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Journal of materials science & Technology 2015年第9期31卷 881-887页

作者： Camelia matei Ghimbeu Aleksandr I.Egunov Andrey S.Ryzhikov Valeriy A.Luchnikov institut de science des matériaux de mulhouse

Ensembles of freeze-dried self-rolled polymer micro-scrolls are explored as template media for produc- ing carbon-iron based composites with fibrous morphology. Polymer fibres impregnated with furfuryl alcohol and loaded with Fe2O3 particles, were thermally treated under inert atmosphere at 700 ℃ and subsequently analysed by scanning and transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, and nitrogen adsorption. The resulting material has a micro-fibrous mor- phology and is basically composed of metallic Fe^0 and FeO particles, i.e., more than 98 wt% of the carbon/ iron-based composite mass. These particles are held together by amorphous porous carbon foam obtained by in-situ carbonization of the polymer/Fe2O3 composite with evacuation of carbon from the system via COx gases released by carbo-reduction of Fe2O3. The material has significant activity in the reaction of catalytic decomposition of hydrogen peroxide in water solutions.

关键词： Composite materialsPorous carbonPolymersIron particles

Schwarzschild black hole surrounded by a cloud of strings in the background of perfect fluid dark matter

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Chinese Physics C 2025年第02期 224-240页

作者： B.Hamil B.C.Lütfüo?lu Laboratoire de Physique mathématique et Subatomique Faculté des Sciences ExactesUniversité Constantine 1 department of Physics Faculty of ScienceUniversity of Hradec Kralove

This manuscript investigates a Schwarzschild black hole surrounded by perfect fluid dark matter embedded in a cloud of strings. The effects of its surroundings on thermodynamics, timelike and null geodesics, shadows,and quasinormal modes are analyzed. It is demonstrated that changes in spacetime, induced by the surrounding environment, significantly influence the stability, thermal phases, energy dynamics, particle trajectories, and observable features of the black hole's shadow, as well as its oscillation frequency and decay rate.

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Importance of Molecular Method for detection of Microorganisms in the Exploration of the Infectious Etiology of Male Infertility in Burkina Faso

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Journal of Biosciences and Medicines 2025年第1期13卷 272-283页

作者： Michel Kiréopori Gomgnimbou Louis Robert W. Belem Armel Moumouni Sanou Claudel Fonessoubo Gbadjolbe Arnaud Quetin Sanou Kobo Gnada Azouman Da Etienne Bilgo Equipe Biologie Molculaire et Biotechnologies Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso Centre dexcellence Africain en Innovations Biotechnologiques pour lElimination des Maladies Transmission Vectorielle (CEA/ITECH-MTV) Universit Nazi BONI Bobo-Dioulasso Burkina Faso institut Suprieur des sciences de la Sant (IN.S.SA) Universit Nazi BONI Bobo-Dioulasso Burkina Faso Laboratoire de Recherche sur les Maladies Infectieuses et Parasitaire (LR-MIP) Institut de Recherche en Science de la Sante Bobo-Dioulasso Burkina Faso institut de Recherche en sciences de la Sant Direction Rgionale de lOuest Bobo-Dioulasso Burkina Faso

In Burkina Faso, as in other African countries, infertility has become a social burden for the population and a public health problem. Male infertility accounts for 30% to 40% of all infertility cases. The diagnosis of male infertility or hypofertility is often made by a simple laboratory analysis of sperm to explore sperm parameters. In most African countries, such as Burkina Faso, microbiological analysis in the context of sperm analysis is still not developed, and is carried out solely based on microscopy and traditional culture, which does not allow the growth of fragile and demanding bacteria. Our study investigated the microorganisms of sperm that may be involved in male infertility, using conventional bacteriology techniques and real-time PCR. However, it did not intend to perform a multivariate statistical association analysis to estimate the association of microorganisms with abnormal semen parameters. This prospective cross-sectional pilot study was carried out on patients who visited the bacteriology laboratory of Centre MURAZ, a research institute in Burkina Faso, for male infertility diagnosis between 2 August and 31 August 2021. Bacteria were isolated and identified using standard bacteriology techniques. In parallel, common pathogenic microorganisms known to be associated with male infertility were targeted and detected in the sperm using a multiplex real-time PCR assay. A total of 38 sperm samples were analyzed by bacteriological culture and bacteria isolated were Staphylococcus aureus (S. aureus) 5.55%, Klebsiella pneumoniae (K. pneumoniae), Enterococcus faecalis (E. faecalis), Streptococcus agalactiae (S. agalactiae) and Staphylococcus hoemalyticus (S. hoemalyticus) respectively 2.70%. Real-time PCR targeted and detected Chlamydia trachomatis (C. trachomatis) at 7.89%, Ureaplasma urealyticum (U. urealyticum) at 21.05%, Ureaplasma parvum (U. parvum) at 18.42%, Mycoplasma hominis (M. hominis) at 15.79%, Mycoplasma genitalium (M. genitalium) at 10.53%

