检索结果-南通市图书馆

Active MoS_(2)-based electrode for green ammonia synthesis

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemical Engineering 2024年第1期65卷 268-275页

作者： Xin Liu Lei Yang Tao Wei Shanping Liu Beibei Xiao School of Energy and Power Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China institute charles gerhardt Montpellier UMR-5253Universite de MontpellierCNRSENSCMPlace E.Bataillon34095 Montpellier Cedex 05France

Nitrogen electro-reduction under mild conditions is one promising alternative approach of the energyconsuming Haber-Bosch process for the artificial ammonia *** critical aspect to unlocking this technology is to discover the catalysts with high selectivity and *** this work,the N_(2)-to-NH_(3)conversion on the functional MoS_(2)is fully investigated by density functional theory calculations since the layered MoS_(2)provides the ideal platform for the elaborating copies of the nitrogenase found in nature,wherein the functionalization is achieved via basal-adsorption,basal-substitution or edge-substitution of transition metal *** results reveal that the edge-functionalization is a feasible strategy for the activity promotion;however,the basal-adsorption and basal-substitution separately suffer from the electrochemical instability and the NRR ***,MoS_(2)functionalized via edge W-substitution exhibits an exceptional *** energetically favored reaction pathway is through the distal pathway and a limiting potential is less than 0.20 ***,this work escalates the rational design of the high-effective catalysts for nitrogen fixation and provides the explanation why the predicated catalyst have a good performance,paving the guidance for the experiments.

关键词： Nitrogen reduction reaction Density functional theory calculations Molybdenum disulfide Electrochemistry Catalyst Thermodynamics

Selective catalytic reduction of nitrogen oxides over a modified silicoaluminophosphate commercial zeolite

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2018年第3期30卷 246-252页

作者： Carolina Petitto Gérard Delahay Institut charles gerhardt Montpellier UMR 5253 CNRS/UM/ENSCM Matériaux Avancés pour la Catalyse et la Santé 8 rue de l'Ecole Normale

Nitrogen oxides（NOx：NO,NO2）are a concern due to their adverse health *** engine transport sector is the major emitter of *** regulations have been strengthened and to comply with them,one of the two methods commonly used is the selective catalytic reduction of NOxby NH3（NH3-SCR）,NH3being supplied by the in-situ hydrolysis of *** and durability of the catalyst for this process are highly *** is evaluated by hydrothermal treatment of the catalysts at temperature above 800℃.In this study,very active catalysts for the NH3-SCR of NOxwere prepared by using a silicoaluminophosphate commercial zeolite as copper host *** by X-ray diffraction（XRD）,scanning electron microscopy（SEM）and temperature programmed desorption of ammonia（NH3-TPD）showed that this commercial zeolite was hydrothermally stable up to 850℃ and,was able to retain some structural properties up to950℃.After hydrothermal treatment at 850℃,the NOxreduction efficiency into NH3-SCR depends on the copper *** catalyst with a copper content of 1.25 wt.%was the most *** difference in activity was much more important when using NO than the fast NO/NO2reaction mixture.

关键词： Diesel Nitrogen oxides SCR process Copper Zeolite Silicoaluminophosphate

Sn/n3O4-x heterostructure rich in oxygen vacancies with enhanced visible light photocatalytic oxidation performance

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2021年第1期28卷 150-159页

作者： Rui-qi Yang Na Liang Xuan-yu Chen Long-wei Wang Guo-xin Song Yan-chen Ji Na Ren Ya-wei Lü Jian Zhang Xin Yu institute for Advanced Interdisciplinary Research(IAIR) University of JinanJinan 250022China School of physics and electronics Hunan UniversityChangsha 410082China institute charles gerhardt UMR 5253CNRS-UM-ENSCMUniversitéde MontpellierPlace Eugène BataillonF-34095 Montpellier cedex 5France

Sn3O4, a common two-dimensional semiconductor photocatalyst, can absorb visible ***, owing to its rapid recombination of photogenerated electron-hole pairs, its absorption is not sufficient for practical *** this work, a Sn nanoparticle/Sn3O4-x nanosheet heterostructure was prepared by in situ reduction of Sn3O4 under a H2 *** Schottky junctions formed between Sn and Sn3O4-x can enhance the photogenerated carrier separation *** the hydrogenation process, a portion of the oxygen in the semiconductor can be extracted by hydrogen to form water, resulting in an increase in oxygen vacancies in the *** heterostructure showed the ability to remove Rhodamine *** cytocompatibility experiments proved that Sn/Sn3O4-x can significantly enhance cell compatibility and reduce harm to *** work provides a new method for the fabrication of a Schottky junction composite photocatalyst rich in oxygen vacancies with enhanced photocatalytic performance.

