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Locally Enhanced Flow and Electric Fields Through a Tip Effect for Efficient Flow‑Electrode Capacitive Deionization

Nano-Micro Letters 2025年第2期17卷 1-17页

作者： Ziquan Wang Xiangfeng Chen Yuan Zhang Jie Ma Zhiqun Lin Amor Abdelkader Maria‑Magdalena Titirici Libo Deng College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Research Center for Environmental Functional Materials College of Environmental Science and EngineeringTongji University1239 Siping RoadShanghai 200092People’s Republic of China Department of chemical and Biomolecular Engineering National University of SingaporeSingapore 117585Singapore Department of Engineering Faculty of Science and TechnologyBournemouth UniversityTalbot CampusFern BarrowPooleEngland BH125BBUK Institut de Chimie de Nice UniversitéCôte d’AzurUMR CNRS 727228 Av.Valrose06108 NiceFrance Department of chemical Engineering Imperial College LondonSouth Kensington CampusExhibition RdLondon SW72AZUK

Low-electrode capacitive deionization(FCDI)is an emerging desalination technology with great potential for removal and/or recycling ions from a range of ***,it still suffers from inefficient charge transfer and ion transport kinetics due to weak turbulence and low electric intensity in flow electrodes,both restricted by the current ***,a new tip-array current collector(designated as T-CC)was developed to replace the conventional planar current collectors,which intensifies both the charge transfer and ion transport *** effects of tip arrays on flow and electric fields were studied by both computational simulations and electrochemical impedance spectroscopy,which revealed the reduction of ion transport barrier,charge transport barrier and internal *** the voltage increased from 1.0 to 1.5 and 2.0 V,the T-CC-based FCDI system(T-FCDI)exhibited average salt removal rates(ASRR)of 0.18,0.50,and 0.89μmol cm^(-2) min^(-1),respectively,which are 1.82,2.65,and 2.48 folds higher than that of the conventional serpentine current collectors,and 1.48,1.67,and 1.49 folds higher than that of the planar current ***,with the solid content in flow electrodes increased from 1 to 5 wt%,the ASRR for T-FCDI increased from 0.29 to 0.50μmol cm^(-2) min^(-1),which are 1.70 and 1.67 folds higher than that of the planar current ***,a salt removal efficiency of 99.89%was achieved with T-FCDI and the charge efficiency remained above 95%after 24 h of operation,thus showing its superior long-term stability.

关键词： Flow-electrode Capacitive deionization Current collector Tip effect Desalination

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The influence of sequence of precursor films on CZTSe thin films prepared by ion-beam sputtering deposition

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Journal of Semiconductors 2017年第2期38卷 15-19页

作者： Jun Zhao Guangxing Liang Yang Zeng Ping Fan Juguang Hu Jingting Luo Dongping Zhang institute of Thin Film Physics and Applications College of Physics and Energy Shenzhen University Shenzhen 518060 China institute of chemical science umr cnrs 6226 University of Rennes 1 35042 Rennes France

The CuZnSn（CZT） precursor thin films are grown by ion-beam sputtering Cu, Zn, Sn targets with different orders and then sputtering Se target to fabricate Cu_2ZnSnSe_4（CZTSe） absorber thin films on molybdenum substrates. They are annealed in the same vacuum chamber at 400 ℃. The characterization methods of CZTSe thin films include X-ray diffraction（XRD）, energy dispersive spectroscopy（EDS）, scanning electron microscopy（SEM）, and X-ray photoelectron spectra（XPS） in order to study the crystallographic properties, composition, surface morphology, electrical properties and so on. The results display that the CZTSe thin films got the strongest diffraction peak intensity and were with good crystalline quality and its morphology appeared smooth and compact with a sequence of Cu/Zn/Sn/Se, which reveals that the expected states for CZTSe are Cu^（1＋）, Zn^（2＋）, Sn^（4＋）, Se^（2）.With the good crystalline quality and close to ideal stoichiometric ratio the resistivity of the CZTSe film with the sequence of Cu/Zn/Sn/Se is lower, whose optical band gap is about 1.50 eV.

