检索结果-南通市图书馆

Pd single atoms cooperate with S vacancies in ZnIn_(2)S_(4) nanosheets for photocatalytic pure-water splitting

Science China Chemistry 2024年第3期67卷 855-861页

作者： Lin Sun Huiping Peng Fei Xue Shangheng Liu Zhiwei Hu Hongbo Geng Xiaozhi Liu Dong Su Yong Xu Xiaoqing Huang State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Guangzhou Key Laboratory of Low-Dimensional Materials and energy Storage Devices Collaborative Innovation Center of Advanced Energy MaterialsSchool of Materials and EnergyGuangdong University of TechnologyGuangzhou 510006China Max Planck Institute for Chemical Physics of Solids Nothnitzer Strasse 40Dresden 01187Germany School of Materials Engineering Changshu Institute of TechnologyChangshu 215500China Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of SciencesBeijing 100190China innovation Laboratory for Sciences and Technologies of energy Materials of Fujian Province(IKKEM) Xiamen 361005China

Photocatalytic water splitting has emerged as a new frontier for converting solar energy to green H_(2) and value-added ***,great challenges still remain for developing efficient photocatalysts for pure water splitting without sacrificial *** this work,we demonstrate that doping hexagonal ZnIn_(2)S_(4)(ZIS) with Pd single atoms(Pd_(0.03)/ZIS) can serve as a highly efficient photocatalyst for pure water splitting to simultaneously produce H_(2) and H_(2)O_(2) without any sacrificial *** from aberration-corrected high-angle annular dark field scanning transmission electron microscopy,X-ray fine spectroscopy,insitu electron paramagnetic resonance and diffuse Fourier transform infrared spectroscopy reveal that doping ZIS with Pd single atoms facilitates the formation of S vacancies(S_(v)),where the photogenerated electrons can transfer to Pd single atoms,as a result of enhanced separation of electron-hole pairs and improved photocatalytic ***,Pd_(0.03)/ZIS displays a stoichiometric ratio of H_(2) and H_(2)O_(2) with the productivity of 1,037.9 and 1,021.4μmol g^(-1)h^(-1),respectively,which has largely outperformed pure ZIS and other reported catalysts for pure water *** work provides an efficient photocatalyst for water splitting to produce H_(2) and H_(2)O_(2),which may attract rapid interest in materials science,chemistry,and heterogeneous catalysis.

关键词： ZnIn_(2)S_(4) Pd single atom S vacancy pure water splitting H_(2)O_(2)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Phase engineering of Pd–Te nanoplates via potential energy trapping

引用

eScience 2024年第2期4卷 117-126页

作者： Mengjun Wang Jun Jia Hao Yan Guang Li Qiming Hong Yuzheng Guo Yong Xu Xiaoqing Huang State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China Guangzhou Key Laboratory of Low-Dimensional Materials and energy Storage Devices Collaborative Innovation Center of Advanced Energy MaterialsSchool of Materials and EnergyGuangdong University of TechnologyGuangdong510006China School of Electrical Engineering and Automation Wuhan UniversityHubei430072China Testing and Analysis Center College of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China innovation Laboratory for Sciences and Technologies of energy Materials of Fujian Province(IKKEM) Xiamen361005China

Phase modulation of noble metal alloys(NMAs)is critically important in nanoscience since the distinct atomic arrangements can largely determine their physicochemical ***,the precise modulation of NMAs is formidably challenging,because thermodynamically stable phases are generally preferential compared to those metastable ***,we proposed a potential energy trapping strategy for phase modulation of Pd–Te alloys with ***,ethylene glycol can increase the energy barrier for both Pd leaching and Te introduction,forming metastable Pd20Te7 ***,N,N-dimethylformamide is unable to trap metastable phase,inducing the phase evolution to thermodynamically stable PdTe phase,and the precise phase modulation was realized including Pd20Te7,PdTe and PdTe2 *** Pd–Te alloys displayed phase-dependent formic acid oxidation catalytic performance with PdTe phase showing the *** work proposes a strategy for creating metastable phase with potential energy trap,which may deepen the understanding of phase engineering for noble metal-based nanocrystals.

