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Bi_(2)O_(3)/g-C_(3)N_(4)hollow core–shell Z-scheme heterojunction for photocatalytic uranium extraction

Nano Research 2024年第7期17卷 5845-5855页

作者： Hao Fu Yuehua Pan Zhenyu Cai Yuxiang Deng Minchen Hou Yuezhou Wei Toyohisa Fujita Shunyan Ning Youbin Wang Shaolong Zhang Xinpeng Wang School of Chemistry&Chemical engineering Guangxi UniversityNanning 530004China School of Resources Environment and MaterialsGuangxi UniversityState Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite StructuresNanning 530004China College of Chemistry and Environmental engineering Shenzhen UniversityShenzhen 518060China School of materials Sun Yat-sen UniversityShenzhen 518107China School of Nuclear Science and Technology University of South ChinaHengyang 421001China

Photocatalytic uranium extraction from radioactive nuclear wastewater and seawater is critical for promoting the sustainable advancement of nuclear industry,but the complexity of real-world environments,particularly the occurrence of anoxic and oxygen-enriched states,presents significant challenges to effective uranium ***,a layered hollow core–shell structure of Bi_(2)O_(3)/g-C_(3)N_(4)Z-scheme heterojunction photocatalyst has been designed and successfully applied for photocatalytic uranium extraction in both aerobic and oxygen-free conditions,and the extraction efficiency of uranium can reach 98.4%and 99.0%,***,the photocatalyst still has ultra-high extraction efficiency under the influence of pH,inorganic ions,and other *** exceptional capability for uranium extraction is on the one hand due to the distinctive hollow core–shell architecture,which furnishes an abundant quantity of active *** the other hand,benefiting from the suitable band gap structure brought by the construction of Z-scheme heterojunction,Bi_(2)O_(3)/g-C_(3)N_(4)exhibits current densities(1.00μA/cm^(2))that are 5.26 and 3.85 times greater than Bi_(2)O_(3)and g-C_(3)N_(4),respectively,and the directional migration mode of Z-scheme carriers significantly prolongs the lifetime of photogenerated charges(1.53 ns),which separately surpass the pure samples by factors of 5.10 and ***,the reaction mechanism and reaction process of photocatalytic uranium extraction are investigated in the presence and absence of oxygen,respectively.

关键词： Bi_(2)O_(3)/g-C_(3)N_(4) Z-scheme photocatalytic uranium extraction

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Inclusion of CoTiO_(3) to ameliorate the re/dehydrogenation properties of the Mg–Na–Al system

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Journal of Magnesium and Alloys 2024年第3期12卷 1215-1226页

作者： N.A.Ali N.Y.Yusnizam N.A.Sazelee Sami-ullah Rather Haizhen Liu M.Ismail Energy Storage Research Group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Department of Chemical and materials engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia guangxi Novel Battery materials Research Center of engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State key laboratory of Featured Metal materials and Life-Cycle Safety for Composite structures Nanning 530004China

For the first time,the MgH_(2)–NaAlH_(4)(ratio 4:1)destabilized system with CoTiO_(3) addition has been *** CoTiO_(3)-doped MgH_(2)–NaAlH_(4) sample begins to dehydrogenate at 130℃,which is declined by 40℃ compared to the undoped MgH_(2)–NaAlH_(4).Moreover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped MgH_(2)–NaAlH_(4) were greatly *** the inclusion of CoTiO_(3),the MgH_(2)–NaAlH_(4) composite absorbed 5.2 wt.%H_(2),higher than undoped MgH_(2)–NaAlH_(4).In the context of dehydrogenation,the CoTiO_(3)-doped MgH_(2)–NaAlH_(4) sample desorbed 2.6 wt.%H_(2),almost doubled compared to the amount of hydrogen desorbed from the undoped MgH_(2)–NaAlH_(4) *** activation energy obtained by the Kissinger analysis for MgH_(2) decomposition was significantly lower by 35.9 kJ/mol than the undoped MgH_(2)–NaAlH_(4) *** reaction mechanism demonstrated that new phases of MgCo and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized MgH_(2)–NaAlH_(4) system with the inclusion of CoTiO_(3).

关键词： Destabilize system Magnesium hydride Sodium alanate Hydrogen storage Additive.

