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Perturbation of autophagy pathways in murine alveolar macrophage by 2D TMDCs is chalcogen-dependent

Journal of environmental Sciences 2024年第1期135卷 97-107页

作者： Xiaofei Zhou Weitao Jin Rui Zhang Xuan Mao Jianbo Jia Hongyu Zhou College of Science&Technology Hebei Agricultural UniversityHuanghua 061100China institute of environmental research at greater bay area Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006China

Increasing risks of incidental and occupational exposures to two-dimensional transition metal dichalcogenides(2D TMDCs)due to their broad application in various areas raised their public health concerns.While the composition-dependent cytotoxicity of 2D TMDCs has been well-recognized,how the outer chalcogenide atoms and inner transition metal atoms differentially contribute to their perturbation on cell homeostasis at non-lethal doses remains to be identified.In the present work,we compared the autophagy induction and related mechanisms in response to WS_(2),NbS_(2),WSe_(2)and Nb Se_(2)nanosheets exposures in MH-S murine alveolar macrophages.All these 2D TMDCs had comparable physicochemical properties,overall cytotoxicity and capability in triggering autophagy in MH-S cells,but showed outer chalcogen-dependent subcellular localization and activation of autophagy pathways.Specifically,WS_(2)and NbS_(2)nanosheets adhered on the cell surface and internalized in the lysosomes,and triggered m TOR-dependent activation of autophagy.Meanwhile,WSe_(2)and Nb Se_(2)nanosheets had extensive distribution in cytoplasm of MH-S cells and induced autophagy in an m TOR-independent manner.Furthermore,the 2D TMDCs-induced perturbation on autophagy aggravated the cytotoxicity of respirable benzo[a]pyrene.These findings provide a deeper insight into the potential health risk of environmental 2D TMDCs from the perspective of homeostasis perturbation.

关键词： Chalcogen group Autophagy pathway Cell function Endosomal escape Inhalation toxicity

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Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction of emerging contaminants

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Frontiers of environmental Science & Engineering 2024年第4期18卷 49-60页

作者： Yuhang Liu Wenxuan Deng Xiaojun Wu Chun Hu Lai Lyu Key Laboratory for Water Quality and Conservation of the Pearl River Delta(Ministry of Education) Institute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou 510006China

Effective removal of emerging contaminants(ECs)to minimize their impacts on human health and the natural environment is a global priority.For the removal of ECs in water,we fabricated a seaweed spherical microsphere catalyst with Cu cation-πstructures by in situ doping of Cu species and ascorbic acid in mesoporous silica(Cu-C-MSNs)via a hydrothermal method.The results indicate that bisphenol A(BPA)is substantially degraded within 5 min under natural conditions,with its biological toxicity considerably weakened.Moreover,industrial wastewater could also be effectively purified by Cu-C-MSNs/H2O2 system.The presence of metal sites and the complexation of ECs via cation-πinteraction andπ-πstacking on the catalyst surface were directly responsible for the polarization distribution of electrons,thus activating H2O2 and dissolved oxygen(DO).The removal of contaminants could be attributed primarily to 1)the activation of H2O2 into•OH to attack the contaminants and 2)self-cleavage because of the transfer of electrons from the contaminants to the catalysts.This study provides an innovative solution for the effective treatment of ECs and has positive implications for easing global environmental crises.

关键词： Cation-πstructures Polarization electric field Fenton-like process Contaminants cleavage

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Anion-induced differential assembly and structural transformation of supramolecular coordination cages

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Chinese Chemical Letters 2024年第3期35卷 268-272页

作者： Shao-Ping Zheng Yao-Wei Xu Pei-Yang Su Chen-Hui Liu Yin-Hui Huang Yu-Lin Lu Zhang-Wen Wei Zhiwei Jiao Hai-Sen Xu Cheng-Yong Su MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional MaterialsSchool of ChemistrySun Yat-sen UniversityGuangzhou 510006China institute of environmental research at greater bay area Guangzhou UniversityGuangzhou 510006China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China

