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Nano Research 2024年第6期17卷 4693-4701页

作者： Xin Yu Jing Mei Yeshuang Du Xiaohong Cheng Xing Wang Qi Wu State key laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430073China hubei key laboratory of pollutant analysis&reuse technology College of Chemistry and Chemical EngineeringHubei Normal UniversityHuangshi 435002China hubei key laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China

Heterojunction structures improve the intrinsic activity of electrocatalysts by enhancing the charge transfer between the catalyst and the *** this paper,the NiS/FeS_(2)heterostructured electrocatalyst is fabricated by a simple sulfidation method using an interface engineering strategy to adjust the surface electron density of the *** expected,NiS/FeS_(2)electrocatalyst exhibits superior activity and durable oxygen evolution reaction(OER)stability,requiring only a low overpotential of 183 mV to achieve a current density of 10 mA·cm^(−2)and can be stable for more than 80 h,superior to NiS,FeS_(2)electrocatalyst individually,and precious RuO_(2).Notably,NiS/FeS_(2)is also a good bifunctional electrocatalyst with good overall water splitting performance,and it only requires a voltage 1.56 V to obtain a current density of 10 mA·cm^(−2)for more than 12 ***,the NiS/FeS_(2)hybridization facilitates the formation of coral-like structures,increasing the electrochemical surface area(ECSA)and enhancing the charge transfer efficiency,thus leading to excellent electrocatalytic *** work proposes a constructive strategy for designing efficient electrocatalysts based on interface engineering,and lays a foundation for designing a new class of electrocatalysts.

关键词： NiS/FeS_(2) interface engineering nanorods bifunctional water splitting

g-C_(3)N_(4)基S型异质结光催化剂

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Science China Materials 2024年第2期67卷 444-472页

作者：吴新鹤谭丽红陈郭强康佳乐王国宏 hubei key laboratory of pollutant analysis and reuse technology College of Chemistry and Chemical EngineeringHubei Normal UniversityHuangshi 435002China

随着工业化的蓬勃发展,能源短缺和环境污染日益严重,威胁到人类的生存.光催化技术因其诸多突出优点和广泛的应用前景被认为是解决能源和环境危机最有前途的技术之一.在众多光催化剂中,石墨氮化碳(g-C_(3)N_(4))以其独特的电子结构、较... 详细信息

随着工业化的蓬勃发展,能源短缺和环境污染日益严重,威胁到人类的生存.光催化技术因其诸多突出优点和广泛的应用前景被认为是解决能源和环境危机最有前途的技术之一.在众多光催化剂中,石墨氮化碳(g-C_(3)N_(4))以其独特的电子结构、较高的热稳定性和突出的光电活性,在清洁燃料生产和环境净化领域得到广泛应用.然而,单组分g-C_(3)N_(4)与其他光催化剂一样,不可能同时拥有高的太阳能利用效率和强氧化还原能力的光生电荷,导致其光催化效率较低.幸运的是,g-C_(3)N_(4)与另一半导体构建异质结可以同时克服太阳能利用效率低、载流子重组快、氧化还原能力弱的缺点,从而显著提高其光催化性能.鉴于目前g-C_(3)N_(4)基S型异质结的广泛研究,本文对g-C_(3)N_(4)基S型异质结研究背景、概念提出、基本理论、设计制备、表征方法等方面的最新研究进展进行了较全面的综述.此外,通过实例讨论和列表比较详细讨论了g-C_(3)N_(4)基S型异质结的各种应用,包括光催化制H_(2)、还原CO_(2)、降解污染物、生产H_(2)O_(2).最后,总结了g-C_(3)N_(4)基S型异质结当前的研究进展和不足,并对未来的研究方向进行了展望.

关键词： photocatalysis g-C_(3)N_(4) heterojunction S-scheme applications

Metagenomics reveals the microbial community and functional metabolism variation in the partial nitritation-anammox process:From collapse to recovery

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Journal of Environmental Sciences 2024年第1期135卷 210-221页

作者： Hong Wang Hui Gong Xiaohu Dai Min Yang State key laboratory of Pollution Control and Resource reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China BIOMATH Department of Data Analysis and Mathematical ModellingGhent UniversityGhent 9000Belgium