关键词： photocatalysis tin oxide oxygen vacancy Schottky junction photodegradation

Selective catalytic reduction of NO by NH3 on cerium modified faujasite zeolite prepared from aluminum scraps and industrial metasilicate

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2020年第3期38卷 250-256页

作者： Rahma Abid Gerard Delahay Hassib Tounsi Laboratory of Advanced Materials National School of Engineers of SfaxUniversity of SfaxTunisia Institut charles gerhardt ENSCM"Advanced Materials for Health and Catalysis"240 Av Professor Emile Jeanbrau34296 MontpellierFrance

This work was devoted to the study of the selective catalytic reduction of NO by NH3 on calcined and hydrothermal treated cerium loaded zeolite *** parent faujasite zeolite Na-F(Si/Al=1.32 and SBET=749 m^2/g) used as support for the preparation of the catalysts was obtained from industrial sodium metasilicate and aluminum *** expected,the NO conversion increases with increasing the percentage of cerium in the structure of the faujasite *** NO conversion into N2 is reached at 400℃at a space velocity of 250 000 h^-*** high conversion is due to the redox shift between Ce^3+/Ce^4+and the strong acid sites related to the rare earth present in the framework that is the key in SCR of NO ***,the highest loaded cerium catalyst retains almost its activity after hydrothermal treatment at 850℃.This higher loading is desirable for both activity and stability provided that two stages of preparation are used to put the Ce ions in the sodalite cages.

关键词： Aluminum scraps Ce-Y NH3-SCR Hydrothermal stability

Light tuning CO/H_(2)composition on Ag:Unraveling CO_(2)mass transfer and electron-phonon coupling in plasmon-enhanced electrocatalysis

在线全文

学校读者我要写书评

暂无评论

Nano Research 2025年第1期18卷 173-185页

作者： Rui Lin Dong Fan Luca MBerger Thomas Possmayer Yu Zhou Jiexin Zhu Xingbao Chen Wen Luo Lars Allmendinger Andreas Tittl Leonardo de Souza Menezes Guillaume Maurin Shihe Yang and Stefan AMaier Nanoinstitute Munich Faculty of PhysicsLudwig-Maximilians-Universität München80539 MunichGermany Institut charles gerhardt Montpellier UMR 5253 CNRS ENSCM UniversitéMontpellierPlace E.Bataillon34090 MontpellierFrance Guangdong Provincial Key Lab of Nano-Micro Material Research School of Advanced MaterialsPeking University Shenzhen Graduate SchoolShenzhen 518055China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Faculty of Chemistry and Pharmacy Ludwig-Maximilians-Universität München81377 MunichGermany Departamento de Física Universidade Federal de Pernambuco50670-901 Recife-PEBrazil School of Physics and Astronomy Monash University Clayton CampusMelbourneVictoria 3800Australia Department of Physics Imperial College LondonSW72AZ LondonUK

Plasmon-enhanced electrocatalysis(PEEC)is an emerging approach to mitigate CO_(2)*** mechanisms behind CO_(2)adsorption and reduction at the catalyst-electrolyte interface in PEEC still need to be further ***,we employ a well-defined Ag nanostructure to elucidate these pivotal *** shining light with wavelengths of 625,525,405 nm on Ag,an adjustable CO/H_(2)ratio from 35 to 1 can be *** reaction pathway changing under plasmonic excitation does not originate from the lowered CO_(2)mass transfer in the vicinity of Ag,as the electrochemical quartz crystal microbalance results unravel that a slightly elevated temperature in bulk electrolyte caused by light irradiation cannot weaken the CO_(2)adsorption at the Ag catalyst-electrolyte *** calculations reveal that optical excitation towards shorter wavelengths leads to a progressive lowered energy barrier for H_(2)formation together with an enhanced energy barrier for^(*)COOH *** thermodynamically suppressed,CO_(2)reduction can still be improved kinetically by optimizing the excitation wavelength and intensity,being accompanied with the enhanced *** absorption spectroscopy results further correlate the higher photocurrent with a prolonged electron-phonon coupling time,verifying that the improvement of CO_(2)reduction kinetics in PEEC can be realized by hot electron harnessing.

关键词： plasmonic catalysis photoelectrochemical CO_(2)reduction CO/H_(2)ratio hot electron generation electronphonon coupling thermal effect

Acidic open-cage solution containing basic cage-confined nanospaces for multipurpose catalysis

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2022年第5期9卷 99-107页

作者： Kang Li Kai Wu Yan-Zhong Fan Jing Guo Yu-Lin Lu Yuan-Fan Wang Guillaume Maurin Cheng-Yong Su MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional MaterialsSchool of ChemistrySun Yat-sen University School of Chemistry South China Normal University institute charles gerhardt Montpellier Centre National de la Recherche Scientifiqueécole Nationale Supérieure de Chimie de MontpellierUniversité de Montpellier