关键词： Male Infertility Sperm Microorganisms Culture Molecular Diagnostic Burkina Faso

Molecular Diagnosis of Sexually Transmitted Infection Reveals a High Frequency of Neisseria gonorrhoeae Infection among Male Urethritis Patients and Highlights the Usefulness of Molecular Testing for Clinical Diagnosis in Burkina Faso

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American Journal of Molecular Biology 2025年第1期15卷 123-134页

作者： Michel Kiréopori Gomgnimbou Azouman Da Louis Robert W. Belem Kobo Gnada Karlhis Raymond Yao Arnaud Quetin Sanou Armel Moumouni Sanou Soufiane Sanou Dramane Kania Equipe Biologie Molculaire et Biotechnologies Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso Centre dexcellence Africain en Innovations Biotechnologiques pour lElimination des Maladies Transmission Vectorielle (CEA/ITECH-MTV) Universit Nazi BONI Bobo-Dioulasso Burkina Faso institut Suprieur des sciences de la Sant (IN.S.SA) Universit Nazi BONI Bobo-Dioulasso Burkina Faso Equipe Bactriologie-Mycobactriologie Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso Laboratoire de Recherche sur les Maladies Infectieuses et Parasitaire (LR-MIP) Institut de Recherche en Science de la Sante Bobo-Dioulasso Burkina Faso Equipe Virologie-Immunologie Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso

Sexually transmitted infections (STIs) represent a public health problem due to their high prevalence worldwide and the emergence of multidrug resistance of responsible microorganisms. Medical laboratory diagnosis of sexually transmitted genital infections by traditional methods as culture remains extremely delicate, difficult or impossible (to find extremely fragile organisms that can be cultured). Thus, molecular techniques constitute an alternative to improve accurate diagnostic, personalized patient treatment, and public health. A total of 83 clinical samples including urethral discharge and urine samples from individual patients with symptoms of urethritis received were analyzed using traditional methods and a commercial real-time PCR (qPCR) method. Out of 83 urethritis patients, n = 55 (66.26%) were positive for at least one of the STI pathogens detected by qPCR. qPCR assay was more sensitive (50/83, positive cases) compared to culture (15/83, positive cases) and light microscopy (28/83, positive cases). The most prevalent NTD pathogen in the suspected patients was N. gonorrhoeae with 60.24% (50/83) based on real-time PCR diagnosis. Among the positive cases of STI pathogens, Neisseria gonorrhoeae had the highest frequency 49/55 (89.01%) followed by low frequencies of Trichomonas vaginalis 4/55 (7.27%) and Chlamydia trachomatis 1/55 (1.82%). This highlights the high prevalence of N. gonorrhoeae infection in male urethritis patients and a very important misdiagnosis using traditional routine methods in Burkina Faso by medical laboratories. Thus, this situation may negatively impact patients’ personalized treatment and care and public health with the possible rapid emergence of multidrug-resistant strains. This study also highlights the urgent need to optimize culture for the diagnosis of NTD pathogens in Burkina Faso and the usefulness and the need for the introduction of molecular diagnostic methods in routine diagnosis for the detection of NTD pathogens in the

关键词： Molecular Diagnostic Methods Pathogens Sexually Transmitted Infection Urethritis Burkina Faso

Spread of Extended-Spectrum Beta-Lactamase-Producing Enterobacteriaceae Clinical Isolates from Patients in Bobo-Dioulasso, Burkina Faso

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Journal of Biosciences and Medicines 2025年第1期13卷 394-405页

