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Assessment of sources and transformation of nitrate in the alluvial-pluvial fan region of north China using a multi-isotope approach

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Journal of Environmental Sciences 2020年第3期32卷 9-22页

作者： Qianqian Zhang Huiwei Wang hebei and China Geological Survey key laboratory of groundwater remediation Institute of Hydrogeology and Environmental GeologyChinese Academy of Geological SciencesShijiazhuang 050061China

A multi-isotope approach and mixing model were combined to identify spatial and seasonal variations of sources,and their proportional contribution to nitrate in the Hutuo River alluvial-pluvial fan *** results showed that the NO3- concentration was significantly higher in the Hutuo River valley plain(178.7 mg/L) region than that in the upper and central pluvial fans of the Hutuo River(82.1 mg/L and 71.0 mg/L,respectively)and in the river(17.0 mg/L).Different land use types had no significant effect on the groundwater nitrate *** on a multi-isotope approach,we confirmed that the main sources of groundwater nitrate in different land use areas were domestic sewage and manure,followed by soil nitrogen,ammonia fertilizer,nitrate fertilizer and rainwater,and there were no significant spatial or seasonal *** δ^15N-NO3,δ^18O-NO3- and δ^37Cl results can increase the accuracy of *** could be the most important nitrogen migration and transformation process,and denitrification did not significantly affected the isotopic composition of the *** SIAR model outputs revealed that the main nitrate pollution sources in groundwater and river water were domestic sewage and manure,accounting for 55.9%-61.0% and 22.6%(dry season),50.3%-60.4% and 34.1%(transition season),42.7%-47.6% and 35.6%(wet season 2016) and 45.9%-46.7% and 38.4%(wet season 2017),*** work suggests that the random discharge and disposal of domestic sewage and manure should be the first target for control in order to prevent further nitrate contamination of the water environment.

关键词： Nitrate Source apportionment Multi-isotope SIAR mixing model

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Influence of Rain on Tetrachloroethylene's Multiphase Migration in Soil

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Journal of Earth Science 2015年第3期26卷 453-460页

作者： Yong Qian Jingli Shao Zhaoji Zhang Yuhong Fei Chunxiao Wang Xiangxiang Cui Suhua Meng School of Water Resources & Environment China University of Geosciences The Institute of Hydrogeology and Environmental Geology Chinese Academy of Geological Sciences hebei key laboratory of groundwater remediation

For the increasingly serious soil and groundwater pollution by volatile organic compounds, tetrachloroethylene（PCE） was selected as the research object in this study. With the in-situ soil column physical simulation experiments, migration law of PCE in soil under rain conditions was studied by monitoring precipitation and soil parameter as well as sampling and analyzing soil and soil gas, and influence of rain on the multiphase migration process of PCE was preliminarily discussed. Research shows that migrations of PCE and soil moisture were not synchronous, and the rate of the former was speeded up by the latter caused by rain. Preliminary analysis indicates that migration of volatile chlorohydrocarbon in soil was not only driven by soil moisture, but also controlled by the nature of volatility of their own, that is to say, volatilization into gas phase was an important way of migrating and diffusing in pore medium, and the rate of migration and diffusion of gaseous PCE was faster than that of solid, resulting in more abroad distribution of gas phase than that in solid phase.

关键词： volatile organic pollution soil water migration tetrachloroethylene(PCE) gas phase

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Multiple isotopes reveal the driving mechanism of high NO_(3)^(-) level and key processes of nitrogen cycling in the lower reaches of Yellow River

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Journal of Environmental Sciences 2024年第4期138卷 597-606页

作者： Qianqian Zhang Huiwei Wang Lu Liu Tianlun Zhai Xueqing Zhang hebei and China Geological Survey key laboratory of groundwater remediation Institute of Hydrogeology and Environmental GeologyChinese Academy of Geological SciencesHebei 050061China Geo-Environmental Monitoring Institute of hebei Province Hebei 050011China hebei Provincial laboratory of Water Environmental Science Hebei 050037China hebei Provincial Academy of Ecological Environmental Science Hebei 050037China

