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The utilization of spent palm cooking oil for formulating oil-based drilling muds with excellent H2S scavenging capability

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Petroleum research 2024年第2期9卷 280-288页

作者： Sagheer A.Onaizi Department of Chemical Engineering and Interdisciplinary Research Center for Hydrogen and Energy StorageKing Fahd University of Petroleum&Minerals31261DhahranSaudi Arabia

In this study,a spent palm cooking oil-based mud with an excellent H2S scavenging capability induced by the inclusion of a small quantity of potassium permanganate is formulated and tested for the first *** mud formulation,containing the spent palm oil as the continuous phase and water as the dispersed phase,respectively,was stabilized by Span 80 and rhamnolipid biosurfactant as primary and secondary emulsifiers,respectively,while hydrophobic zinc nanoparticles(NPs)were used as weighting *** results showed that H2S scavenging capacity at the breakthrough time reached 182.4 g H2S/barrel mud,which increased to 417.9 g H2S/barrel mud at the saturation time,demonstrating the effective H2S scavenging performance of the formulated *** spent palm oil-based mud(SPOBM)also showed a good flow behavior that could be well fitted using the Herschel-Bulkley and Casson *** effect of temperature on the apparent viscosity of the SPOBM has been investigated,and the fitting of the viscosity-temperature data provided an estimate of the activation energy as 23.53 kJ/*** findings reported in this article reveal the feasibility of transforming the spent/waste cooking oils into a valuable commodity for formulating greener drilling fluids with acceptable rheology and excellent H2S scavenging performance.

关键词： hydrogen sulfide(H2S) Oil-based mud(OBM)drilling fluids Spent palm oil H2S scavengers Rheology

Heterovalent ion exclusion principle in atomically single site metal(hydr)oxide catalysts design

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Science Bulletin 2024年第13期69卷 2009-2012页

作者： Daojin Zhou Fengmei Wang Yun Kuang Xiaoming Sun State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Ocean hydrogen Energy R&D center Research Institute of Tsinghua University in ShenzhenShenzhen 518057China

Single-atom catalysts(SACs)are a series of catalysts in which all metal species are atomically dispersed on oxides,zeolites,sulfides,carbons,and so *** concept describing how atoms arrange with their nearest neighbors was proposed in 1969 by Van Hardeveld and co-workers[1],and researchers witness the growing popularity of SACs[2].However,the first long-standing issue in SACs is that the low concentration of active sites on the ***,weak chemical bonds between active sites with supports cannot sustain the functionalities of the SACs during long-term reactions,especially ones run at harsh conditions(high temperature or humidity,strong oxidative conditions).The loss or aggregation of active sites in SACs require substantial efforts to address the existing drawbacks in traditional SACs.

关键词： atomic bonds valent

Advancements,strategies,and prospects of solid oxide electrolysis cells(SOECs):Towards enhanced performance and large-scale sustainable hydrogen production

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Journal of Energy Chemistry 2024年第7期94卷 688-715页

作者： Amina Lahrichi Youness El Issmaeli Shankara S.Kalanur Bruno G.Pollet Green hydrogen Lab(GH2Lab) Hydrogen Research Institute(HRI)Universitédu QuébecàTrois-Rivières(UQTR)3351 boulevard des ForgesTrois-RivièresQuébec G9A 5H7Canada

Solid oxide electrolysis cells(SOECs)represent a crucial stride toward sustainable hydrogen generation,and this review explores their current scientific challenges,significant advancements,and potential for large-scale hydrogen *** SOEC technology,the application of innovative fabrication tech-niques,doping strategies,and advanced materials has enhanced the performance and durability of these systems,although degradation challenges persist,implicating the prime focus for future *** we provide in-depth analysis of the recent developments in SOEC technology,including Oxygen-SOECs,Proton-SOECs,and ***,Hybrid-SOECs,with their mixed ionic conducting electrolytes,demonstrate superior efficiency and the concurrent production of hydrogen and *** with the capacity to harness waste heat,these advancements in SOEC technology present signif-icant promise for pilot-scale applications in *** review also highlights remarkable achieve-ments and potential reductions in capital expenditure for future SOEC systems,while elaborating on the micro and macro aspects of sOECs with an emphasis on ongoing research for optimization and *** concludes with the potential of SOEC technology to meet various industrial energy needs and its significant contribution considering the key research priorities to tackle the global energy demands,ful-fillment,and decarbonization efforts.