作者： Kobo Gnada Michel Kiréopori Gomgnimbou Armel Moumouni Sanou Louis Robert W. Belem Azouman Da Arnaud Quetin Sanou Do Malick Soufiane Sanou Equipe Biologie Molculaire et Biotechnologies Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso Centre dexcellence Africain en Innovations Biotechnologiques pour lElimination des Maladies Transmission Vectorielle (CEA/ITECH-MTV) Universit Nazi BONI Bobo-Dioulasso Burkina Faso institut Suprieur des sciences de la Sant (IN.S.SA) Universit Nazi BONI Bobo-Dioulasso Burkina Faso Laboratoire de Recherche sur les Maladies Infectieuses et Parasitaire (LR-MIP) Institut de Recherche en Science de la Sante Bobo-Dioulasso Burkina Faso Equipe Bactriologie-Mycobactriologie Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso

Antimicrobial resistance (AMR) is one of the top 10 threats to global health and it is estimated around 10 millions of deaths per year are associated with AMR until 2050. Burkina Faso is also facing the emergence and spread of AMR of several bacteria resistant strains such as those of public health concerns under surveillance Enterobacteriaceae. The aim of this study was to assess the prevalence of extended-spectrum beta-lactamase-producing Enterobacteriaceae (ESBL-PE) clinical isolates from patients attending the bacteriology laboratory of the Centre MURAZ in Bobo-Dioulasso, Burkina Faso. Clinical isolates from urine, pus, stool, and semen were collected from April to June 2017. Identification and antibiotic susceptibility testing were performed using the VITEK 2 compact automated system according to EUCAST version 2015 recommendations. ESBL detection was then performed on the Muller-Hinton medium using the combined disc method. One hundred (100) strains of Enterobacteriaceae were isolated from 100 patients, including 52% of ESBLS. Escherichia coli (E. coli) was the most commonly isolated ESBL [(84.62, 44/72) ESBL], followed by Klebsiella spp. [(40%, 06/15) ESBL], then Enterobacter spp. [(40%, 2/5) ESBL]. Risk factor analysis revealed that ESBL-PE infection was frequently found in pus samples (P = 0.042;[OR] = 3.16;95% [CI] = 1.04 - 9.61) and that E. coli was the strain most likely to harbour ESBL (P = 0.008;[OR] = 3.60;95% [CI] = 1.40 - 9.31). This study reports a high prevalence of ESBL-PE associated with strong resistance to quinolones and cotrimoxazole (over 80%), which calls for increased surveillance of these superbugs, the adoption of a rational antibiotic prescription policy, and rigorous hygiene measures to prevent the spread of these multi-resistant bacteria.

关键词： Enterobacteriaceae ESBL Resistance Antibiogram Phenotypes Burkina Faso

Soil Fertility Improvement by Using Crotalaria Species Combined to Organic Amendment

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Open Journal of Soil science 2025年第1期15卷 22-42页

作者： Pane Jeanne d’Arc Coulibaly Lassané Ouédraogo Abdoulaziz Sandwidi Barkissa Fofana Fanta Blagnan Tionyélé Fayama Badiori Ouattara Ousmane Boukari Diallo Dpartement Gestion des Ressources Naturelles et Systmes de Production (GRN-SP) Institut de lEnvironnement et de Recherches Agricoles (INERA)/Centre National de Recherche Scientifique et Technologique (CNRST) Ouagadougou Burkina Faso Dpartement Environnement et Fort (deF) Institut de lEnvironnement et de Recherches Agricoles (INERA)/Centre National de Recherche Scientifique et Technologique (CNRST) Ouagadougou Burkina Faso Universit de Dori Universit Thomas Sankara Ouagadougou Burkina Faso

In Burkina Faso, agricultural land degradation, including soil fertility decline, has prompted the implementation of agricultural innovations to address this challenge. Therefore, this study aimed to evaluate the contribution of four Papilionaceous ecotypes in enhancing the fertility of degraded soils. Experiments were conducted in Noumousso and Arbollé from July to december 2024, using a randomized split-plot design combining ecotypes and organic matter and/or Burkina Phosphate amendments. Amendments were applied in four treatments: T0 (control), T1 (Organic matter), T2 (OM + Burkina Phosphate), and T3 (BP). determined physico-chemical properties were: particle size distribution, pH, carbon (C), nitrogen (Nt), total Phosphorus (Pt), available P (P_Bray), potassium (Kt), exchangeable bases (EB), cation exchange capacity (CEC), and saturation rate (SR). The evaluated agronomic parameter was total biomass. Results revealed that the soils at both sites were characterized by acidic sandy-clay texture and low levels of C, N, P, K, EB, and CEC. Cultivating papilionaceous and applying organo-mineral amendments contributed to increased levels of C, available P, and Mg2+, as well as improved SR. Acidity decreased at Arbollé, while showing a slight increase at Noumousso. Interaction between the two factors helped reduce acidity at both sites and significantly increased C, N, and available P contents. The organo-mineral amendment also enhanced biomass production across all ecotypes. At Noumousso, compared to T0, OM, OM + BP, and BP treatments resulted in biomass increases of 64.8%, 73.1%, and 38.6%, respectively. At Arbollé, the corresponding increases were 33.5%, 47%, and 23.4%. On both sites, OM + BP amendment had the greatest impact on improving biomass production, followed by organic amendment. These findings are of great importance to farmers for restoring the fertility of degraded soils. Therefore, the use of leguminous species in combination with organic matter enriched