The continuous increase of nitrate(NO_(3)^(-))level in rivers is a hot issue in the ***,the driving mechanism of high NO_(3)^(-)level in large rivers is still lacking,which has limited the use of river water and increased the cost of water *** this study,multiple isotopes and source resolution models are applied to identify the driving mechanism of high NO_(3)^(-)level and key processes of nitrogen cycling in the lower reaches of the Yellow River(LRYR).The major sources of NO_(3)^(-)were sewage and manure(SAM)in the low-flow season and soil nitrogen(SN)and chemical fertilizer(CF)in the high-flow *** was the most key process of nitrogen cycling in the ***,in the biological removal processes,denitrification may not occur *** temporal variation of contributions of NO_(3)^(-)sources were estimated by a source resolution model in the *** proportional contributions of SAM and CF to NO_(3)^(-)in the low-flow and high-flow season were 32.5%-52.3%,44.2%-46.2%and 36.0%-40.8%,54.9%-56.9%,*** driving mechanisms of high NO_(3)^(-)level were unreasonable sewage discharge,intensity rainfall runoff,nitrification and lack of nitrate removal *** control the NO_(3)^(-)concentration,targeted measures should be implemented to improve the capacity of sewage and wastewater treatment,increase the utilization efficiency of nitrogen fertilizer and construct ecological *** study deepens the understanding of the driving mechanism of high nitrate level and provides a vital reference for nitrogen pollution control in rivers to other area of the world.

关键词： Nitrate Driving mechanism Nitrogen cycle Source apportionment Transformation Yellow River

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Application of bioremediation in oil contaminated soil

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Journal of groundwater Science and Engineering 2017年第2期5卷 116-123页

作者： ZHANG Sheng ZHANG Cui-yun HE Ze CHEN Li YIN Mi-ying NING Zhuo SUN Zhen-hua ZHEN Shl-jun ZHANG Fa-wang Institute of Hydrogeology and Environment Geology Chinese Academy of Geological Sciences Shijiazhuang 050061 China hebei key laboratory of groundwater remediation Shijiazhuang 050061 China

The long-term oil exploitation in oil fields has led to pollution of surrounding soil, creating a serious ecological problem. In order to promote and improve the application of microbial remediation in oil contaminated soil, experiment is carried out in polluted area in Zhongyuan Oilfield. In the experiment, indigenous microorganisms and other physical and chemical methods are employed, ryegrass is grown, and environmental factors in soil are regulated to degrade the oil and treat the polluted soil. Results show that when the average oil content in the soil is about 523.08 mg/kg, 65 days' remediation through plants and microorganisms could help bring the oil content down to 74.61 mg/kg, achieving a degradation rate of 85.74%; through salinity treatment, salt content in soil is reduced by 62.93-82.03% to 399-823 mg/kg from previous 2.22 g/kg. Through this experiment, the bioremediation method is improved and its effectiveness and feasibility are testified. The result has been applied in Zhongyuan Oilfield and has brought fair ecological and economic benefits, providing technical support to the treatment of contaminated soil of the same kind, and offering some insights to the treatment of soil contaminated by other organic pollutants.

关键词： Central plain Oil contaminated soil Bioremediation Application

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Temporal and spatial variations hydrochemical components and driving factors in Baiyangdian Lake in the Northern Plain of China

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Journal of groundwater Science and Engineering 2024年第3期12卷 293-308页

作者： Tian-lun Zhai Qian-qian Zhang Long Wang Hui-wei Wang hebei and China Geological Survey key laboratory of groundwater remediation Institute of Hydrogeology and Environmental GeologyChinese Academy of Geological SciencesShijiazhuang 050061China

Understanding the temporal and spatial variation of hydrochemical components in large freshwater lakes is crucial for effective management and *** this study,we identify the temporalspatial characteristics and driving factors of the hydrochemical components in Baiyangdian Lake using geochemical methods(Gibbs diagram,Piper diagram and End-element diagram of ion ratio)and multivariate statistical techniques(Principal component analysis and Correlation analysis).16 sets of samples were collected from Baiyangdian Lake in May(normal season),July(flood season),and December(dry season)of *** indicate significant spatial variation in Nat,ci,SO and NO,,suggesting a strong influence of human *** concentrations exhibit greater seasonal variation in the dry season compared to the flood season,while the concentrations of the four anions show inconsistent seasonal changes due to the combined effects of river water chemical composition and human *** hydrochemical type of Baiyangdian Lake is primarily HCO,***,Mg*and HCO,originate mainly from silicate and carbonate rock dissolution,while Kt,Nat and CI originate mainly from sewage and salt dissolution in ***42 may mainly stem from industrial wastewater,while NO,primarily originates from animal feces and domestic *** the use of Principal Component Analysis,it is identified that water-rock interaction(silicate and carbonate rocks dissolution,and dissolution of salt in sediments),carbonate sedimentation,sewage,agricultural fertilizer and manure,and nitrification are the main driving factors of the variation of hydrochemical components of Baiyangdian Lake across three hydrological *** findings suggest the need for effective control of substandard domestic sewage discharge,optimization of agricultural fertilization strategies,and proper management of animal manure to comprehensively improve the water environment in Baiyangdian Lake.

