检索结果-南通市图书馆

Spray pyrolysis-derived W-doped MoSe2/rGO paper-like microspheres:optimization of microstructure and mesostructure for enhanced lithium storage

引用

Rare Metals 2024年第7期43卷 3019-3031页

作者： Wei Wang Jun-Yu Chen Jie Ouyang Hong Yin Ao-Jie Li Liang Chen Jun-Lin Huang Yu-Can Zhu Gang-Yong Li Zhao-Hui Hou Key Laboratory of hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology School of Chemistry and Chemical Engineering Hunan Institute of Science and Technology hunan Province Key Laboratory of Materials Surface & Interface science and technology Material Science and Engineering SchoolCentral South University of Forestry and Technology International Iberian Nanotechnology Laboratory (INL)

Two-dimensional MoSe2is a promising candidate for lithium-ion battery ***,its conductivity and lithium storage volumetric effect still need to be *** this work,W-doped MoSe2/rGO paper-like microspheres are successfully prepared through ultrasonic spray pyrolysis,achieving optimization at both the microstructure and mesostructure to enhance the lithium storage performance of the ***,by utilizing the similar two-dimensional structure between MoSe2and rGO,self-assembly is achieved through spray pyrolysis,resulting in a well-defined van der Waals heterostructure at the interface on the microscale,enhancing the electron and ion transfer capability of the ***,the mesoscale paper-like microsphere morphology provides additional volume expansion buffering ***,W-doping not only increases the interlayer spacing of MoSe2（0.73 nm）,thereby reducing the diffusion resistance of Li+,but also allow for the modulation of the energy band structure of the *** functional theory（DFT） calculations confirm that W-doped MoSe2/rGO exhibits the narrowest bandgap（0.892 eV）.Therefore,the composite demonstrates excellent lithium storage performance,maintaining a specific capacity of 732.9 mAh·g-1after 300 cycles at a current density of 1 A·g-1.

关键词： Molybdenum selenide Heterostructure Microspheres Li-ion batteries Kinetics

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Interface engineering strategy via electron-defect trimethyl borate additive toward 4.7 V ultrahigh-nickel LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)battery

引用

Journal of Energy Chemistry 2024年第5期92卷 639-647页

作者： Yilin Zhang Yuqing Chen Qiu He Jinlong Ke Wei Wang Jian-Fang Wu Peng Gao Yanhua Li Jilei Liu College of Materials science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan Province Key Laboratory for Advanced Carbon Materials and Applied TechnologyHunan UniversityChangsha 410082HunanChina College of Materials science and Engineering Sichuan UniversityChengdu 610065SichuanChina School of Materials science and Engineering Hunan Institute of TechnologyHengyang 421002HunanChina

The Li metal battery with ultrahigh-nickel cathode(LiNi_(x)M_(1-x)O_(2),M=Mn,Co,and x≥0.9)under high-voltage is regarded as one of the most promising approaches to fulfill the ambitious target of 400 Wh/***,the practical application is impeded by the instability of electrode/electrolyte interface and Ni-rich cathode *** we proposed an electron-defect electrolyte additive trimethyl borate(TMB)which is paired with the commercial carbonate electrolyte to construct highly conductive fluorine-and boron-rich cathode electrolyte interface(CEI)on LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)(NCM90)surface and solid electrolyte interphase(SEI)on lithium metal *** modified CEI effectively mitigates the structural transformation from layered to disordered rock-salt phase,and consequently alleviate the dissolution of transition metal ions(TMs)and its“cross-talk”effect,while the enhanced SEI enables stable lithium plating/striping and thus demonstrated good compatibility between electrolyte and lithium metal *** a result,the common electrolyte with 1 wt%TMB enables 4.7 V NCM90/Li cell cycle stably over 100 cycles with 70%capacity *** work highlights the significance of the electron-defect boron compounds for designing desirable interfacial chemistries to achieve high performance NCM90/Li battery under high voltage operation.