The intimate host-anion interactions will regulate thermodynamics and kinetics in the self-assembly of cationic cages mimicking biological counterparts.Herein,we report construction and transformation of three Pd(Ⅱ)-based metal-organic cages(MOCs)depending on different anions.Stoichiometric conversions of the lantern-shaped MOC-34 into either octahedral MOC-35 or tricapped trigonal prism MOC-36 are induced by BF_(4)^(–)or NO_(3)^(–),respectively.MOC-36 is kinetically favored and can undergo quantitative conversion to the thermodynamically preferred MOC-35 upon heating,accelerated by excess BF_(4)^(–)to motivate dissociative dynamics of Pd-vertices and lower activation barrier of cage transformation.The guest encapsulation behaviors of MOC-35 and MOC-36 have also been tested.These results manifest a significance of host-anion dynamics beyond complementary anion template,shedding light on the understanding of intricate anion recognition in nature.

关键词： Supramolecular coordination cage Dynamic host-anion interactions Structural transformation Anion receptor Guest inclusion

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Evaluation and attribution of trends in compound dry-hot events for major river basins in China

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Science China Earth Sciences 2024年第1期67卷 79-91页

作者： Shaotang XIONG Tongtiegang ZHAO Chengchao GUO Yu TIAN Fang YANG Wenlong CHEN Xiaohong CHEN Key Laboratory of Water Security Guarantee in Guangdong-Hong Kong-Marco greater bay area of Ministry of Water Resources&Sun Yatsen University/Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Guangzhou 510275China China institute of Water Resource and Hydropower research Beijing 100038China Pearl River Hydraulic research institute Guangzhou 510611China

Concurrent compound dry and hot events(CDHEs)amplified more damange on the ecosystems and human society than individual extremes.Under climate change,compound dry and hot events become more frequent on a global scale.This paper proposes a mathematical method to quantitatively attribute changes of CDHEs to changes of precipitation,change in temperature and change in the dependence between precipitation and temperature.The attribution is achieved by formulating the total differential equation of the return period of CDHEs among Meta-gaussian model.A case study of China is devised based on monthly precipitation and temperature data during the period from 1921 to 2020 for 80 major river basins.It is found that temperature is the main driving factor of increases in CDHEs for 49 major river basins in China,except for the upper and middle reaches of the Yangtze River.In West China,precipitation changes drove the increase in CDHEs in 18 river basins(23%),particularly in parts of North Xinjiang,Qinghai and Gansu.On the other hand,dependence between precipitation and temperature dominated changes of CDHEs in 13 river basins(16%)of China with other factors,including parts of South China,East China and Northwestern China.Furthermore,changes in both the mean and spread of precipitation and temperature can also contribute to changes in CDHEs.

关键词： Climate extreme Compound dry and hot extreme Precipitation Temperature Return period

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Selective synthesis of heteroleptic PdAB-cages: modulating size-preference of supramolecular hosts via endo-functionalization

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Science China Chemistry 2024年

作者： Wen-Tao Dai Ting-Ting Liu Qixia Bai Zhe Zhang Pingshan Wang Wei Lu Qi Zhang Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University institute of environmental research at greater bay area Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of Education Guangzhou University

The size complementarity between a host and a guest is a critical prerequisite for selective molecular recognition. Numerous artificial host systems have been designed to achieve size-selective recognition and chemical transformations. However, the inherent challenge lies in the fixed selectivity governed by a size-exclusion mechanism dictated by the host’s structure.Modulating the selectivity necessitates structural modifications of hosts. Examples of host systems with modifiable sizeselectivity are rare. In this study, we present an approach to modulating guest-selectivity via endo-functionalization of supramolecular cavities. Heteroleptic Pd2A3B-cages are constructed with a Pd2A3precursor or directly from palladium ions and relevant ligands. Furthermore, the simultaneous and selective formation of multiple hetero-cages was achieved by simply mixing PdIIand the free ligands in a one-pot reaction. The fidelity of the assembly process relies on cooperative steric control at the periphery and within the cavity of the hetero-cages, respectively. The central steric group also functions as the endohedral moiety. Variations of the endohedral groups facilitate facile and modular derivatization of the microenvironment within the cages, enabling the fine-tuning of guest binding affinities as evidenced by titration experiments. This strategy offers a new solution for the development of customized host structures.

