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Biomass-derived porous carbon with single-atomic cobalt toward high-performance aqueous zinc-sulfur batteries at room temperature

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Journal of energy Chemistry 2024年第8期95卷 325-335页

作者： Shenfei Zhao Xiaoshuai Wu Jiliang Zhang Chunjie Li Zixiang Cui Weihua Hu Ruguang Ma Changming Li institute for Clean energy & Advanced materials School of Materials & Energy Southwest University institute for materials Science and Devices School of Materials Science and Engineering Suzhou University of Science and Technology School of materials Science and Engineering Dalian Jiaotong University

Aqueous zinc-sulfur batteries at room temperature hold great potential for next-generation energy storage technology due to their low cost, safety and high energy density. However, slow reaction kinetics and high activation energy at the sulfur cathode pose great challenges for the practical applications. Herein,biomass-derived carbon with single-atomic cobalt sites（MMPC-Co） is synthesized as the cathode in Zn-S batteries. The catalysis of single-atom Co sites greatly promotes the transform of cathode electrolyte interface（CEI） on the cathode surface, while offering accelerated charge transfer rate for high conversion reversibility and large electrochemical surface area（ECSA） for high electrocatalytic current. Furthermore,the rich pore structure not only physically limits sulfur loss, but also accelerates the transport of zinc ions.In addition, the large pore volume of MMPC-Co is able to relieve the stress effect caused by the volume expansion of Zn S during charge/discharge cycles, thereby maintaining the stability of electrode structure.Consequently, the sulfur cathode maintains a high specific capacity of 729.96 m A h g-1after 500 cycles at4 A g-1, which is much better than most cathode materials reported in the literature. This work provides new insights into the design and development of room-temperature aqueous Zn-S batteries.

关键词： Aqueous zinc-sulfur batteries Biomass-derived carbon Rich pore structure Single-atom catalysts Sulfur cathode

On-demand engineerable visible spectrum by fine control of electrochemical reactions

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National Science Review 2024年第3期11卷 239-249页

作者： Qirong Liu Lei Liu Yongping Zheng Min Li Baofu Ding Xungang Diao Hui-Ming Cheng Yongbing Tang Advanced energy Storage technology Research Center Shenzhen Institute of Advanced TechnologyChinese Academy of Sciences institute of technology for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences School of energy and Power Engineering North University of China School of Resource Environment and Safety EngineeringHunan University of Science and Technology School of energy and Power Engineering Beihang University Shenzhen Key Laboratory of energy materials for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences Shenyang National Laboratory for materials Science Institute of Metal Research Chinese Academy of Sciences

Tunability of optical performance is one of the key technologies for adaptive optoelectronic applications,such as camouflage clothing, displays, and infrared shielding. High-precision spectral tunability is of great importance for some special applications with on-demand adaptability but remains challenging. Here we demonstrate a galvanostatic control strategy to achieve this goal, relying on the finding of the quantitative correlation between optical properties and electrochemical reactions within materials. An electrochromic electro-optical efficiency index is established to optically fingerprint and precisely identify electrochemical redox reactions in the electrochromic device. Consequently, the charge-transfer process during galvanostatic electrochemical reaction can be quantitatively regulated, permitting precise control over the final optical performance and on-demand adaptability of electrochromic devices as evidenced by an ultralow deviation of energy storage, electrocatalysis, and material chemistry.

关键词： electrochromics fine control spectral tunability high precision galvanostatic control

Multifunctional photon conversion materials for enhancing silicon solar cells

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Light(Science & Applications) 2024年第4期13卷 598-601页

作者： Yiyan Zhang Guanying Chen MIIT Key Laboratory of Critical materials technology for New energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of Technology150001 HarbinChina

A type of multifunctional erbium(Er^(3+))and ytterbium(Yb^(3+))codoped NaY(WO4)2 phosphors,with simultaneous photon upconversion,photon quantum cutting,and luminescence ratiometric temperature sensing abilities,have b... 详细信息

关键词： photon luminescence quantum

Enhanced photothermal dehydration of methanol over W_(18)O_(49)/Au/SAPO-34 catalysts with broadened light absorption

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Rare Metals 2024年第3期43卷 1139-1152页

作者： Ya-Qin Tang Meng-Xia Yan Chang-Qian Lu Shao-Yuan Li Kui-Xian Wei Tao Qu Wen-HuiMa Yong-Nian Dai Kong-Zhai Li Da-Jun Luo Xue-Liang Zhang Yi-Ke Liu Faculty of Metallurgical and energy Engineering Kunming University of Science and TechnologyKunming650093China School of materials and energy Engineering Guizhou Institute of TechnologyGuiyang550003China