关键词： Hydrochemical variation Sources Human activities Water-rock interaction Multivariate statistical techniques

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Predicting the effect of dissolved humic acid on sorption of benzotriazole to biochar

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Biochar 2022年第1期4卷 959-971页

作者： Lin Wu Xiaoli Zhao Erping Bi School of Water Resources and Environment Beijing Key Laboratory of Water Resources and Environmental Engineeringand MOE Key Laboratory of Groundwater Circulation and Environmental EvolutionChina University of Geosciences(Beijing)Beijing 100083China China Geological Survey(CGS)&hebei Province key laboratory of groundwater Contamination and remediation Institute of Hydrogeology and Environmental GeologyChinese Academy of Geological SciencesShijiazhuang 050061China

Dissolved organic matter plays a critical role in affecting sorption properties of biochar for organic *** this study,dissolved humic acid(DHA)as a representative of dissolved organic matter and oak sawdust-derived biochar as a sorbent were prepared and *** of DHA in sorption of benzotriazole(BTA),an emerging organic contaminant,to biochar in different electrolyte solutions were *** results revealed the dual roles of DHA in BTA sorption to *** the one hand,DHA can compete for sites and/or block pores available for BTA to inhibit the adsorption of BTA to *** the other hand,the sorbed DHA on biochar can serve as additional partitioning phase to promote the partition of *** finding was in accordance with the site energy distribution analysis of BTA sorption that the site energy of the highest occurring frequency in the DHA-BTA system was lower than that in the DHA-free system(3.41-10.4 versus 13.1-20.1 kJ mol^(−1)).The variation in apparent BTA sorption to biochar affected by DHA was thus a combination of changes in both its partition and adsorption properties.A modified Dual-mode model including the aqueous concentration of DHA was proposed to predict the effect of DHA on BTA sorption to biochar in different electrolyte solutions,which showed good prediction performance with most BTA sorption coefficient(K_(d),L g^(−1))deviations within 0.1 log unit.

关键词： Emerging organic contaminant Black carbon Dissolved organic matter Sorption Site energy distribution

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Activation-induce d bowl-shape d nitrogen and oxygen dual-doped carbon material and its excellent supercapacitance

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Journal of Materials Science & Technology 2023年第29期160卷 1-8页

作者： Junyan Wang Xinta Li Wanchun Guo Kesong Tian Jiamin Zhang Bosen Zhang Xueai Li Haiyan Wang hebei key laboratory of Heavy Metal Deep-remediation in Water and Resource Reuse State Key Laboratory of Metastable Materials Science and TechnologySchool of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China

Porous heteroatom-doped carbon materials exhibit promising electrochemical applications because of tunable porous structure and doping heteroatom-induced charge ***,it is still a great challenge to develop porous heteroatom-doped carbon materials with both high-content active heteroatom species and facilitated diffusion ***,we report a bowl-shaped nitrogen and oxygen dual-doping carbon(N,O-doped carbon)material based on low-temperature defluorination pyrolysis and alkali-etched activation of 3-fluorophenol-3-amino-4-hydroxypyridine-formaldehyde co-condensed resin and its excellent *** low-temperature thermal treatment strategy ensures high-content pyrrolic nitrogen(4.6 at.%)and oxygen species(15.9 at.%)to avoid high-temperature treatment-induced heteroatom loss and undesired configuration *** these processes,the defluorination pyrolysis promotes the transformation from the resin to carbon material to some extent,and KOH activation also promotes the ordered arrangement of 002 planes,which together assure the appropriate conductivity of the final microporous carbon *** importantly,KOH-etched activation partially removes an un-stable nano/microscale domain of the intermediate carbon microspheres to form a unique bowl-shaped structure extremely facilitating the diffusion of the substitutes and/or electrolyte *** expected,N,O-doped carbon material displays a remarkable specific capacitance of 486.4 F g^(−1)at 1 A g^(−1)with nitro-gen/oxygen species-dependant pseudocapacitance and good electrochemical durability.

关键词： N O-doped carbon Bowl-shaped structure Low-temperature pyrolysis Alkali activation Supercapacitance

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The adsorption effect of aquaculture residual feed on heavy metals and its impact on microbial metabolism of feed

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Ecological Processes 2024年第2期13卷 246-259页

作者： Sufeng Wang Zijng Wang Wen Zhang Jingshan Li Mingyang Lin Li Chen State key laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse Yanshan University key laboratory of Pollution Exposure and Health Intervention of Zhejiang Province College of Biology and Environmental EngineeringZhejiang Shuren University hebei Ocean & Fisheries Science Research Institute