Mainstream partial nitritation-anammox(PNA)process easily suffers from performance instability and even reactor collapse in ***,it is of great significance to unveil the characteristic of performance recovery,understand the intrinsic mechanism and then propose operational *** this study,we combined long-term reactor operation,batch tests,and metagenomics to reveal the succession of microbial community and functional metabolism variation from system collapse to *** aeration control(0.10-0.25mg O_(2)/L)was critical for performance *** was also found that Candidatus Brocadia became the dominant flora and its abundance increased from 3.5%to 11.0%.Significant enhancements in carbon metabolism and phospholipid biosynthesis were observed during system recovery,and the genes abundance related to signal transduction was dramatically *** up-regulation of sdh and suc genes showed the processes of succinate dehydrogenation and succinyl-CoA synthesis might stimulate the production of amino acids and the synthesis of proteins,thereby possibly improving the activity and abundance of AnAOB,which was conducive to the performance ***,the increase in abundance of hzs and hdh genes suggested the enhancement of the anammox *** in the abundance of key genes involved in nitrogen metabolism indicated that nitrogen removal pathway was more diverse after system *** achievement of performance recovery was driven by anammox,nitrification and denitrification coupled with dissimilatory nitrate reduction to *** results provide deeper insights into the recovery mechanism of PNA system and also provide a potential regulation strategy for the stable operation of the mainstream PNA process.

关键词： Partial nitritation-anammox Metagenomics Microbial community Functional metabolism Recovery

Scientific and technological innovations of wastewater treatment in China

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Frontiers of Environmental Science & Engineering 2024年第6期18卷 43-48页

作者： Hui Huang Rui Ma Hongqiang Ren State key laboratory of Pollution Control and Resource reuse School of the EnvironmentNanjing UniversityNanjing 210023China

The“dual-carbon”strategy promotes the development of the wastewater treatment sector and is an important tool for leading science and technology *** on the global climate change and the new policies introduced by China,this paper described the new needs for the development of wastewater treatment science and *** offered a retrospective analysis of the historical trajectory of scientific and technological advancements in this *** bibliometrics,it delineated the research hotspots within wastewater treatment,notably highlighting materials genomics,artificial intelligence,and synthetic ***,it posited that,in the future,the field of wastewater treatment should follow the paths of technological innovations with multi-dimensional needs,such as carbon reduction,pollution reduction,health,standardisation,and *** purpose of this paper was to provide references and suggestions for scientific and technological innovations in the field of wastewater treatment,and to contribute to the common endeavor of moving toward a Pollution-Free Planet.

关键词： Wastewater treatment Dual-carbon strategy Technological innovation Carbon reduction

Recent advances in iron-based sulfides electrocatalysts for oxygen and hydrogen evolution reaction

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Chinese Chemical Letters 2024年第1期35卷 181-195页

作者： Jing Mei Yuqing Deng Xiaohong Cheng Xing Wang Qi Wu State key laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China hubei key laboratory of pollutant analysis&reuse technology College of Chemistry and Chemical EngineeringHubei Normal UniversityHuangshi 435002China hubei key laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China

Increasing environmental pollution and shortage of conventional fossil fuels have made it urgent to develop renewable and clean energy sources. Electrocatalytic water splitting, with its abundant raw materials, simple process, and zero carbon emission, is considered one of the most promising processes for producing carbon-neutral hydrogen which has excellent energy conversion efficiency and high gravimetric energy density. Among them, oxygen evolution reaction (OER) electrocatalysts and hydrogen evolution reaction (HER) electrocatalysts are critical to decreasing the intrinsic reaction energy barrier and boosting the hydrogen evolution efficiency. Therefore, it is imperative to develop and design low-cost, highly active, and stable OER and HER electrocatalysts to lower the overpotential and drive the electrocatalytic reactions. Transition metal sulfides, especially iron-based sulfides, have attracted extensive exploration by researchers as a result of its high abundance in the Earth's crust and near-metallic conductivity. Consequently, in this review, we systematically and comprehensively summarize the progress in the application of iron-based sulfides and their composites as OER and HER electrocatalysts in electrocatalysis. Detailed descriptions and illustrations of the special relationships among their composition, structure, and electrocatalytic performance are presented. Finally, this review points out the challenges and future prospects of iron-based sulfides in practical applications for designing and fabricating more promising iron-based sulfide OER and HER electrocatalysts. We believe that iron-based sulfide materials will have a wide range of application prospects as OER and HER electrocatalysts in the future.

