检索结果-南通市图书馆

Review Article Li-current collector interface in lithium metal batteries

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano research 2024年第10期17卷 8706-8728页

作者： Tian-Yu Wang Dingyi Zhao Keyue Liang Yuzhang Li Department of Chemical and biomolecular Engineering University of CaliforniaLos AngelesLos AngelesCalifornia 90095USA

Interfaces within batteries,such as the widely studied solid electrolyte interface(SEI),profoundly influence battery *** these interfaces,the solid-solid interface between electrode materials and current collectors is crucial to battery performance but has received less discussion and *** review highlights the latest research advancements on the solid-solid interface between lithium metal(the next-generation anode)and current collectors(typically copper),focusing on factors affecting the Li-current collector interface and improvement strategies from perspectives of current collector substrate(lithiophilicity,crystal facets,mechanical properties,and topological structure),electrolyte chemistry,current density,stacking pressure,SEI,electric field and temperature,and provides a future directions and opportunities on this topic.

关键词： lithium metal anode current collectors Li-current collector interface solid-solid interface improvement strategies

Hyperreflective photonic crystals created by shearing colloidal dispersions at ultrahigh volume fraction

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Microsystems & Nanoengineering 2024年第1期10卷 161-173页

作者： Minji Kim Jong Bin Kim Shin-Hyun Kim Department of Chemical and biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea

Colloidal crystallization serves as one of the most economic and scalable production methods for photonic ***,insufficient optical performance,nonuniformity and low reproducibility remain challenges for advanced high-value *** this study,we optimally formulate a photocurable dispersion of silica particles and apply shear flow to unify the orientation of the colloidal crystals,ensuring high optical performance and *** silica particles experience strong repulsion at ultrahigh volume fractions of 50%but demonstrate low mobility,leading to polycrystalline *** shear flow to the dispersions allows the silica particles to rearrange into larger crystalline domains with a unidirectional orientation along the *** shear-induced structural change produces absolute reflectivity at the stopband as high as 90%and a high transparency of 90%at off-resonant wavelengths with minimal diffusive ***,the strong interparticle repulsion ensures a uniform volume fraction of particles throughout the dispersion,reducing deviations in the optical *** intricately micropattern the photocurable dispersions using ***,the photonic films and patterns can be stacked to form multiple layers,displaying mixed structural colors and multiple reflectance peaks without sacrificing *** superior photonic materials hold promise for various optical applications,including optical components and anticounterfeiting patches.

关键词： properties. dispersion reflectivity

Practical operating flexibility of a bifunctional freestanding membrane for efficient anion exchange membrane water electrolysis across all current ranges

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Carbon Energy 2024年第9期6卷 306-324页

作者： Hong-Jin Son Jeemin Hwang Min Young Choi Seung Hee Park Jae Hyuk Jang Byungchan Han Sung Hoon Ahn Department of Bio-Chemical Engineering Chosun UniversityGwangjuRepublic of Korea Fuel Cell research and Demonstration Center Hydrogen Energy Research DivisionKorea Institute of Energy Research(KIER)Buan-gunJeollabuk-doRepublic of Korea Department of Chemical and biomolecular Engineering Yonsei UniversitySeoulRepublic of Korea Center for research Equipment Korea Basic Science InstituteDaejeonRepublic of Korea

This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic ***,a rapid and mild synthesis technique for fabricating fibrous membrane-type catalyst electrodes is *** method leverages the contrasting oxidation states between the sulfur-doped NiFe(OH)2 shell and the metallic Ni core,as revealed by electron energy loss *** evaluations confirm that the S–NiFe(OH)_(2) active sites optimize free energy for alkaline water electrolysis *** technique bypasses traditional energy-intensive processes,achieving superior bifunctional activity beyond current *** symmetric AEM water electrolyzer demonstrates a current density of 2 A cm^(-2) at 1.78 V at 60℃ in 1 M KOH electrolyte and also sustains ampere-scale water electrolysis below 2.0 V for 140 h even in ambient *** results highlight the system's operational flexibility and structural stability,marking a significant advance-ment in AEM water electrolysis technology.

