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Chinese Journal of Polymer Science 2024年第6期42卷 815-825页

作者： Chao-Ying Sun Hai-Jun Ji Li-Wei Li Hui Yang Xiao-Peng An Yi-Ping Chen Ming-Jian Han Can Jiang Li-Qun Zhang Peng Yu Run-Guo Wang State Key Laboratory of organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing100029China School of materials Science and Engineering Wuhan Institute of TechnologyWuhan430205China

Rubbers or elastomers play an important role in hi-tech technology and civilian daily life because of their unique and strategical ***,the rubber additives are essential components for rubbers’practical ***,developing novel multifunctional additives has attracted increasing research *** this work,low-cost crude carbon dots(CCDs)were used as multifunctional additives for natural rubber/silica system(without any additional modification)through industrial compatible melt-mixing *** results revealed that the CCDs could disperse well in the NR/silica system,and they could not only endow the rubber compound with excellent anti-aging capability due to CCDs’radical scavenging activity because of their plenty of nitrogen-containing species,but also improve the curing rate and mechanical performance of the rubber ***,the CCDs could reduce the rolling resistance of the rubber composites(tanδvalue at 7%strain of the rubber composite could be decreased by 34%),which is promising for the application of energy-saving tire ***,the addition of CCDs could effectively reduce the ZnO dosage by at least 40%in the rubber composite without deteriorating its ***,this work provides valuable guidance to develop novel cheap yet effective additives for the elastomer.

关键词： Natural rubber Crude carbon dots Antioxidant ZnO reduction Vulcanization

3D Foam-Based MXene Architectures:Structural and Electrolytic Engineering for Advanced Potassium-Ion Storage

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Energy & Environmental materials 2024年第4期7卷 64-73页

作者： Peng Zhang Yanmeng Peng Qizhen Zhu Razium Ali Soomro Ning Sun Bin Xu State Key Laboratory of organic-Inorganic Composites Beijing Key Laboratory of Electrochemical Process and Technology for Materials Beijing University of Chemical Technology Beijing Advanced Innovation Centre for Soft Matter Science and Engineering Beijing University of Chemical Technology

MXenes are emerging rapidly as promising electrode materials for energy storage due to their high electronic conductivity and rich surface chemistry,but their potassium storage performance is unsatisfactory because of... 详细信息

关键词： 3D foam-like scaffold electrolyte chemistry electrostatic neutralization MXene potassium-ion batteries

Lithiophilic CoF2@C hollow spheres towards spatial lithium deposition for stable lithium metal batteries

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Journal of Energy Chemistry 2024年第10期97卷 55-67页

作者： Jianxing Wang Shuhao Yao Runming Tao Xiaolang Liu Jiazhi Geng Chang Hong Huiying Li Guiyun Yu Haifeng Li Xiao-Guang Sun Jianlin Li Jiyuan Liang School of Optoelectronic materials & technology Jianghan University institute for Advanced materials and Manufacturing University of Tennessee Applied materials Division Argonne National Laboratory School of Chemistry & chemical Engineering Yancheng Institute of Technology chemical Sciences Division Oak Ridge National Laboratory

Lithium metal（LM） is a promising anode for next-generation batteries due to its high theoretical capacity and low electrode ***,side reactions,volume change,and unwanted lithium dendrite growth seriously limit the practical application of ***,with the aid of a hard template approach,a novel lithiophilic CoF2-carbon hollow sphere（CoF2@C-HS） composite material is successfully prepared via a facile in-situ fluorination and etching *** lithiophilic CoF2acts as nucleation sites to reduce nucleation overpotential as well as induces the spatial Li deposition and the formation of LiFrich solid electrolyte interphase（SEI）,and the hollow carbon matrix can enhance the electrical conductivity and offer free space for LM *** simulations reveal that the synergistic effect of lithiophilic CoF2and hollow carbon matrix homogenizes the electric field distribution and Li+*** from these advantages,the CoF2@C-HS-modified copper substrate electrode delivers an enhanced Coulombic efficiency（CE） of 93.7% for 280 cycles at 1 mA cm-2and 1 mA h *** symmetrical cell using CoF2@C-HS can stably cycle more than 1800 h with a low voltage hysteresis of 11 mV at a current density of 0.5 MA cm-2and an areal capacity of 0.5 mA h ***,the Li@CoF2@C-HS composite anode enables more than 300 stable cycles at 1 C with a capacity retention of 95% in LiFePO4-based full cell and 110 stable cycles at 1 C in LiNi0.8Co0.1Mn0.1O2（NCM811）-based highvoltage full *** work might shed a new light on designing lithiophilic hosts to spatially confine LM deposition,realizing dendrite-free LM anodes and the practical applications of LM batteries.