关键词： Solid oxide electrolysis cells Proton-SOECs Oxygen-SoECs Hybrid-SOECs Intermediate-high temperature electrolysers hydrogenproduction

吩嗪类衍生物用于快速充放电和长寿命的水系钾离子全电池负极

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Science China Materials 2024年第5期67卷 1464-1470页

作者：郑易帆于丹丹王健晨杨杰罗稳戈天奇秦来顺黄岳翔陈达 College of Materials and Chemistry China Jiliang UniversityHangzhou310018China hydrogen Energy research center PetroChina Petrochemical research Institute Beijing102200China

有机电极材料因具有结构多样性和可持续性,在水系钾离子电池研究领域展示出广阔的前景,但它们大多数存在导电性差、易溶于电解液的问题,导致电极活性物质利用率低、循环稳定性差.本文通过含氮苯环的共轭延申、引入氰基活性中心,获得了3C... 详细信息

有机电极材料因具有结构多样性和可持续性,在水系钾离子电池研究领域展示出广阔的前景,但它们大多数存在导电性差、易溶于电解液的问题,导致电极活性物质利用率低、循环稳定性差.本文通过含氮苯环的共轭延申、引入氰基活性中心,获得了3CN-HATN.与经#吩嗪负极相比,3CN-HATN的最低未占据分子轨道能级更低,更容易被还原,且其能带隙较窄,改善了导电性,其共轭结构可有效抑制循环过程中3CN-HATN的溶解.3CN-HATN负极在80 C(1 C=350 mA g^(-1))下比容量高达233.8 mA h g^(-1),将其与Ni(OH)_(2)正极匹配,构建的水系钾离子全电池具备优异的循环稳定性和快充性能,30 C下循环10,000圈后容量保持率达81.5%.

关键词： aqueous rechargeable batteries π-conjugated structure organic electrodes K+storage phenazine derivatives

Implications of electrode modifications in aqueous organic redox flow batteries

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Journal of Energy Chemistry 2024年第8期95卷 499-510,I0011页

作者： Zahid Manzoor Bhat Mohammad Furquan Muhammad Aurang Zeb Gul Sial Umair Alam Atif Saeed Alzahrani Mohammad Qamar Interdisciplinary research center for hydrogen Technologies and Carbon Management(IRC-HTCM) King Fahd University of Petroleum&Minerals(KFUPM)Dhahran 31261Saudi Arabia Department of Materials Science and Engineering King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia Interdisciplinary research center for Sustainable Energy Systems(IRC-SES) King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia

Aqueous organic redox flow batteries(RFBs)exhibit favorable characteristics,such as tunability,multielectron transfer capability,and stability of the redox active molecules utilized as anolytes and catholytes,making them very viable contenders for large-scale grid storage *** attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance *** the fact that electrodes are vital to optimal performance,they have not garnered significant *** research has been conducted on the effects of electrode modifications to improve the performance of *** primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic *** overview of electron transfer at the electrode-electrolyte interface is *** implications of electrode modification on the performance of redox flow batteries,with a particular focus on the anodic and cathodic half-cells separately,are then *** each section,significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and ***,we have presented a comprehensive assessment along with our perspectives on the future trajectory.