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3D-printed self-healing,biodegradable materials and their applications

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Frontiers of Mechanical engineering 2024年第3期19卷 1-22页

作者： Yu LI Guangmeng MA Fawei GUO Chunyi LUO Han WU Xin LUO MingtaoZHANG Chenyun WANG Qingxin JIN Yu LONG School of Mechanical engineering Guangxi UniversityNanning 530004China State key laboratory of Featured Metal materials and Life-cycle Safety for Composite structures Guangxi UniversityNanning 530004China Institute of Laser Intelligent Manufacturing and Precision Processing School of Mechanical EngineeringGuangxi UniversityNanning 530004China College of Mechanical and Electrical engineering Central South UniversityChangsha 410083China State key laboratory of Precision Manufacturing for Extreme Service Performance Central South UniversityChangsha 410083China

3D printing is a versatile technology capable of rapidly fabricating intricate geometric structures and enhancing the performance of flexible devices in comparison to conventional fabrication ***,3D-printed devices are susceptible to failure as a result of minuscule structural impairments,thereby impacting their overall *** utilization of self-healing,biodegradable materials in 3D printing holds immense potential for increasing the longevity and safety of devices,thereby expanding the application prospects for such ***,enhancing the self-repairing capability of devices and refining the 3D printing performance of self-healing materials are still considerable challenges that need to be addressed to achieve optimal *** paper reviews recent developments in the field of advancements in 3D printing using self-healing and biodegradable ***,it investigates self-healing and biodegradable materials that are compatible with 3D printing techniques,discussing their printability,material properties,and factors that influence print ***,it explores practical applications of selfhealing and biodegradable 3D printing technology in ***,it critically offers practical perspectives on this topic.

关键词： 3D printing self-healing biodegradable soft materials covalent bonds non-covalent bonds

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Self-Powered Piezo-Supercapacitors Based on ZnO@Mo-Fe-MnO2 Nanoarrays

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Energy & Environmental materials 2024年第4期7卷 304-314页

作者： Luo Sun Zhiguo Ye Xinyuan Peng Shaojie Zhuang Duosheng Li Zhong Jin School of materials Science and engineering Nanchang Hangkong University State key laboratory of Coordination Chemistry MOE Key Laboratory of Mesoscopic Chemistry MOE Key Laboratory of High Performance Polymer Materials and Technology Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing University

The development of self-charging supercapacitor power cells （SCSPCs） has profound implications for smart electronic devices used in different ***,we epitaxially electrodeposited Mo-and Fe-codoped MnO2films on piezoe... 详细信息

关键词： MnO2 piezoelectric self-charging supercapacitors ZnO nanoarray

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An aptamer-driven DNA nanodevice for improved delivery of synthetic immunostimulants

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Nano Research 2024年第10期17卷 9078-9083页

作者： Dejie Lu Zhenghan Di Lele Li Jian Zhao Li Zheng guangxi engineering Center in Biomedical materials for Tissue and Organ Regeneration Collaborative Innovation Centre of Regenerative Medicine and Medical BioResource Development and ApplicationGuangxi Key Laboratory of Regenerative MedicineThe First Affiliated Hospital of Guangxi Medical UniversityGuangxi Medical UniversityNanning 530021China CAS key laboratory for Biomedical Effects of Nanomaterials and Nanosafety National Center for Nanoscience and TechnologyBeijing 100190China

Efficient delivery of therapeutics to immune cells remains a formidable challenge for cancer *** this work,we demonstrate that an aptamer-driven DNA nanodevice,constructed through linkage of a synthetic immunostimulant(Toll-like receptor 9 agonist:CpG motif)to an aptamer,could significantly enhance the immunostimulatory activity by facilitating the uptake and retention of therapeutics in *** administration of the DNA nanodevice results in efficient tumor growth inhibition in both breast cancer and melanoma mouse *** studies suggest that the DNA nanodevice leads to reeducation of tumor-associated macrophages and ultimately to reversing the tumor immune *** strategy for aptamer-mediated and vehicle-free delivery of immunostimulatory oligonucleotides provides a potential platform for cancer immunotherapy.

关键词： aptamer immunostimulatory oligonucleotides DNA nanodevice tumor-associated macrophages cancer therapy

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High energy storage density in NaNbO_(3) antiferroelectrics with double hysteresis loop

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Journal of Materiomics 2024年第5期10卷 1026-1035页

作者： Li Ma Zhenpei Chen Gengguang Luo Zhiyi Che Chao Xu Dongliang Shan Zhenyong Cen Qin Feng Xiyong Chen Toyohisa Fujita Ye Zhu Yunya Liu Jing-Feng Li Shujun Zhang Nengneng Luo State key laboratory of Featured Metal materials and Life-cycle Safety for Composite structures School of ResourcesEnvironment and MaterialsGuangxi UniversityNanning530004China School of Chemistry and Chemical engineering Guangxi UniversityNanning530004China Department of Applied Physics Research Institute for Smart EnergyThe Hong Kong Polytechnic UniversityHung HomKowloonHong KongChina key laboratory of Low Dimensional materials and Application Technology of Ministry of Education School of Materials Science and EngineeringXiangtan UniversityXiangtan411105HunanChina State key laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China Institute for Superconducting and Electronic materials Australian Institute of Innovative MaterialsUniversity of WollongongWollongongNSW2500Australia