关键词： Lithiophilic CoF2 Lithium metal anode Nanocomposite Spatial deposition, Stability

Multiple conductive network for KTi_(2)(PO_(4))_(3)anode based on MXene as a binder for high-performance potassium storage

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Chinese chemical Letters 2024年第8期35卷 539-544页

作者： Tong Su Yue Wang Qizhen Zhu Mengyao Xu Ning Qiao Bin Xu State Key Laboratory of organic-Inorganic Composites Beijing Key Laboratory of Electrochemical Process and Technology for MaterialsBeijing University of Chemical TechnologyBeijing 100029China

KTi_(2)(PO_(4))_(3)is a promising anode material for potassium storage,but suffers from low conductivity and difficult balance between high capacity and good structural ***,the Ti_(3)C_(2)T_(x)MXene is used as a multifunctional binder to fabricate the KTi_(2)(PO_(4))_(3)electrode by the traditional homogenizing-coating *** MXene nanosheets,together with the conductive agent super P nanoparticles,construct a multiple conductive network for fast electron/ion transfer and high electrochemical ***,the network ensures the structural stability of the KTi_(2)(PO_(4))_(3)electrode during the de-intercalation/intercalation of 4 K^(+)ions,which is beneficial for simultaneously achieving high capacity and good cycle ***,the MXene-bonded KTi_(2)(PO_(4))_(3)electrode delivers a reversible capacity of 255.2 mAh/g at 50 mA/g,outstanding rate capability with 132.3 mAh/g at 2 A/g,and ex-cellent cycle performance with 151.6 mAh/g at 1 A/g after 2000 *** work not only suggests a high-performance anode material for potassium-ion batteries,but also demonstrates that the MXene is a promising binder material for constructing conductive electrodes in rechargeable batteries.

关键词： MXene Ti_(3)C_(2)T_(x) KTi_(2)(PO_(4))_(3) Anode Conductive network Potassium storage

Revealing the Multifunctional Electrocatalysis of Indium-Modulated Phthalocyanine for High-Performance Lithium-Sulfur Batteries

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Energy & Environmental materials 2024年第1期7卷 1-8页

作者： Yang Guo Zhaoqing Jin Jianhao Lu Zilong Wang Zihao Song Anbang Wang Weikun Wang Yaqin Huang Beijing Key Laboratory of Electrochemical Process and technology for materials Key Laboratory of Biomedical Materials of Natural MacromoleculesMinistry of EducationBeijing University of Chemical TechnologyBeijing 100029China Research institute of chemical Defense Beijing Key Laboratory of Advanced Chemical Energy Storage Technology and MaterialsBeijing 100191China

The sluggish kinetics of complicated multiphase conversions and the severe shuttling effect of lithium polysulfides(LiPSs)significantly hinder the applications of Li-S battery,which is one of the most promising candidates for the next-generation energy storage ***,a bifunctional electrocatalyst,indium phthalocyanine self-assembled with carbon nanotubes(InPc@CNT)composite material,is proposed to promote the conversion kinetics of both reduction and oxidation processes,demonstrating a bidirectional catalytic effect on both nucleation and dissolution of Li_(2)S *** theoretical calculation shows that the unique electronic configuration of InPc@CNT is conducive to trapping soluble polysulfides in the reduction process,as well as the modulation of electron transfer dynamics also endows the dissolution of Li_(2)S in the oxidation reaction,which will accelerate the effectiveness of catalytic conversion and facilitate sulfur ***,the InPc@CNT modified separator displays lower overpotential for polysulfide transformation,alleviating polarization of electrode during *** integrated spectroscopy analysis,HRTEM,and electrochemical study reveal that the InPc@CNT acts as an efficient multifunctional catalytic center to satisfy the requirements of accelerating charging and discharging ***,the Li-S battery with InPc@CNT-modified separator obtains a discharge-specific capacity of 1415 mAh g^(-1)at a high rate of 0.5 ***,the 2 Ah Li-S pouch cells deliver 315 Wh kg^(-1)and achieved 80%capacity retention after 50 cycles at 0.1 C with a high sulfur loading of 10 mg cm^(-2).Our study provides a practical method to introduce bifunctional electrocatalysts for boosting the electrochemical properties of Li-S batteries.