关键词： CZTSe thin films ion-beam sputtering chalcogenide

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Selective CO_(2) reduction into formate using Ln-Ta oxynitrides combined with a binuclear Ru(Ⅱ)complex under visible light

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Journal of Energy Chemistry 2021年第4期30卷 176-182页

作者： Kanemichi Muraoka Miharu Eguchi Osamu Ishitani Francois Chevire Kazuhiko Maeda Department of Chemistry School of ScienceTokyo Institute of TechnologyMeguro-ku152-8550 TokyoJapan Japan Society for the Promotion of science Chiyoda-ku102-0083 TokyoJapan Research Center for Functional Materials National Institute for Materials ScienceTsukuba 305-0044IbarakiJapan Univ Rennes CNRSISCR-UMR 6226Rennes F-35000France

Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired *** this work,defect fluorite-type Ln-Ta oxynitrides LnTaO_(x)N_(y)(Ln=Nd,Sm,Gd,Tb,Dy and Ho)were examined as the semiconductor component in a hybrid photocatalyst system combined with known Ag nanoparticle promoter and binuclear ruthenium(Ⅱ)complex(RuRu’).Among the LnTaO_(x)N_(y) examined,TbTaO_(x)N_(y) gave the highest performance for CO_(2) reduction under visible light(k>400 nm),with a Ru Ru0-based turnover number of 18 and high selectivity to formate(>99%).Physicochemical analyses indicated that high crystallinity and more negative conduction band potential of Ln Ta O_(x)N_(y)with the absence of Ln-4 f states in the band gap structure contributed to higher activity of the hybrid photocatalyst.

关键词： Artificial photosynthesis Heterogeneous photocatalysis Mixed anion compounds Solar fuels

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Experimental and numerical investigation of mid-infrared laser in Pr^(3+)-doped chalcogenide fiber

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Chinese Physics B 2019年第2期28卷 257-263页

作者： Hua Chen Ke-Lun Xia Zi-Jun Liu Xun-Si Wang Xiang-Hua Zhang Yin-Sheng Xu Shi-Xun Dai Laboratory of Infrared Materials and Devices Advanced Technology Research InstituteNingbo University Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province Laboratory of Glasses and Ceramics UMR CNRS 6226University of Rennes 1

We report on a chalcogenide glass fiber doped with Pr^(3+) that can be used for commercialized 1.5-μm and 2-μm laser excitations by emitting broadband 3 μm–5.5 μm fluorescence, which is extruded into a preform and then drawn into a step-index fiber. The spectroscopic properties of the fiber and glass are reported, and the mid-infrared fiber lasers are also numerically investigated. Cascade lasing is employed to increase the inversion population of the upper laser level. The particle swarm approach is applied to optimize the fiber laser parameters. The output power can reach 1.28 W at 4.89-μm wavelength, with a pump power of 5 W, excitation wavelength at 2.04 μm, Pr^(3+) ion concentration at 4.22 × 10^(25) ions/m^3,fiber length at 0.94 m, and fiber background loss at 3 dB/m.

关键词： mid-infrared fiber laser chalcogenide glass fiber rare earth doped glass fiber laser modelling

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SURFACE MODIFICATION OF MICROPOROUS POLYPROPYLENE MEMBRANES BY GRAFT POLYMERIZATION OF N,N-DIMETHYLAMINOETHYL METHACRYLATE

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Chinese Journal of Polymer science 2004年第4期22卷 369-377页

作者：徐志康 Patrick Seta institute of Polymer science Zhejiang University Hangzhou 310027 China LMPM UMR 5635 CNRS 34293 Montpellier Cedex 05 France

Surface modification of microporous polypropylene hollow fiber membranes was performed by radical-induced graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA). The influences of temperature, monomer concentration and pre-adsorbed amount of benzoyl peroxide on grafting degree were studied respectively. It was found that the appropriate graft temperature was 75 'C, at which the grafting degree was the highest and the hydrolytic decomposition of DMAEMA the lowest. Scanning electron photomicrography and the average pore diameters of the modified membranes demonstrated that part of the micropores on the membrane surface was plugged by the grafted polyDMAEMA chains, especially at high grafting degree. Contact angle and water swelling experiments showed that a moderate grafting degree could improve the hydrophilicity of the membranes. In the range of 11.3%-12.0% grafting degree, the water swelling percentage reached its maximum (51.1%) and the contact angle reached its minimum (74 degrees). The bovine serum albumin (BSA) adsorption experiment indicated that the grafted polyDMAEMA had a dual effect on protein adsorption. At the first stage, the BSA adsorption decreased with increasing of DMAEMA grafting degree. As the interaction between BSA and polyDMAEMA on membrane surface increased, the BSA adsorption increased with increasing of DMAEMA grafting degree.