Methanol-to-olefins(MTO)process is one of the most critical pathways to produce low carbon olefins.Typically,the reaction is driven by thermal catalysis,which inevitably needs to consume large amounts of fossil fuel.Developing a new technique to substitute for the fuel burning is urgent for MTO process to improve the industry prospects and sustainability.Herein,we report a novel W_(18)O_(49)/Au/SAPO-34(W/Au/S),a multifunctional photothermal catalyst for the MTO reaction.A high methanol conversion was achieved under xenonum(Xe)lamp irradiation,yielding methyl ether(ME)and ethylene as the main products.The optimized W/Au/S catalysts showed ethylene yield as high as 250μmol in 60 min,which was 2.5 times higher than that of Au/SAPO-34.The physiochemical characterization revealed that the SAPO-34 molecular sieves were surrounded by Au and W_(18)O_(49)nanoparticles,which exhibited a strong localized surface plasmon resonance excitation around 540 nm and light absorption beyond 500 nm.The multifunctional catalysts showed a strong photothermal effect,arising from the broadened light absorption of Au and W_(18)O_(49)nanoparticles,leading to a temperature as high as 250℃on the surface of the catalysts.Mechanism study showed that the superior ethylene selectivity of W/Au/S catalysts was attributed to the moderating acidic sites of W_(18)O_(49)for methanol dehydration to ethylene.This research may provide new insight for designing heterostructures to improve photo-to-chemical conversion performance and is expected to accelerate progress toward the excellent multifunctional photothermal catalysts with broad light absorption for methanol activation and C-C bond formation.

关键词： Methanol conversion Ethylene Photothermal catalysis W_(18)O_(49) BrΦnsted-acid

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PDOL-Based Solid Electrolyte Toward Practical Application:Opportunities and Challenges

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Nano-Micro Letters 2024年第7期16卷 109-141页

作者： Hua Yang Maoxiang Jing Li Wang Hong Xu Xiaohong Yan Xiangming He institute for Advanced materials School of Materials Science and EngineeringJiangsu UniversityZhenjiang 212013People’s Republic of China institute of Nuclear and New energy technology Tsinghua UniversityBeijing 100084People’s Republic of China

Polymer solid-state lithium batteries(SSLB)are regarded as a promising energy storage technology to meet growing demand due to their high energy density and safety.Ion conductivity,interface stability and battery assembly process are still the main challenges to hurdle the commercialization of SSLB.As the main component of SSLB,poly(1,3-dioxolane)(PDOL)-based solid polymer electrolytes polymerized in-situ are becoming a promising candidate solid elec-trolyte,for their high ion conductivity at room temperature,good battery elec-trochemical performances,and simple assembly process.This review analyzes opportunities and challenges of PDOL electrolytes toward practical application for polymer SSLB.The focuses include exploring the polymerization mechanism of DOL,the performance of PDOL composite electrolytes,and the application of PDOL.Furthermore,we provide a perspective on future research directions that need to be emphasized for commercialization of PDOL-based electrolytes in SSLB.The exploration of these schemes facilitates a comprehensive and profound understanding of PDOL-based polymer electrolyte and provides new research ideas to boost them toward practical application in solid-state batteries.

关键词： Poly(1,3-dioxolane) Solid electrolyte Polymerization mechanism Composite electrolyte Practical application

维普期刊数据库

Magnetic-biased chiral molecules enabling highly oriented photovoltaic perovskites

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National Science Review 2024年第2期11卷 221-230页

作者： Jing Chen Caner Deger Zhen-Huang Su Kai-Li Wang Guang-Peng Zhu Jun-Jie Wu Bing-Chen He Chun-Hao Chen Tao Wang Xing-Yu Gao Ilhan Yavuz Yan-Hui Lou Zhao-Kui Wang Liang-Sheng Liao institute of Functional Nano&Soft materials(FUNSOM) Laboratory of Advanced Negative Carbon TechnologiesSoochow University Department of Physics Marmara University Shanghai Synchrotron Radiation Facility(SSRF) Shanghai Advanced Research InstituteChinese Academy of Sciences College of energy Soochow Institute for Energy and Materials Innovations Soochow University Macao institute of materials Science and Engineering Macau University of Science and Technology

The interaction between sites A, B and X with passivation molecules is restricted when the conventional passivation strategy is applied in perovskite（ABX3） photovoltaics. Fortunately, the revolving A-site presents an opportunity to strengthen this interaction by utilizing an external field. Herein, we propose a novel approach to achieving an ordered magnetic dipole moment, which is regulated by a magnetic field via the coupling effect between the chiral passivation molecule and the A-site（formamidine ion） in perovskites.This strategy can increase the molecular interaction energy by approximately four times and ensure a well-ordered molecular arrangement. The quality of the deposited perovskite film is significantly optimized with inhibited nonradiative recombination. It manages to reduce the open-circuit voltage loss of photovoltaic devices to 360 mV and increase the power conversion efficiency to 25.22%. This finding provides a new insight into the exploration of A-sites in perovskites and offers a novel route to improving the device performance of perovskite photovoltaics.