关键词： NCM90 batteries Electrolyte additive Trimethyl borate

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effect of micro-Al_(2)O_(3) powders on oxidation and corrosion behaviors of low-carbon MgO-C refractories

引用

Journal of Iron and Steel Research(International) 2024年第6期31卷 1522-1534页

作者： Yang Chen Zeng-yi Li Hao-bo Tan Yu-ran Fu Jun Ding Cheng-ji Deng Chao Yu School of Materials science and Engineering Hunan Institute of TechnologyHengyang 421002HunanChina The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

To solve the problem of poor high-temperature service performance caused by low carbonization of MgO-C refractories,low-carbon MgO–C refractories with excellent thermal shock,oxidation and corrosion resistances were successfully designed by using SiC whiskers as reinforcing phases and introducing micro-Al_(2)O_(3) powders as *** results indicated that the addition of micro-Al_(2)O_(3) powders optimized the internal structure of the material,like the columnar β-Si_(3)N_(4) with a stepped distribution and the mosaic structure formed between granular and flaky Mg_(2)SiO_(4),which synergistically strengthened and toughened the material and gave the material excellent mechanical properties and thermal shock ***,the cold modulus of rupture and cold crushing strength after thermal shock were increased by 4.1 and 20.3 MPa,***,the addition of micro-Al_(2)O_(3) powders promoted the formation of fine particles of Mg_(2)SiO_(4),MgAl_(2)O_(4) and MgO,as well as a dense protective layer of Mg_(2)SiO_(4) in the material under high-temperature ***,spinel and high-temperature solid solution were formed in the corrosion *** oxidation and corrosion resistances were greatly improved by 41%and 15%,respectively.

关键词： Low-carbon MgO-C refractory Oxidation resistance Corrosion resistance Thermal shock resistance Micro-Al_(2)O_(3)powder

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Carbon enhanced nucleophilicity of Na_(3)V_(2)(PO_(4))_(3):A general approach for dendrite-free zinc metal anodes

引用

Journal of Energy Chemistry 2024年第4期91卷 203-212页

作者： Sijun Wang Lingzi Hu Xiaohui Li Dan Qiu Shunhang Qiu Qiancheng Zhou Wenwen Deng Xiaoying Lu Ze Yang Ming Qiu Ying Yu institute of Nanoscience and Nanotechnology School of Physical Science and TechnologyCentral China Normal UniversityWuhan 430079HubeiChina School of Material science and Engineering Suzhou University of Science and TechnologySuzhou 215000JiangsuChina Faculty of science and technology Technological and Higher Education Institute of Hong KongHong KongChina

Zincophilic property and high electrical conductivity are both very important parameters to design novel Zn anode for aqueous Zn-ion batteries(AZIBs).However,single material is difficult to exhibit zincophilic property and high electrical conductivity at the same ***,originating from theoretical calculation,a zincophilic particle regulation strategy is proposed to address these limitations and carbon coated Na_(3)V_(2)(PO_(4))_(3)is taken as an example to be a protective layer on zinc metal(NVPC@Zn).Na_(3)V_(2)(PO_(4))_(3)(NVP)is a common cathode material for Zn-ion batteries,which is *** materials not only offer an electron pathway to help Zn deposition onto NVPC surface,but also enhance the zinc nucleophilicity of Na_(3)V_(2)(PO_(4))_(3).Hence,this hybrid coating layer can tune zinc deposition and resist side reactions such as hydrogen generation and Zn metal ***,a symmetrical battery with NVPC@Zn electrode displays highly reversible plating/stripping behavior with a long cycle lifespan over 1800 h at2 mA cm^(-2),much better than carbon and Na_(3)V_(2)(PO_(4))_(3)solely modified Zn *** the Na_(3)V_(2)(PO_(4))_(3)is replaced with zincophobic Al2O3or zincophilic V2O3,the stability of the modified zinc anodes is also *** strategy expands the option of zincophilic materials and provides a general and effective way to stabilize the Zn electrode.

关键词： Zinc-ion batteries Zinc anode Carbon enhanced nucleophilicity Zincophilic particle regulation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Microscopic growth mechanism and edge states of monolayer 1T'-MoTe2

引用

Chinese Physics B 2024年第4期33卷 474-480页

作者：赵海鹏刘隐杨胜国林陈昉陈明星 Kai Braun 罗心仪李思宇潘安练王笑 Key Laboratory for Micro-Nano Physics and technology of hunan Province School of Physics and ElectronicsCollege of Materials Science and Engineering Hunan University Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of Ministry of education Synergetic Innovation Centre for Quantum Effects and Applications (SICQEA) Hunan Normal University State Key Laboratory of Powder Metallurgy Central South University institute of physical and Theoretical Chemistry and LISA+ University of Tübingen