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Potential and prospects in molecular orbital level micro-electric field for low energy consumption water purification

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National Science Open 2024年第3期 194-233页

作者： Lai Lyu Yumeng Wang Chao Lu Fan Li Wenrui Cao Yingtao Sun Chun Hu institute of environmental research at greater bay area Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou University

Conventional water purification technologies struggle to simultaneously address purification efficiency and energy consumption.Molecular orbital level surface micro-electric field（MEF）-driven water purification is an original and innovative concept conceived and developed by our group in recent years.The core idea involves creating electron-rich and electron-poor micro-areas on the nanomaterial surface,which drive pollutants or H2O molecules to provide electrons in the electron-poor micro-areas while other environmental factors（such as H2O2and O2） obtain electrons in the electron-rich micro-areas.This process effectively utilizes the internal energy contained within wastewater and emerging contaminants（ECs）.Centered on this core,this review systematically examines the discovery,construction,and characteristics of MEF and MEF-like systems and summarizes their application directions.The challenges,bottlenecks,and future development directions of MEF technology are also analyzed and discussed.Reviews of MEFs can facilitate the development of low-consumption,high-efficiency water purification technologies.

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Fast source mask co-optimization method for high-NA EUV lithography

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Opto-Electronic Advances 2024年第4期7卷 44-54页

作者： Ziqi Li Lisong Dong Xu Ma Yayi Wei EDA Center Institute of Microelectronics of Chinese Academy of SciencesBeijing 100029China Key Laboratory of Photoelectronic Imaging Technology and System of Ministry of Education of China School of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China University of Chinese Academy of Sciences Beijing 100049China Guangdong greater bay area Applied research institute of Integrated Circuit and Systems Guangzhou 510700China

Extreme ultraviolet(EUV)lithography with high numerical aperture(NA)is a future technology to manufacture the integrated circuit in sub-nanometer dimension.Meanwhile,source mask co-optimization(SMO)is an extensively used approach for advanced lithography process beyond 28 nm technology node.This work proposes a novel SMO method to improve the image fidelity of high-NA EUV lithography system.A fast high-NA EUV lithography imaging model is established first,which includes the effects of mask three-dimensional structure and anamorphic magnification.Then,this paper develops an efficient SMO method that combines the gradient-based mask optimization algorithm and the compressivesensing-based source optimization algorithm.A mask rule check(MRC)process is further proposed to simplify the optimized mask pattern.Results illustrate that the proposed SMO method can significantly reduce the lithography patterning error,and maintain high computational efficiency.

关键词： computational lithography high-NA EUV lithography source-mask co-optimization lithography imaging model

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Non-Hermitian CHSH^(*)Game with a Single Trapped-Ion Qubit

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Chinese Physics Letters 2024年第6期41卷 1-10页

作者：宋潇刘腾边纪陆鹏飞刘泱朱峰罗乐 School of Physics and Astronomy Sun Yat-sen UniversityZhuhai 519082China Shenzhen research institute of Sun Yat-Sen University Shenzhen 518057China Quantum Science Center of Guangdong-HongKong-Macao greater bay area Shenzhen 518048China Guangdong Provincial Key Laboratory of Quantum Metrology and Sensing Zhuhai 519082China

The Clauser-Horne-Shimony-Holt(CHSH)game provides a captivating illustration of the advantages of quantum strategies over classical ones.In a recent study,a variant of the CHSH game leveraging a single qubit system,referred to as the CHSH^(*)game,has been identified.We demonstrate that this mapping relationship between these two games remains effective even for a non-unitary gate.Here we delve into the breach of Tsirelson’s bound in a non-Hermitian system,predicting changes in the upper and lower bounds of the player’s winning probability when employing quantum strategies in a single dissipative qubit system.We experimentally explore the impact of the CHSH^(*)game on the player’s winning probability in a single trapped-ion dissipative system,demonstrating a violation of Tsirelson’s bound under the influence of parity-time(PT)symmetry.These results contribute to a deeper understanding of the influence of non-Hermitian systems on quantum games and the behavior of quantum systems under PT symmetry,which is crucial for designing more robust and efficient quantum protocols.

