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Chinese Journal of Polymer Science 2024年第10期42卷 1595-1601,I0015页

作者： Meng Wei Wei-Hao Feng Chen Yu Zhen-Yi Jiang Guang-Qiang Yin Wei Lu Tao Chen Key Laboratory of Advanced marine Materials Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo315201China School of Chemical sciences University of Chinese Academy of SciencesBeijing100049China School of Materials Science and Chemical Engineering Ningbo UniversityNingbo315211China

Achieving versatile room temperature phosphorescence(RTP)materials,especially with tunable mechanical properties and shape memory is attractive and essential but rarely ***,a strategy was reported to realize multi-functional RTP films with multicolor fluorescence,ultralong afterglow,adjustable mechanical properties,and shape memory through the synergistic dynamic interaction of lanthanide(Ln~Ⅲ)-terpyridine coordination,borate ester bonds,and hydrogen bondings in a poly(vinyl alcohol)(PVA)*** varying the amount of borax,the mechanical properties of the films could be finely controlled due to the change of crosslinking degree of dynamic borate ester bonds in *** assembly and disassembly of borate ester bonds upon the trigger of borax and acid were applied as reversible linkage to achieve programmable shape memory *** addition,the films displayed both fascinating multicolor fluorescence and ultralong afterglow characteristics due to the presence of Ln III doping and confinement of terpyridine in *** study provides a new avenue to impart modulable mechanical strength and shape memory to RTP materials.

关键词： Room temperature phosphorescence materials Dynamic bonds Multicolor fluorescent Tunable mechanical properties Shape memory

Linking coral fluorescence phenotypes to thermal bleaching in the reef-building Galaxea fascicularis from the northern South China Sea

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marine Life Science & Technology 2024年第1期6卷 155-167页

作者： Sanqiang Gong Jiayuan Liang Gang Li Lijia Xu Yehui Tan Xinqing Zheng Xuejie Jin Kefu Yu Xiaomin Xia Key Laboratory of Tropical marine Bio-Resources and Ecology&Guangdong Provincial Key Laboratory of Applied marine Biology South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou 510301China Southern marine Science and Engineering Guangdong Laboratory(Guangzhou) Guangzhou 510301China Coral Reef Research Center of China Guangxi UniversityNanning 53004China South China institute of Environmental sciences The Ministry of Ecology and Environment of PRCGuangzhou 510530China Third institute of Oceanography Ministry of Natural ResourcesXiamen 361005China

Coral fluorescence phenotypes have been suggested as an adaptation to a broad range of environmental conditions,yet the mechanisms linking thermal bleaching tolerance in reef-building coral populations,associated with fluorescence phenotypes due to GFP-like proteins,remains *** this study,the relationship between the thermal sensitivity and phenotypic plasticity of corals was investigated using two phenotypes of Galaxea fascicularis,green and *** results reveal that brown *** was more susceptible to bleaching than green *** when exposed to a higher growth temperature of 32℃.Both phenotypes of *** were associated with the thermotolerant Symbiodiniaceae symbiont,Durusdinium ***,the brown *** showed a significant decrease in Symbiodiniaceae cell density and a significant increase in pathogenic bacteria abundance when the growth temperature was raised from 29 to 32℃.The physiological traits and transcriptomic profiles of Symbiodiniaceae were not notably affected,but there were differences in the transcriptional levels of certain genes between the two phenotype hosts of *** heat stress of 32℃,the gene encoding green fluorescent protein(GFP)-like and chromosome-associated proteins,as well as genes related to oxidative phosphorylation,cell growth and death showed lower transcriptional levels in the brown *** compared to the green ***,the results demonstrate that the green form of *** is better able to tolerate ocean warming and defend against pathogenic bacteria,likely due to higher gene transcription levels and defense ability.

关键词： Fluorescence phenotype Thermal bleaching Microbiome Galaxea fascicularis Ocean warming

Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs

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Petroleum Science 2024年第04期21卷 2485-2501页

作者： Zhao-Bin Zhang Maryelin Josefina Brice?o Montilla Shou-Ding Li Xiao Li Jian-Peng Xing Yan-Zhi Hu Key Laboratory of Shale Gas and Geoengineering Institute of Geology and Geophysics Chinese Academy of Sciences institute of Earth sciences Chinese Academy of Sciences College of Earth and Planetary sciences University of Chinese Academy of Sciences institute of Energy Peking University

In-situ conversion presents a promising technique for exploiting continental oil shale formations,characterized by highly fractured organic-rich rock. A 3D in-situ conversion model, which incorporates a discrete fracture network, is developed using a self-developed thermal-flow-chemical(TFC) *** of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages. The findings indicate that kerogen decomposition increases fluid pressure, activating fractures and subsequently enhancing permeability. A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes, highlighting that increasing heating power correlates with higher cumulative fluid production. Activated fractures, with heightened permeability, facilitate the mobility of heavy oil toward production wells but hinder its cracking, thereby limiting light hydrocarbon ***, energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization, especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.