关键词： AEM water electrolysis fibrous membrane iR correction free operational stability symmetric configuration

High-performance nickel metal hydride battery anode with enhanced durability and excellent low-temperature discharge capability

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano research 2024年第10期17卷 8819-8825页

作者： Zhitao Chen Huitian Liu Jean Nei Nian Liu School of Chemical and biomolecular Engineering Georgia Institute of TechnologyAtlantaGA 30332USA GP Batteries HongkongChina

Current AB_(5)-type hydrogen storage alloys employed in nickel-metal hydride(NiMH)batteries exhibit exceptional low-temperature discharge performance but suffer from limited cycle life and insufficient high-temperature *** overcome these challenges,we introduce a hydrothermal synthesized LaF_(3)coating layer on the surface of the AB_(5)anode *** LaF_(3)coating layer adds a protective barrier for the active material,significantly improving the battery's cycle life and high-temperature *** findings indicate that(1)the LaF_(3)coated anode demonstrates an extended cycle life with increased specific capacity and a capacity retention of 88%after 40 cycles of abusive overcharging and rapid discharging at room temperature.(2)The synthesized anode exhibits a 97%recovery of its specific capacity of 292.7 mAh/g following 144 h of high-temperature storage.(3)The low-temperature discharge capacity of the synthesized anode remains on par with the pristine AB_(5)alloy at 230.4 mAh/g in a-40℃*** research presents a significant advancement in hydrogen storage alloy coatings and offers valuable insights for designing electrodes in NiMH batteries.

关键词： nickel metal hydride(NiMH)batteries hydrothermal synthesis lanthanum fluoride discharge capacity low temperature

Bioinspired nanomaterials for the treatment of bacterial infections

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano research 2024年第2期17卷 691-714页

作者： Xiaojing Ma Wenjing Tang Rong Yang Robert F.Smith School of Chemical&biomolecular Engineering Cornell UniversityIthacaNY 14853USA

Infectious diseases pose a serious threat to global *** immunizations can control most viral infections,bacterial infections,particularly those caused by drug-resistant strains,continue to cause high rates of illness and ***,the creation of new antibiotics has come to a grinding halt in the last ten *** response to this crisis,nanotechnology has emerged as a hopeful solution to tackle drug resistance and enhance treatment results.A large variety of biomimetic nanomaterials,termed nanozymes,have demonstrated strong antimicrobial *** the inherent toxicity of nanomaterials is a concern,recent studies have harnessed the stimuli-responsiveness of nanomaterials to enable local and/or targeted delivery to reduce the treatment side ***,the physicochemical versatility of nanomaterials affords many degrees of freedom that enable rational design of smart or autonomous therapeutics,which cannot be achieved using conventional *** design straddles the fields of catalysis,nanoscience,microbiology,and translational *** provide an overview of this interdisciplinary landscape,this review is organized based on composition into lipid,metal,metal oxide,and non-metallic *** as a delivery vehicle enhance bioavailability and reduce ***-and metal oxide-based nanomaterials inhibit bacterial growth by mimicking natural enzymatic activities such as peroxidase(POD)and ***,carbon-,polymer-,and cell membrane-based nanomaterials are combined into a discussion on non-metallic *** the end of this review,potentially fruitful directions for future bioinspired nanomaterials in infectious disease treatment are included.

关键词： bioinspired nanomaterial bacteria infectious disease antimicrobial liposome nanozyme

Porous Indium Nanocrystals on Conductive Carbon Nanotube Networks for High-Performance CO2-to-Formate Electrocatalytic Conversion

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第4期7卷 413-421页

作者： Liangping Xiao Rusen Zhou Tianqi Zhang Xiaoxiang Wang Renwu Zhou Patrick J.Cullen Kostya (Ken) Ostrikov Department of Physics Research Institute for Biomimetics and Soft Matter Fujian Provincial Key Laboratory for Soft Functional Materials Jiujiang Research Institute Xiamen University School of Chemistry and Physics QUT Centre for Materials Science and QUT Centre for a Waste-Free World Queensland University of Technology(QUT) School of Chemical and biomolecular Engineering University of Sydney

Ever-increasing emissions of anthropogenic carbon dioxide （CO2） cause global environmental and climate *** by biological photosynthesis,developing effective strategies NeuNlto up-cycle CO2into high-value organics is *** CO2reduction reaction （CO2RR） is highly promising to convert CO2into economically viable carbon-based chemicals or fuels under mild process conditions.