The nanoscale chemical spaces inherent in porous organic/coordination cages or solid/liquid materials have been continuously explored for their nanoconfinement effect on selective adsorption and reaction of small gas or organic ***,we aim to rationalize the unconventional chemical reactivities motivated by the cage-confined nanospaces in aqueous solutions,where the robust yet permeable nanospaces defined by the open cages facilitate dynamic guest exchange and unusual chemical *** high positive charges on [(Pd/Pt)6(RuL3)8]28+nanocages drive imidazole-proton equilibrium to display a significantly perturbed pKashift,creating cage-defined nanospaces in solution with distinct intrinsic basicity and extrinsic *** supramolecular cage effect plays pivotal roles in elaborating robust solution nanospaces,controlling ingress-and-egress molecular processes through open-cage portals and endowing nanocages with transition-state stabilization,amphoteric reactivities and the phase transfer of insoluble molecules,thus promoting chemical transformations in unconventional ***,a wide range of application of cage-confined catalysis with anomalous reactivities maybe expected based on this kind of open-cage solution medium,which combines cage nanocavity,solution heterogeneity and liquid-phase fluidity to benefit various potential mass transfer and molecular process options.

关键词： open-cage solution supramolecular cage effect supramolecular catalysis cage-confined catalysis cage-confined nanospaces in solution

Mechanisms behind elevated serum levels of plasminogen activator inhibitor-1 in frontotemporal lobar degeneration

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第8期20卷 2317-2318页

作者： Francesco Angelucci Jakub Hort Memory Clinic Department of NeurologySecond Faculty of MedicineCharles University and Motol University HospitalPragueCzech Republic International Clinical Research Centre St.Anne’s University HospitalBrnoCzech Republic

Frontotemporal lobar degeneration(FTLD)is a form of progressive dementia characterized by degeneration of the frontal and temporal lobes of the *** pathology involves a series of cognitive,behavioral,and neurological ... 详细信息

关键词： degeneration elevated pathology

An aqueous magnesium-ion hybrid supercapacitor operated at-50℃

在线全文

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第4期9卷 702-712页

作者： Guoshen Yang Gangrui Qu Chi Fang Jie Deng Xianqi Xu Yinghao Xie Tian Sun Yachao Zhu Jiaxin Zheng Hang Zhou School of Electronic and Computer Engineering Peking University Shenzhen Graduate SchoolShenzhen518055China School of Advanced Materials Peking University Shenzhen Graduate SchoolShenzhenChina College of Food and Biological Engineering Chengdu UniversityChengdu610106China institute charles gerhardt Montpellier UMR 5253Universitae MontpellierMontpellierCC 1502France

The recent advances in aqueous magnesium-ion hybrid supercapacitor(MHSC)have attracted great attention as it brings together the benefits of high energy density,high power density,and synchronously addresses cost and safety ***,the freeze of aqueous electrolytes discourages aqueous MHSC from operating at low-temperature ***,a low-concentration aqueous solution of 4 mol L^(-1) Mg(ClO_(4))_(2) is devised for its low freezing point(-67℃)and ultra-high ionic conductivity(3.37 mS cm^(-1) at-50℃).Both physical characterizations and computational simulations revealed that the Mg(ClO_(4))_(2) can effectively disrupt the original hydrogen bond network among water molecules via transmuting the electrolyte structure,thus yielding a low freezing ***,the Mg(ClO_(4))_(2) electrolytes endue aqueous MHSC with a wider temperature operation range(-50℃–25℃)and a higher energy density of 103.9 Wh kg^(-1) at 3.68 kW kg^(-1) over commonly used magnesium salts(i.e.,MgSO_(4) and Mg(NO_(3))_(2))***,a quasi-solid-state MHSC based on polyacrylamide-based hydrogel electrolyte holds superior low-temperature performance,excellentﬂexibility,and high *** work pioneers a convenient,cheap,and eco-friendly tactic to procure low-temperature aqueous magnesium-ion energy storage device.

关键词： Low-concentration aqueous electrolyte Anti-freezing property Magnesium-ion hybrid supercapacitor High energy density

Hermitian Generalization of the Rarita-Schwinger Operators

在线全文

学校读者我要写书评

暂无评论

Acta Mathematica Sinica,English Series 2010年第2期26卷 311-330页

作者： Alberto DAMIANO David EELBODE Mathematics institute of charles University Department of Mathematics and Computer Science University of Antwerp

We introduce two new linear differential operators which are invariant with respect to the unitary group SU（n）. They constitute analogues of the twistor and the Rarita-Schwinger operator in the orthogonal case. The natural setting for doing this is Hermitian Clifford Analysis. Such operators are constructed by twisting the two versions of the Hermitian Dirac operator 6z_ and 6z_ and then projecting on irreducible modules for the unitary group. We then study some properties of their spaces of nullsolutions and we find a formulation of the Hermitian Rarita-Schwinger operators in terms of Hermitian monogenic polynomials.

关键词： Hermitian Clifford analysis Rarita-Schwinger operator