关键词： Potential energy trap Phase modulation Metastable Pd-Te alloys

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Research on swarm intelligence optimization algorithm

引用

The Journal of China Universities of Posts and Telecommunications 2020年第3期27卷 1-20,30页

作者： Fei Wei Liu Cong Hu Sheng hubei Key Laboratory for high-efficiency utilization of solar energy and Operation Control of energy Storage System Hubei University of TechnologyWuhan 430068China hubei collaborative innovation Center for high-efficiency utilization of solar energy Hubei University of Technologywuhan 430068China Wuhan Hua'an Science and Technology Co. Ltd.Postdoctoral WorkstationWuhan 430068.China

The bionics-based swarm intelligence optimization algorithm is a typical natural heuristic algorithm whose goal is to find the global optimal solution of the optimization *** simulates the group behavior of various animals and uses the information exchange and cooperation between individuals to achieve optimal goals through simple and effective interaction with experienced and intelligent *** paper first introduces the principles of various swarm intelligent optimization ***,the typical application of these swarm intelligence optimization algorithms in various fields is *** that,the advantages and defects of all swarm intelligence optimization algorithms are ***,the improvement strategies of various swarm intelligence optimization algorithms are ***,the future development of various swarm intelligence optimization algorithms is prospected.

关键词： bionics natural heuristic algorithm swarm intelligence algorithm intelligent computing

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Strong metal–support interaction boosts the electrocatalytic hydrogen evolution capability of Ru nanoparticles supported on titanium nitride

引用

Carbon energy 2024年第1期6卷 245-254页

作者： Xin Wang Xiaoli Yang Guangxian Pei Jifa Yang Junzhe Liu Fengwang Zhao Fayi Jin Wei Jiang Haoxi Ben Lixue Zhang College of Chemistry and Chemical Engineering Collaborative Innovation Center for Hydrogen Energy Key Materials and Technologies of Shandong ProvinceQingdao UniversityQingdaoShandongChina State Key Laboratory of Bio-fibers and Eco-Textiles Qingdao UniversityQingdaoShandongChina Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of ScienceQingdaoShandongChina

Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group ***,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic *** reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree *** study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption ***,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 *** study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.

关键词： electronic structure hydrogen evolution reaction ruthenium strong metal-support interaction titanium nitride

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Heterostructure:application of absorption-catalytic center in lithium-sulfur batteries

引用

Rare Metals 2024年第4期43卷 1461-1487页

作者： Fei Wang Chun-Man Yang Yong-Qi Wang Dan You Wen-Hao Yang Rong-Wei Huang Ji-Yue Hou Qian Wang Ying-Jie Zhang Ying Wang Yue-Jing Zeng Yi-Yong Zhang Xue Li National Local Joint Engineering Research Center for Lithium-Ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming650093China College of Electrical Information Engineering Panzhihua UniversityPanzhihua617000China State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Centre of Chemistry for Energy MaterialsState-Province Joint Engineering Laboratory of Power Source Technology for New Energy VehicleEngineering Research Center of Electrochemical TechnologyMinistry of EducationCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China

Due to the high theoretical specific capacity(1675 mAh·g^(-1)),low cost,and high safety of the sulfur cathodes,they are expected to be one of the most promising rivals for a new generation of energy storage ***,the shuttle effect,low conductivity of sulfur and its discharge products,volume expansion,and other factors hinder the commercialization of lithium-sulfur batteries(LSBs).The development of sulfur-fixing materials and the design of multifunctional materials to enhance the electrochemical performance of LSBs have been the main research priorities in recent *** of the advantages of high conductivity,built-in electric field,and good synergism,more and more researchers have employed heterostructure into sulfur-fixing materials to enhance the catalytic and absorption ability for *** this review,the principle of heterostructure and the mechanism of enhancing the performance of lithium-sulfur batteries are *** applications of heterostructure in cathode and interlayer of LSBs in the latest years are ***,the cutting-edge troubles and possibilities of heterostructures in LSBs are briefly presented.

关键词： Lithium-sulfur batteries(LSBs) Heterostructure Built-in electric field Catalytic Absorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Static recrystallization behaviors and mechanisms of 7Mo super-austenitic stainless steel with undissolved sigma precipitates during double-stage hot deformation

引用

Journal of Iron and Steel Research International 2024年第2期31卷 475-487页

作者： Shi-guang Xu Jin-shan He Run-ze Zhang Fu-cheng Zhang Xi-tao Wang collaborative innovation Center of Steel Technology University of Science and Technology BeijingBeijing100083China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao066004HebeiChina Shandong Provincial Key Laboratory for high Strength Lightweight Metallic Materials Advanced Materials InstituteQilu University of Technology(Shandong Academy of Science)Jinan250353ShandongChina

Static recrystallization(SRX)behaviors and corresponding recrystallization mechanisms of 7Mo super-austenitic stainless steel were studied under different deformation *** order of influence of deformation parameters on static recrystallization behaviors,from high to low,is followed by temperature,first-stage strain and strain ***,the effect of holding time on static recrystallization behaviors is significantly controlled by *** addition,with the increase in temperature from 1000 to 1200°C,the static recrystallization mechanism evolves from discontinuous static recrystallization and continuous static recrystallization(cSRX)to metadynamic recrystallization and cSRX,and finally to *** cSRX exists at all *** is because high stacking fault energy(56 mJ m−2)promotes the movement of dislocations,making the deformation mechanism of this steel is dominated by planar slip of *** undissolved sigma precipitates promote static recrystallization through particle-stimulated ***,small strain-induced precipitates at grain boundaries hinder the nucleation of conventional SRX and the growth of recrystallized grains,while the hindering effect decreases with the increase in temperature.