关键词： CO2RR conductive network electrocatalysts formate

Flexible Covalent Organic Frameworks:Design,Synthesis,and Applications

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

CCS Chemistry 2024年第4期6卷 856-881页

作者： Chunqing Ji Chengjun Kang Bidhan Chandra Patra Dan Zhao Department of Chemical and biomolecular Engineering National University of SingaporeSingapore 117585

Structural flexibility is an intriguing characteristic observed in materials that endows them with dynamic properties,allowing for intelligent adaptation and deformation in response to varying *** organic frameworks(COFs),a promising class of crystalline porous polymers,have garnered significant attention due to their unique features,including well-ordered,predesignable,and tunable structures,as well as their light-weighted nature and high thermal/chemical *** flexibility into COFs offers a captivating pathway for developing advanced materials with dynamic properties and versatile *** flexible COF field is currently experiencing rapid expansion,and there is a growing need for systematic review articles that offer a comprehensive overview of the developments in this *** this mini-review,we delve into the factors that contribute to structural flexibility in COFs from the point of structural *** summarize and categorize various modes of achieving flexibility across different dimensions,and discuss the potential applications of flexible COFs in vapor/gas adsorption,sensing,and smart membrane separations;further,we highlight their prospects and future research advancement.

关键词： covalent organic frameworks framework flexibility inducing factors flexibility modes smart materials

Challenges and Opportunities in Preserving Key Structural Features of 3D-Printed Metal/Covalent Organic Framework

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第8期16卷 362-381页

作者： Ximeng Liu Dan Zhao John Wang Department of Materials Science and Engineering National University of SingaporeSingapore 117574Singapore Department of Chemical and biomolecular Engineering National University of SingaporeSingapore 117585Singapore National University of Singapore(Chongqing)research Institute Chongqing 401123People’s Republic of China

Metal-organic framework(MOF)and covalent organic framework(COF)are a huge group of advanced porous materials exhibiting attractive and tunable microstructural features,such as large surface area,tunable pore size,and functional surfaces,which have significant values in various application *** emerging 3D printing technology further provides MOF and COFs(M/COFs)with higher designability of their macrostructure and demonstrates large achievements in their performance by shaping them into advanced 3D ***,the currently available 3D printing M/COFs strategy faces a major challenge of severe destruction of M/COFs’microstructural features,both during and after 3D *** is envisioned that preserving the microstructure of M/COFs in the 3D-printed monolith will bring a great improvement to the related *** this overview,the 3D-printed M/COFs are categorized into M/COF-mixed monoliths and M/COF-covered *** differences in the properties,applications,and current research states are *** up-to-date advancements in paste/scaffold composition and printing/covering methods to preserve the superior M/COF microstructure during 3D printing are further discussed for the two types of 3D-printed M/*** the analysis of the current states of 3D-printed M/COFs,the expected future research direction to achieve a highly preserved microstructure in the 3D monolith is proposed.

关键词： Metal-organic frameworks Covalent organic frameworks 3D printing Microstructure Monolith

The adsorption effect of aquaculture residual feed on heavy metals and its impact on microbial metabolism of feed

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Ecological Processes 2024年第2期13卷 246-259页

作者： Sufeng Wang Zijng Wang Wen Zhang Jingshan Li Mingyang Lin Li Chen State Key Laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse Yanshan University Key Laboratory of Pollution Exposure and Health intervention of Zhejiang Province College of Biology and Environmental EngineeringZhejiang Shuren University Hebei Ocean & Fisheries Science research Institute

Background Intensive and large-scale aquaculture has a high biological density, and a large amount of artificial feed must be provided. As a result, residual feed would be discharged into natural water bodies with water exchange. Due to heavy metal pollution in surface water, residual feed may adsorb heavy metals in the water, affecting the subsequent microbial degradation of feed and the restoration of the water environment. The combined ecological impacts of these two types of pollution urgently need to be *** This study explored the adsorption effect of residual feed on heavy metals and its impact on microbial degradation of residual feed. The results showed that both the insoluble component（mainly fiber, ash, and ether extract, abbreviated as FAE） and soluble component（soluble protein and starch） of the feed had adsorption effects on heavy metals. As the salinity increased, the adsorption capacity of Cu2+and Cd2+decreased, while the adsorption effect on Pb2+was not changed significantly. The adsorption of heavy metals by residual feed could affect the biological degradation of residual feed. The residual feed could adsorb heavy metals and bacterial cells simultaneously, forming FAE-B（bacteria）-S（starch）-Pr（protein）-metal adsorption complex. This adsorption effect could reduce the negative impact of heavy metals on microbial degradation of residual feed. The simulated degradation experiments in actual water bodies also confirmed this. However, the accumulation of heavy metals in residual feed may bring negative effects, such as being consumed by aquatic organisms and entering the food *** The results of this study provide a basis for the collection and centralized treatment of residual feed in aquaculture, as well as the control and remediation of residual feed pollution in natural water bodies.

关键词： Residual feed Adsorption complex Feed pollution Heavy metal