关键词： Redox flow batteries Electrode modification Organic redox molecules Outer sphere and inner sphere

Oxygen vacancy engineering for tuning the catalytic activity of LaCoO_(3) perovskite

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Journal of Rare Earths 2024年第3期42卷 506-514,I0003页

作者： Jeong Hyun Cho Minjae Kim Inchan Yang Kyung Tae Park Chang Houn Rhee Hai Woong Park Ji Chul Jung Department of Chemical Engineering Myongji UniversityYongin 17058Republic of Korea Institute of Advanced Composite Materials Korea Institute of Science and TechnologyWanju-gunJeollabuk-do 55324Republic of Korea Iron&Steel Process Engineering research Group POSCOPohang 37859Republic of Korea hydrogen research center Research Institute of Industrial Science&Technology(RIST)Pohang 37673Republic of Korea

Herein, we attempted to engineer oxygen vacancies on the surface of LaCoO_(3) perovskite through simple post-treatments(acid or reductive thermal treatments). Acid treatment induces oxygen vacancies through the selective etching of the La cations, whereas thermal treatment in a reducing atmosphere generates oxygen vacancies by directly removing lattice oxygen. The characterization results confirm that the number of surface oxygen vacancies, which are crucial in various catalytic oxidation reactions,considerably increases in the LaCoO_(3) catalysts treated with acid or reducing gas. Acid treatment enriches the oxygen vacancies while maintaining the structure of the LaCoO_(3) catalysts, which can not be achieved through reductive thermal treatment. Therefore, the acid treatment is considered a promising technique for oxygen vacancy engineering of perovskite catalysts for tuning their catalytic activities. Furthermore,the catalytic activities of the posttreated LaCoO_(3) catalysts for CO oxidation were evaluated and are noted to be considerably better than those of the pristine LaCoO_(3) catalyst due to their abundant oxygen vacancies. Consequently, we conclude that the oxygen vacancies of perovskite catalysts can be effectively engineered via two simple methods and play a significant role in CO oxidation.

关键词： LaCoO_(3)perovskite Acid treatment Reductive thermal treatment Oxygen vacancy CO oxidation Rare earths

Boosting hydrogen Storage Performance of MgH_(2) by Oxygen Vacancy-Rich H-V_(2)O_(5) Nanosheet as an Excited H-Pump

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Nano-Micro Letters 2024年第8期16卷 398-416页

作者： Li Ren Yinghui Li Zi Li Xi Lin Chong Lu Wenjiang Ding Jianxin Zou National Engineering research center of Light Alloys Net Forming&State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Shanghai Engineering research center of Mg Materials and Applications&School of Materials Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China center of hydrogen Science Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Instrumental Analysis center of SJTU Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

MgH_(2) is a promising high-capacity solid-state hydrogen storage material,while its application is greatly hindered by the high desorption temperature and sluggish ***,intertwined 2D oxygen vacancy-rich V_(2)O_(5) nanosheets(H-V_(2)O_(5))are specifically designed and used as catalysts to improve the hydrogen storage properties of MgH_(2).The as-prepared MgH_(2)-H-V_(2)O_(5) composites exhibit low desorption temperatures(Tonset=185℃)with a hydrogen capacity of 6.54 wt%,fast kinetics(Ea=84.55±1.37 kJ mol^(-1) H_(2) for desorption),and long cycling ***,hydrogen absorption can be achieved at a temperature as low as 30℃ with a capacity of 2.38 wt%within 60 ***,the composites maintain a capacity retention rate of~99%after 100 cycles at 275℃.Experimental studies and theoretical calculations demonstrate that the in-situ formed VH_(2)/V catalysts,unique 2D structure of H-V_(2)O_(5) nanosheets,and abundant oxygen vacancies positively contribute to the improved hydrogen sorption ***,the existence of oxygen vacancies plays a double role,which could not only directly accelerate the hydrogen ab/de-sorption rate of MgH_(2),but also indirectly affect the activity of the catalytic phase VH_(2)/V,thereby further boosting the hydrogen storage performance of MgH_(2).This work highlights an oxygen vacancy excited“hydrogen pump”effect of VH_(2)/V on the hydrogen sorption of Mg/MgH_(2).The strategy developed here may pave a new way toward the development of oxygen vacancy-rich transition metal oxides catalyzed hydride systems.