关键词： Agricultural Innovations Burkina Phosphate Herbaceous Papilionaceous Organic matter

Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators

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Chinese Journal of Polymer science 2016年第12期34卷 1456-1468页

作者： Xing-yu Wu 金明 Jian-chao Xie de-cheng Wan Jean Pierre Malval School of materials science and Engineering Tongji UniversityShanghai 201804China institut de science des mattériaux de mulhouse UMR CNRS 7361Universitéde Haute-Alsace15 rue Jean Starcky68057 MulhouseFrance

A series of D-π-A type sulfonium salt photoacid generators with different π-conjugated structures, such as triphenyl, phenylstilbene, styryl-biphenyl, and stilbene, were designed to determine the effect of molecular structures on the photochemical and photophysical properties. The mechanisms of photochemical generation of H＋ were studied by UV-Vis spectroscopy, theoretical calculations, and fluorescence spectroscopy. It is found that the frontier orbits determine the absorption, the molar extinction coefficients, and the quantum yields of photoacid generation. Triphenyl systems connected with sulfonium are beneficial to increase the quantum yields of acid generation. The photoreactivity of four sulfonium salts was further evaluated through the polymerizations of various epoxide monomers at different irradiation wavelengths （365- 425 nm） by using the real-time infrared spectroscopy with light-emitting diodes. The high quantum yields for acid generation （ФH＋ = -0.32 to 0.58） and the high molar extinction coefficients （ε = -23500 ***-1 to 31000 ***-1） of the sulfonium salts lead to high conversion rates （over 50%-80%）. Hence, these photoinitiators exhibit potential for the photocuring applications.

关键词： Sulfonium salt Photoacid generators π-conjugated structures.

Evaluation of Diagnostic Performance of a Multiplex RT-qPCR Method for detecting deNV Serotypes and CHIKV in Clinical Samples, Ouagadougou, Burkina Faso

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Journal of Biosciences and Medicines 2025年第1期13卷 13-20页

作者： Michel Kiréopori Gomgnimbou Louis Robert W. Belem Boukandou Passi L. Mongo Shoukrat O. T. Bello Armel Moumouni Sanou Albert Théophane Yonli Théodora Mahoukèdè Zohoncon Jacques Simpore Equipe Biologie Molculaire et Biotechnologies Laboratoire de Recherche Centre MURAZ Institut National de Sant Publique Bobo-Dioulasso Burkina Faso Centre dexcellence Africain en Innovations Biotechnologiques pour lElimination des Maladies Transmission Vectorielle (CEA/ITECH-MTV) Universit Nazi BONI Bobo-Dioulasso Burkina Faso institut Suprieur des sciences de la Sant (IN.S.SA) Universit Nazi BONI Bobo-Dioulasso Burkina Faso Centre de Recherche Biomolculaire Pietro Annigoni (CERBA) Ouagadougou Burkina Faso Laboratoire de Recherche sur les Maladies Infectieuses et Parasitaire (LR-MIP) Institut de Recherche en Science de la Sante Bobo-Dioulasso Burkina Faso Laboratoire de Biologie Molculaire et de Gntique (LABIOGENE) UFR/SVT Universit Joseph Ki-Zerbo Ouagadougou Burkina Faso Facult de Mdecine Universit Saint Thomas dAquin (USTA) Ouagadougou Burkina Faso

