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Regulating^(*)COOH intermediate via amino alkylation engineering for exceptionally effective photocatalytic CO_(2) reduction

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Journal of Energy Chemistry 2024年第5期92卷 282-291页

作者： Chengcheng Chen Qiaoyu Zhang Fangting Liu Zhengguo Zhang Qiong Liu Xiaoming Fang Key Laboratory of Enhanced heat Transfer and Energy Conservation The Ministry of EducationSchool of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640GuangdongChina guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test technology(China) Institute of AnalysisGuangdong Academy of Sciences(China National Analytical CenterGuangzhou)Guangzhou 510070GuangdongChina guangdong engineering technology research center of efficient heat storage and application South China University of TechnologyGuangzhou 510640GuangdongChina guangdong Provincial Key Laboratory of Fuel Cell technology South China University of TechnologyGuangzhou 510640GuangdongChina

Photocatalytic reduction of CO_(2) into fuel represents a promising approach for achieving carbon neutrality,while realizing high selectivity in this process is challenging due to uncontrollable reaction intermediate and retarded desorption of target products.engineering the interface microenvironment of catalysts has been proposed as a strategy to exert a significant influence on reaction outcomes,yet it remains a significant challenge.In this study,amino alkylation was successfully integrated into the melem unit of polymeric carbon nitrides(PCN),which could efficiently drive the photocatalytic CO_(2) reduction.Experimental characterization and theoretical calculations revealed that the introduction of amino alkylation lowers the energy barrier for CO_(2) reduction into^(*)COOH intermediate,transforming the adsorption of^(*)COOH intermediate from the endothermic to an exothermic process.Notably,the as-prepared materials demonstrated outstanding performance in photocatalytic CO_(2) reduction,yielding CO_(2)at a rate of 152.8μmol h^(-1) with a high selectivity of 95.4%and a quantum efficiency of 6.6%.

关键词： Polymeric carbonnitride Regulate intermediate Photocatalytic CO_(2)reduction Amino alkylation ^(*)COOH adsorption

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Self‑Assembly of Binderless MXene Aerogel for Multiple‑Scenario and Responsive Phase Change Composites with Ultrahigh Thermal Energy storage Density and Exceptional Electromagnetic Interference Shielding

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Nano-Micro Letters 2024年第3期16卷 367-382页

作者： Chuanbiao Zhu Yurong Hao Hao Wu Mengni Chen Bingqing Quan Shuang Liu Xinpeng Hu Shilong Liu Qinghong Ji Xiang Lu Jinping Qu Key Laboratory of Material Chemistry for Energy Conversion and storage of Ministry of Education School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China Qingdao Mental Health center Qingdao 266034People’s Republic of China Hubei engineering research center for Biomaterials and Medical Protective Materials Huazhong University of Science and TechnologyWuhan 430074People’s Republic of China Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China National engineering research center of Novel Equipment for Polymer Processing Key Laboratory of Polymer Processing Engineering(South China University of Technology)Ministry of EducationGuangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced ManufacturingSchool of Mechanical and Automotive EngineeringSouth China University of TechnologyGuangzhou 510641People’s Republic of China

The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs.

关键词： Self-assembly Multiple-scenario Phase change composites Thermal energy storage Electromagnetic interference shielding

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N-doped hollow carbon nanospheres embedded in N-doped graphene forming a three-dimensional interconnected layered porous support loaded with palladium nanoparticles as an efficient electrocatalyst for formic acid oxidation

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新型炭材料(中英文) 2024年

作者： FANG Yue YANG Fu-kai QU Wei-li DENG Chao WANG Zhen-bo Key Laboratory of Photochemical Biomaterials and Energy storage Materials Shenzhen Key Laboratory of Special Functional Materials Shenzhen Engineering Laboratory for Advance Technology of Ceramics Guangdong Research Center for Interfacial Engineering of Functional Materials College of Materials Science and Engineering Shenzhen University MIIT Key Laboratory of Critical Materials technology for New Energy Conversion and storage School of Chemistry and Chemical Engineering State Key Lab of Urban Water Resource and Environment Harbin Institute of Technology College of Chemistry and Chemical engineering Harbin Normal University No.1 Normal University South Road