关键词： hydrogen storage MgH_(2) V_(2)O_(5)nanosheets Oxygen vacancies VH_(2)

Synthesis of boron nitride nanorod and its performance as a metalfree catalyst for oxidative desulfurization of diesel fuel

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Chinese Journal of Chemical Engineering 2024年第4期68卷 120-132页

作者： Tanaz Ghanadi Gholamreza Moradi Alimorad Rashidi Catalyst research center Faculty of Chemical and Petroleum EngineeringRazi UniversityKermanshahIran Nanotechnology research center Research Institute of Petroleum Industry(RIPI)TehranIran

In order to reduce the sulfur compounds in diesel fuel,boron nitride(BN)has been used as a novel metal-free catalyst in the present *** nanocatalyst was synthesized via template-free approach followed by heating treatment at 900℃ in nitrogen atmosphere that the characteristics of the sample were identified by the X-ray diffraction,Fourier-transform infrared spectroscopy,Raman spectroscopy,field emission scanning electron microscopy,transmission electron microscopy,atomic force microscopy,and N2 adsorption-desorption *** results of structural and morphological analysis represented that BN has been successfully *** efficacy of the main operating parameters on the process was studied by using response surface methodology based on the Box-Behnken design *** prepared catalyst showed high efficiency in oxidative desulfurization of diesel fuel with initial sulfur content of 8040 mg·kg^(-1)*** statistical analysis,a significant quadratic model was obtained to predict the sulfur removal as a function of efficient *** maximum efficiency of 72.4%was achieved under optimized conditions at oxidant/sulfur molar ratio of 10.2,temperature of 71℃,reaction time of 113 min,and catalyst dosage of 0.36 ***,the reusability of the BN was studied,and the result showed little reduction in activity of the catalyst after 10 times ***,a plausible mechanism was proposed for oxidation of sulfur compounds on the surface of the *** present study shows that BN materials can be selected as promising metal-free catalysts for desulfurization process.

关键词： Desulfurization Boron nitride(BN)nanostructure Experimental design BoxeBehnken

Revealing the influence of in-situ formed LiCl on garnet/Li interface for dendrite-free solid-state batteries

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Journal of Energy Chemistry 2024年第5期92卷 394-403页

作者： Seoyoon Shin Jinuk Lee Tae Ho Shin Seokhee Lee hydrogen Energy Materials center Korea Institute of Ceramic Engineering&TechnologyJinju-siGyeongsangnam-do 52851Republic of Korea Department of Materials Science and Engineering Yonsei UniversitySeoul 03722Republic of Korea

Inadequate interfacial contact between lithium and solid-state electrolytes(SSEs)leads to elevated impedance and the growth of lithium dendrites,presenting significant obstacles to the practical viability of solid-state batteries(SSBs).To ameliorate interfacial contact,optimizing the surface treatment of SSEs has been widely ***,the formation of LiCl through acid treatment,an equally crucial factor impacting SSB performance,has received limited attention,leaving its underlying mechanism *** study aims to shed light on SSE characteristics following LiCl formation and the removal of Li_(2)CO_(3) through acid *** seek to establish quantifiable links between SSE surface structure and SSB performance,focusing on interfacial resistance,current distribution,critical current density(CCD),and lithium *** formation of LiCl,occurring as Li_(2)CO_(3) is removed through acid treatment,effectively mitigates lithium dendrite formation on SSE *** action inhibits electron injection and reduces the diffusion rate of Li ***,acid treatment transforms the SSE surface into a lithiophilic state by eliminating surface Li_(2)CO_(3).Consequently,the interfacial resistance between lithium and SSEs substantially decreases from 487.67 to 35.99Ωcm^(2) at 25°*** leads to a notably high CCD of 1.3 mA cm^(-2) and a significantly extended cycle life of 1,000 ***,in full SSBs incorporating LiCoO_(2)cathodes and acid-treated garnet SSEs,we observe exceptional cyclability and rate *** findings highlight that acid treatment not only establishes a fundamental relationship between SSE surfaces and battery performance but also offers an effective strategy for addressing interfacial challenges in SSBs.

关键词： Solid-statebatteries Acidtreatment Interfacial stability LiCl Surface modification