Antiferroelectrics(AFEs)possess great potential for high performance dielectric capacitors,due to their distinct double hysteresis loop with high maximum polarization and low remnant ***,the well-known NaNbO3 lead-free antiferroelectric(AFE)ceramic usually exhibits square-like P–E loop related to the irreversible AFE P phase to ferroelectric(FE)Q phase transition,yielding low recoverable energy storage density(Wrec).Herein,significantly improved Wrec up to 3.3 J/cm^(3) with good energy storage efficiency(η)of 42.4% was achieved in Na_(0.7)Ag_(0.3)Nb_(0.7)Ta_(0.3)O_(3)(30Agsingle bond30Ta)ceramic with well-defined double P–E loop,by tailoring the A-site electronegativity with Ag+and B-site polarizability with Ta^(5+).The Transmission Electron Microscope,Piezoresponse Force Microscope and in-situ Raman spectra results verified a good reversibility between AFE P phase and high-field-induced FE Q *** improved stability of AFE P phase,being responsible for the double P–E loop and improved Wrec,was attributed to the decreased octahedral tilting angles and cation *** mechanism was revealed by synchrotron X-ray diffraction and Scanning Transmission Electron *** work provides a good paradigm for achieving double P–E loop and high energy storage density in NaNbO_(3)-based ceramics.

关键词： Sodium niobate Antiferroelectrics Double hysteresis loop Energy storage performance Reversibility

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Indentation behavior of a semi-infinite piezoelectric semiconductor under a rigid flat-ended cylindrical indenter

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Applied Mathematics and Mechanics(English Edition) 2024年第4期45卷 649-662页

作者： Shijing GAO Lele ZHANG Jinxi LIU Guoquan NIE Weiqiu CHEN State key laboratory of Mechanical Behavior and System Safety of Traffic engineering structures Shijiazhuang Tiedao UniversityShijiazhuang 050043China School of Mechanical engineering Shijiazhuang Tiedao UniversityShijiazhuang 050043China Hebei key laboratory for Mechanics of Intelligent materials and structures Department of Engineering MechanicsShijiazhuang Tiedao UniversityShijiazhuang 050043China State key laboratory of Computer Aided Design and Computer Graphics Key Laboratory of Soft Machines and Smart Devices of Zhejiang ProvinceDepartment of Engineering MechanicsZhejiang UniversityHangzhou 310027China

This paper theoretically studies the axisymmetric frictionless indentation of a transversely isotropic piezoelectric semiconductor(PSC)half-space subject to a rigid flatended cylindrical *** contact area and other surface of the PSC half-space are assumed to be electrically *** the Hankel integral transformation,the problem is reduced to the Fredholm integral equation of the second *** equation is solved numerically to obtain the indentation behaviors of the PSC half-space,mainly including the indentation force-depth relation and the electric potential-depth *** results show that the effect of the semiconductor property on the indentation responses is limited within a certain range of variation of the steady carrier *** dependence of indentation behavior on material properties is also analyzed by two different kinds of *** element simulations are conducted to verify the results calculated by the integral equation technique,and good agreement is demonstrated.

关键词： piezoelectric semiconductor(PSC) insulating indenter electromechanical response singular integral equation finite element simulation

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Revealing interfacial charge redistribution of homologous Ru-RuS_(2) heterostructure toward robust hydrogen oxidation reaction

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Journal of Energy Chemistry 2024年第7期94卷 332-339页

作者： Yi Liu Lianrui Cheng Shuqing Zhou Yuting Yang Chenggong Niu Tayirjan Taylor Isimjan Bao Wang Xiulin Yang guangxi key laboratory of Low Carbon Energy materials School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilin 541004GuangxiChina State key laboratory of Biochemical engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Saudi Arabia Basic Industries Corporation(SABIC)at King Abdullah University of Science and Technology(KAUST) Thuwal 23955-6900Saudi Arabia