Transition metal ditellurides（TMTDs） have versatile physical properties,including non-trivial topology,Weyl semimetal states and unique spin *** growth of high-quality and large-scale monolayer TMTDs with preferred crystal phases is crucial for their ***,we demonstrate the epitaxial growth of 1T'-MoTe2on Au（111）and graphitized silicon carbide（Gr/SiC） by molecular beam epitaxy（MBE）.We investigate the morphology of the grown1T'-MoTe2at the atomic level by scanning tunnelling microscopy（STM） and reveal the corresponding microscopic growth *** is found that the unique ordered Te structures preferentially deposited on Au（111） regulate the growth of monolayer single crystal 1T'-MoTe2,while the Mo clusters were preferentially deposited on the Gr/SiC substrate,which impedes the ordered growth of monolayer *** confirm that the size of single crystal 1T'-MoTe2grown on Au（111）is nearly two orders of magnitude larger than that on Gr/*** scanning tunnelling spectroscopy（STS）,we observe that the STS spectrum of the monolayer 1T'-MoTe2nano-island at the edge is different from that at the interior,which exhibits enhanced conductivity.

关键词： 1T′-MoTe2 microscopic growth mechanism scanning tunneling microscopy/spectroscopy (STM/S) transition metal ditellurides

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Covalency competition induced selective bond breakage and surface reconstruction in manganese cobaltite towards enhanced electrochemical charge storage

引用

Green Energy & Environment 2024年第5期9卷 909-918页

作者： Peng Gao Pei Tang Ying Mo Peitao Xiao Wang Zhou Shi Chen Hongliang Dong Ziwei Li Chaohe Xu Jilei Liu College of Materials science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan Province Key Laboratory for Advanced Carbon Materials and Applied TechnologyHunan UniversityChangshaHunan410082China Department of Materials science and Engineering National University of Defense TechnologyChangshaHunan410073China Joint Key Laboratory of the Ministry of education Institute of Applied Physics and Materials EngineeringUniversity of MacaoAvenida da UniversidadeTaipaMacao999078China Center for High Pressure science and technology Advanced Research PudongShanghai201203China College of Aerospace Engineering Chongqing UniversityChongqing400044China

Manganese cobaltite(MnCo_(2)_(4))is a promising electrode material because of its attractive redox chemistry and excellent charge storage *** previous work demonstrated that the octahedrally-coordinated Mn are prone to react with the hydroxyl ions in alkaline electrolyte upon electrochemical cycling and separates on the surface of spinel to reconstruct into d-MnO_(2) nanosheets irreversibly,thus results in a change of the reaction mechanism with Kþion ***,the low capacity has greatly limited its practical ***,we found that the tetrahedrally-coordinated Co_(2) þions were leached when MnCo_(2)_(4) was equilibrated in 1 mol L^(-1) HCl solution,leading to the formation of layered CoOOH on MnCo_(2)_(4) surface which is originated from the covalency competition induced selective breakage of the CoT–O bond in CoT–O–CoO and subsequent rearrangement of free Co_(6) *** as-formed CoOOH is stable upon cycling in alkaline electrolyte,exhibits conversion reaction mechanism with facile proton diffusion and is free of massive structural evolution,thus enables utilization of the bulk electrode material and realizes enhanced speciﬁc capacity as well as facilitated charge transfer and ion *** general,our work not only offers a feasible approach to deliberate modiﬁcation of MnCo_(2)_(4)'s surface structure,but also provides an in-depth understanding of its charge storage mechanism,which enables rational design of the spinel oxides with promising charge storage properties.

关键词： Manganese cobaltite Tetrahedrally-coordinated Co^(2+)leaching Selective bond breakage Surface reconstruction Charge storage mechanisms

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Speed limit effect during lane change in a two-lane lattice model under V2X environment

引用

Chinese Physics B 2024年第3期33卷 718-722页

作者：金灿彭光含聂方彦 College of physical science and technology Guangxi Normal UniversityGuilin 541004China Guangxi Key Laboratory of Nuclear Physics and technology Guangxi Normal UniversityGuilin 541004China Information and Modern education technology Center Hunan University of Arts and ScienceChangde 415000China Computer and Information Engineering College Guizhou University of CommerceGuiyang 550014China

Speed limit measures are ubiquitous due to the complexity of the road environment,which can be supplied with the help of vehicle to everything(V2X)communication ***,the influence of speed limit on traffic system will be investigated to construct a two-lane lattice model accounting for the speed limit effect during the lane change process under V2X ***,the stability condition and the mKdV equation are closely associated with the speed limit effect through theory ***,the evolution of density and hysteresis loop is simulated to demonstrate the positive role of the speed limit effect on traffic stability in the cases of strong reaction intensity and high limited speed.