关键词： 7Mo super-austenitic stainless steel Double-stage hot deformation Conventional static recrystallization Metadynamic recrystallization Strain-induced precipitation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Manipulating the Spatial Structure of Second-Order Quantum Coherence Using Entangled Photons

引用

Chinese Physics Letters 2024年第7期41卷 58-73页

作者：黄双印高菁任志成程子默朱文正薛舒天娄严超刘志峰陈超朱飞杨立平汪喜林王慧田 National Laboratory of Solid State Microstructures and School of Physics Nanjing UniversityNanjing 210093China collaborative innovation Center of Advanced Microstructures Nanjing UniversityNanjing 210093China Intelligent Scientific Systems Co.Limited Beijing 102208China Center for Quantum Sciences and School of Physics Northeast Normal UniversityChangchun 130024China Hefei National Laboratory Hefei 230088China Synergetic innovation Center of Quantum Information and Quantum Physics University of Science and Technology of ChinaHefei 230026China collaborative innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China

high-order quantum coherence reveals the statistical correlation of quantum particles. Manipulation of quantum coherence of light in the temporal domain enables the production of the single-photon source, which has become one of the most important quantum resources. high-order quantum coherence in the spatial domain plays a crucial role in a variety of applications, such as quantum imaging, holography, and microscopy. However, the active control of second-order spatial quantum coherence remains a challenging task. Here we predict theoretically and demonstrate experimentally the first active manipulation of second-order spatial quantum coherence,which exhibits the capability of switching between bunching and anti-bunching, by mapping the entanglement of spatially structured photons. We also show that signal processing based on quantum coherence exhibits robust resistance to intensity disturbance. Our findings not only enhance existing applications but also pave the way for broader utilization of higher-order spatial quantum coherence.

关键词： particles quantum spatially

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Greenhouse gas emissions from Daihai Lake,China:Should eutrophication and salinity promote carbon emission dynamics?

引用

Journal of Environmental Sciences 2024年第1期135卷 407-423页

作者： Xiangwei Li Ruihong Yu Jun Wang Heyang Sun Xinyu Liu Xiaohui Ren Shuai Zhuang Zhiwei Guo Xixi Lu Inner Mongolia Key Laboratory of River and Lake Ecology School of Ecology and EnvironmentInner Mongolia UniversityHohhot 010070China Key Laboratory of Mongolian Plateau Ecology and Resource utilization Ministry of EducationHohhot 010070China Autonomous Region collaborative innovation Center for Integrated Management of Water Resources and Water Environment in the Inner Mongolia Reaches of the Yellow River Hohhot 010018China Department of Geography National University of Singapore117570Singapore

Greenhouse gases(GHGs)emitted or absorbed by lakes are an important component of the global carbon ***,few studies have focused on the GHG dynamics of eutrophic saline lakes,thus preventing a comprehensive understanding of the carbon ***,we conducted four sampling analyses using a floating chamber in Daihai Lake,a eutrophication saline lake in Inner Mongolia Autonomous Region,China,to explore its carbon dioxide(CO_(2))and methane(CH_(4))*** mean CO_(2)emission flux(FCO_(2))and CH_(4)emission flux(FCH_(4))were 17.54±14.54 mmol/m^(2)/day and 0.50±0.50 mmol/m^(2)/day,*** results indicated that Daihai Lake was a source of CO_(2)and CH_(4),and GHG emissions exhibited temporal *** mean CO_(2)partial pressure(p CO_(2))and CH_(4)partial pressure(p CH_(4))were 561.35±109.59μatm and 17.02±13.45μatm,which were supersaturated relative to the *** regression and correlation analysis showed that the main influencing factors of p CO_(2)were wind speed,dissolved oxygen(DO),total nitrogen(TN)and Chlorophyll a(Chl.a),whereas the main influencing factors of p CH_(4)were water temperature(WT),Chl.a,nitrate nitrogen(NO_(3)^(-)-N),TN,dissolved organic carbon(DOC)and water *** regulated carbon mineralization and organic matter decomposition,and it was an important influencing factor of p CO_(2)and p CH_(4).Additionally,the trophic level index(TLI)significantly increased p CH_(4).Our study elucidated that salinity and eutrophication play an important role in the dynamic changes of GHG ***,research on eutrophic saline lakes needs to be strengthened.