The efficient electrocatalysts with low cost, high activity and good durability plays a crucial role in the application of direct formic acid fuel cells. Herein, Pd nanoparticles supported on N-doped hollow carbon nanospheres (NHCN) embedded in Ndoped graphene (NG) with three-dimensional (3D) layered porous configuration by a simple and economical method were investigated as direct formic acid fuel cell catalysts. Owing to the unique 3D interconnected layered porous configuration doped with nitrogen atoms, Pd/NHCN@NG catalyst with smaller Pd nanoparticle size shows large catalytic active surface area, superior electrocatalyticactivity,highsteady-statecurrentdensity,strongabilitytoresistCOpoisoning,farsurpassingthoseofconventionalPd/C,Pd/NG,andPd/***/GOratio,itisfoundthatwhenthe HCN/GO mass ratio is 1∶1, Pd/NHCN@NG catalyst has the most outstanding performance in catalytic oxidation of formic acid,with an activity 4.21 times that of Pd/C. This work has developed a superior carbon-based support material for electrocatalysts, which brings broad application prospects for the development of fuel cells.

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efficient flexible perovskite solar cells and modules using a stable SnO_(2)-nanocrystal isopropanol dispersion

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Nano research 2024年第4期17卷 2704-2711页

作者： Zhiwei Su Jing Li Ruixuan Jiang Shujie Zhang Chengkai Jin Feng Ye Bingcan Ke Mengjun Zhou Jinhui Tong Hyesung Park Fuzhi Huang Yi-Bing Cheng Tongle Bu State Key Laboratory of Advanced technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Material Science and engineering Wuhan University of TechnologyWuhan 430070China Department of Materials Science and engineering Graduate School of Semiconductor Materials and Devices EngineeringGraduate School of Carbon NeutralityLow Dimensional Carbon Materials CenterUlsan National Institute of Science and TechnologyUlsan 44919Republic of Korea Xianhu Laboratory of the Advanced Energy Science and technology guangdong Laboratory Foshan 528200China

The outstanding advantages of lightweight and flexibility enable flexible perovskite solar cells(PSCs)to have great application potential in mobile energy devices.Due to the low cost,low-temperature processibility,and high electron mobility,SnO_(2) nanocrystals have been widely employed as the electron transport layer in flexible PSCs.To prepare high-quality SnO_(2) layers,a monodispersed nanocrystal solution is normally used.However,the SnO_(2) nanocrystals can easily aggregate,especially after long periods of storage.Herein,we develop a green and cost-effective strategy for the synthesis of high-quality SnO_(2) nanocrystals at low temperatures by introducing small molecules of glycerol,obtaining a stable and well-dispersed SnO_(2)-nanocrystal isopropanol dispersion successfully.Due to the enhanced dispersity and super wettability of this alcohol-based SnO_(2)-nanocrystal solution,large-area smooth and dense SnO_(2) films are easily deposited on the plastic conductive substrate.Furthermore,this contributes to effective charge transfer and suppressed non-radiative recombination at the interface between the SnO_(2) and perovskite layers.As a result,a greatly enhanced power conversion efficiency(PCE)of 21.8%from 19.2%is achieved for small-area flexible PSCs.A large-area 5 cm×5 cm flexible perovskite solar mini-module with a champion PCE of 16.5%and good stability is also demonstrated via this glycerol-modified SnO_(2)-nanocrystal isopropanol dispersion approach.