关键词： traffic flow lattice model speed limit

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Kerr black hole shadows cast by extraordinary light rays with Weyl corrections

引用

science China(Physics,Mechanics & Astronomy) 2024年第5期67卷 18-26页

作者： Songbai Chen Jiliang Jing Department of Physics Institute of Interdisciplinary StudiesKey Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of EducationSynergetic Innovation Center for Quantum Effects and ApplicationsHunan Normal UniversityChangsha 410081China Center for Gravitation and Cosmology College of Physical Science and TechnologyYangzhou UniversityYangzhou 225009China

We investigate the equation of motion for photons with Weyl corrections in a Kerr black hole spacetime in a small coupling *** results show that Weyl corrections yield phenomena of *** light rays propagating in the spacetime are separated into the ordinary rays and the extraordinary rays,and the propagation of the latter depends on the *** probe the effects of Weyl corrections on the Kerr black hole shadows casted by the extraordinary rays and find that such corrections result in a weak stretching or squeezing in the vertical direction for the black hole ***,we also study the change of the length of the Near-Horizon Extremal Kerr line(NHEK line)with Weyl *** features could help us to understand the electrodynamics with Weyl corrections from black hole shadows.

关键词： correction light stretching

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A high Li-ion diffusion kinetics in multidimensional and compact-structured electrodes via vacuum filtration casting

引用

Journal of Energy Chemistry 2024年第6期93卷 368-376,I0010页

作者： Jieqiong Li Ting Ouyang Lu Liu Shu Jiang Yongchao Huang M.-Sadeeq Balogun College of Materials science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan UniversityChangsha 410082HunanChina institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006GuangdongChina

Manufacturing process,diffusion co-efficient and areal capacity are the three main criteria for regulating thick electrodes for lithium-ion batteries(LIBs).However,simultaneously regulating these criteria for LIBs is desirable but remains a significant *** this work,niobium pentoxide(Nb_(2)O_(5))anode and lithium iron phosphate(LiFePO_(4))cathode materials were chosen as the model materials and demonstrate that these three parameters can be simultaneously modulated by incorporation of micro-carbon fibers(MCF)and carbon nanotubes(CNT)with both Nb_(2)O_(5) and LFP via vacuum filtration *** as-prepared MNC-20 anode and MLC-20 cathode achieves high reversible areal capacity of≈5.4 m A h cm^(-2)@0.1 C and outstanding Li-ion diffusion coefficients of≈10~(-8)cm~2 s~(-1)in the half-cell *** assembled MNC-20‖MLC-20 full cell LIB delivers maximum energy and power densities of244.04 W h kg^(-1)and 108.86 W kg^(-1),*** excellent electrochemical properties of the asprepared thick electrodes can be attributed to the highly conductive,mechanical compactness and multidimensional mutual effects of the MCF,CNT and active materials that facilitates rapid Li-ion diffusion ***,electrochemical impedance spectroscopy(EIS),symmetric cells analysis,and insitu Raman techniques clearly validates the enhanced Li-ion diffusion kinetics in the present architecture.

关键词： Thick electrodes Carbon nanotubes Li-ion diffusion co-efficient Vacuum filtration technique High areal capacity Lithium-ion batteries

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Merger estimates for a disformal Kerr black hole in quadratic degenerate higher-order scalar-tensor theories

引用

Chinese Physics C 2024年第5期48卷 284-292页

作者：蒋洪鑫杜欣怡潘启沅陈松柏荆继良 Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of education Synergetic Innovation Center for Quantum Effects and Applicationsand Department of PhysicsHunan Normal UniversityChangsha 410081China institute of Interdisciplinary Studies Hunan Normal UniversityChangsha 410081China Center for Gravitation and Cosmology College of Physical Science and TechnologyYangzhou UniversityYangzhou 225009China

We investigate the main features of a disformal Kerr black hole merger in quadratic degenerate higher-order scalar-tensor *** the ringdown stage of the black hole merger,for the prograde orbit,the real part of the quasinormal modes decreases with an increase in the disformal parameter,and the imaginary part also decreases,except in the Kerr case for a large spin ***,for the retrograde orbit,the real part increases with an increase in the disformal parameter,and the imaginary part always decreases with *** the approximate final spin,regardless of an equal spin,unequal spin,or generic spin configuration merger,the final black hole spin always increases with an increase in the disformal *** results show that the disformal parameter in the disformal Kerr solution and the MOG parameter in the Kerr-MOG case have obviously different effects on the black hole merger,which suggests the differences between these two spacetime structures.

关键词： black hole merger quasinormal modes final black hole spin disformal Kerr black hole quadratic degenerate higher-order scalar-tensor(DHOST)theory

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：