Background Intensive and large-scale aquaculture has a high biological density, and a large amount of artificial feed must be provided. As a result, residual feed would be discharged into natural water bodies with water exchange. Due to heavy metal pollution in surface water, residual feed may adsorb heavy metals in the water, affecting the subsequent microbial degradation of feed and the restoration of the water environment. The combined ecological impacts of these two types of pollution urgently need to be *** This study explored the adsorption effect of residual feed on heavy metals and its impact on microbial degradation of residual feed. The results showed that both the insoluble component（mainly fiber, ash, and ether extract, abbreviated as FAE） and soluble component（soluble protein and starch） of the feed had adsorption effects on heavy metals. As the salinity increased, the adsorption capacity of Cu2+and Cd2+decreased, while the adsorption effect on Pb2+was not changed significantly. The adsorption of heavy metals by residual feed could affect the biological degradation of residual feed. The residual feed could adsorb heavy metals and bacterial cells simultaneously, forming FAE-B（bacteria）-S（starch）-Pr（protein）-metal adsorption complex. This adsorption effect could reduce the negative impact of heavy metals on microbial degradation of residual feed. The simulated degradation experiments in actual water bodies also confirmed this. However, the accumulation of heavy metals in residual feed may bring negative effects, such as being consumed by aquatic organisms and entering the food *** The results of this study provide a basis for the collection and centralized treatment of residual feed in aquaculture, as well as the control and remediation of residual feed pollution in natural water bodies.

关键词： Residual feed Adsorption complex Feed pollution Heavy metal

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Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes

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Chinese Chemical Letters 2024年第6期35卷 146-154页

作者： Shili Wang Mamitiana Roger Razanajatovo Xuedong Du Shunli Wan Xin He Qiuming Peng Qingrui Zhang State key laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseYanshan UniversityQinhuangdao 066004China hebei key laboratory of Agroecological Safetye key laboratory Hebei University of Environmental EngineeringQinhuangdao 066102China College of Life&Environment Sciences Huangshan UniversityHuangshan 245041China

In some industrial wastewater,heavy metals combine with organic complexing agents to form heavy metal complexes(HMCs).These HMCs can be difficult to decompose and remove through conventional techniques due to their higher stability than free heavy metal *** recent years,persulfate based advanced oxidation processes(PS-based AOPs)have been recognized as a viable technique for HMCs ***,a comprehensive and in-depth understanding of the relevant HMCs decomplexation mechanisms in PS-based AOPs is still *** review delineates the current progress of HMCs decomplexation in PS-based *** discuss the distinctions between the two widely used oxidant types in PS-based AOPs ***,we summarize and highlight the decomplexation mechanisms based on electron and energy transfer,and degradation pathways of *** also emphasize the effects of environmental water constituents,namely p H,inorganic ions,and natural organic matter(NOM),on HMCs ***,we identify the existing challenges and perspectives that will steer the direction of advancing PS-based AOPs to remove HMCs.

关键词： Heavy metal complexes Persulfate Advanced oxidation processes Decomplexation mechanisms Electron and energy transfer

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Ferric ion-ascorbic acid complex catalyzed calcium peroxide for organic wastewater treatment:Optimized by response surface method

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Chinese Chemical Letters 2021年第11期32卷 3387-3392页

作者： Deling Yuan Chen Zhang Shoufeng Tang Zetao Wang Qina Sun Xiaoyu Zhang Tifeng Jiao Qingrui Zhang hebei key laboratory of Heavy Metal Deep-remediation in Water and Resource Reuse Hebei Key Laboratory of Applied ChemistrySchool of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China State key laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China

Hydrogen peroxide(H_(2)O_(2))disproportionation,iron precipitation,and narrow pH range are the drawbacks of traditional Fenton *** surmount these barriers,we proposed a ferric ion(Fe^(3+))-ascorbic acid(AA)complex catalyzed calcium peroxide(CaO_(2))Fenton-like system to remove organic dyes in *** collaborative Fe^(3+)/AA/CaO_(2)system presented an obvious improvement in the methyl orange(MO)decolorization,and also effectively eliminated other *** surface method was employed to optimize the running parameters for this coupling *** the optimized arguments(2.76 mmol/L Fe^(3+),0.68 mmol/L AA,and 4 mmol/L CaO_(2)),the MO removal achieved 98.90%after 15 min at pH 6.50,which was close to the computed outcome of 99.30%.Furthermore,this Fenton-like system could perform well in a wide range of pH(3-11),and enhance the H_(2)O_(2)decomposition and Fe ions *** scavenger experiment result indicated that hydroxyl radical,superoxide anion free radical,and singlet oxygen were acted on the dye ***,electron spin resonance analysis corroborated that the existences of these active species in the Fe^(3+)/AA/CaO_(2)*** study could advance the development of Fenton-like technique in organic effluent disposal.

关键词： Ferric ion Ascorbic acid Calcium peroxide Response surface method Dye removal

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