关键词： bidirectional catalyst indium phthalocyanine lithium-sulfur batteries pouch cells

Diatomic Pd catalyst with conjugated backbone for synergistic electrochemical CO_(2)reduction

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Nano Research 2024年第6期17卷 4850-4855页

作者： Wenxuan Zhang Mengran Zhang Hongjuan Wang Wen Zhang Min Zhang MOE International Joint Laboratory of materials Microstructure Institute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Tianjin Key Laboratory of organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin 300384China

Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence ***,the development of bimetallic sites catalysts that coordinate with definite atoms is still in the exploratory ***,we designed and synthesized a bimetallic palladium complex(BPB-Pd_(2))with conjugated *** supported BPB-Pd_(2)was applied to electrochemical CO_(2)reduction reaction(CO_(2)RR)for the first *** as-obtained BPB-Pd_(2)gives an exceptional Faradaic efficiency of CO(FECO)of 94.4%at−0.80 V *** hydrogen electrode(RHE),which is significantly superior to monoatomic palladium catalyst(BPB-Pd1).The density functional theory(DFT)calculations revealed that the essential reason for the outstanding activity of BPB-Pd_(2)toward CO_(2)RR was that the electronic effect between diatomic palladium reduces the free energy change for CO_(2)RR ***,BPB-Pd_(2)exhibits moderate free energy change to form COOH*intermediate,which was beneficial for the generation of CO in CO_(2)RR.

关键词： synthesis electrocatalysis CO_(2)reduction bimetallic palladium complex synergistic catalysis

Engineering S-scheme W_(18)O_(49)/ZnIn_(2)S_(4)heterojunction by Co_(x)P nanoclusters for enhanced charge transfer capability and solar hydrogen evolution

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Nano Research 2024年第9期17卷 8095-8103页

作者： Xiaojie Liu Erkang Liu Zixian Wang Wen Zhang Mingyu Dou Hua Yang Changhua An Dacheng Li Jianmin Dou Shandong Provincial Key Laboratory of chemical Energy Storage and Novel Cell technology School of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059China Tianjin Key Laboratory of organic Solar Cell and Photochemical Conversion School of Chemistry and Chemical EngineeringTianjin Key Laboratory of Advanced Functional Porous MaterialsInstitute for New Energy Materials and Low-Carbon TechnologiesTianjin University of TechnologyTianjin 300384China institute of Powder Metallurgy and Advanced Ceramics School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China

Enhancement of the light-absorption response and utilization of the photogenerated carriers represent a robust strategy for the design of high-performance *** this work,grafting Co_(x)P nanoclusters onto S-scheme heterojunction of W18O49/ZnIn2S4(WO/ZIS-CoxP)with strong response to the ultraviolet-visible-near infrared ray(UV-vis-NIR)region has been achieved,which possesses efficient electron-transfer-channel,and boosts charge-separation and transport *** as-prepared WO/ZIS-Co_(x)P yields an impressive solar-driven hydrogen production rate of 45 mmol·g^(-1)·h^(-1).The increased photocatalytic performance is attributed to the synergistic effect of the composite catalyst:(1)The local surface plasmon resonance-induced“hot electron”injection of W_(18)O_(49)significantly increases the electron density;(2)the engineered S-scheme directional electron transfer promotes charge separation and enhances the reducing capability of photoexcited electrons;and(3)Co_(x)P as electron-trap site for accelerating surface proton reduction *** work provides a platform to impart nonprecious co-catalyst for engineering S-scheme heterojunction,serving a class of efficient solar-driven photocatalyst towards hydrogen production.

关键词： hydrogen cocatalyst photocatalysis S-scheme hot electron

Defect engineering of W^(6+)-doped NiO for high-performance black smart windows

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Nano Research 2024年第4期17卷 3043-3052页

作者： Yingjun Xiao Xiang Zhang Dukang Yan Jianbo Deng Mingjun Chen Hulin Zhang Wenhai Sun Jiupeng Zhao Yao Li School of Chemistry and chemical Engineering Harbin Institute of TechnologyHarbin 150001China Center for Composite materials and Structure Harbin Institute of TechnologyHarbin 150001China