关键词： Eutrophication Salinity Greenhouse gas emissions Inland lake Inner Mongolia Autonomous Region

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Changes in Polyphenols and Antioxidant Activities of Yingshan Yunwu Tea during Digestion in Vitro

引用

Medicinal Plant 2024年第2期15卷 21-25页

作者： Ruyi ZHENG Jinjie ZHOU Wenzhuo WU Jianfeng ZHAN Peng WU Ting DING Weixin WANG College of Biology and Agricultural Resources Huanggang Normal UniversityHubei Collaborative Innovation Center for the Characteristic Resources Exploitation of Dabie MountainsHubei Key Laboratory of Economic Forest Germplasm Improvement and Resources Comprehensive UtilizationHuanggang 438000China hubei Hongan County Public Inspection and Testing Center Huanggang 438000China

[Objectives]To explore the change rule of polyphenol content and antioxidant activity of coarse old leaves of Yingshan Yunwu Tea in the process of human digestion.[Methods]The coarse and old leaves of Yunwu tea in Yingshan,Huanggang,hubei Province were selected as the research object,and their digestion in vitro was *** total polyphenol content was determined by Folin-phenol reagent colorimetric method,and the DPPH radical scavenging activity and total antioxidant activity were determined.[Results]After simulated gastrointestinal digestion in vitro,the polyphenol content and antioxidant activity of coarse old leaf tea soup showed a downward *** gastrointestinal digestion,the polyphenol content in tea infusion separately decreased by 31.8%and 8.5%;the scavenging rate of DPPH free radical was 97%before digestion,decreased to 92%after gastric digestion and 65%after intestinal digestion,which decreased by 5%and 27%,respectively;after gastrointestinal digestion,the total antioxidant capacity of tea soup decreased by 4.7%and 3.1%,respectively.[Conclusions]This study provided a reference for the development and application of coarse old leaves of Yingshan Yunwu tea,and provided a reference for the nutritional value evaluation and comprehensive utilization of coarse old leaves,so as to make the best use of coarse tea leaves and reduce the waste of resources.

关键词： Coarse old leaves of Yunwu tea Polyphenol Digestion in vitro Antioxidant activity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Discovering Cathodic Biocompatibility for Aqueous Zn–MnO_(2) Battery:An Integrating Biomass Carbon Strategy

引用

Nano-Micro Letters 2024年第6期16卷 111-126页

作者： Wei Lv Zilei Shen Xudong Li Jingwen Meng Weijie Yang Fang Ding Xing Ju Feng Ye Yiming Li Xuefeng Lyu Miaomiao Wang Yonglan Tian Chao Xu Institute of energy Power innovation North China Electric Power UniversityBeijing 102206People’s Republic of China Department of Power Engineering School of EnergyPower and Mechanical EngineeringNorth China Electric Power UniversityBaoding 071003People’s Republic of China Key Laboratory of RNA Biology Institute of BiophysicsChinese Academy of SciencesBeijing 100101People’s Republic of China collaborative innovation Center of Integrated Exploitation of Bayan Obo Multi‑Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010People’s Republic of China

Developing high-performance aqueous Zn-ion batteries from sustainable biomass becomes increasingly vital for large-scale energy storage in the foreseeable ***,γ-MnO_(2) uniformly loaded on N-doped carbon derived from grapefruit peel is successfully fabricated in this work,and particularly the composite cathode with carbon carrier quality percentage of 20 wt%delivers the specific capacity of 391.2 mAh g^(−1)at 0.1 A g^(−1),outstanding cyclic stability of 92.17%after 3000 cycles at 5 A g^(−1),and remarkable energy density of 553.12 Wh kg^(−1) together with superior coulombic efficiency of~100%.Additionally,the cathodic biosafety is further explored specifically through in vitro cell toxicity experiments,which verifies its tremendous potential in the application of clinical ***,Zinc ion energy storage mechanism of the cathode is mainly discussed from the aspects of Jahn–Teller effect and Mn domains distribution combined with theoretical analysis and experimental ***,a novel perspective of the conversion from biomass waste to biocompatible Mn-based cathode is successfully developed.

关键词： Aqueous Zn-ion batteries Biocompatibility Jahn-Teller effect Mn domains γ-MnO_(2)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：