关键词： Polypropylene hollow fiber membrane N,N-Dimethylaminiethyl methacrylate Surface modification Graft polymerization BSA adsorption

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Sunlight activated ultra-stable long persistent luminescence glass ceramic for outdoor information display

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Journal of Advanced Ceramics 2022年第6期11卷 974-983页

作者： Jingtao ZHAO Lei LEI Renguang YE Junjie ZHANG Xianghua ZHANG Shiqing XU Key Laboratory of Rare Earth Optoelectronic Materials and Devices of Zhejiang Province Institute of Optoelectronic Materials and DevicesChina Jiliang UniversityHangzhou 310018China Laboratory of Glasses and Ceramics Univ RennesCNRSISCR(Institute des Sciences Chimiques de Rennes)UMR CNRS 6226University of Rennes 1Rennes 35042France

Natural sunlight activated persistent luminescence(PeL)is ideal candidate for optical information display in outdoors without the requirement of electric *** the brightness and duration,the stability especially water resistance of the PeL materials is of significant importance for practical application,which remains a great obstacle up to ***,we report a new sunlight activated PeL glass ceramic containing hexagonal Sr_(13)Al_(22)Si_(10)O_(66):Eu^(2+)crystals,which exhibits strong blue PeL and can last more than 200 *** PeL can be charged by the full wavelengths located in AM 1.5G due to the broad distribution of traps in the crystal *** PeL is clearly observed by the naked eye even after 24 h upon sunlight irradiation irrespective of the weather,and the photoluminescence intensity only decreased~3.3%after storing in water for 365 *** demonstrate its potential application for thermal and stress responsive display as well as long-term continuous security indication upon sunlight irradiation,which not only save vast energy and reduce environment pollution,but also are appropriate for outdoor usage.

关键词： solar energy persistent luminescence(PeL) glass ceramic optical information display stability

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Anharmonic electron-phonon coupling in ultrasoft and locally disordered perovskites

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npj Computational Materials 2023年第1期9卷 744-756页

作者： Marios Zacharias George Volonakis Feliciano Giustino Jacky Even Univ Rennes INSA RennesCNRSInstitut FOTON-UMR 6082F-35000 RennesFrance Univ Rennes ENSCRINSA RennesCNRSISCR-UMR 6226F-35000 RennesFrance Oden institute for Computational Engineering and sciences The University of Texas at AustinAustinTX 78712USA Department of Physics The University of Texas at AustinAustinTX 78712USA

Anharmonicity and local disorder(polymorphism)are ubiquitous in perovskite physics,inducing various phenomena observed in scattering and spectroscopy *** of these phenomena still lack interpretation from first principles since,hitherto,no approach is available to account for anharmonicity and disorder in electron–phonon ***,relying on the special displacement method,we develop a unified treatment of both and demonstrate that electron–phonon coupling is strongly influenced when we employ polymorphous perovskite *** uncover that polymorphism in halide perovskites leads to vibrational dynamics far from the ideal noninteracting phonon picture and drives the gradual change in their band gap around phase transition *** also clarify that combined band gap corrections arising from disorder,spin-orbit coupling,exchange–correlation functionals of high accuracy,and electron–phonon coupling are all *** findings agree with experiments,suggesting that polymorphism is the key to address pending questions on perovskites’technological applications.