关键词： tin oxide isopropanol dispersion colloid stability flexible perovskite solar cells

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Thermally Conductive,Healable Glass Fiber Cloth Reinforced Polymer Composite based onβ-Hydroxyester Bonds Crosslinked Epoxy with Improved heat Resistance

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Chinese Journal of Polymer Science 2024年第5期42卷 643-654,I0009页

作者： Fang Chen Xiao-Yan Pang Ze-Ping Zhang Min-Zhi Rong Ming-Qiu Zhang Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education GD HPPC LabIGCMESchool of ChemistrySun Yat-sen UniversityGuangzhou510275China guangdong Provincial Laboratory of Chemistry and Fine Chemical engineering Jieyang center Jieyang515200China

To simultaneously endow thermal conductivity,high glass transition temperature(Tg)and healing capability to glass fiber/epoxy(GFREP)composite,dynamic crosslinked epoxy resin bearing reversibleβ-hydroxyl ester bonds was reinforced with boron nitride nanosheets modified glass fiber cloth(GFC@BNNSs).The in-plane heat conduction paths were constructed by electrostatic self-assembly of polyacrylic acid treated GFC and polyethyleneimine decorated BNNSs.Then,the GFC@BNNSs were impregnated with the mixture of lower concentration(3-glycidyloxypropyl)trimethoxysilane grafted BN micron sheets,3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate and hexahydro-4-methylphthalic anhydride,which accounted for establishing the through-plane heat transport pathways and avoiding serious deterioration of mechanical performances.The resultant GFREP composite containing less boron nitride particles(17.6 wt%)exhibited superior in-plane(3.29 W·m^(-1)·K^(-1))and through-plane(1.16 W·m^(-1)·K^(-1))thermal conductivities,as well as high Tg of 204℃(Tg of the unfilled epoxy=177℃).The reversible transesterification reaction enabled closure of interlaminar cracks within the composite,achieving decent healing efficiencies estimated by means of tensile strength(71.2%),electrical breakdown strength(83.6%)and thermal conductivity(69.1%).The present work overcame the disadvantages of conventional thermally conductive composites,and provided an efficient approach to prolong the life span of thermally conductive GFREP laminate for high-temperature resistant integrated circuit application.

关键词： Thermally conductive composites Boron nitride High-temperature resistance β-Hydroxyl ester bond Healing

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Experimental research and numerical simulation of the thermal performance of a tube-fin cold energy storage unit using water/modified expanded graphite as the phase change material

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Energy storage and Saving 2022年第2期1卷 71-79页

作者： Jinxin Feng Ziye Ling Jiangchang Huang Xiaoming Fang Zhengguo Zhang Key Laboratory of Enhanced heat Transfer and Energy Conservation The Ministry of EducationSchool of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou510640China guangdong engineering technology research center of efficient heat storage and application South China University of TechnologyGuangzhou510640China

In this study,experimental and numerical investigations were conducted on a tube-fin heat-exchanger latent-heat cold energy storage unit.The fin side of the heat exchanger was filled with water as the energy storage medium,and modified expanded graphite(MEG)was employed to improve the thermal characteristics of water.The water contact angle of the expanded graphite decreased from 106.31°to 0°,and the hydrophilicity and the absorption rate of water significantly improved after the modification.Moreover,the experimental analyses of the charge/discharge process showed that the cooling capacity of the system filled with 90 wt.%water/MEG was 80.8%of that of pure water,whereas its cooling time was only 69.7%of that of pure water.The average power increased by 15.9%compared with that of water.The system filled with 90 wt.%water/MEG completed two energy charging and discharging cycles,whereas the system filled with water completed only 1.5 cycles within 15000 s.Furthermore,the effects of the flow rate and inlet temperature of the heat transfer fluid on the charging process were explored.Finally,a numerical model was built and validated to investigate the phase change behavior and the effect of the structure size on the performance of the system.The heat-exchanger fin spacing had no significant effect on the cold energy storage unit,whereas the vertical spacing of the tube pass had the highest effect.It can be concluded that the heat exchanger combined with high-thermal-conductivity water/MEG exhibits better energy storage capacity and working power,showing a wide application prospect in the field of cold energy storage.