Precisely tailoring the surface electronic structures of electrocatalysts for optimal hydrogen binding energy and hydroxide binding energy is vital to improve the sluggish kinetics of hydrogen oxidation reac-tion(HOR).Herein,we employ a partial desulfurization strategy to construct a homologous Ru-RuS_(2) heterostructure anchored on hollow mesoporous carbon nanospheres(Ru-RuS_(2)@C).The disparate work functions of the heterostructure contribute to the spontaneous formation of a unique built-in electric field,accelerating charge transfer and boosting conductivity of ***,Ru-RuS_(2)@C exhibits robust HOR electrocatalytic activity,achieving an exchange current density and mass activity as high as 3.56 mA cm^(-2) and 2.13 mAμg_(Ru)^(-1),*** those of state-of-the-art Pt/C and most contemporary Ru-based HOR ***,Ru-RuS_(2)@C can tolerate 1000 ppm of cO that lacks in Pt/*** analysis reveals that the directional electron transfer across Ru-RuS_(2) heterointerface induces local charge redistribution in interfacial region,which optimizes and balances the adsorption energies of H and OH species,as well as lowers the energy barrier for water formation,thereby promoting theHoR performance.

关键词： Heterostructure Hollow spherical structure Hydrogen oxidation reaction Charge redistribution Density functional calculation

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Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density

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结构化学 2024年第3期43卷 25-32页

作者： Huyi Yu Renshu Huang Qian Liu Xingfa Chen Tianqi Yu Haiquan Wang Xincheng Liang Shibin Yin guangxi key laboratory of Electrochemical Energy materials School of Chemistry and Chemical EngineeringGuangxi University100 Daxue RoadNanning530004China

Li-CO2 batteries(LCBs)suffer from high overpotentials caused by sluggish CO2 reaction *** work designs a Te-doped Fe3O4(Te-Fe3O4)flower-like microsphere catalyst to lower the overpotential and improve the reversibility of *** results reveal that Te doping modifies the electronic structure of Fe3O4 and reduces the *** stable Te-O bond between Te and C2O4-could effectively inhibit the dispro-portionation reaction of the latter,enabling the Te-Fe3O4 cathodes to exhibit a remarkable capacity(9485 mAh g-1)and a long cycling life(155 cycles)with an overpotential of 1.21 V and an energy efficiency of about 80％at a high current density(2000 mA g-1).Through the interaction between Te and Li2C2O4 to inhibit the dispro-portionation reaction,this work successfully achieves long-term cycling of LCBs with low overpotential at high current density.

关键词： Li-CO_2 batteries Catalyst Tellurium Li_2C_2O_4 Large current density

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Valence electronic engineering of superhydrophilic Dy-evoked Ni-MOF outperforming RuO_(2) for highly efficient electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2024年第3期90卷 244-252,I0007页

作者： Zhiyang Huang Miao Liao Shifan Zhang Lixia Wang Mingcheng Gao Zuyang Luo Tayirjan Taylor Isimjan Bao Wang Xiulin Yang guangxi key laboratory of Low Carbon Energy materials School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGulin 541004GuangxiChina State key laboratory of Biochemical engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Saudi Arabia Basic Industries Corporation(SABIC)at King Abdullah University of Science and Technology(KAUST) Thuwal 23955-6900Saudi Arabia

Tackling the problem of poor conductivity and catalytic stability of pristine metal-organic frameworks(MOFs) is crucial to improve their oxygen evolution reaction(OER) ***,we introduce a novel strategy of dysprosium(Dy) doping,using the unique 4f orbitals of this rare earth element to enhance electrocatalytic activity of *** method involves constructing Dy-doped Ni-MOF(Dy@Ni-MOF) nanoneedles on carbon cloth via a Dy-induced valence electronic perturbation *** and density functional theory(DFT) calculations reveal that Dy doping can effectively modify the electronic structure of the Ni active centers and foster a strong electronic interaction between Ni and *** resulting benefits include a reduced work function and a closer proximity of the d-band center to the Fermi level,which is conducive to improving electrical conductivity and promoting the adsorption of oxygen-containing ***,the Dy@Ni-MOF achieves superhydrophilicity,ensuring effective electrolyte contact and thus accelerating reaction kinetics,Ex-situ and in-situ analysis results manifest Dy_(2)O_(3)/NiOOH as the actual active ***,Dy@Ni-MOF shows impressive OER performance,significantly surpassing ***,the overall water splitting device with Dy@NiMOF as an anode delivers a low cell voltage of 1.51 V at 10 mA cm^(-2) and demonstrates long-term stability for 100 h,positioning it as a promising substitute for precious metal catalysts.

关键词： Dy@Ni-MOF Dy incorporation Electronic interaction Superhydrophilicity Oxygen evolution reaction

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