关键词： In-situ conversion Continental shale oil Natural fracture network TFC model

Vampyroteuthis pseudoinfernalis ***.:the second extant widespread deep sea squid species of Vampyromorpha(Cephalopoda:Coleoidea)

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Zoological Systematics 2024年第3期49卷 246-257页

作者： Dajun Qiu Bilin Liu Yupei Guo Wijesooriya A.S.W.Lakmini Yehui Tan Gang Li Zhixin Ke Kaizhi Li Liangmin Huang CAS Key Laboratory of Tropical marine Bio-resources and Ecology South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou 510301China University of Chinese Academy of sciences Beijing 100049China College of marine sciences Shanghai Ocean UniversityShanghai 200090China

The vampire squid,Vampyroteuthis infernalis Chun,1903,is currently the only extant species in the family Vampyroteuthidae Chun,***,specimens from the Gulf of Guinea,Africa,and California suggested the possibility of additional ***,we report the second species of Vampyroteuthis,collected from the South China Sea,China,which differs from *** by its tail shape,lower beak,photophores position,and the phylogenetic analysis of mitochondrial COI and nuclear large subunit ribosomal DNA(LSU)sequences:*** present by the lacking of the tail,photophores located approximately one-third of the points between the fins and end,and the lower beak with a broad,short wing;*** Qiu,Liu&Huang,*** by an acuate tail,a pair of photophores located at the midpoints between the fins and tail,and a lower beak with a broad,elongate wing.

关键词： Nuclear gene mitochondrial COI phylogeny morphology South China Sea

Genome-Wide Characterization of the Hyaluronidase Gene Family and Their Potential Roles in Viviparous Black Rockfish(Sebastes schlegeli)

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Journal of Ocean University of China 2024年第2期23卷 487-498页

作者： LIU Zhiying NIU Jingning ZHAO Xi LIU Huaxiang LI Zibin HE Yan QI Jie MOE Key Laboratory of marine Genetics and Breeding College of Marine Life SciencesOcean University of ChinaQingdao 266003China Key Laboratory of Tropical Aquatic Germplasm of Hainan Province Sanya Oceanographic InstituteOcean University of ChinaSanya 572025China

Black rockfish(Sebastes schlegelii)has evolved viviparous reproduction *** from the oviparous fishes,the spermatozoa of black rockfish are stored on the surface of ovarian follicle for over four months until the egg mature in ovary,while the adaptive evolution of fertilization-related genes remains to be *** the present study,based on the genome and transcriptome information of black rockfish,a total of 10 hyaluronidase genes were identified by phylogenetic and sequence analyses,including hyal1,hyal2,hyal3,hyal4,hyal6 and spam1a,spam1b,spam1c and *** spam1 subfamilies,including spam1a,spam1b,spam1c and spam1d,were significantly expanded compared to other *** adaptive evolution of hyaluronidase was further investigated by selection pressure analysis of branch model and branch site *** results showed that only spam1 subfamily was positively selected with a large number of positive selection sites,and the evolution rate was significantly higher thanthose of other *** positively selected sites,LYS-171 and GLY-164,were located in the neutral hyaluronidase activity domain,which was pivotal for SPAM1 to participate in enzymatic hydrolysis of the extracellular hyaluronic acid matrix and mediate acrosome reaction in ***,spam1 was mainly expressed in spermatocytes,secondary spermatocytes,and spermatids of testis,whereas it was not found in metamorphic sperm and mature sperm based on the spatiotemporal expression *** results indicated that spam1 might originate from the testis and might be an adaptation of viviparous trait in black rockfish.

关键词： adaptation of viviparous black rockfish(Sebastes schlegelii) hyaluronidase selective pressure analysis

The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties

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Chinese Journal of Polymer Science 2024年第1期42卷 63-72,I0008页

作者： Ming-Xuan Chen Jin-Yue Dai Li-Yue Zhang Shuai-Peng Wang Jing-Kai Liu Yong-Gang Wu Xin-Wu Ba Xiao-Qing Liu School of Chemistry and Materials Science Hebei UniversityBaoding 071000China Ningbo institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Key Laboratory of marine Materials and Related Technologies Chinese Academy of SciencesNingbo 315201China

It is of great significance to design epoxy coatings with superior antibacterial properties and high adhesive properties, as well as excellent processing, superior durability, and high transparency. However, it is still a challenge because of the common complex design and synthesis. Herein, the bio-based monomer protocatechuic acid(PCA) was used as raw material, the catechol structure with high bonding and antibacterial properties was introduced into the flexible alkane segment of ethylene glycol diglycidyl ether(EGDE) through an efficient, and green method, and it was cured with isophorone diamine(IPDA) to prepare corresponding thermosets. The cured resins exhibited excellent allaround qualities, particularly in bonding and antibacterial. When 30% PCA was added to pure epoxy resin, the adhesion between substrate and coating increased from 4.40 MPa to 13.60 MPa and the antibacterial rate of coating against E. coli and S. aureus could approach 100%. All of this is due to the fact that the catechol structure present in PCA has the ability to interact with various substrates and alter the permeability of bacterial cell membranes. The architecture of this method offers a fresh approach to dealing with the issues of challenging raw material selection and complex synthesis techniques.