关键词： Cold energy storage Tube-fin heat exchanger Phase change material Water Modified expanded graphite

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Tetradentate cyclometalated platinum complex enables high-performance near-infrared electroluminescence with excellent device stability

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Chinese Chemical Letters 2023年第2期34卷 511-514页

作者： Chengjun Wu Youming Zhang Jingsheng Miao Kai Li Weiguo Zhu Chuluo Yang Shenzhen Key Laboratory of New Information Display and storage Materials Guangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhen 518055China Jiangsu engineering Laboratory of Light-Electricity-heat Energy-Converting Materials and applications Changzhou UniversityChangzhou 213164China

Due to the high decay rate of the non-radiative transition of long wavelengths, the molecular design of efficient and stable near-infrared(NIR) electroluminescent materials remains a big challenge. Herein,a new tetradentate cyclometalated platinum(II) complex with an N∧C∧C∧N coordinated framework has been developed and used as a dopant for NIR organic light-emitting diodes(OLEDs). The complex exhibited a short-lived(0.5–1.5 μs) metal-to-ligand charge transfer(MLCT) excited state in doped and neat films. The resulting NIR OLEDs(λ_(EL)= 730 nm) achieved maximum external quantum efficiency(EQE_(max))of 5.2% and radiance of 74626 m W sr^(-1)m^(–2). Of note, the device exhibited excellent stability with operational lifetime of 119 h for LT_(90). This work demonstrated the great potential of tetradentate platinum(II)complexes in the field of NIR OLEDs.

关键词： Near-infrared emitter Phosphorescence Platinum complex OLED Operational lifetime

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Enhance hydrates formation with stainless steel fiber for high capacity methane storage

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Chinese Journal of Chemical engineering 2022年第10期50卷 435-443页

作者： Zhixia Deng Shuanshi Fan Yanhong Wang Xuemei Lang Gang Li School of Chemistry and Chemical engineering South China University of TechnologyGuangzhou 510640China guangdong engineering technology research center of Advanced Insulating Coating Zhuhai 519175China Institute of Modern Industrial Innovation South China University of TechnologyZhuhai 519175China Key Laboratory of Fuel Cell technology of guangdong Province Guangzhou 510640China

In order to realize efficient gas storage of hydrate,stainless steel fiber(SSF)was added to 0.03%(mass)sodium dodecyl sulfate(SDS)solution for gas storage experiment.SSF can not only improve the problem that hydration heat cannot be removed effectively in the hydration process,but also improve gas storage speed and gas storage by increasing hydrate nucleation sites.Under the experimental conditions(273.2 K,5-9 MPa),the peaks of temperature rise in SDS+SSF systems were found to become much smaller than those in SDS systems.The maximum gas storage rate and the maximum methane uptake of SSF+SDS system reached 9.89-24.90 cm^(3)·g^(-1)·min^(-1) and 178.65-200.89 cm^(3)·(g H_(2)O)-1,respectively.Compared with the surfactant SDS solution without SSF,they increased by 10.47%-33.22%and 9.16%-25.36%,respectively.The effect of SSF length on gas storage performance was studied.Due to the continuous thermal conduction network,longer SSF showed a higher gas storage capacity and methane uptake rate compared with shorter SSF.At the same time,compared with other metal fillers,SSF+SDS not only had excellent gas storage performance,but also the amount of SSF(0.1 g·ml^(-1))was only 7.6%of foamed aluminum,and the volume gas storage density was increased by 145.4%.The use of stainless steel fiber made the best use of the thermal conductivity of metal,reduced the amount of metal used,and improved the volume density and mass density of gas storage.