关键词： Iron-based sulfides Electrocatalysts Doping Composites Water splitting

Enrichment of anammox biomass during mainstream wastewater treatment driven by achievement of partial denitrification through the addition of bio-carriers

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Journal of Environmental Sciences 2024年第3期137卷 181-194页

作者： Yuqing Ma Bo Wang Xiaodi Li Shuo Wang Wen Wang Yongzhen Peng National Engineering laboratory for Advanced Municipal Wastewater Treatment and reuse technology Engineering Research Center of BeijingBeijing University of TechnologyBeijing 100124China

Anammox is widely considered as the most cost-effective and sustainable process for nitrogen ***,how to achieve the enrichment of anammox biomass remains a challenge for its large-scale application,especially in mainstream wastewater *** this study,the feasibility of enrichment of anammox biomass was explored through the realization of partial denitrification and the addition of *** using ordinary activated sludge,a sequencing batch reactor(SBR)followed by an up-fow anaerobic sludge bed(UASB)was operated at 25±2℃ for 214 *** long-term operation was divided into five phases,in which SBR and UASB were started-up in Phases I and II,*** eliminating oxygen and adjusting the infow ratios in Phases III-V,advanced nitrogen removal was achieved with the effuent total nitrogen being 4.7 mg/L and the nitrogen removal efficiency being 90.5%in Phase *** in-situ and ex-situ activity tests demonstrated the occurrence of partial denitrification and ***,16S rRNA high-throughput sequencing analysis revealed that Candidatus Brocadia was enriched from below the detection limit to in biofilms(0.4%in SBR,2.2%in UASB)and the foc sludge(0.2%in SBR,1.3%in UASB),while Thauera was mainly detected in the foc sludge(8.1%in SBR,8.8%in UASB),which might play a key role in partial ***,this study provides a novel strategy to enrich anammox biomass driven by rapid achievement of partial denitrification through the addition of bio-carriers,which will improve large-scale application of anammox processes in mainstream wastewater treatment.

关键词： Enrichment Anammox biomass Bio-carriers Partial denitrification Mainstream wastewater

Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ)

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Chinese Chemical Letters 2024年第5期35卷 392-396页

作者： Guorong Li Yijing Wu Chao Zhong Yixin Yang Zian Lin Ministry of Education key laboratory of Analytical Science for Food Safety and Biology Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food SafetyCollege of ChemistryFuzhou UniversityFuzhou 350108China

Targeted construction of new covalent organic frameworks(COFs)with specific purposes and rationalities to build colorimetric assay platform for environmental pollutant monitoring have attracted increasing ***,it is still challenging due to lack of available coordination sites inside COFs pores and only a slight bonding ability for anchoring *** this work,a two-dimensional(2D)COFs(termed as Tz-COF)with high crystallinity,excellent chemical stability,and abundant sulfur coordination in its skeletons was synthesized and used for the confined growth of Au *** was found that the Au NPs showed significant dispersibility for the support of *** proposed Tz-COF@Au NPs possessed outstanding Hg^(2+)-activated peroxidase-like activity benefited from physicochemical properties of gold amalgam and synergistic effect between COFs and Au NPs to oxidize chromogenic *** on highly efficient activity and distinctive color evolution,the strategy for detecting Hg^(2+)was developed and successfully applied to determine the content of Hg^(2+)in real environmental *** work manifests that a potential strategy to establish a colorimetric assay platform for environmental pollutant monitoring based on the targeted manufacturing of novel COFs with specific functions.

关键词： Covalent organic frameworks Thiazole Sulfur coordination Au nanoparticles Hg^(2+)-activated peroxidase-like activity

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S型纤维异质结实现高效纯水光合成过氧化氢

Science China Materials 2024年第2期67卷 484-492页

作者：李可梅骏伦李静萍刘易斯王国宏胡蝶严素定王楷 hubei key laboratory of pollutant analysis and reuse technology Research Center for Transition and Development of Resources-exhausted CityCollege of Chemistry and Chemical EngineeringHuangshi Key Laboratory of Prevention and Control of Soil PollutionHubei Normal UniversityHuangshi 435002China Engineering Research Center for Clean Production of Textile Printing and Dyeing Ministry of EducationWuhan Textile UniversityWuhan 430073China School of Chemistry Chemical Engineering and BiotechnologyNanyang Technological University62 Nanyang DriveSingapore 637459Singapore

太阳能驱动在纯水中生成过氧化氢(H_(2)O_(2))被认为是一种具有成本效益且环保的方法.然而,大多数光催化剂只有在存在牺牲供体的情况下才会表现出性能,从而限制了其实用性.本文通过静电纺丝辅助离子交换策略,制备出了S型纤维异质结Nb_(2... 详细信息

太阳能驱动在纯水中生成过氧化氢(H_(2)O_(2))被认为是一种具有成本效益且环保的方法.然而,大多数光催化剂只有在存在牺牲供体的情况下才会表现出性能,从而限制了其实用性.本文通过静电纺丝辅助离子交换策略,制备出了S型纤维异质结Nb_(2)O_(5)@NiS(NONS),作为光催化产过氧化氢的催化剂.通过原位X射线光电子能谱分析研究了S型电荷转移路径.通过捕获实验和电子自旋共振光谱,证实了单线态氧(1O_(2))与H_(2)O_(2)的形成有关.这项工作还揭示了通过制造纤维异质结光催化剂产生H_(2)O_(2)的另一种反应途径.