In this report,W^(6+)doping as a defect engineering strategy has been proposed to improve the electrochromic properties of NiO *** research was conducted to explore the electrochromic properties and the modified mechanism of W-doped NiO *** to the pure NiO,W-doped NiO film exhibits improved electrochromic properties with significant optical modulation(61.56%at 550 nm),fast switching speed(4.42 s/1.40 s for coloring/bleaching),high coloration efficiency(45.41 cm^(2)·C-1)and outstanding cycling stability(no significant attenuation after 2000 cycles)in Li-based *** functional theory(DFT)calculations combined with the experimental results indicate that the improved electrochromic properties were due to enhanced the electronic conductivity and ion conductivity after the introduction of W^(6+).The charge capacity of W-doped NiO has also been improved,and it can function with WO_(3) to achieve a high performance black electrochromic smart window(ECSW)by balancing *** work could advance the fundamental understanding of defect engineering as an effective strategy to boost the electrochromic properties of NiO anodic material,manifesting a significant development as a candidate counter electrode in high-performance black smart windows.

关键词： NiO defect engineering charge balance black electrochromic windows

The principle and amelioration of lithium plating in fast-charging lithium-ion batteries

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Journal of Energy Chemistry 2024年第10期97卷 453-459页

作者： Yi Yang Xia-Lin Zhong Lei Xu Zhuo-Lin Yang Chong Yan Jia-Qi Huang School of materials Science and Engineering Beijing Institute of Technology Advanced Research institute of Multidisciplinary Science Beijing Institute of Technology Beijing Key Laboratory of Green chemical Reaction Engineering and technology Department of Chemical Engineering Tsinghua University Yangtze River Delta Graduate School of Beijing institute of technology

Fast charging is restricted primarily by the risk of lithium（Li） plating,a side reaction that can lead to the rapid capacity decay and dendrite-induced thermal runaway of lithium-ion batteries（LIBs）.Investigation on the intrinsic mechanism and the position of Li plating is crucial to improving the fast rechargeability and safety of ***,we investigate the Li plating behavior in porous electrodes under the restricted transport of Li+.Based on the theoretical model,it can be concluded that the Li plating on the anodeseparator interface（ASI） is thermodynamically feasible and kinetically ***,the prior deposition of metal Li on the ASI rather than the anode-current collector interface（ACI） is verified *** order to facilitate the transfer of Li+among the electrode and improve the utilization of active materials without Li plating,a bilayer asymmetric anode composed of graphite and hard carbon（GH） is *** and simulation results suggest that the GH hybrid electrode homogenizes the lithiated-rate throughout the electrode and outperforms the pure graphite electrode in terms of the rate performance and inhibition of Li *** work provides new insights into the behavior of Li plating and the rational design of electrode structure.

关键词： Fast charging Graphite Hard carbon Lithium plating Lithium-ion batteries

PVDF-assisted pyrolysis strategy for corrugated plate oxygen electrocatalysis nanoreactor:Simultaneously realizing efficient active sites and rapid mass transfer

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Journal of Energy Chemistry 2024年第10期97卷 612-621页

作者： Chenxi Xu Liang Chen Haihui Zhou Shifeng Qin Zhaohui Hou Yangyang Chen Jiale Sun Junwei Xu Zhongyuan Huang College of Chemistry and chemical Engineering Hunan University College of materials Science and technology Central South University of Forestry and Technology Key Laboratory of Hunan Province for Advanced Carbon-based Functional materials School of Chemistry and Chemical Engineering Hunan Institute of Science and Technology

Though Zn-air batteries(ZABs) are one of the most promising system for energy storage and conversion,challenge still persists in its commercial application due to the sluggish kinetics of oxygen reduction/evolution reaction(ORR/OER).Hereby,a polyvinylidene fluoride(PVDF)-assisted pyrolysis strategy is proposed to develop a novel corrugated plate-like bifunctional electrocatalyst using two-dimensional zeolitic imidazolate frameworks(2D ZIF-67) as the *** employed PVDF plays an important role in inheriting the original 2D structure of ZIF-67 and modulating the composition of the final *** a result,a corrugated plate-like electrocatalyst,high-density Co nanoparticles decorated 2D Co,N,and F tri-doped carbon nanosheets,can be *** acquired electrocatalyst enables efficient active sites and rapid mass transfer simultaneously,thus showing appreciable electrocatalytic performance for rechargeable Zn-air ***,our proposed strategy offers a new perspective to the design of advanced oxygen electrocatalysts.

关键词： Active sites Corrugated plate Mass transfer Oxygen electrocatalyst Zn-air batteries