解制备多壁碳纳米管

燃料化学学报 2021年第10期49卷 1421-1434页

作者： ABOUL-ENEIN Ateyya A AWADALLAH Ahmed E EL-DESOUKI Doaa S ABOUL-GHEIT Noha AK Process development Division Egyptian Petroleum Research InstituteCairo 11727Egypt EPRI-Nanotechnology Center Egyptian Petroleum Research InstituteCairo 11727Egypt

通过催化热解农业废弃物甘蔗渣(SCB),采用两步工艺生产具有显著应用价值的碳纳米管(CNTs)。主要研究沸石催化剂(HZSM-5、HMOR和HY)、热解温度(450−700℃)和SCB/ZSM-5的比例(3−12)对SCB催化热解的影响,确定最佳工艺参数。随后,将第一步... 详细信息

通过催化热解农业废弃物甘蔗渣(SCB),采用两步工艺生产具有显著应用价值的碳纳米管(CNTs)。主要研究沸石催化剂(HZSM-5、HMOR和HY)、热解温度(450−700℃)和SCB/ZSM-5的比例(3−12)对SCB催化热解的影响,确定最佳工艺参数。随后,将第一步产生富含碳的热解产物用于第二步由Co-Mo/MgO催化生长CNTs。通过简单的两步工艺催化热解SCB生产CNTs。SCB的催化热解在半间歇式反应器(外径=4 cm,长度=90 cm)中进行,CNTs的生长在水平反应器(外径=2.5 cm,长度=100 cm)中进行。两个反应器通过玻璃管(直径0.6 cm,长度12 cm)连接并将热解产物从反应器I转移到反应器II。在半间歇式反应器中放入经过预处理的SCB和沸石催化剂,并以20℃/min加热到反应所需温度。随后,将0.5 g Co-Mo/MgO加入到水平反应器中作为CNTs的生长催化剂。在一个典型的实验中,将2 g沸石催化剂、24 g SCB放入半间歇式反应器,研究了不同种类沸石催化剂在500℃温度条件下对SCB热解的影响。接着,使用HZSM-5研究了不同温度(450−700℃)对SCB热解的影响。最后,研究了不同SCB/ZSM-5投料比例(SCB/ZSM-5=3、6、9、12)对SCB热解的影响。此外,水平反应器中的CNTs生长温度恒定为700℃。通过XRD、TPR和TPD进行催化剂表征。XRD谱图证实了催化剂存在MgO和Co_(3)O_(4),以及以小尺寸颗粒形式存在的CoMoO4和MgMoO4。使用XRD数据根据Scherrer方程计算45%Co-5%Mo/MgO催化剂的平均晶粒尺寸为25.8 nm。TPR分析表明,Co-Mo/MgO催化剂是由未反应的Co_(3)O_(4)以及混合氧化物组成。使用XRD数据,计算得到HZSM-5、HMOR和HY的平均晶粒尺寸分别为43、41和51 nm。NH3-TPD分析表明沸石催化剂存在大量的酸性位点。催化热解SCB结果表明,由HY和HZSM-5催化剂在500℃得到的挥发性产品(生物油和气体)的总收率值分别为34.4%和32.8%,而使用HMOR产生的这些挥发性产品的收率值最低(28.8%)。用HZSM-5催化热解SCB获得了最高的炭产量(23.1%)。然而,使用HMOR和HY热解催化剂产生的炭产量值较低,分别为15.8%和9.8%。使用TEM表征通过两步法生产的碳纳米管,并且测量了CNTs的外径。数据显示,用HZSM-5进行SCB热解产生了直径分布范围较宽的CNTs(10−56 nm),而用HMOR和HY热解催化剂则分别获得了直径较窄的CNTs(13−44 nm,12−28 nm)。拉曼光谱分析表明,使用HZSM-5作为SCB热解的催化剂可以生产最优的CNTs。研究了不同热解温度对CNTs产量的影响。结果显示,将热解温度从450℃提高到500℃,炭产率值从6.7%达到最佳值23.1%,接着增加温度至700℃,炭产量下降至16.7%。随后对不同温度下催化热解形成的炭产品进行TEM表征,结果显示,随着温度的升高炭产品中CNTs的比例下降,CNTs的直径范围变窄。拉曼光谱分析结果表明,在500和700℃形成的CNMs具有最少的缺陷。研究了投料比例对炭产品产量的影响,结果表明,SCB/ZSM-5的比例从3提高到12,生物油和气体的总产量从36.4%下降到32.8%,而生物炭的产量分别从63.6%增加到67.2%。根据催化剂的质量计算得到炭产量的最佳值是使用SCB/ZSM-5比例为6。使用TEM表征不同投料比例生产的炭产品,分析表征结果可得SCB/ZSM-5的比例为6,是形成具有良好质量的致密CNTs的最佳选择。并且不同投料比例的拉曼光谱显示,SCB/ZSM-5比例为6可以生产最优的CNTs。沸石类型(HZSM-5、HMOR和HY)、热解温度(450−700℃)和SCB/ZSM-5比例(3−12)影响CNTs和热解产物(气体、生物油和生物炭)的产量。实验结果表明,获得最高CNTs产量的条件为:热解温度为500℃、SCB/ZSM-5比例为6;获得最高生物油和气体总产量(40%)的条件为:热解温度为700℃、SCB/ZSM-5比例为12。TEM分析表明,使用HZSM-5催化剂在热解温度450℃只生成竹节状碳纳米管(BCNTs),而CNTs和碳纳米洋葱(CNO)是在较高温度热解温度(500−700℃)下产生的。使用SCB/ZSM-5的比例为6时,生成CNTs的直径分布范围最大(7−76 nm)。拉曼光谱分析表明,使用SCB/ZSM-5的比例为6时,形成的CNTs最优。该研究显示,在半间歇式反应器中催化热解SCB是生产CNTs的有效技术,通过对工艺和反应器的优化可以达到更好的效果。

关键词：碳纳米管 Co-Mo/MgO 热解甘蔗渣 ZSM-5沸石