关键词： Epoxy coatings Thermosets Catechol structure Antibacterial High adhesion

Pichia pastoris composition expressed aerolysin mutant of Aeromonas veronii as an oral vaccine evaluated in zebrafish(Danio rerio)

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marine Life Science & Technology 2024年第3期6卷 475-487页

作者： Yuan-Yuan Yao Qing-Shuang Zhang Shu-Bin Liu Hong-Wei Yang Xing-Yu Chen Ya-Lin Yang Chen-Chen Gao Chao Ran Tsegay Teame Zhen Zhang Zhi-Gang Zhou Key Laboratory for Feed Biotechnology of the Ministry of Agriculture Institute of Feed Research of Chinese Academy of Agricultural SciencesBeijing 100081China Sino-Norway Fish Gastrointestinal Microbiota Joint Lab Institute of Feed Research of Chinese Academy of Agricultural SciencesBeijing 100081China institute of marine sciences Shantou UniversityShantou 515063China Tigray Agricultural Research institute(TARI)Mekelle Center Tigray 7101Ethiopia

Vaccines are one of the most practical means to stop the spreading of Aeromonas veronii in *** this study,virulence factor aerolysin mutant NTaer which has lost its hemolytic activity was used as a target *** pastoris constitutive secretory expression NTaer(GS115-NTaer)was used as a potential safe oral vaccine to evaluate its effectiveness on zebrafish *** result shows that vaccination of GS115-NTaer for four weeks did not affect the growth performance of the host,while eliciting an effective immune protective *** with the control group,the GS115-NTaer could significantly up-regulate the relative expression level of the intestinal tight junction protein 1α(TJP1α)gene,and significantly increased the contents of lysozyme(LYZ),complement C3 and C4 in the gut,indicating that the innate immune response of the fish was *** relative gene expression levels of macrophage-expressed gene 1(MPEG1)and T cell receptor(TCR-α)in the gut,and MPEG1,CD4,CD8,TCR-α,GATA3,and T-bet in the spleen were all increased significantly,indicating that the cellular immune response of the fish was ***,the contents of serum IgM and intestinal mucosa IgZ antibodies were significantly increased,which showed that humoral immunity was also ***,inoculation with GS115-NTaer significantly changed the structure of gut *** particular,the relative ratio of(Firmicutes+Fusobacteriota+Bacteroidota)/Proteobacteria was significantly higher than that of the control and GS115 ***,the vaccinated fish were challenged with ***,and the relative percent survival of GS115 and the GS115-NTear groups was 14.28%and 33.43%.This improvement of immunity was not only due to the specific immune response but also attributed to the improvement of innate immunity and the gut microbiota which was demonstrated by the germ-free zebrafish ***,this study provides information on the effectiveness of GS115-NTear

关键词： Aeromonas veronii Aerolysin mutant NTaer Oral vaccine Immune response Gut microbiota

Investigating the Impact of Ocean Acidification on Anti-Stress Mechanisms in Sepia esculenta Larvae Based on Transcriptome Profiling

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Journal of Ocean University of China 2024年第4期23卷 1054-1066页

作者： WANG Yongjie LIU Xiumei LV Tingjin WANG Weijun SUN Guohua YANG Jianmin LI Zan School of Agriculture Ludong UniversityYantai 264025China College of Life sciences Yantai UniversityYantai 264005China Yantai institute of marine Economy Yantai 264003China

With the rapid development of oil,energy,power and other industries,CO_(2) emissions rise sharply,which will cause a large amount of CO_(2) in the air be absorbed by the ocean and lead to ocean *** growth and development of organisms can be seriously affected by acidified *** esculenta is a mollusk with high nutritional and economic value and is widely cultured in offshore waters of *** are the early life forms of the organism and are more vulnerable to changes in the external *** low pH will lead to some adverse reactions in larvae,which will affect metabolism,immune response and other life *** this study,we sequenced the transcriptome of *** subjected to acidified seawater stress and identified 1072differentially expressed genes(DEGs).The detected atypical expression of DEGs substantiates cellular malformation and translocation in *** under low pH ***,this also substantiates the notable impact of ocean acidification on *** DEGs were used for functional enrichment analysis of GO and KEGG,and the top twenty items of the biological process classification in GO terms and 11 KEGG signaling pathways were significantly ***,the constructed proteinprotein interaction network(PPI)was used to analyze protein-protein interactions,and 12 key DEGs and 3 hub genes were *** reliability of 12 genes was verified by quantitative RT-PCR.A comprehensive analysis of the KEGG signaling pathway and PPI revealed that ocean acidification leads to abnormalities in lipid metabolism in *** larvae,which can lead to cancer development and metastasis,accompanied by some degree of *** results of the study will help to further investigate the physiological processes of *** when stimulated by ocean acidification,and provide a reference to cope with the captive breeding of *** affected by acidification.

