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Mechanism of Methylene Blue adsorption on hybrid laponite-multi-walled carbon nanotube particles

Journal of Environmental Sciences 2016年第4期28卷 134-141页

作者： Maryna Manilo Nikolai Lebovka Sandor Barany institute of biocolloidal chemistry named after F.D. Ovcharenko National Academy of Sciences of Ukraine 42 Vernadsky blvd. 030142 Kyiv Ukraine University of Miskolc MTA-ME Materials Science Research Group and Institute of Chemistry Hungary The Transcarpathian II. Ferenc Rakoczi Hungarian institute Beregovo Ukraine

The kinetics of adsorption and parameters of equilibrium adsorption of Methylene Blue（MB）on hybrid laponite-multi-walled carbon nanotube（NT）particles in aqueous suspensions were *** laponite platelets were used in order to facilitate disaggregation of NTs in aqueous suspensions and enhance the adsorption capacity of hybrid particles for *** were performed at room temperature（298 K）,and the laponite/NT ratio（Xl）was varied in the range of 0–*** elucidation of the mechanism of MB adsorption on hybrid particles,the electrical conductivity of the system as well as the electrokinetic potential of laponite-NT hybrid particles were *** different stages in the kinetics of adsorption of MB on the surface of NTs or hybrid laponite-NT particles were discovered to be a fast initial stage Ⅰ（adsorption time t=0–10 min）,a slower intermediate stage Ⅱ（up to t=120 min）and a long-lasting final stage Ⅲ（up to t=24 hr）.The presence of these stages was explained accounting for different types of interactions between MB and adsorbent particles,as well as for the changes in the structure of aggregates of NT particles and the long-range processes of restructuring of laponite platelets on the surface of *** analysis of experimental data on specific surface area versus the value of Xl evidenced in favor of the model with linear contacts between rigid laponite platelets and *** was also concluded that electrostatic interactions control the first stage of adsorption at low MB concentrations.

关键词： Multi-walled carbon nanotubes Laponite platelets Methylene Blue Adsorption Kinetics Zeta potential

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Hybrid bimetallic cluster ZrO_(2)/Rh@N,S co-doped porous carbon nanosheets for efficient hydrogen evolution in acid electrolytes

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Tungsten 2024年第4期6卷 657-662页

作者： Xin-Yi Zhang Igor V.Zatovsky Jun-Ming Cao Xing-Long Wu Faculty of chemistry Northeast Normal UniversityChangchun130024China F.D.Ovcharenko institute of biocolloidal chemistry NAS UkraineKiev03142Ukraine MOE Key Laboratory for UV Light-Emitting Materials and Technology Northeast Normal UniversityChangchun130024China

Acid hydrogen evolution reaction(HER)is a critical energy conversion process,which is significantly important in hydrogen energy manufacturing and storage[1].Although the performance of noble metal platinum(Pt)-based catalysts in acidic HER is well known,the challenges are high cost,limited reserves,poor stability,and susceptibility to toxic substances[2].Therefore,it is urgent to design and manufacture acidic HER catalysts with high reactivity,high stability,and low cost.

关键词： stability cluster porous

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Synergistic Co-doping effect of CNTs and PVP in Na_(4)MnCr(PO_(4))3 cathode as a strategy for improving the electrochemical performance of SIBs

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Chinese Chemical Letters 2024年第2期35卷 539-543页

作者： Ruoyu Chen Denys S.Butenko Shilin Li Xinyu Zhang Guangshe Li Igor V.Zatovsky Wei Han College of Physics State Key Laboratory of Inorganic Synthesis and Preparative ChemistryInternational Center of Future ScienceJilin UniversityChangchun 130012China Academy for Advanced Interdisciplinary Studies Southern University of Science and TechnologyShenzhen 518055China State Key Laboratory of Inorganic Synthesis and Preparative chemistry College of ChemistryJilin UniversityChangchun 130012China F.D.Ovcharenko institute of biocolloidal chemistry NAS UkraineKyiv 03142Ukraine

In order to solve the contradiction between the rapidly growing energy demand and the excessive exploitation of fossil fuels,it is urgent to research and develops more environmentally friendly and efficient energy storage ***,the development of high-performance cathode materials to enhance the energy density of SIB is currently one of the most important topics of scientific *** high-voltage and low-cost cathode material for SIBs,a composite of carbon-coated Na_(4)MnCr(PO_(4))_(3)(NASICON-type),polyvinylpyrrolidone(PVP),and modified carbon nanotubes(CNTs)is prepared by sol-gel and freeze-drying *** to the high conductivity of CNTs,the conductivity of the composite is significantly improved,and its initial capacity is increased to 114 mAh/g at 0.5 C and 96 mAh/g at 5 C(Mn^(2+)/Mn^(4+)conversion for voltage windows 1.4-4.3 V).Moreover,the multi-electrons transfer of Cr^(3+)/Cr^(4+) and Mn^(2+)/Mn^(4+) can provide a high capacity of 165 mAh/g at 0.1 C and 102 mAh/g at 5 C in the high voltage window of 1.4-4.6 ***,PVP can effectively inhibit the Jahn-Teller effect caused by Mn ion,making the composite have more excellent high-rate performance and *** addition,GITT,EIS and CV curves were drawn to better reveal the excellent kinetic properties of Na_(4)MnCr(PO_(4))_(3)@C@PVP@CNT cathode,and the mechanism of its performance improvement is deeply studied and ***,the co-doping of CNTs and PVP is a simple way to high conductivity and fast charging of cathode materials for SIBs.

关键词： Sodium-ion batteries Na_(4)MnCr(PO_(4))_(3) Carbon nanotubes Polyvinylpyrrolidone Synergistic effect

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Thermo- and pH-Responsive Hydrogels Based on N-Isopropylacrylamide and Allylamine Copolymers

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Soft 2013年第4期2卷 19-26页

作者： Victoria Konovalova Yuri Samchenko Ganna Pobigai Anatoly Burban Zoya Ulberg Department of chemistry National University of Kiev-Mohyla Academy Kiev Ukraine institute of biocolloidal chemistry National Academy of Sciences of Ukraine Kiev Ukraine

The thermo- and pH-responsive hydrogels were synthesized via copolymerization of N-isopropylacrylamide and al-lylamine hydrochloride monomers. The equilibrium swelling of the hydrogels was studied as a function of temperature and pH in aqueous solutions. It was shown that controlled alteration of the hydrogel phase transition temperature can be achieved by changing their composition and pH of the environment. Increase in content of hydrophilic allylamine from 10 to 60 wt% in monomer mixture causes a shift of the phase transition temperature from 35oC to 47oC. Hydrogels with N-isopropylacrylamide/allylamine hydrochloride mass ratio of 3:2 show the highest pH-response. Values of average molecular weight between polymer cross-links, , and Flory parameter, χ, were calculated using temperature dependences of the equilibrium swelling of the synthesized hydrogel.

关键词： Thermo-Responsive Hydrogels Copolymer Hydrogels Allylamine Hydrochloride N-Isopropyl-Acrylamide The Parameter of Flory

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