关键词： quantum system dissipative

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A high Li-ion diffusion kinetics in multidimensional and compact-structured electrodes via vacuum filtration casting

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Journal of Energy Chemistry 2024年第6期93卷 368-376,I0010页

作者： Jieqiong Li Ting Ouyang Lu Liu Shu Jiang Yongchao Huang M.-Sadeeq Balogun College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan UniversityChangsha 410082HunanChina institute of environmental research at greater bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006GuangdongChina

Manufacturing process,diffusion co-efficient and areal capacity are the three main criteria for regulating thick electrodes for lithium-ion batteries(LIBs).However,simultaneously regulating these criteria for LIBs is desirable but remains a significant challenge.In this work,niobium pentoxide(Nb_(2)O_(5))anode and lithium iron phosphate(LiFePO_(4))cathode materials were chosen as the model materials and demonstrate that these three parameters can be simultaneously modulated by incorporation of micro-carbon fibers(MCF)and carbon nanotubes(CNT)with both Nb_(2)O_(5) and LFP via vacuum filtration approach.Both as-prepared MNC-20 anode and MLC-20 cathode achieves high reversible areal capacity of≈5.4 m A h cm^(-2)@0.1 C and outstanding Li-ion diffusion coefficients of≈10~(-8)cm~2 s~(-1)in the half-cell configuration.The assembled MNC-20‖MLC-20 full cell LIB delivers maximum energy and power densities of244.04 W h kg^(-1)and 108.86 W kg^(-1),respectively.The excellent electrochemical properties of the asprepared thick electrodes can be attributed to the highly conductive,mechanical compactness and multidimensional mutual effects of the MCF,CNT and active materials that facilitates rapid Li-ion diffusion kinetics.Furthermore,electrochemical impedance spectroscopy(EIS),symmetric cells analysis,and insitu Raman techniques clearly validates the enhanced Li-ion diffusion kinetics in the present architecture.

关键词： Thick electrodes Carbon nanotubes Li-ion diffusion co-efficient Vacuum filtration technique High areal capacity Lithium-ion batteries

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Genomic analysis of Nypa fruticans elucidates its intertidal adaptations and early palm evolution

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Journal of Integrative Plant Biology 2024年第4期66卷 824-843页

作者： Weihong Wu Xiao Feng Nan Wang Shao Shao Min Liu Fa Si Linhao Chen Chuanfeng Jin Shaohua Xu Zixiao Guo Cairong Zhong Suhua Shi Ziwen He State Key Laboratory of Biocontrol and Guangdong Provincial Key Laboratory of Plant Resources School of Life SciencesSun Yat-sen UniversityGuangzhou 510275China greater bay area institute of Precision Medicine School of Life SciencesFudan UniversityGuangzhou 511462China Hainan Academy of Forestry(Hainan Academy of Mangrove) Haikou 571100China

Nypa fruticans(Wurmb),a mangrove palm species with origins dating back to the Late Cretaceous period,is a unique species for investigating long-term adaptation strategies to intertidal environments and the early evolution of palms.Here,we present a chromosome-level genome sequence and assembly for N.fruticans.We integrated the genomes of N.fruticans and other palm family members for a comparative genomic analysis,which confirmed that the common ancestor of all palms experienced a whole-genome duplication event around 89 million years ago,shaping the distinctive characteristics observed in this clade.We also inferred a low mutation rate for the N.fruticans genome,which underwent strong purifying selection and evolved slowly,thus contributing to its stability over a long evolutionary period.Moreover,ancient duplicates were preferentially retained,with critical genes having experienced positive selection,enhancing waterlogging tolerance in N.fruticans.Furthermore,we discovered that the pseudogenization of Early Methionine-labelled 1(EM1)and EM6 in N.fruticans underly its crypto-vivipary characteristics,reflecting its intertidal adaptation.Our study provides valuable genomic insights into the evolutionary history,genome stability,and adaptive evolution of the mangrove palm.Our results also shed light on the long-term adaptation of this species and contribute to our understanding of the evolutionary dynamics in the palm family.

关键词： crypto-vivipary genome stability long-term adaptation mangrove Nypa fruticans palm

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