关键词： Sepia esculenta ocean acidification protein-protein interaction network transcriptome immunity

Two-dimensional MOF-based materials:Preparations and applications as electrodes in Li-ion batteries

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Journal of Energy Chemistry 2024年第10期97卷 388-418页

作者： Narges Nobakht Seyyed Ahmad Etghani Mohammad Hosseini Seyed Hamed Aboutalebi Condensed Matter National Laboratory Institute for Research in Fundamental Sciences Batt Scout Company School of Biological sciences Institute for Research in Fundamental Sciences

Two-dimensional(2D) metal-organic frameworks(MOFs) are rapidly emerging as a unique class of mushrooming family of 2D materials offering distinctive features,such as hierarchical porosity,extensive surface area,easily available active sites,and versatile,adaptable *** promising characteristics have positioned them as highly appealing alternatives for a wide range of applications in energy storage technologies,including lithium ***,the poor conductivity and limited stability of 2D MOFs have limited their real applications in electrochemical energy *** limitations have therefore warranted ongoing research to enhance the performance of 2D *** the significance of 2D MOF-based materials as an emerging class of advanced materials,a multitude of strategy has been devised to address these challenges such as synthesizing 2D conductive MOFs and derivatives along with 2D MOF *** promising approach involves the use of 2D MOF derivatives,including transition metal oxides,which due to their abundant unsatu rated active metal sites and shorter diffusion paths,offer superior electrochemical ***,by combining pristine 2D MOFs with other materials,hybrid 2D MOF materials can be *** hybrids,with their enhanced stability and conductivity,can be directly utilized as active materials in lithium *** the present review,we categorize 2D MOF-based materials into three distinct groups:pristine 2D MOFs,2D MOFderived materials,and 2D MOF hybrid *** synthesis methods for each group,along with their specific applications as electrode materials in lithium-ion batteries,are discussed in *** comprehensive review provides insights into the potential of 2D MOFs while highlighting the opportunities and challenges that are present in this evolving field.

关键词： 2D materials 2D metal-organic frameworks Energy storage Li-ion batteries Synthesis

Catch organism assemblages along artificial reefs area and adjacent waters in Haizhou Bay

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Acta Oceanologica Sinica 2024年第2期43卷 34-42页

作者： Shike Gao Bin Xie Chengyu Huang Xiao Zhang Shuo Zhang Wenwen Yu College of marine Living Resource sciences and Management Shanghai Ocean UniversityShanghai 201306China Jiangsu Research institute of marine Fisheries Nantong 226007China Third institute of Oceanography Ministry of Natural ResourcesXiamen361005China Joint Laboratory for Monitoring and Conservation of Aquatic Living Resources In the Yangtze Estuary Shanghai 200000China

To better understand the community patterns mediated by connectivity in artificial reefs of coastal areas, it is necessary to understand the distribution and coexistence of organisms with artificial reefs area and adjacent waters. This study was conducted to examine main catches assemblages collected by trawls in Haizhou Bay,which included five habitats: the artificial reef area(AR), aquaculture area(AA), natural area(NA), estuary area(EA) and comprehensive effect area(CEA). The result shows that the total abundances of species in the five habitats were highly different(univariate PERMANOVA: P = 0.001, n = 24), but some species were also unique in their habitat(e.g. Scapharca subcrenata and Glossaulax didyma in AA). The body size distribution of specific species between habitats are different. For Collichthys lucidus, their body size in AR(14.63 cm ± 1.64 cm) and EA(14.3 cm ± 0.85 cm) is higher than that in NA(10.65 cm ± 1.64 cm), CEA(11.28 cm ± 1.85 cm) and AA(12.1 cm ±0.43 cm), which indicates the potential connection from AR to EA mediated by their adult population. We concluded that artificial reefs in AR can be considered key components that have the ability to support species assemblages in adjacent habitats. This study has implications for the conservation and monitoring of species assemblages in coastal areas in terms of that artificial reefs can be applied in different stages of habitat protection implementation and in different combinations of scenarios.

关键词： assemblage artificial reefs adjacent water Haizhou Bay