Introduction: Arbovirus diseases such as dengue and chikungunya threaten public health worldwide. Early and rapid diagnosis and surveillance of dengue virus (deNV) and chikungunya virus (CHIKV) infections are essential to the control of these diseases. In this study, we evaluate the diagnostic performance of our new in-house multiplex RT-qPCR method for detecting deNV serotypes and CHIKV in an external laboratory. Methodology: The evaluation study was conducted on 200 clinical samples of suspected patients for arbovirus disease infection, collected in Centre de Recherche Biomoléculaire Pietro Annigoni (CERBA), Ouagadougou, Burkina Faso. Our new multiplex RT-qPCR was compared to the commercial kit, the Zika, dengue, and Chikungunya (ZDC) Real-Time PCR Assays kit (Bio-Rad, California, USA). Results and Conclusions: Among 200 samples, 21.5% (43/200) were deNV-positive by multiplex RT-qPCR, and 21.5% (43/200) were also deNV-positive by reference real-time RT-PCR. 157 (78.5%) samples tested negative for deNV by both tests (new mRT-qPCR and reference test). The sensitivity and specificity of mRT-qPCR were 100%. The deNV serotypes detected were deNV-1 60.5% (26/43) and deNV-3 39.5% (17/43). CHIKV was not detected in this study. Our new mRT-qPCR is sensitive, cost-effective, simple, and can be used in developing country laboratories.

关键词： Evaluation Multiplex RT-qPCR dengue Virus Chikungunya Burkina Faso

Nonaqueous potassium-ion full-cells:Mapping the progress and identifying missing puzzle pieces

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Journal of Energy Chemistry 2024年第6期93卷 384-399,I0010页

作者： Badre Larhrib Louiza Larbi Lénaïc Madec Universite de Pau et des Pays de l’Adour E2S UPPACNRSIPREMPauFrance Universitéde Haute-Alsace Institut de Science des Matériaux de Mulhouse(IS2M)CNRS UMR 7361F-68100 MulhouseFrance Universitéde Strasbourg F-67081 StrasbourgFrance Réseau sur le Stockage Electrochimique de l’Energie CNRS FR3459AmiensFrance institut des matériaux Jean Rouxel(IMN) CNRS UMR 6502Univ.Nantes44322 Cedex 3 NantesFrance

This review addresses the growing interest for potassium-ion full-cells(KIFCs)in view of the transition from potassium-ion half-cells(KIHCs)toward commercial K-ion batteries(KIBs).It focuses on the key parameters of KIFCs such as the electrode/electrolyte interfaces challenge,major barriers,and recent advancements in *** strategies for enhancing KIFC performance,including interfaces co ntrol,electrolyte optimization,electrodes capacity ratio,electrode material screening and electrode design,are *** review highlights the need to evaluate KIBs in full-cell configurations as half-cell results are strongly impacted by the K metal *** also emphasizes the importance of understanding solid electrolyte interphase(SEI)formation in KIFCs and explores promising nonaqueous as well as quasiand all-solid-state electrolytes *** review thus paves the way for practical,cost-effective,and scalable KIBs as energy storage systems by offering insights and guidance for future research.

关键词： K-ion full-cells Potassium-ion batteries Cross-talk Solid-state batteries Potassium reactivity Electrolyte design Electrode design

Microstructure and Transformation Behavior of in-situ Shape Memory Alloys by Selective Laser Melting Ti-Ni Mixed Powder

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Journal of materials science & Technology 2013年第9期29卷 863-867页

作者： Baicheng Zhang Jing Chen Christian Coddet LERMPS Université de Technologie de Belfort-Montbéliard Site de Sévenans Laboratoire des matériaux Macromoléculaires Ingénierie des Matériaux Polymères

The selective laser melting （SLM） of Ti-Ni mixed powder with atomic ratio of 1：1 was performed in the present work in order to elaborate shape memory alloy （SMA）. The martensite phase of Ti-Ni alloy can be found by X-ray diffraction （XRD） analysis under temperature field, moreover, the Ti2Ni phase at a high scanning velocity. The crystalline phase images also show that the synthesized Ti-Ni alloy possessed a refined martensite microstructure. In order to evaluate the mechanical properties, the microhardness and porosity were measured. The microhardness is relatively high about 400HVo.2 with champ temperature. Besides, the porosity is quite low due to the excellent laser energy absorptivity and meltability of Ni element. The differential scanning calorimetry （DSC） analysis shows that the transformation temperature from austenite phase to martensite phase is relatively high and stable.

关键词： Selective laser melting Microstructnre Shape memory alloy