关键词： hydrogen peroxide photocatalysis nanofibers heterojunction S-scheme mechanism

Confinement of Fe atoms between MoS_(2) interlayers drives phase transition for improved reactivity in Fenton-like reactions

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Nano Research 2024年第3期17卷 1132-1139页

作者： Yibing Sun Yu Zhou Hongchao Li Chuan Wang Xuan Zhang Qian Ma Yingchun Cheng Jieshu Qian Bingcai Pan Jiangsu key laboratory of Chemical Pollution Control and Resources reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China key laboratory of Flexible Electronics and Institute of Advanced Materials Jiangsu National Synergetic Innovation Center for Advanced MaterialsNanjing Tech UniversityNanjing 211816China Department of General Dentistry Affiliated Stomatological Hospital of Nanjing Medical UniversityJiangsu Province Key Laboratory of Oral DiseasesNanjing 210029China Research Center for Environmental Nanotechnology(ReCENT) State Key Laboratory of Pollution Control and Resources ReuseSchool of EnvironmentNanjing UniversityNanjing 210023China

Phase manipulation of MoS_(2) from thermodynamically stable 2H phase to the unstable but more reactive 1T phase represents a crucial strategy for improving the reactivity in many *** widely adopted wet chemistry approach uses intercalating entities especially alkali metal ions to achieve the phase transition;however,these entities are normally inert for the target ***,we describe the first use of iron atoms for the intercalation of 2H-MoS_(2) layers,driving the partial transition from 2H to 1T ***,in the peroxymonosulfate(PMS)-based Fenton-like reactions,the interlayered confinement of Fe atoms not only activates the inert basal plane,but also adds more reactive Fe sites for the formation of metal-PMS complex as primary reactive species for pollutant *** the degradation of a model pollutant carbamazepine(CBZ),the Fe-intercalated MoS_(2) exhibits a first order rate constant 13.3 times higher than 2H-MoS_(2).This strategy is a new direction for manipulating the phase composition and boosting the catalytic reactivity of MoS_(2)-based catalysts in various scenarios,including environmental remediation and energy applications.

关键词： confinement MoS_(2) Fe atoms Fenton-like reactions hydrogen evolution reaction

Identification of high oxygen-consuming substances in stormwater drainage systems illicitly connected with sewage system

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Journal of Environmental Sciences 2024年第4期138卷 132-140页

作者： Chen Xu Zuxin Xu Wenhai Chu Shanshan Wu Rong Xiao Lei Su State key laboratory of Pollution Control and Resource reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Ministry of Education key laboratory of Yangtze River Water Environment Tongji UniversityShanghai 200092China Guangzhou Resource Environmental Protection technology Co. Ltd.Guangzhou 510030China

The dissolved oxygen content in water is an important indicator for assessing the quality of the water environment,and maintaining a certain amount of dissolved oxygen is essential for the healthy development of the ecological *** a water body is anoxic,the activity of anaerobic microorganisms increases and organic matter is decomposed to produce a large number of blackening and odorizing substances,resulting in black and odorous water bodies,which is a very common and typical phenomenon in ***,there is still a relatively universal occurrence of illicitly connected stormwater and sewage pipes in the urban drainage pipe network in China,which makes oxygen-consuming substances be directly discharged into rivers through stormwater pipes and consume the dissolved oxygen in the water bodies,resulting in an oxygen deficiency of the *** induces seasonal or year-round black and stink phenomena in urban ***,identifying high oxygen-consuming substances,which lays the foundation for the subsequent removal of oxygen-consuming substances,is *** a series of comparisons of water quality indicators and analysis of organic characteristics,it was found that the oxygen consumption capacity of domestic sewage was higher than that of industrial wastewater in the selected area of this study,and the oxygen-consuming substances of domestic sewage were small molecular amino *** comparing 20 conventional free amino acids,it was found that seven of them consumed oxygen easily,and compared with chemical oxygen consumption,biological oxygen consumption was in a leading position.

关键词： Urban drainage system Oxygen-consuming substances Domestic sewage Amino acid