关键词： perovskite photovoltaics magnetic moment A-site regulation chiral molecules

Nanocavity enriched CuPd alloy with high selectivity for CO2 electroreduction toward C2H4

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Rare Metals 2024年第4期43卷 1513-1523页

作者： Ze-Yu Zhang Hai-Bin Wang Fei-Fei Zhang Jing-Wei Li Xin-Zhuo Hu Si-Wei Yan Yi-Ming Bai Xun Zhang Gu-Rong Shen Peng-Fei Yin Jing Yang Cun-Ku Dong Jing Mao Hui Liu Xi-Wen Du institute of New-energy materials School of Materials Science and EngineeringTianjin University

Electrocatalysis of CO2reduction reaction is an effective way to convert CO2into high value-added products,but the selectivity of Cu-based catalysts for C2+products needs to be improved due to the high energy barrier of C-C coupling.Therefore,a viable catalyst design strategy to decrease energy barrier of C-C coupling should be put forward.Here,a nanocavity-enriched CuPd single atom alloy（CuPd SAA） catalyst is designed to promote CC coupling process.The faradaic efficiency of CuPd SAA for ethylene and C2+reaches 75.6% and 85.7% at-0.7 V versus reversible hydrogen electrode（RHE）,respectively.Based on the results given by in situ characterization,the porous hollow structure dramatically increases the ratio of the linear-bond*CO,thus enhancing the faradaic efficiency for ethylene.Density functional theory（DFT） calculation reveals that the Pd doping can regulate the electronic structure of neighboring Cu atoms to decrease the energy barrier of C-C coupling,further improving the faradaic efficiency.This work provides a new idea for designing catalyst with high selectivity for ethylene.

关键词： Adsorption configuration C–C coupling CO 2 electrocatalysis Ethylene Single atom alloy

Unique polysulfide reaction on VO2 for restraining shuttle effect in soft-packaged Li-S pouch cells

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Rare Metals 2024年第6期43卷 2842-2850页

作者： Ruo-Xuan Yang Qing-Chun Zhang Jing-Sheng Cai Xuan Cao Qin Yang Ying-Ze Song Wei Zhang State Key Laboratory of Environment-Friendly energy materials Tianfu Institute of Research and InnovationSchool of Materials and ChemistrySouthwest University of Science and Technology School of materials Engineering Changshu Institute of Technology Chongqing institute of Green and Intelligent Technology Chinese Academy of Sciences

The shuttle phenomenon and retarded conversion kinetics of lithium poly sulfides （LiPSs） are relatively severe in lithium-sulfur （Li-S） pouch cells.Owing to their redox potential in the sulfur working window,VO2na... 详细信息

关键词： Vanadium dioxide

Numerical Study of Water Transport and Operating Strategy for Fuel Cells with Segmented Water Management Flow Fields

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Journal of Thermal Science 2024年第4期33卷 1577-1589页

作者： CHEN Chengdai WANG Changhong ZHENG Zijun School of materials and energy Guangdong University of Technology

The effective cathode flow field design can realize the internal water balance and higher current density output of proton exchange membrane fuel cells(PEMFC).Therefore,a segmented water management flow field is proposed in this study,i.e.a half separated-half coupled cathode(HSHC) flow field which has two inlets but just one outlet.A 3D numerical PEMFC model is applied to study the effect of the HSHC flow field on PEMFC performance and its operating strategy in terms of operating conditions.The study results are shown as follows:Compared with the two conventional cathode flow fields,the HSHC flow field improves the water balance along the channel and increases the current density by 17.1% at a cathode stoichiometry of 3.25.It is because the HSHC flow field can overcome the water loss at channels upstream and the water accumulation at channels downstream.The draw water phenomenon(DWP) in the HSHC flow field is observed,which is mainly affected by the water vapor pressure of channel.Based on the DWP,cooling channel inlet flow rates can be used to adjust water balance,but severe water loss should be avoided.In addition,the inlet temperature control in HSHC flow field should be that cell temperature>cathode channel inlet temperature>cooling channel inlet temperature> ambient temperatures for better water balance.

关键词： proton exchange membrane fuel cells channel design segmented water management water balance operating strategy