关键词： perovskite phonon harmonic

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Room-Temperature Electroreductiveα-Alkylation of N-Heteroarenes with Styrenes

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CCS Chemistry 2024年第2期6卷 342-352页

作者： Maorui Wang Chengqian Zhang He Zhao Huanfeng Jiang Pierre HDixneuf Min Zhang Key Lab of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510641 ISCR umr cnrs 6226 Univ.RennesRennes 35000

Despite their interesting applications,direct and diverse syntheses of aryl-fused 2-alkyl cyclic amines still remain ***,the concept of incorporating a C–C coupling process into the N-heteroaryl reduction was successfully applied to fulfill such a synthetic *** to our use of controllable electroreduction coupled with proton abstraction,we can report a room-temperature reductiveα-alkylation of the inert N-heteroarenes with abundantly available styrenes in an undivided Zn(+)/C(−)*** proceeds with good substrate compatibility and operational simplicity,utilizes cost-effective sacrificial Zn-anode,exhibits high selectivity,and does not need pressurized H2 gas and transition-metal *** current work offers a useful platform for direct construction of valuable aryl-fused 2-alkyl cyclic amines that are difficult to access with conventional methods.

关键词： electroreductive C-C cross-coupling N-heteroarenes styrenes 2-alkyl cyclic amines alkylation

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Electronic engineering of Co-Ru diatomic sites and Ru nanoparticles for synergistic promotion of hydrogen evolution

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Nano Research 2024年第5期17卷 3714-3723页

作者： Wei Zhang Cong Li Yongyong Cao Jun-Yang Ji Zhao-Chen Li Zheng Niu Hongwei Gu Pierre Braunstein Jian-Ping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China College of Biological Chemical Science and EngineeringJiaxing UniversityJiaxing 314001China Universitéde Strasbourg-cnrs Institut de Chimie(UMR 7177 CNRS)4 rue Blaise Pascal-CS 9003267081 StrasbourgFrance

The coexistence of multi-component active sites like single-atom sites,diatomic sites(DAS)and nanoclusters is shown to result in superior performances in the hydrogen evolution reaction(HER).Metal diatomic sites are more complex than single-atom sites but their unique electronic structures can lead to significant enhancement of the HER *** the synthesis and identification of DAS is usually challenging,we report a simple access to a diatomic catalyst by anchoring Co-Ru DAS on nitrogen-doped carbon supports along with Ru nanoparticles(NPs).Experimental and theoretical results revealed the atomic-level characteristics of Co-Ru sites,their strong electronic coupling and their synergy with Ru NPs within the *** unique electronic structure of the catalyst resulted in an excellent HER activity and stability in alkaline *** work provides a valuable insight into a widely applicable design of diatomic catalysts with multi-component active sites for highly efficient HER electrocatalysis.

关键词： Co-Ru diatomic sites Ru nanoparticles multiple active sites synergistic effect hydrogen evolution reaction

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Parametric instability of a liquid metal sessile drop under the action of low-frequency alternating magnetic fields

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Journal of Hydrodynamics 2013年第2期25卷 300-308页

作者：雷作胜郭加宏 FAUTRELLE Yves ERNST Roland ETAY Jacqueline 任忠鸣 Shanghai Key Laboratory of Modern Metallurgy and Materials Processing Shanghai University SIMAP-EPM Laboratory Grenoble Institute of Technology/CNRS UMR 5266 France Shanghai institute of Applied Mathematics and Mechanics Shanghai University SIMAP-EPM Laboratory Grenoble Institute of Technology/CNRS UMR 5266France

A 2-D mathematical model is developed in order to simulate a parametric electromagnetic instability oscillation process of a liquid metal droplet under the action of low frequency magnetic field. The Arbitrary Lagrangian-Eulerian （ALE） method and weak form constraint boundary condition are introduced in this model for implementation of the surface tension and electromagnetic force on liquid droplet free surface. The results of the numerical calculations indicate the appearance of various regimes of oscillation. It is found that according to the magnetic field frequency various types of oscillation modes may be found. The oscillation is originated from an instability phenomenon. The stability diagram of liquid metal droplet in the parameter space of magnetic frequency and magnetic flux density is determined numerically. The diagram is very similar to that found in the so-called parametric instability.

关键词： sessile drop parametric instability low-frequency alternating magnetic fields numerical simulation

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