关键词： Methane Stainless steelfiber Gas storagecapacity Hydrate Gas storagerate heat transfer

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Responsive hyperbranched poly(formyl-1,2,3-triazole)s toward quadruple-modal information security protection

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Science China Chemistry 2022年第4期65卷 771-777页

作者： Baixue Li Zhen Li Kai You Anjun Qin Ben Zhong Tang State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesCenter for Aggregation Induced EmissionSouth China University of TechnologyGuangzhou 510640China Shenzhen Institute of Molecular Aggregate Science and engineering School of Science and EngineeringThe Chinese University of Hong KongShenzhen 518172China Hong Kong Branch of Chinese National engineering research center for Tissue Restoration and Reconstruction The Hong Kong University of Science and TechnologyClear Water BayKowloonHong KongChina School of Electromechanical engineering Guangdong University of TechnologyGuangzhou 510006China Foshan Nanhai guangdong technology University CNC Equipment Cooperative Innovation Institute Foshan 528225China

Secrecy has received tremendous attention in modern information society. Innovative polymer-based fluorescent materials with multiple mode emission are quite desirable to achieve multistage data security. Herein, a series of soluble and thermally stable hyperbranched poly(formyl-1,2,3-triazole)s(hb-PFTAs) with high molecular weights were facilely prepared by catalyst-free polycycloaddition of aldehyde-activated internal triyne and diazides. Functional moieties of triphenylamine and binaphthyl could be incorporated into the polymers to offer them with unique fluorescence and circular dichroism properties, respectively.By taking advantage of activated ethynyl and aldehyde groups on their peripheries and in the internal branch chains, the hbPFTAs can undergo efficient single-and double-stage post-functionalization. More importantly, based on the remarkable fluorescence responses to hydrazine and hydrochloric acid, the hyperbranched polymers are featured with triple-mode fluorescent patterns and have been applied in quadruple-modal information encryption and storage with enhanced security and density. Collectively, this work not only enriches the structural diversity of the existing triazole-based material library, but also provides new polymeric materials for data and information security application.

关键词： activated internal triyne hyperbranched poly(formyl-1,2,3-triazole)s post-polymerization modification multilevel information security

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Self-enhancing photothermal conversion of 2D Weyl semimetal WTe_(2)with topological surface states for efficient solar vapor generation

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Nano research 2023年第8期16卷 10976-10984页

作者： Chun Du Ziyi Yang Anzhen Mo Xuanming Duan Guowei Yang guangdong Provincial Key Laboratory of Optical Fiber Sensing and Communications Institute of Photonics TechnologyJinan UniversityGuangzhou 511443China State Key Laboratory of Optoelectronic Materials and Technologies Nanotechnology Research CenterSchool of Materials Science&EngineeringSun Yat-sen UniversityGuangzhou 510275China

To improve the performance of solar energy-driven water generation,two-dimensional(2D)photothermal materials requisite to be optimized by some strategies such as alloying,combination of plasmonic and defect modulation.However,the challenges faced in practical utilization are the complex preparation process and insufficient solar spectrum absorption.Herein,we propose a strategy of self-enhancing photothermal performance induced by topological surface states(TSSs).2D WTe_(2)is fabricated on the mixed cellulose ester(MCE)for photothermal device.Compared to the MCE and pure water,WTe_(2)@MCE has an excellent photothermal evaporation rate of 1.09 kg·m^(−2)·h^(−1)upon 1 sun irradiation,promoting 6.1 and 3.1 times,respectively.It can be attributed to the characteristics of 2D Weyl semimetal WTe_(2)with TSSs bringing about high optical absorption capacity,low thermal diffusivity,specific heat capacity,and high carrier density,which are strongly proved by experiments and calculation.More importantly,the contribution of TSSs to the enhancement of optical absorption for efficient solar water generation is revealed by the comparative experiment between 2D WTe_(2)with TSSs and that without TSSs.Furthermore,photothermal conversion mechanism is explored in-depth understanding that the photoexcited electrons recombinate with the holes through nonradiative mode for releasing thermal energy by phonons emission via multiple pathway.This work promotes the application of Weyl semimetal material with TSSs in solar water evaporation.

关键词： two-dimensional(2D)WTe_(2) Weyl semimetals topological surface states(TSSs) photothermal conversion

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